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Changes of Functional Properties of Acylated Fish Protein (Acyl화에 의한 어류 단백질의 이화학적 성질의 변화)

  • Bang, Chan-Sik;Kim, Ze-Uook
    • Applied Biological Chemistry
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    • v.33 no.1
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    • pp.52-61
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    • 1990
  • Fish protein was acylated with acetic anhydride(AA), succinic anhydride(SA) and maleic anhydride(MA) in order to improve the functional properties of the protein. The surface hydrophobicity and functional properties of protein were measured to study the relationship between them. It was found that the extented acylation of nucleophilic groups such as amino and sulfhydryl groups of the amino acid residues of fish protein was higher than other groups when acylated with AA, and the degree of acylation was 89.5 % for amino groups and 72.2 % for sulfhydryl groups. The surface hydrophobicity of fish protein was decreased by succinylation and maleylation, whereas acetylation caused tittle change. The acylated fish protein concentrate(FPC) showed higher surface hydrophobicity than the acylated fish myofibrilla protein(FMP). Acylation with AA, SA and MA of fish protein resulted in a significant increase in protein solubility, emulsifier properties, foaming properties, water adsorption capacity and oil adsorption capacity. These properties of acylated FMP were more improved than those of acylated FPC. Decrease in protein hydrophobicity was highly correlated with increase in protein solubility, and emulsifier properties and foaming properties were largely dependent on the solubility as well as surface hydrophobicity. The water adsorption capacity of the protein was significantly affected by solubility. Surface hydrophobicity had greater influence on oil adsorption capacity, whereas it had tittle effect on water adsorption capacity.

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Manufacture of Alkyl Acrylate Multi Core-shell Composite Particle (알킬 아크릴레이트계의 다중 Core-shell 복합입자의 제조)

  • Cho, Dae-Hoon;Choi, Sung-Il;Go, Hyun-Mi;Seul, Soo-Duk
    • Journal of Adhesion and Interface
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    • v.12 no.1
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    • pp.16-25
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    • 2011
  • Multi core-shell composite particles were prepared by the water-born emulsion polymerization of various core monomer such as methyl methacrylate (MMA), n-butyl methacrylate (BMA), and shell monomer such as MMA, BMA, stylene (St), 2-hydroxyl ethyl methacrylate (2-HEMA) and acrylic acid (AA) in the presence of different concentration of sodium dodecyl benzene sulfonate (SDBS). The following conclusions are drawn from the measured conversion, particle size and distribution, average molecular weight, molecular structure, glass transition temperature with DSC, morphology, tensile strength and elongation. In the case of the concentration of 0.02 wt% SDBS, the conversion of MMA core-(BMA/St/AA) shell composite particle was excellent as 98%. In the case of the concentration of 0.03 wt% SDBS, the particle size of BMA core-(MMA/St/AA) shell composite particle was high as $0.47{\mu}m$. We confirmed that 3 points of glass transition temperatures appear for multi core-shell composite particles compared to 2 points of glass transition temperatures appear for general core-shell composite particles. We showed that it is possible to adjust glass transition temperatures according to the kind and composition of the inner shell monomer that it is can be used as a adhesive binder material with improved adhesive power.

Light-weight Design of Automotive AA6061 Rear Sub-frame Based on CAE Simulation (CAE 해석을 이용한 자동차용 AA6061 리어 서브-프레임의 경량화 설계)

  • Kim, Kee-Joo;Lim, Jong-Han;Park, Jun-Hyub;Choi, Byung-Ik;Lee, Jae-Woong;Kim, Yoon-Jae
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.3
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    • pp.77-82
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    • 2012
  • It is well known that the targeted fuel efficiency could only be achieved by more than 40% reduction of the vehicle weight through improved design and extensive utilization of lightweight materials. In order to obtain the goal of the weight reduction of automobiles, the researches about lighter and stronger rear sub-frame have been studied without sacrificing the safety of rear sub-frame. In this study, the weight reduction design process of rear sub-frame could be proposed based on the variation of von-Mises stress contour by substituting an AA6061 (aluminum 6061 alloy) having tensile strength of 310 MPa grade instead of SAPH440 steels. In addition, the stress ratio variations (stress over fatigue limit) of the rear sub-frame were examined and compared carefully. It could be reached that this approach method could be well established and be contributed for light-weight design guide and the optimum design conditions of the automotive rear sub-frame development.

Hydro-forming Process Development of Automotive AA6061 Rear Sub-frame Side Member by Computer Aided Engineering (CAE) (컴퓨터 시뮬레이션(CAE)을 이용한 자동차용 AA6061 리어 서브-프레임 사이드멤버의 하이드로-포밍 공정 개발)

  • Kim, Kee-Joo;Kim, Jae-Hyun;Choi, Byung-Ik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.5
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    • pp.45-49
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    • 2010
  • The automotive industry has shown a growing interest in tube hydroforming during the past years. The advantages of hydroforming (less thinning, a more efficient manufacturing process, etc.) can, for instance, be combined with the high strength of extra high strength steels, which are usually less formable, to produce structural automotive components which exhibit lower weight and improved service performance. Design and production of tubular components require knowledge about tube material and forming behavior during hydroforming and how the hydroforming operation itself should be controlled. These issues are studied analytically in the present paper. In this study, the whole process of rear sub-frame parts development by tube hydroforming using AA6061 material is presented. At the part design stage, it requires feasibility study and process design aided by CAE (Computer Aided Engineering) to confirm hydroformability in details. Effects of parameters such as internal pressure, axial feeding and geometry shape in automotive rear sub-frame by hydroforming process were carefully investigated. Overall possibility of hydroformable rear sub-frame parts could be examined by cross sectional analyses. Moreover, it is essential to ensure the formability of tube material on every forming step such as pre-bending and hydroforming. In addition, all the components of prototyping tool are designed and interference with press is examined from the point of geometry and thinning.

Analysis of Horizontal Neutron Reflectometer for Nanointerfaces Using McStas (나노 계면분석을 위한 수평형 중성자 반사율 측정장치의 McStas 시뮬레이션 분석)

  • Kwon, Oh-Sun;Shin, Kwan-Woo
    • Journal of the Korean Vacuum Society
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    • v.16 no.1
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    • pp.7-14
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    • 2007
  • A new horizontal neutron reflectometer has been designed and now under construction at the HANARO, 30 MW research reactor, in Daejon, Korea. We performed simulations of neutron ray-tracing to evaluate the performance of all of the optical components of the instrument with a Monte Carlo technique using McStas. The feasible wavelength of the incident neutron beam is $2.5{\AA}$. It produces a q-range up to $0.126{\AA}^{-1}$ with a supermirror as a deflector. Our studies showed improvement of the performance of the guide tube and monochromators. Although the performance is limited in q-range, it promises to be the first reflectometer in Korea for the study of free surfaces, which is currently in demand.

Observation of the Effects of Auricular Acupressure on Smoking Cessation in Male High School Students from 2015 to 2017 (2015년부터 2017년까지 시행한 이압요법을 통한 남자 고등학생 금연효과 관찰)

  • Lee, Gi-hyang;Jeon, Sang-woo;Kan, Sei-young
    • The Journal of Internal Korean Medicine
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    • v.40 no.6
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    • pp.1202-1209
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    • 2019
  • Objectives: The purpose of this study was to confirm the effects of an auricular acupressure (AA) program for smoking cessation in high school students from 2015 to 2017. Methods: The study investigated 12 high school students who had been smokers. Subjects were treated for three years. Each program was composed of five AA treatments. Average daily smoking and adverse reactions were checked for one week before each procedure. The AA was administered weekly at the endocrine point, lung point, throat point, nasal fossae point, bronchial tube point, and mouth point. Results: The mean number of cigarettes smoked per day after each year of treatment significantly decreased from 5.33±3.58 to 3.54±2.08 in 2015 (p=0.046). However, it increased from 5.75±2.30 to 6.00±3.61 in 2017 (p=0.80). The number of cigarettes smoked before treatment was found to be higher than the number of cigarettes after treatment in the previous year. No significant results were obtained from analysis of the change in the amount of smoking within each year. Conclusion: Social influence, such as the subject's academic stress and peer relationships, may have been a major factor in the change in the amount of smoking. Although the AA did not show a strong effect in smoking cessation, it appears to have value as a supplementary means of stopping smoking.

Vertical Neutron Reflectometer at HANARO (하나로 수직형 중성자 반사율 측정장치)

  • Lee J.S.;Lee C.H.;Hong K.P.;Choi B.H.;Choi Y.H.;Kim Y.J.;Shin K.W.
    • Journal of the Korean Vacuum Society
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    • v.14 no.3
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    • pp.132-137
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    • 2005
  • Neutron reflectometer has been installed at HANARO, research reactor in Korea. It has vertical sample geometry and the wavelength of incident neutron beam is $2.459\;\AA$ Neutron fluxes at monochromator and sample position were $4.5\times10^9\;n/cm^2/sec,\;6.64\times10^6\;n/cm^2/sec4 those were measured by gold wire activation method. Also, some reference thin films such as d-PS, $SiO_2$ were measured and analyzedwith HANARO neutron reflectometer. As result of the work, it was certified that minimum reflectivity and available Q range were $10^{-6},\;and\;0.003\sim0.3\;\AA^{-1}$ respectively.

Dependence of the lithium ionic conductivity on the B-siteion substitution in $(Li_{0.5}La_{0.5})Ti_{1-x}M_xO_3$

  • Kim, Jin-Gyun;Kim, Ho-Gi
    • Electrical & Electronic Materials
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    • v.11 no.11
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    • pp.9-17
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    • 1998
  • The dependence of the ionic conductivity on the B-site ion substitution in (Li0.5La0.5)Ti1-xMxO3 (M=Sn, Zr, Mn, Ge) system has been studied. Same valence state and various electronic configuration and ionic radius of Sn4+, Zr4+, Mn4+ and Ge4+(4d10(0.69$\AA$), 4p6(0.72$\AA$), 3d10(0.54$\AA$) and 3d3(0.54$\AA$), respectively) induced the various crystallographic variaton with substitutions. So it was possibleto investigate the crystallographic factor which influence the ionic conduction by observing the dependence of the conductivity on the crystallographic factor which influence the ionic conduction by observing the dependence of the conductivity on the crystallographic variations. We found that the conductivity increased with decreasing the radii of B-site ions or vice versa and octahedron distortion disturb the ion conduction. The reason for this reciprocal proportion of conductivity on the radius of B-site ions has been examined on the base of the interatomic bond strength change due to the cation substitutions. The results were good in agreement with the experimental results. Therefore it could be concluded that the interatomic bond strength change due to the cation substitutions may be the one of major factors influencing the lithium ion conductivity in perovskite(Li0.5La0.5) TiO3system.

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Effect of Low Temperature Annealing on the Magnetoresistance in Co/Cu Artificial Superlattice (Co/Cu인공초격자에서 저온 열처리가 자기저항에 미치는 영향)

  • 민경익;송용진;이후산;주승기
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.305-309
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    • 1993
  • Thermal stability of Co/Cu artificial superlattice (AS) prepared by RF-magnetron sputtering and the effect of low temperature annealing on the magnetoresistance of the AS have been investigated in this work. Dependence of annealing behavior on the Cu spacer thickness, Fe underlayer thickness, and kind of the underlayer was examined and the relationship between the interfacial reaction and magnetoresistance was studied. It turned out that when Co/Cu AS was annealed at low temperature ($<450^{\circ}C$), the magnetoresistance could increase in the case of AS with thick spacer Cu ($20~25\AA$) layer, whereas it decreased in the case of AS with thin spacer Cu ($7\AA$) layer, which of the former is in contrast with previous reports and the latter in consistent with them. The increase of magnetoresistance is due to increase of interfacial atomic sharpness, which is supported by low angle X-ray diffraction analysis. The thermal stability of Co/Cu AS was better in the case of thick Fe underlayered AS. Interfacial reaction (separation of intermixed Co and Cu) could be observed at lower temperature for (200)-textured samples than for (111)-textured samples, which can be interpreted in terms of interdiffusion kinetics depending on the crystallographic orientation.

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Analysis of structural properties of epitaxial BST thin films prepared by pulsed laser deposition (펄스형 레이저 증착법으로 제조된 에피탁시 BST 박막의 구조 분석)

  • 김상섭;제정호
    • Journal of the Korean Vacuum Society
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    • v.7 no.4
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    • pp.355-360
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    • 1998
  • Epitaxial $Ba_{0.5}Sr_{0.5}TiO_3$thin films of two different thickness (~250 $\AA$ and ~1340 $\AA$) on MgO(001) prepared by a pulsed laser deposition method were studied by synchroton x-ray scattering measurements. The film initially grew on MgO(001) with a cube-on-cube relationship, maintaining it during further growth. As the film grew, the surface of the film became rough significantly, but the interface between the film and the substrate seemed to have changed little. In the early stage, the film was highly strained in a tetragonal structure with the longer axis parallel to the surface normal direction. As the growth proceeded further, it was mostly relaxed to a cubic structure with the lattice parameter of the bulk value and the mosaic distribution improved significantly in both in-plane and out-of-plane directions.

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