• Title/Summary/Keyword: Absorption wavelength

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Spectrophotometric Determination of Scandium(III) with Eriochrome Cyanine R in the Presence of Cetyltrimethylammonium bromide (Cetyltrimethylammonium bromide에서 Eriochrome Cyanine R에 의한 스칸듐(III)의 분광광도법 정량)

  • Cha, Ki-Won;Park, Chan-Il;Kim, Jong-Whon
    • Analytical Science and Technology
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    • v.9 no.2
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    • pp.139-144
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    • 1996
  • The spectrophotometric determination method of scandium with eriochrome cyanine R(ECR) and the composition ratio of the complex were investigated in the presence of surfactants. The absorbance increase and red shift of maximum adsorption wavelength of Sc(III)-ECR complex were observed in cetyltrimethylammonium bromide (CTMAB), but those changes were not observed in the sodium dodecyl sulfate(SDS) and Triton X-100. A volume of 5ml of $1{\times}10^{-3}M$ ECR and 10ml of $2{\times}10^{-4}M$ CTMAB are necessary for the determination of $1{\times}10^{-7}{\sim}3.0{\times}10^{-6}M$ Sc(III) at pH 6.5. The apparent molar absorption coefficient of the Sc(III)-ECR-CTMAB, temary complex at 610nm is $5.6{\times}10^5mol^{-1}cm^{-1}L$ and its detection limit is $1.0{\times}10^{-7}M$. The binary complex composition of Sc(III)-ECR is 1:2 and the ternary complex composition of Sc(III)-ECR-CTMAB is 1:3:1.

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Fabrication of Transition-metal-incorporated TiO2 Nanopowder by Flame Synthesis (화염법에 의한 천이금속 첨가 이산화티타늄 나노분말의 제조)

  • Park Hoon;Jie Hyunseock;Lee Seung-Yong;Ahn Jae-Pyoung;Lee Dok-Yol;Park Jong-Ku
    • Journal of Powder Materials
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    • v.12 no.6 s.53
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    • pp.399-405
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    • 2005
  • Nanopowders of titanium dioxide $(TiO_2)$ incorporating the transition metal element(s) were synthesized by flame synthesis method. Single element among Fe(III), Cr(III), and Zn(II) was doped into the interior of $TiO_2$ crystal; bimetal doping of Fe and Zn was also made. The characteristics of transition-metal-doped $TiO_2$ nanopowders in the particle feature, crystallography and electronic structures were determined with various analytical tools. The chemical bond of Fe-O-Zn was confirmed to exist in the bimetal-doped $TiO_2$ nanopowders incorporating Fe-Zn. The transition element incorporated in the $TiO_2$ was attributed to affect both Ti 3d orbital and O 2p orbital by NEXAFS measurement. The bimetal-doped $TiO_2$ nanopowder showed light absorption over more wide wavelength range than the single-doped $TiO_2$ nanopowders.

Feasibility Study on Potassium Iodide (KI) Sensor for Measuring Total Resiudual Oxidant in Ballast Water (선박 평형수 내 총 잔류 산화물(Total Residual Oxidant) 분석을 위한 Potassium Iodide (KI) Sensor 적용가능성 평가)

  • Kwon, Jae Hyeong;Lim, Heon Jin;Lee, Gwan Ho;Lee, Hai Don;Kim, Dae Won
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.11
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    • pp.596-602
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    • 2016
  • Potassium iodide (KI) TRO sensor for measuring total residual oxidant which is an index for disinfection and neutralization in ballast water has been constructed. The results of UV absorption wavelength and absorbance test in various TRO concentrations show high linear correlation ($r^2=0.9825$) at 350 nm wavelengths and it can be possible to visualize numerical value of TRO concentration (0.1~7.0 mg/L). The result of comparison test according to TRO concentration between the KI based TRO sensor system and the DPD based TRO sensor system showed identical trend. Overall results indicated that the KI TRO sensing system could be applied for continuous TRO concentration measurement in ballast water treatment system.

STELLAR POPULATION SYNTHESIS OF THE ELLIPTICAL GALAXY NGC 4649 (타원은하 NGC 4649의 종족합성)

  • 천문석;김문환;손영종
    • Journal of Astronomy and Space Sciences
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    • v.18 no.3
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    • pp.175-190
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    • 2001
  • We investigated population of the elliptical galaxy NGC 4649 using the spectral synthesis technique based on the linear program in the spectral regions between $3160\AA$to $10800\AA$. We used the spectral data of stars obtained by Gunn & Striker (1983), and the integrated spectrum of NGC 4649 observed by Bertola et al. (1982). Among four models with different main sequence turn-off points, G8-K0V main sequence turn-off model is best fitted to the integrated spectrum of NGC 4649. We also found that super metal rich K giants are needed to describe the absorption lines in the long wavelength regions of integrated spectrum of NGC 4649. The mass to absolute light ratio obtained from the spectral synthesis is ~ 20 similar to those calculated dynamically.

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Effect of Photoinitiators on Adhesion Properties of 2-EHA/AA PSA (광개시제의 종류에 따른 2-EHA/AA 점착제의 접착특성)

  • Yoon, Hong-Beom;Kim, Ho-Gyum;Min, Kyung-Eun
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.491-495
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    • 2014
  • Pressure sensitive adhesive (PSA) based on 2-ethylhexyl acrylate (2-EHA)/acrylic acid (AA) copolymer was synthesized using different photoinitiators. Results showed that PSA with Irgacure$^{(R)}$651 (benzyldimethylketal) and Irgacure$^{(R)}$184(1-hydroxy-cyclohexylphenyl ketone) proved to be good for adhesion properties. This may be attributed to strong absorption near 350 nm wavelength and also high solubility in monomer mixtures. The addition of Irgacure$^{(R)}$819, bisacylphosphine oxides as a photoinitiator caused cohesive failure with high loading in a peel test owing to the additional radical formation. It is assumed that the insoluble photoinitiator reacts with oxygene, which may act as a hydrogen donor.

Study on the Preferred Orientation Using White Neutron

  • Lee, Yun-Peel
    • Nuclear Engineering and Technology
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    • v.6 no.4
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    • pp.219-230
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    • 1974
  • The previous expression for the diffracted neutron intensity by a highly oriented polycrystalline is modified using the Kunitomi's formula of the crystal reflectivity The method of studying the preferred orientation in metals with white neutron is proposed utilizing the above formula and the fact that the real position of the diffraction of certain grain in the sample can be found by the comparison of the smaller angle part of the maxwellian curve of the calculated intensity of neutrons diffracted and the experimenal curves. The most probable wavelength of thermal neutrons from the reactor is found by the measurement of the neutron spectrum with the correction for the crystal about the multiple reflection and the absorption of neutrons and turned out to be 1.025 $\pm$ 0.001$\AA$. The preferred orientations of some electric steel sheets, mostly with the cube-on-face orientations, are investigated by the present method. The orientations of most grains relative to the rolling directions are found to be within 5 degrees. It is found the most of theories for large crystals may be extended to highly oriented polycrystalline materials without extensive modification.

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Investigation of Stimulated Polariton Scattering from the B1-symmetry Modes of the KNbO3 Crystal

  • Li, Zhongyang;Wang, Mengtao;Wang, Silei;Yuan, Bin;Bing, Pibin;Xu, Degang;Yao, Jianquan
    • Current Optics and Photonics
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    • v.2 no.1
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    • pp.90-95
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    • 2018
  • Stimulated polariton scattering from the $B_1$-symmetry modes of a $KNbO_3$ crystal to generate a terahertz wave (THz-wave) with a noncollinear phase-matching scheme is investigated. The frequency-tuning characteristics of the THz-wave by varying the phase-matching angle and pump wavelength are analyzed. The expression for the effective parametric gain length under the noncollinear phase-matching condition is deduced. Parametric gain and absorption characteristics of the THz-wave in $KNbO_3$ are theoretically simulated. The characteristics of $KNbO_3$ for a terahertz parametric oscillator (TPO) are compared to those of $MgO:LiNbO_3$. The analysis indicates that $KNbO_3$ is an excellent optical crystal for a TPO, to enhance the THz-wave output.

Dye-binding Capacities of Proteins using Coomassie blue G250 in an Acidic Solution (단백질과 색소(色素) Comassie blue G250과의 결합능력)

  • Park, Ro-Dong;Lee, Yeon;Shin, Yong-Kwang
    • Applied Biological Chemistry
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    • v.25 no.4
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    • pp.248-251
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    • 1982
  • Commassie blue G250 produced metachromatic effect with some solvents. The absorptivity and molar absorptivity of the dye in ethanol were 82.4 and $70.4{\times}10^3$ at maximum absorption wavelength 610nm, respectively. The dye had a red from$({\lambda}_m=465nm)$ in ethanol-phosphoric acid-water solution and converted to a blue form$({\lambda}_m=590nm)$ after binding to protein. Absorbance at 590nm gave linear responses with respect to protein contents. The dye-binding capacities of proteins varied considerably with the content and source of proteins. Under the experimental condition the dye-binding capacities of bovine serum albumin, cytochrome C and ${\gamma}-globulin$ were 110, 103, and $88{\mu}g$ commassie blue G250 bound per $100{\mu}g$ protein, respectively.

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A Study on the Development of Pulse Oximeter based on Standard Protocol (표준 프로토콜 기반의 산소포화도 계측기(SPo2) 개발에 관한 연구)

  • Kang, Sung-In;Park, Yoon-A;Oh, Am-Suk;Jean, Je-Hwan
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.05a
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    • pp.751-753
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    • 2011
  • Pulse Oximeter is used two different wavelength light sources. Two signals measured by light transmission in the body parts. SPo2 is calculated from the measured signal. These optical methods is have the light absorption properties of oxygen in the blood. SPo2 is to be called vital signs of $5^{th}$and important in modern medical. But, exist pulse oximeter was used just user for viewing the SPo2. That was a lack of used communication Monitoring function. In this paper using the Bluetooth feature on the exist pulse oximeter to communicate with the outside of the Gateway for design medical devices standards protocol IEEE 11073-10404 built-in pulse oximeter. Also user can be monitoring the U-Health Gateway through the pass SPo2 information.

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Photoluminescence of Multinary-compound Semiconductor $ZnGaInS_4:Er^{3+}$ Single Crystals (다원화합물 반도체 $ZnGaInS_4:Er^{3+}$ 단결정의 광발광 특성)

  • Kim, Nam-Oh;Kim, Hyung-Gon;Bang, Tae-Hwan;Hyun, Seung-Cheol;Kim, Duck-Tae
    • Proceedings of the KIEE Conference
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    • 2000.07e
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    • pp.35-39
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    • 2000
  • $ZnIn_2S_4$ and $ZnGaInS_4:Er^{3+}$ single crystals crystallized in the rhombohedral (hexagonal) space group $C_{3v}^5(R3m)$, with lattice constants $a=3.852{\AA},\;c=37.215{\AA}$ for $ZnIn_2S_4$, and $a=3.823{\AA}$, and $c=35.975{\AA}$ for $ZnIn_2S_4:Er^{3+}$. The optical absorption measured near the fundamental band edge showed that the optical energy band structure of there compounds had a direct and indirect band gap, the direct and indirect energy gaps are found to be 2.778 and 2.682 eV for $ZnIn_2S_4$, and 2.725 and 2.651eV for $ZnIn_2S_4:Er^{3+}$ at 293 K. The photoluminescence spectra of $ZnIn_2S_4:Er^{3+}$ measured in the wavelength ranges of $500nm{\sim}900nm$ at 10 K. Eight sharp emission peaks due to $Er^{3+}$ ion are observed in the regions of $549.5{\sim}550.0nm,\;661.3{\sim}676.5nm$, and $811.1{\sim}834.1nm$, and $1528.2{\sim}1556.0nm$ in $CdGaInS_4:Er^{3+}$ single crystal. These PL peaks were attributed to the radiative transitions between the split electron energy levels of the $Er^{3+}$ ions occupied at $C_{2v}$, symmetry of the $ZnIn_2S_4$ single crystals host lattice.

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