• Title/Summary/Keyword: Absorption wavelength

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Nonlinear optical properties of $TiO_{2}$ single crystal ($TiO_{2}$ 단결정의 비선형광학 특성)

  • 신재혁;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.3
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    • pp.240-249
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    • 1995
  • Rutile type of $TiO_{2}$ single crystal was grown by floating zone method in order to obtain the highly transparent and contamination-free single crystal. The linear refractive index of perpendicular and parallel to c-axis was measured as a function o f wavelength from 500 to 1000nm. The optical energy band gap was estimated as 2.99 eV from the absorption spectrum. The theoretical $\chi^{(3)}$} value of $TiO_{2}$ was discussed in comparison with that of $SiO_{2}$ quartz single crystal on the basis of semiempirical model. On the other hand, the second-hyperpolarizability, ${\gamma}({Ti}^{4+})$ was calculated in order to describe the effect of $Ti_{4}$ ion on the third order nonlinear optical properties.

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A Wireless Optical Identification System Using Solar Cells (솔라 셀을 이용한 무선광 인식 장치)

  • Lee, Seong-Ho
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.5
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    • pp.494-500
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    • 2010
  • In this paper, we newly propose a wireless optical identification system and carried out experiments. A wireless optical identification system consists of a reader and a transponder. The configuration of a reader is the same as that of a transponder, which uses LED light as transmission media and detects the signal light with a solar cell. Optical alignment with a lens is not required because the absorption area of a solar cell is wide and flat, and it is very easy to attach a solar cell on the surface of an object. As the light wavelength does not interfere with radio frequency, a wireless optical identification system shows stable operation. In experiments, we realized a wireless optical identification system that automatically identifies the transponder data at a distance of 1 m using solar cells.

Photodegradation of VOCs by Using TiO$_2$-Coated POF (광촉매가 코팅된 플라스틱 광섬유을 이용한 VOC 광분해반응)

  • Ha, Jin-Wook;Joo, Hyun-Ku
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.3
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    • pp.199-203
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    • 2003
  • In this study plastic optical fibers (POFs) were considered as light-transmitting media and substrates for the potential use in photocatalytic environmental purification system. After the characteristics of POFs in terms of light transmittance and absorption were determined at the beginning, the further investigation was performed through the photocatalytic degradation of trichloroethylene (TCE), iso-propanol and etc. with TiO$_2$-coated optical fiber reactor systems (POFR). It is concluded that the use of POFs is preferred to quartz optical fibers (QOFs) since the advantages such as ease of handling, lower cost, relatively reasonable light attenuation at the wavelength of near 400nm can be obtained. Various geometrical reactor shapes have been constructed and applied for the last one and half years. For the use of POF in water phase treatment, however, more detailed scientific and engineering aspects should be envisaged. This case requires a suitable mixture to obtain more stable and innocuous immobilization of photocatalyst on POF. To overcome this disadvantage, metal-organic chemical vapor deposition (MOCVD) was conducted in a fluidized bed to deposit thin films of titania on glass and alumina beads. Those can be used as photocatalysis for the removal of pollutants especially in liquid phases.

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Spectral Reflectance of Mongsanpo Tidal Flat, Korea, by using Spectroradiometer Experiments and Landsat Data

  • Kim, Bum-Jun;Lee, Sungsoon;Lee, Hoonyol
    • Korean Journal of Remote Sensing
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    • v.33 no.4
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    • pp.411-422
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    • 2017
  • This research aims to analyze spectral reflectance of intertidal zone and its changes under various environmental conditions. We sampled sand of Mongsanpo tidal flat, Korea, and measured its spectral reflectance by using a spectroradiometer under various water contents, compositions and granularity. We also simulated the reflectance of Landsat 7 ETM+ and compared it with an actual satellite data. Five locations were selected for sampling from the coastline towards the ocean. Grain size diminished stepwise from the coastline to ocean direction, while spectral reflectance differed with wavelength. Water contents lowered the overall reflectance especially at the water absorption bands. Spectral reflectance data were then converted into the simulated one by using Landsat 7 ETM+ spectral reflectance function to be compared with the actual Landsat 7 ETM+ images. It showed the decrease of the spectral reflectance due to the increase of moisture contents from seashore towards the ocean. It is shown that Landsat 7 ETM+ imagery can be efficient to extract moisture contents in the tidal flat while compositional analysis needs satellite sensors with much higher spectral resolution.

Computational Analysis of 355 nm UV Laser Single-Pulsed Machining of Copper Material Considering the Strain Rate Effect (변형률 속도 효과를 고려한 355 nm UV 레이저 구리재질의 싱글 펄스 전산해석)

  • Lee, Jung-Han;Oh, Jae Yong;Park, Sang Hu;Shin, Bo Sung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.9 no.3
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    • pp.56-61
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    • 2010
  • Recently, UV pulse laser is widely used in micro machining of the research, development and industry field of IT, NT and BT products because the laser short wavelength provides not only micro drilling, micro cutting and micro grooving which has a very fine line width, but also high absorption coefficient which allows a lot of type of materials to be machined more easily. To analyze the dynamic deformation during a very short processing time, which is nearly about several tens nanoseconds, the commercial Finite Element Analysis (FEA) code, LS-DYNA 3D, was employed for the computitional simulation of the UV laser micro machining behavior for thin copper material in this paper. A finite element model considering high strain rate effect is especially suggested to investigate the micro phenomena which are only dominated by mechanically pressure impact in disregard of thermally heat transfer. From these computational results, some of dynamic deformation behaviors such as dent deformation shapes, strains and stresses distributions were observed and compared with previous experimental works. These will help us to understand micro interaction between UV laser beam and material.

Synthesis and photovoltaic performance of novel ionic dyes for the dye-sensitized solar cells (신규 유기염료를 적용한 염료감응 태양전지의 광전변환거동)

  • Jung, Mi Ran;Lee, Jeong Gwan;Kim, Sang Ah;Kim, Jae Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.120.2-120.2
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    • 2011
  • The improvement of solar energy-to-electricity conversion efficiency has continued to be an important research area of dye-sensitized solar cells (DSSCs). The mechanism of DSSCs is based on the injection of electrons from the photoexcited dye into the conduction band of nanocrystalline TiO2 or ZnO. Thus, the electronic structures, such as HOMO, LUMO, and HOMO-LUMO band gaps of dye moleculed in DSSC are deeply related to the electron transfer by photoexcitation and redox potential. Organic dyes, because of their many advantages, such as high molar extinction coefficients, convenience of customized molecular design for desired photophysical and photochemical properties, inexpensiveness with no transition metals contained, and environment-friendliness, are suitable as photosensitizers for DSSC. We believe that practically useful organic dye photosensitizers can be produced by exploiting electron donor/acceptor system with proper length of ${\pi}$-conjugation in a chromophore to control the absorption wavelength and enhance the photovoltaic performance. In this research, We designed and synthesized organic dyes also investigated the photoelectrochemical properties of a series of ionic dyes in DSSCs.

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Preparation and Characteristics of Elongated CdSe nanoparticles (CdSe 나노 입자의 이방성 구조 제어 및 특성연구)

  • Kim, Shin-Ho;Park, Myoung-Guk;Kim, Yang-Do
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.210-213
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    • 2008
  • Elongated CdSe nanoparticles with a diameter of 3-7nm have been successfully synthesized using two surfactants of trioctylphospine (TOP) and hexadecylamine (HDA) at $160^{\circ}C$. The formation of elongated CdSe nanoparticles is possibly due to the cooperative effects from both the different binding capability of two surfactants (TOP and HDA) and intrinsically anisotropic crystal structure of the CdSe. The electron diffraction pattern of CdSe nanoparticles revealed the formation of wurzite phase. The CdSe samples showed red-shifted wavelength from 560 to 580nm with increasing the refluxing time due to the gradual growth of CdSe nanoparticles. The relatively broad absorption band can be attributed to the surface state of CdSe nanoparticles. The possible formation mechanism of elongated CdSe nanoparticles was proposed and the characteristics of CdSe have been discussed as well.

Photocatalytic Behaviors of Transition Metal Ions Doped TiO2 Synthesized by Mechanical Alloying (기계적 합금화법을 이용한 전이금속 도핑에 따른 TiO2분말의 광촉매 특성)

  • Woo S.H.;Kim W.W.;Kim S.J.;Rhee C.K.
    • Journal of Powder Materials
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    • v.12 no.4 s.51
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    • pp.266-272
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    • 2005
  • Transition metal ions($Ni^{2+}$, $Cr^{3+}$ and $V^{5+}$) doped $TiO_2$ nanostructured powders were synthesized by mechanical alloying(MA) to shift the adsorption threshold into the visible light region. The synthesized powders were characterized by XRD, SEM, TEM and BET for structural analysis, UV-Vis and photoluminescence spectrum for the optical study. Also, photocatalytic abilities were evaluated by decomposition of 4-chlorophenol(4CP) under ultraviolet and visible light irradiations. Optical studies showed that the absorption wavelength of transition metal ions doped $TiO_2$ powders moved to visible light range, which was believed to be induced by the energy level change due to the doping. Among the prepared $TiO_2$ powders, $NiO^{2+}$ doped $TiO_2$ powders, showed excellent photooxidative ability in 4CP decomposition.

Output characteristics of diode-laser-pumped Tm:YAG laser (다이오드 레이저로 여기되는 Tm:YAG 레이저의 출력 특성연구)

  • 정태문
    • Korean Journal of Optics and Photonics
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    • v.11 no.4
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    • pp.289-293
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    • 2000
  • Diode-laser-pumped Tm:YAG laser of wavelength $2.02\mu\textrm{m}$has been manufactured and its excitation efficiency and output characteristics have been investigated. The excitation efficiency was varied from 66 to 68% with respect to the pump power, yielding pump power absorption of 87-89%. The output power was sensitively varied with the temperature of Tm:YAG rod. When the concave output coupler with a focal length of 25 mm and a transmittance of 3% was used, the maximum output power reached up to 1.2 W. The slope and optical efficiency of this Tm: YAG laser was 29% and 20% at $6^{\circ}C$, respectively.tively.

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Wavefront Distortion caused by High Energy Laser Beam in the Relay Mirrors of the Laser Beam Director (고에너지 레이저빔에 의해 유발된 광집속장치 반사경 광파면 왜곡)

  • Choi, Jong-Ho;Kim, Yeon-Soo
    • Korean Journal of Optics and Photonics
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    • v.19 no.2
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    • pp.144-149
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    • 2008
  • Thermal distortion of the laser mirrors which are the Coude mirrors of the laser beam director and the wavefront error caused by the thermal distortion are studied. Coude mirrors consist of three relay mirrors and one fast steering mirror. The mirrors have reflectivity of 99.5% with respect to the laser wavelength of $3.8\;{\mu}m$, and absorption of 500 W per second. Thermal distortion and its related wavefront errors are studied with laser beam irradiation for 5 seconds. For the relay mirror, the wavefront error is 334 nm_PV, 98 nm rms and for fast steering mirror, $11.5\;{\mu}m$_PV, $3{\mu}m$ rms.