• Title/Summary/Keyword: Acid deposition

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Numerical Simulation of Tracer Distribution during CAPTEX (CAPTEX 자료에 나타난 추적물 농도 분포의 수치 모사)

  • Kim, Seung-Bum;Lee, Tae-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.E
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    • pp.357-370
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    • 1994
  • This paper introduces an Eulerian long- range transport model coupled with a mesoscale atmospheric model. The model has been applied to the simulation of tracer distribution during two cases of Cross Appalachian Tracer Experiment (CAPIEX). Meteorological fields are Predicted by CSU RAMS with four-dimensional assimilation and tracer transport is computed from an Eulerian dispersion model. The atmospheric model with a four-dimensional assimilation has produced meteorological fields that agree well with observation and has proved its high potential as a generator of meteorological data for a long-range transport model. The Present transport model Produces reasonable simulations of observed tracer transport although it was partially successful in the case with complicated structure in observed concentration. Model with Bott's 2nd-order scheme performs as well as that with Bott's 4th-order scheme and increased explicit horizontal diffusivity. Diagnosis of the model results indicates that the Present long-range transport model has a good potential as a framework for the acid deposition model with detailed cloud and chemical processes.

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Cloning and Expression of Lactate Dehydrogenase H Chain Gene in Adipose Tissues of Korean Cattle

  • Kim, H.H.;Seol, M.B.;Jeon, D.H.;Sun, S.S.;Kim, K.H.;Choi, Y.J.;Baik, M.G.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.12
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    • pp.1670-1674
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    • 2001
  • To understand molecular mechanisms that regulate deposition and release of intramuscular fat, a fasting-induced clone was identified by differential screening from cDNA library of adipose tissues of Korean cattle. The clone had a total length of 1,319 nucleotides coding for 334 amino acids. It was identified as one encoding L-lactate dehydrogenase H chain (LDH-B). Comparison of the deduced amino acid sequences of bovine LDH-B with those of pig, human, rat, and mouse showed 98%, 98%, 97%, and 96% identity, respectively. Food deprivation for 48 h increased mRNA levels of LDH-B gene in adipose tissues of Korean cattle compared to fed- and 6 h refed- tissues. The expression of obese mRNA was examined for individual adipose tissue from several fat depots. Fasting induced expression of LDH-B gene in subcutaneous adipose tissues, but it did not affect expression levels in abdominal, perirenal and intramuscular tissues. Results demonstrate that induction of LDH-B gene during fasting may represent a metabolic shift from anaerobic state to aerobic predominance in fasted adipose tissues and that its responses to fasting are different among several adipose tissues.

Inclusion of Ensiled Cassava KM94 Leaves in Diets for Growing Pigs in Vietnam Reduces Growth Rate but Increases Profitability

  • Ly, Nguyen T.H.;Ngoan, Le D.;Verstegen, Martin W.A.;Hendriks, Wouter H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.8
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    • pp.1157-1163
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    • 2011
  • This study was conducted to determine the effect of the inclusion of different levels of ensiled cassava leaves (variety KM94) in the diets on performance and carcass characteristics of growing pigs in Vietnam. A total of 40 crossbreds pigs (Large White${\times}$Mong Cai, 20 males and 20 females) with an initial live weight of 23.5 kg (SD = 0.86) were randomly allocated to one of the four pens across 5 units. Four experimental diets were formulated for two growth periods, period 1 (60 days) for 20 to 50 kg and period 2 lasted 30 days, from 50 kg until slaughter. Four diets were formulated containing inclusion levels of ensiled cassava KM94 leaves diet of 0, 10, 15 and 20% in the DM. Diets were formulated based on previously determined ileal amino acid digestibility values of the KM94 products and were isonitrogenous and isocaloric on a metabolizable energy basis. Each pen of pigs was randomly assigned to one of the four dietary treatments. Dry matter intake and final weight tended to decreased with increasing levels of ensiled cassava KM94 leaves in the diet while there was a significant (p = 0.022) decrease in average daily gain. Protein depositions of the F1 pigs tended (p = 0.093) to decrease with increasing inclusion levels of ensiled cassava KM94 leaves. There was no significant difference in feed conversion ratio, carcass quality and fat gain between the groups of pigs. There were clear differences in feed costs among the experimental diets (p = 0.001) with increasing levels of ensiled cassava KM 94 leaves in the diet reducing feed costs. It was concluded that, in diets for growing pig, inclusion of ensiled cassava leaves reduces growth rate of pigs in Vietnam but increases profitability as measured by feed costs.

Effect of Excess Calcium and Iron Supplement on Bone Loss, Nephrocalcinosis and Renal Function in Osteoporotic Model Rats (골다공증 모델 흰쥐에서 칼슘과 철 보충제의 과다섭취가 골격손실과 신석회침착 및 신장기능에 미치는 영향)

  • 이종현
    • Journal of Nutrition and Health
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    • v.33 no.2
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    • pp.147-157
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    • 2000
  • This study examined the effects of excess intake of calcium (Ca) and iron (Fe) supplement on bone loss, nephrocalcinosis and renal function in osteoporotic model rats. Seven-week-old female rats were first fed a Ca-deficient diet for four weeks after ovariectomy operation, and then one of nine experimental diets for additional eight weeks, containing three levels of Ca, normal (0.5%) or high (1.5%) or excess (2.5%) and three levels of Fe, normal (35ppm) or high (210ppm) or excess (350ppm). The osteoporotic model rats showed a remarkable increase in body weight, serum alkaline phosphatase (ALP) and decrease in breaking force, Ca, P, Mg contents of femur. Serum Ca concentration was not significantly affected by dietary Ca and Fe levles. Liver Ca content increased in rats fed a high-and excess-Ca diet. Kidney Ca content and microscopic Ca deposition remarkably increased in osteoporotic model rats compared to control group, and showed a tendency to decrease in rats fed a excess-Ca diet. Breaking force of femur increased with increasing dietary Ca levels, but Ca, P contents of femur and serum ALP were not significantly affected by dietary Ca and Fe levels. Serum total protein decreased in rats fed a excess-Ca diet, BUN increased in rats fed a excess-Ca diet, while serum uric acid and creatinine were not significantly affected by dietary Ca levels. Urinary creatinine, GFR increased in rats fed a high-and excess-Ca, diet, and GFR was highest in rats fed a excess-Ca/excess-Fe diet. These results suggest that excess intake of Ca may increase breaking force of femur, but not increase mineral contents of femur, and decrease kidney function. Furthermore, excess intake of Fe and Ca concurrently may aggravate kidney function leading to potential health problems in ovariectomized osteoporotic model rats.

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Formation of Optical Fiber Preform Using Octamethylcyclotetrasiloxane (Octamethylcyclotetrasiloxane를 이용한 광섬유 클래드 프리폼 형성)

  • Choi, Jinseok;Lee, Tae Kyun;Park, Seong Gyu;Lee, Ga Hyoung;Jun, Gu Sik;An, Sung Jin
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.6-11
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    • 2018
  • There are various manufacturing processes for pure $SiO_2$ that is used as abrasives, chemicals, filters, and glasses, and in metallurgy and optical industries. In the optical fiber industry, to produce $SiO_2$ preform, $SiCl_4$ is utilized as a raw material. However, the combustion reaction of $SiCl_4$ has caused critical environmental issues, such as ozone deficiency by chlorine compounds, the greenhouse effect by carbon dioxide and corrosive gas such as hydrochloric acid. Thus, finding an alternative source that does not have those environmental issues is important for the future. Octamethylcyclotetrasiloxane (OMCTS or D4) as a chlorine free source is recently promising candidate for the $SiO_2$ preform formation. In this study, we first conducted a vaporizer design to vaporize the OMCTS. The vaporizer for the OMCTS vaporization was produced on the basis of the results of the vaporizer design. The size of the primary particle of the $SiO_2$ formed by OMCTS was less than 100 nm. X-ray diffraction patterns of the $SiO_2$ indicated an amorphous phase. Fourier-transform infrared spectroscopy analysis revealed the Si-O-Si bond without the -OH group.

Corrosion Behavior of Si,Zn and Mn-doped Hydroxyapatite on the PEO-treated Surface

  • Park, Min-Gyu;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.78-78
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    • 2017
  • Pure Titanium and alloy have been widely used in dental implants and orthopedics due to their excellent mechanical properties, biocompatibility and corrosion resistance. However, due to the biologically inactive nature of Ti metal implants, it cannot bind to the living bone immediately after transplantation into the body. In order to improve the bone bonding ability of titanium implants, many attempts have been made to alter the structure, composition and chemical properties of titanium surfaces, including the deposition of bioactive coatings. The PEO method has the advantages of short experiment time and low cost. These advantages have attracted attention recently. Recently, many metal ions such as silicon, magnesium, zinc, strontium, and manganese have received attention in this field due to their impact on bone regeneration. Silicon (Si) in particular has been found to be essential for normal bone and cartilage growth and development. Zinc (Zn) plays very important roles in bone formation and immune system regulation and promotes bone metabolism and growth. Manganese (Mn) is an essential trace metal found in all tissues and is required for normal amino acid, lipid, protein and carbohydrate metabolism. The objective of this work was research on the corrosion behavior of Si, Zn and Mn-doped hydroxyapatite on the PEO-treated surface. Anodized alloys was prepared at 270V~300V voltage in the solution containig Zn, Si, and Mn ions. Ion release test was carried out using potentidynamic and AC impedance method in 0.9% NaCl solution. The surface characteristics of PEO treated Ti-6Al-4V alloy were investigated using XRD, FE-SEM, AFM and EDS.

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Failure Analysis on Scale Formation of Thermostat Housing and Development of Accelerated Test Methodology (써모스타트 하우징의 침전물 생성에 관한 고장분석 및 가속시험법 개발)

  • Cho, In-Hee;Hyung, Sin-Jong;Choi, Kil-Yeong;Weon, Jong-Il
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.177-185
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    • 2009
  • The failure analysis of scales deposited on automotive thermostat housing has been carried out. Observations using energy dispersive spectroscopy and electron probe micro analyzer indicate that the main components of scales are some of additives of coolant used. For a detailed investigation of organic matters pyrolysis-GC/MS is employed. The result shows that the main organic component is benzoic acid and furthermore, a small amount of acetophenone, benzene and phenyl group is detected. Based on the results of failure analysis performed, the scales on automotive thermostat housing appear due to the deposition of coolant components, followed by crevice corrosion, into gap between housing and rubber horse. New accelerated test methodology, which could mimic the scale formation and the crevice corrosion on thermostat housing, is developed considering the above results. In order to reproduce the real operating conditions, the accelerating factors, i.e. temperature and humidity, are changed and programmed. The reproducibility of the accelerated test proposed is confirmed after analyzing the scales obtained from the accelerated test.

The Acidity and Chemical Compositions of the Snowfall at Pinus koraiensis Stand in Pyungchang Region - A centering around the Daegwalyung and Woongyori - (강원도 평창지역의 산림내 강설 산성도와 화학적 조성 -대관령과 운교리를 중심으로 -)

  • 김영채;정동준;김홍률
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.3 no.3
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    • pp.143-149
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    • 2001
  • This study was conducted to analyze the propertis, acidity and chemical compositions of the snowfall in the bare land and Idlest stand. The research sites of this study are the Daegwalyung (a high hill) and Woongyori in Pyungchang-gun, Kangwon province. The results of this study are as follows: The snowfall pH showed large changes when the snowfall was small. The more snow falls, the smaller changes of the pH are narrow. According to the local conditions, it means that the acid deposition changed over adsorption ratio in suspended matters of the atmosphere. Changes of the ion concentrations for the snowfall in the forest stand showed a thendency to increase. Chemical composition of the snowfall for each sampling site showed that the ion concentrations of $Ca^{2+}$and anions had higher value than other ions.s.

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Comparative Study on the Structural and Thermodynamic Features of Amyloid-Beta Protein 40 and 42

  • Lim, Sulgi;Ham, Sihyun
    • Proceeding of EDISON Challenge
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    • 2014.03a
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    • pp.237-249
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    • 2014
  • Deposition of amyloid-${\beta}$ ($A{\beta}$) proteins is the conventional pathological hallmark of Alzheimer's disease (AD). The $A{\beta}$ protein formed from the amyloid precursor protein is predominated by the 40 residue protein ($A{\beta}40$) and by the 42 residue protein ($A{\beta}42$). While $A{\beta}40$ and $A{\beta}42$ differ in only two amino acid residues at the C-terminal end, $A{\beta}42$ is much more prone to aggregate and exhibits more neurotoxicity than $A{\beta}40$. Here, we investigate the molecular origin of the difference in the aggregation propensity of these two proteins by performing fully atomistic, explicit-water molecular dynamics simulations. Then, it is followed by the solvation thermodynamic analysis based on the integral-equation theory of liquids. We find that $A{\beta}42$ displays higher tendency to adopt ${\beta}$-sheet conformations than $A{\beta}40$, which would consequently facilitate the conversion to the ${\beta}$-sheet rich fibril structure. Furthermore, the solvation thermodynamic analysis on the simulated protein conformations indicates that $A{\beta}42$ is more hydrophobic than $A{\beta}40$, implying that the surrounding water imparts a larger thermodynamic driving force for the self-assembly of $A{\beta}42$. Taken together, our results provide structural and thermodynamic grounds on why $A{\beta}42$ is more aggregation-prone than $A{\beta}40$ in aqueous environments.

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Synthesis of Co Diffused Cu Matrix by Electroplating and Annealing for Application of Mössbauer Source (뫼스바우어선원적용을 위한 전기도금과 열처리기법을 이용한 Co가 확산된 Cu기지체 제조)

  • Choi, Sang Moo;Uhm, Young Rang
    • Journal of the Korean Magnetics Society
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    • v.24 no.6
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    • pp.186-190
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    • 2014
  • To establish the coating conditions for $^{57}Co$, non-radioactive Co ions are dissolved in an acid solution and electroplated on to a copper plate. Then, the thermal diffusion of electroplated Co into a copper matrix was studied to apply a $^{57}Co$ $M{\ddot{o}}ssbauer$ source. Nanocrystalline Co particles were coated on a Cu substrate using DC electro-deposition at a pH of 1.89 to 5 and $20{\sim}30mA/cm^2$. The average grain size was up to 54 nm as the pH increased to 5. The second phase of Co-oxide was formatted as the pH was increased above 4. The diffusion degree was evaluated by mapping using scanning electron microscopy (SEM). The influence of different annealing conditions was investigated. The diffusion depth of Co depends on the annealing temperature and time. The results obtained confirm that the deposited Co diffused almost completely into a copper matrix without substantial loss at an annealing temperature of $900^{\circ}C$ for 2 hours.