• 한국응용과학기술학회지
• /
• 제33권3호
• /
• pp.483-491
• /
• 2016

나노실리카가 코팅된 유리 표면은 나노실리카 표면에 존재하는 친수성 수산기로 인해 방담성이 매우 증가하나, 실외에 설치된 유리에 코팅된 경우는 비에 의해 씻겨 나가 방담 특성의 내구성이 급격히 감소한다. 또한 나노실리카가 코팅된 유리 표면의 토폴로지는 광투과율 또는 반사방지 특성을 좌우하는 매우 중요한 인자이다. 이러한 나노실리카 코팅의 특성에 관한 내구성을 향상시키기 위하여 가교제로 테트라에틸오르소실리케이트 (TEOS)를 사용하여 나노실리카 (Ludox) 현탁액으로 친수성 나노실리카피막을 제조하였다. 산성 또는 염기성 수용액 중에서의 TEOS의 가수 분해 최적 조건도 물에 대한 접촉각 측정을 통하여 조사하였다. pH=4의 산성 조건에서 1.5 wt% 나노실리카-TEOS 코팅액으로 얻은 최종 투명한 친수성 코팅층은 매우 향상된 친수성에 대한 내구성뿐만 아니라, 코팅하지 않은 유리에 비해 약 2 % 포인트 정도 높은 가시광투과율을 나타내었다.

• Journal of Ginseng Research
• /
• 제43권1호
• /
• pp.27-37
• /
• 2019

Background: The structural conversions in ginsenosides induced by steaming or heating or acidic condition could improve red ginseng bioactivities significantly. In this paper, the chemical transformations of red American ginseng from fresh Panax quinquefolium L. under steaming were investigated, and the possible mechanisms were discussed. Methods: A method with reversed-phase high-performance liquid chromatography coupled with linear ion trap mass spectrometry ($HPLC-MS^n$)-equipped electrospray ionization ion source was developed for structural analysis and quantitation of ginsenosides in dried and red American ginseng. Results: In total, 59 ginsenosides of protopanaxadiol, protopanaxatriol, oleanane, and ocotillol types were identified in American ginseng before and after steaming process by matching the molecular weight and/or comparing $MS^n$ fragmentation with that of standards and/or known published compounds, and some of them were determined to be disappeared or newly generated under different steaming time and temperature. The specific fragments of each aglycone-type ginsenosides were determined as well as aglycone hydrated and dehydrated ones. The mechanisms were deduced as hydrolysis, hydration, dehydration, and isomerization of neutral and acidic ginsenosides. Furthermore, the relative peak areas of detected compounds were calculated based on peak areas ratio. Conclusion: The multicomponent assessment of American ginseng was conducted by $HPLC-MS^n$. The result is expected to provide possibility for holistic evaluation of the processing procedures of red American ginseng and a scientific basis for the usage of American ginseng in prescription.

• 펄프종이기술
• /
• 제48권1호
• /
• pp.119-126
• /
• 2016

In this study, we separated the lignin from the wood by using the high boiling point solvent for developing more environmental friendly pulping method. High boiling point solvents as Ethers, glycols and ketones were used to remove the lignin in the pine wood meals. The Yield and lignin content of residual wood meals was reduced according to the input of the catalyst. Me-C, E-Ca, TEG and MIBK had the best delignification rate of 9 kinds of high-boiling point solvents. At the hydrolysis ratio of the selected solvents, The TEG was highest remain ratio of carbohydrates and the E-Ca was lowest remain ratio of lignin. And the Me-C was most excellent lignin hydrolysis ratio at the low catalyst. The selectivity of delignification of Me-C, E-Ca, TEG and MIBK solvents were 49.6, 49.9, 53.8 and 53.1%, respectively, and its values were similar to those of the commercial Kraft Pulp.

• 한국환경농학회지
• /
• 제24권2호
• /
• pp.123-131
• /
• 2005

살균제 procymidone의 토양 중 행적에 관한 흡 탈착, 용탈실험과 광분해 및 가수분해 실험을 통한 농업환경 중 동태를 구명코자 하였으며, 그 결과는 다음과 같다. 흡착은 직선식과 Freundlich식에 부합하였고, 분배계수는 $2.75{\sim}12.18$, Kf값은 $1.99{\sim}9.98$로 토양유기물 함량에 비례하였다. 토양별 탈착율은 백산>지곡>남계통의 순서로 높게 나타났다. 자연광 하에서의 광분해는 느려 자연광에 의한 직접적인 분해는 적을 것으로 사료되었으며, 용탈 이동성은 낮아 Macall총설 및 SSLRC 이동성 분류에 따라 low class에 속했고 특히 유기물 함량이 높은 남계통은 2주 경과후에도 농약이 용탈되지 않았다. 가수분해 실험결과 procymidone은 산성 및 중성보다 알칼리 조건에서 가수분해가 빨랐으며, 높은 온도에서 분해가 빨랐다. 이상의 결과 procymidone은 토양환경에서 흡착량이 높고 이동성이 낮아 타 환경계로의 전이 정도는 매우 낮다고 평가되었다.

• Bulletin of the Korean Chemical Society
• /
• 제32권8호
• /
• pp.2565-2570
• /
• 2011

The reaction of bromoacetonitrile with 3,14-dimethyl-2,6,13,17-tetraazatetracyclo[$16.4.1^{2.6}.0^{1.18}.0^{7.12}$]tricosane ($L^{10}$) containing a N-$CH_2$-N linkage produces 17-cyanomethyl-3,14-dimethyl-2,6,13,17-tetraazatetracyclo-[$16.4.1^{2.6}.0^{1.18}.0^{7.12}$]tricosane ($L^{11}$). The mono-N-functionalized macrocyclic complexes $[ML^2]^{2+}$ (M = Ni(II) or Cu(II); $L^2$ = 2-cyanomethyl-5,16-dimethyl-2,6,13,17-tetraazatricyclo[$16.4.0.0^{7.12}$]docosane) can be prepared by the reaction of $L^{11}$ with nickel(II) or copper(II) ion in acetonitrile. The N-$CH_2CN$ group attached to $[ML^2]^{2+}$ readily reacts with water or methanol to yield the corresponding complexes of $HL^3$ bearing one N-$CH_2CONH_2$ pendant arm or $L^4$ bearing one $N-CH_2C(=NH)OCH_3$ group. The $N-CH_2CONH_2$ or $N-CH_2C(=NH)OCH_3$ group of each complex is coordinated to the central metal ion. Both $[NiL^4(H_2O)]^{2+}$ and $[CuL^4]^{2+}$ are quite stable in acidic aqueous solutions, but undergo hydrolysis to yield $[Ni(HL^3)(H_2O)]^{2+}$ or $[Cu(HL^3)]^{2+}$ in basic aqueous solutions. In contrast to $[Cu(HL^3)]^{2+}$, $[Ni(HL^3) (H_2O)]^{2+}$ is readily deprotonated to form $[NiL^3 (H_2O)]^+$ ($L^3$ = a deprotonated form of $HL^3$) in basic aqueous solutions.

• 한국수소및신에너지학회논문집
• /
• 제20권4호
• /
• pp.300-308
• /
• 2009

In a pursuit of the development of alternative mobile power sources with a high energy density, a planar and air-breathing PEMFCs with a new type of hydrogen cartridge which uses onsite $H_2$ generated from sodium borohydride ($NaBH_4$) hydrolysis have been investigated for use in advanced power systems. Two types of $H_2$ generation through $NaBH_4$ hydrolysis are available: (1) using organic acids such as sulphuric acid, malic acid, and sodium hydrogen carbonate in aqueous solution with solid $NaBH_4$ and (2) using solid selected catalysts such as Pt, Ru, CoB into the stabilized alkaline $NaBH_4$ solution. It might therefore be relevant at this stage to evaluate the relative competitiveness of the two methods mentioned above. The effects of flow rate of stabilized $NaBH_4$ solution, MEA (Membrane Electrode Assembly) improvement, and type and flow control of the catalytic acidic solution have been studied and the cell performances of the planar, air-breathing PEMFCs using $NaBH_4$ has been measured from aspects of power density, fuel efficiency, energy density, and fast response of cell. In our experiments, planar, air-breathing PEMFCs using $NaBH_4$ achieved to maximum power density of 128mW/$cm^2$ at 0.7V and energy efficiency of 46% and has many advantages such as low operating temperature, sustained operation at a high power density, compactness, the potential for low cost and volume, long stack life, fast star-up and suitability for discontinuous operation.

• 한국잠사곤충학회지
• /
• 제41권2호
• /
• pp.108-115
• /
• 1999

An improvement of methods in fibroin hydrolysates preparat significantly enlarges their applications to practical use. Acidic hydrolysis by hydrohloric acid is one of the methods for silk fibroin depolymeriza6tion. A low yield of final product and long time of the process are the demerits of this method. Possibility of preparation of water-soluble silk hydrolysates with more yield and less expenses is investigated in this study. Such possibility is occurred with the increasing tratment temperature and simultaneously decreasing treatment time, concentration of hydrochoric acid respectively, the concentration of sodium hydroxide used for neutraliza6tion of hydolysates after hydrolysis. Colour is decreased in this case and a small amount of activated, too. Protection of hydrolysates against precipitation after neutraliza6tion, and separation and during concentrating process is the other merit of this method. Creamy-coloured insoluble silk powder is the remainder of hydrolyzed fibroin. This is the only the immobiliza6tion of enzymes and other physiological active substances. Fine particles of this powder can be used as additives for artificial diets and cultural media, as well as raw materials for polymer membranes, etc.

• 한국미생물·생명공학회지
• /
• 제49권1호
• /
• pp.45-56
• /
• 2021

Improved amylases were developed from protoplast fusants of two amylase-producing Aspergillus species. Twenty regenerated fusants were screened for amylase production using Remazol Brilliant Blue agar. Crude enzyme extracts produced by solid state fermentation of rice bran were assayed for activity. Three variable factors (temperature, pH and enzyme type) were optimized to increase the amylase activity of the parents and selected fusants using rice bran medium and solid state fermentation. Analysis of this optimization was completed using the Central Composite Design (CCD) of the Response Surface Methodology (RSM). Amylase activity assays conducted at room temperature and 80℃ demonstrated that Aspergillus designates, T5 (920.21 U/ml, 966.67 U/ml), T13 (430 U/ml, 1011.11 U/ml) and T14 (500.63 U/ml, 1012.00 U/ml) all exhibited improved function making them the preferred fusants. Amylases produced from these fusants were observed to be active over the entire pH range evaluated in this study. Fusants T5 and T14 demonstrated optimal activity under acidic and alkaline conditions, respectively. Fusants T13 and T14 produced the most amylase at 72 h while parents TA, TC and fusant T5 produced the most amylase after 96 h of incubation. Response surface methodology examinations revealed that the enzyme from fusant T5 was the optimal enzyme demonstrating the highest activity (1055.17 U/ml) at pH 4 and a temperature of 40℃. This enzyme lost activity with further increases in temperature. Starch hydrolysis using fusant T5 gave the highest yield of glucose (1.6158 g/100 ml). The significant activities of the selected fusants at 28 ± 2℃ and 80℃ and the higher sugar yields from cassava starch hydrolysis over their parental strains indicate that it is possible to improve amylase activity using the protoplast fusion technique.

• 농약과학회지
• /
• 제2권2호
• /
• pp.39-44
• /
• 1998

국내에서 많이 사용되고 있는 수도용 농약중 iprobenfos, isoprothiolane 및 diazinon의 수중 분해속도를 구명하기 위하여 수중 농약분해의 주요 요인인 가수분해, 미생물분해 및 광분해에 대해서 실험한 결과는 다음과 같다. Iprobenfos는 주로 미생물에 의해서 분해되었는데 반감기는 $4.0{\sim}5.7$일이었고, 고온일수록 가수분해가, pH가 낮을수록 분분해가 촉진되었다. Isoprothiolane은 미생물과 광에 의해서 주로 분해되었는데 광영향이 더 크게 작용한 것으로 나타났으며, 광분해는 pH 9.0에서 반감기가 91일인 반면 pH 4.0, 7.2에서는 각각 13, 16일로 pH가 낮을수록 분해가 신속하였다. Diazinon은 이 세가지 요인에 의해 분해가 일어났으며 pH가 낮을수록 가수분해가 매우 빠르게 일어났다. 농업환경에서 iprobenfos, isoprothiolane 및 diazinon의 수중분해는 각각 미생물분해, 광분해, 가수분해가 주요인으로 판단되었다. 시험농약을 분해하는 미생물을 동정한 결과 iprobenfos, isoprothiolane 및 diazinon은 각각 Pseudomonas putida, Alcaligenes xylosoxydans, Klebsiella planticola/ornithinllytica었고 유사도는 $54.8{\sim}86.2%$였다.

• Korean Chemical Engineering Research
• /
• 제54권4호
• /
• pp.443-447
• /
• 2016

미세조류 세포벽은 셀룰로오스가 주요 구성성분으로 리그닌을 포함하지 않아 낮은 온도의 전처리 조건에서도 효과적으로 셀룰로오스와 헤미셀룰로오스 분해가 가능하다. 차세대 바이오매스로 주목 받는 미세조류(Tetraselmis KCTC 12236BP)로부터 $120^{\circ}C$ 이하의 낮은 온도 조건에서 열수전처리를 이용한 발효당 생산 증대를 위해 공정조건을 최적화하였다. 주요 공정조건인 추출온도, 황산농도와 추출시간에 따른 당화율 변화를 확인하였을 때, 온도와 황산농도가 글루코오스 생산에 큰 영향을 컸으며 당화율이 비례하여 증가하는 경향을 보였다. 경제성을 고려한 열수전처리 최적조건은 $120^{\circ}C$, 2 mol 황산, 40분으로 95.9%의 당화율을 얻을 수 있었다. 탈지미세조류의 황산 열수전처리와 효소당화를 비교했을 때, 황산 열수전처리의 당화율이 2.1배 이상 높고 전처리 시간이 짧아 황산 열수전처리가 효소당화에 비해 효과적인 공정임을 확인하였다.