• Title/Summary/Keyword: Absorption wavelength

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Spectral Reflectivity on Geological Materials in Yangsan-Dongrae Fault Area (양산-동래 단층 지역의 암석에 대한 분광학적 연구)

  • 姜必鍾;智光薰
    • Korean Journal of Remote Sensing
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    • v.3 no.1
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    • pp.1-10
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    • 1987
  • The study was performed to recognize the most preferable spectral chennels for discriminating geological materials using the portable radiometer. The portable radiometer covers the visible and short infrared regions from approximately 0.4 to 2.5 microns which are coincided with Landsat TM, and the rock samples used for the study are pyrophylites, andesites, granite, granodiorite and silicified sedimentary rocks which are collected in Yangsan-Dongrae fault area. The analysis of the rock sample provides a preliminary basis for determining the wavelength regions showing diagnostic spectral features and for discriminating hydrothermal altered rocks from the unaltered rocks. The measurement of spectral of spectral reflectance for the rock samples was carried out in the laboratory which environment condition such as temperature, light sources, and humidity are constant. The analysis of the measured data was based on correlation between the reflectance value of the rock samples, and the follow discriptions are output of the study. 1) Pyrophyllite shows absorption at 0.83 $\mu\textrm{m}$ due to the oxidation of pyrite, and absorption at 2.22 $\mu\textrm{m}$ due to OH. 2) The altered rocks have generally higher reflectance than the unaltered rocks. 3) The ratio mesurement of pyrophyllites shows strong absorption at band 5/6 and band 6/4(in Landsat TM 5/7, 7/4). The ratio 1/5(Landsat TM 1/5) may be useful to discriminate andesite from the granite.

Effects of Synthesis Conditions on Luminescence Characteristics of Glutathione Capped ZnSe Nano particles (글루타티온이 캡핑된 ZnSe 나노 입자 발광 특성에 미치는 합성 조건의 영향)

  • Back, Geum Ji;Song, Ha Yeon;Lee, Min Seo;Hong, Hyun Seon
    • Journal of Powder Materials
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    • v.28 no.1
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    • pp.44-50
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    • 2021
  • Zinc selenide (ZnSe) nanoparticles were synthesized in aqueous solution using glutathione (GSH) as a ligand. The influence of the ligand content, reaction temperature, and hydroxyl ion concentration (pH) on the fabrication of the ZnSe particles was investigated. The optical properties of the synthesized ZnSe particles were characterized using various analytical techniques. The nanoparticles absorbed UV-vis light in the range of 350-400 nm, which is shorter than the absorption wavelength of bulk ZnSe particles (460 nm). The lowest ligand concentration for achieving good light absorption and emission properties was 0.6 mmol. The reaction temperature had an impact on the emission properties; photoluminescence spectroscopic analysis showed that the photo-discharge characteristics were greatly enhanced at high temperatures. These discharge characteristics were also affected by the hydroxyl ion concentration in solution; at pH 13, sound emission characteristics were observed, even at a low temperature of 25℃. The manufactured nanoparticles showed excellent light absorption and emission properties, suggesting the possibility of fabricating ZnSe QDs in aqueous solutions at low temperatures.

A Study on the Real-Time Temperature and Concentration Measurement of Combustion Pipe Flow Field (연소 배관 유동장의 실시간 온도, 농도 측정에 관한 연구)

  • Hong, Jeong Woong;Yoon, Sung Hwan;Jeon, Min Gyu
    • Journal of the Korean Society of Visualization
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    • v.20 no.2
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    • pp.86-92
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    • 2022
  • Pipe failure due to thermal fatigue and environmental regulations are increasing the importance of pipe monitoring systems in industrial plants. Since most pipe monitoring systems are focus on external crack inspected, it is necessary to temperature and concentration measuring monitoring system inside the pipe. These systems have spatial uncertainty due to sample inspection by one-point measurement. In addition, real-time measurement is not possible due to the limitation of time delay due to contact measurement. In this study, CT-TDLAS (Computed tomography-Tunable diode laser absorption spectroscopy) apply to overcome the limitations of existing methods. Lasers exhibiting an absorption response at a wavelength of 1395 nm were arranged in a lattice pattern on measuring cell. It showed that the inside of the pipe changed to an unstable combustion state over time.

Independent Control of Wrinkle Wavelength and Height for Optoelectronic Devices via Changing Stress Relaxation Time (응력 해소 시간 변화를 통한 광전자소자용 주름구조 주기와 높이의 독립적 제어 연구)

  • Gu, Bongjun;Kim, Jongbok
    • Journal of Adhesion and Interface
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    • v.23 no.2
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    • pp.39-43
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    • 2022
  • In optoelectronic devices including displays and solar cells that convert electricity into light or light into electricity, it is important to control optical behavior of light to improve device efficiency. Specifically, the control of internal emitting light in the OLEDs can induce more light to go out, improving luminous efficiency. In addition, the control of optical behavior of incident light in solar cells can increase optical path in the light absorption layer, increasing power-conversion efficiency. In this study, we generated wrinkles as a physical structure to control optical behavior of light and independently controlled their wavelength and height by changing stress relaxation time. To explore the effect of wavelength and height on optical behavior, we conducted UV/Vis spectroscopy analysis of wrinkles with various heights at a constant wavelength or various wavelengths at a comparable height, figuring out a wrinkle with high aspect ratio has more dispersive light and less straight light. It indicates that high aspect ratio is required to change the optical behavior and increase the optical path.

An Ultra-thin IR Cut-off Filter Based on Nanostructures (나노구조 기반 초박형 적외선 차단 필터)

  • Hyundo Yang;Jong-Kwon Lee
    • Korean Journal of Optics and Photonics
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    • v.35 no.1
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    • pp.24-29
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    • 2024
  • We propose a hyperbolic metastructure based on a nanopatterned metal (Ag)-dielectric (PDMS) multilayer and report on its performance in an infrared (IR) cut-off filter for imaging devices. By optimizing the size of the square-shaped Ag nanopattern and the thickness of PDMS surrounding the Ag nanopattern, the proposed IR cut-off filter blocks 99% of light in the 0.70-1.01 ㎛ wavelength band while maintaining a high transmittance of over 94% in the visible region. Here, the cut-off wavelength band starts at a region above the epsilon-near-zero wavelength of the hyperbolic metastructure and ends at the point where plasmonic absorption appears strongly. It is observed that transmittance in the wavelength region longer than the IR cut-off band increases again due to plasmonic coupling among horizontally adjacent Ag nanopatterns. This metastructure can improve the performance of IR-blocking filters as well as allow it to be manufactured ultra-thin, which is applicable to various planar optical elements and integrated optical components.

Influence of para-orientating Methoxyl Units on the Electronic Structures and Light Absorption Properties of the Triphenylamine-based dyes by DFT Study

  • Liang, Guijie;Xu, Jie;Xu, Weilin;Wang, Luoxin;Shen, Xiaolin;Yao, Mu
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2279-2285
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    • 2011
  • The geometries, electronic structures and absorption spectra of the two organic triphenylamine-based dyes TA-St-CA and TA-DM-CA, containing identical electron donors and acceptors but the different conjugated bridges, were studied by density functional theory (DFT) at the B3LYP and PBE1PBE levels, respectively. The influence of para-orientating methoxyl units on the electronic structures and light absorption properties of the dyes and the consequent photovoltaic performance of the dye-sensitized solar cells (DSSCs) were investigated in detail. The results indicate that the introduction of the para-orientating methoxyl units into the conjugated bridge induces the increased absorption wavelength as well as the more negative EHOMO corresponding to the bigger driving force $(E_{I^-/I^-_3}-E_{HOMO})$ for dye reduction, which together improve the photovoltaic performance of TA-DM-CA, although there is a decline of the open circuit voltage caused by the more negative $E_{LUMO}$.

Optical Properties of Undoped and $Ni^{2+}$ -doped $MgIn_2Se_4$ Single Crystals ($MgIn_2Se_4 및 MgIn_2Se_4 : Ni^{2+}$ 단결정 성장의 광학적 특성에 관한 연구)

  • Kim, Hyeong-Gon;Kim, Byeong-Cheol;Sin, Seok-Du;Kim, Deok-Tae;Choe, Yeong-Il;Kim, Nam-O
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.1
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    • pp.12-17
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    • 1999
  • $MgIn_2Se_4 and MgIn_2Se_4 : Ni^{2+}$ single crystals were grown in the rhombohedral structure by the chemical transport reaction (C.T.R.) method using iodine as a transport agent. The optical absorption measured near the fundamental band edge showed that the optical energy band structure of these compounds had a direct band gap. The fundamental absorption band edge of these single crystals shift to a shorter wavelength region by decreasing temperature and the temperature dependence of the optical energy gaps in these compounds satisfy Varshni equation. The impurity optical absorption peaks due to nickel are observed in $MgIn_2Se_4 and MgIn_2Se_4 : Ni^{2+}$ single crystal. These impurity optical absorption peaks can be attributed to the electronic transitions between the split energy levels of $Ni_{2+}$ ions located at $T_d$ symmetry site of $MgIn_2Se_4$ host lattice. In the hotoluminescence spectrum of the single crystal at 10 K, a blue emission with a peak at 687nm and a green emission with a peak at 815nm for the $MgIn_2Se_4$ single crystal were observed.

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The identification of amethyst origins by using FT-IR, UV-VIS spectrum analysis (ET-IR, UV-VIS 분광분석을 통한 자수정의 산지감별)

  • Yoon Si-Nae;Yon Seog-Joo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.1
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    • pp.25-31
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    • 2006
  • Many amethysts of different origins such as South America, Aftrica, and Asia were compared. According to ICP-AES analysis, the colorizing elements were Fe, Cr, Cu, and Co. Amethysts from South America showed higher concentrations of the elements. UV- VIS analysis showed that both natural and synthetic amethysts were characterized by the higher absorption at 350 nm and 550 nm wavelength. The natural amethysts had lower permeability than that of the synthetic amethysts. According to FT-IR analysis, the synthetic amethysts were distinguished from the natural amethysts in that they had a typical absorption band of $3543cm^{-1}$. The amethyst from South America showed strong absorption bands of $3584cm^{-1}\;and\;3435cm^{-1}$, and African amethyst had absorption bands of $3299cm^{-1}\;and\;3196cm^{-1}$. $3381cm^{-1}$ absorption band was shown strongly for Asian origins.

Fabrication of Transient Absorption Spectroscopic System and Measurement of Transient Absorption Changes of DDI (순간흡수 분광학 측정장치 구성 및 DDI의 순간흡수율 변화 측정)

  • Seo, Jung-Chul;Lee, Min-Yung;Kim, Dong-Ho;Jeong, Hong-Sik;Park, Seung-Han;Kim, Ung
    • Korean Journal of Optics and Photonics
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    • v.2 no.4
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    • pp.209-213
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    • 1991
  • Recently, the developments in generating and amplifying ultrashort optical pulses $(ps=10^{-12}s or fs=10^{-15}s)$ have imposed on great advances in the time-resolved laser spectroscopy. Especially, the transient absorption spectroscopy has a wide application range and the main idea of this technique is pump & probe method. After the pump pulse makes the material an excited or a transient states, the probe pulse is sent through the material to measure the absorbance change due to the transient states. Here, if the absorbance change was measured by the time delay between pump & probe pulses, the dynamic information of the excited or the transient states (the transient abnsorption changes by time & wavelength) can be obtained. At our laboratory, the ultrashort optic1 pulse (

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Numerical Analysis of Differential Absorption Lidar for Measuring Atmospheric Pollutants (대기오염 측정용 DIAL시스템의 오차해석)

  • 박진화;이용우
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.10a
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    • pp.428-433
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    • 2003
  • In this study, we composed algorithm of DIAL(Differential Absorption Lidar). we investigated the absorption spectrum of $O_3$, S $O_2$ and N $O_2$ dependent on wavelengths using data base UV-Bank and determine the optimized wavelength model. Here, the selected optimal wavelengths are 292.00(λ$_{on}$ ), 295.20(λ$_{off}$) for $O_3$, 299.38(λ$_{on}$ ), 300.05(λ$_{off}$) for S $O_2$ and 448.00(λ$_{on}$ ), 449.85(λ$_{off}$) for N $O_2$. In particular, we established the supposed model of DIAL and simulated the error of measuring distance using the selected optimal wavelength. In the model-I with telescope of 300 mm diameter, laser energy of 3 mJ and transmission of 10000 shots, maximum distances are 4 km for $O_3$ measurement and 5 km for S $O_2$ and N $O_2$ measurements. Also, in the model-II with telescope of 600 mm diameter, laser energy of 30 mJ and transmission of 10000 shots, maximum distances are 13 km for S $O_2$ and N $O_2$ measurements.ments.

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