• Journal of the Korean institute of surface engineering
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• v.44 no.6
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• pp.239-245
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• 2011

Magnesium alloys is the lightest by structural metals, but it is not good corrosion resistant because of pit, void. Particularly, AZ31B magnesium alloy sheets that have slag, scratch by rolling process indicate some defects. The objective of this research is to perform uniform plating on AZ31B by studying etching and zincate process. Especially, zincate treatment by zinc salt and pyrophosphate is the most important in the decoration plating. Dissolution of magnesium is reduced by the formation of uniform zinc conversion layer during strick and post process, which decreases defects for plating process.

• Journal of the Korean institute of surface engineering
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• v.47 no.4
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• pp.147-154
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• 2014

Formation behavior of PEO (Plasma Electrolytic Oxidation) films on AZ31 Mg alloy was studied in aqueous solutions containing various concentrations of hydroxide ion ($OH^-$) and silicate ion ($SiO_3{^{2-}}$) by voltage-time curves, and corrosion resistance of the PEO film-covered specimen was investigated by immersion test in 0.5 M NaCl solution. From the analyses of the voltage-time curves, it is suggested that two different types of anions are essentially needed for the formation of PEO films on AZ31 Mg alloy: film formation agent and local film breakdown agent. $SiO_3{^{2-}}$ ion acts only as a film formation agent but $OH^-$ ion acts not only as a film formation agent but also film breakdown agent. The PEO films prepared on AZ31 Mg alloy in alkaline silicate solution showed very good corrosion resistance without any pitting or filiform corrosions up to 480 h of immersion in 0.5 M NaCl.

• Transactions of Materials Processing
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• v.15 no.3 s.84
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• pp.232-240
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• 2006

Magnesium alloys are expected to be widely used fur the parts of structural and electronic appliances due to their lightweight and EMI shielding characteristics. While the die casting has been mainly used to manufacture the parts from the magnesium alloys, the press forming is considered as an alternative to the die casting for saving the manufacturing cost and improving the structural strength of the magnesium alloy parts. However, the magnesium alloy has low formability at room temperature and therefore, in many cases, forming at elevated temperatures is necessary to obtain the required material flow without failure. In the present study, square cup deep drawing tests using the magnesium alloy AZ31 sheet were experimentally conducted at various elevated temperatures as well as room temperature, and the corresponding finite-element simulations, which calculated the damage evolution based on the Oyane's criterion, were conducted using the stress-strain relations from the tensile tests at various temperatures. The formability predictability by the finite-element analysis was investigated by comparing the predicted damage distributions over the deformed AZ31 sheet at elevated temperatures with the corresponding experimental deformations with failures.

• Journal of the Korean Society for Heat Treatment
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• v.17 no.5
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• pp.299-304
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• 2004

Influence of Ca addition on microstructure and room temperature mechanical properties has been studied for AZ31(Mg-3%Al-1%Zn-0.2%Mn)-(0~0.5)%Ca wrought alloys, based on experimental results from metallography, X-ray diffractometry and mechanical tests. Yield strength, ultimate tensile strength and hardness of the alloys increased remarkably with increasing Ca content, whereas elongation was deteriorated continuously. Microstructural examination revealed that Ca addition efficiently refined grains of ${\alpha}$(Mg) phase and that some of the Ca dissolved in ${\beta}(Mg_{17}Al_{12})$ precipitates. The former and the latter facts are thought to be responsible for improved strength and loss of ductility of the AZ31+Ca wrought alloys, respectively.

• Journal of the Korean institute of surface engineering
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• v.43 no.2
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• pp.73-79
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• 2010

A chromium-free conversion coating for AZ31 magnesium alloy has been obtained by using a permanganatephosphate solution, which has been developed with acid pickling. Examination have been carried out on the conversion coatings for morphology, composition and corrosion resistance. The morphology of the conversion-coated layer was observed using optical microscope and SEM. It was shown that the conversion coatings are relatively uniform and continuous, with thickness 1.8 to 2.7 ${\mu}m$. The chemical composition of conversion coating was mainly consisted of Mg, O, P, K, Al and Mn by EDS analysis. It was found that the corrosion resistance of the AZ31 magnesium alloy has been improved by the permanganate-phosphate conversion treatment from electrochemical polarization.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2005.05a
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• pp.73-77
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• 2005

In this work, the influences of tool temperature on the formability of AZ31 sheet material in warm deep drawing processes of square cup were investigated. Deep drawing tests under different tool temperatures for magnesium alloy sheet at elevated temperature $250^{\circ}C$, where AZ31 sheet shows a good formability, and FE analyses were carried out. The successfully formed part without any defects was obtained when temperature of tool was over $100^{\circ}C$ while the fracture was occurred at the corner of the square cup below $100^{\circ}C$. It is shown that lower temperature of tool than that of magnesium sheet causes the temperature drop of the material by heat transfer and thus Interrupts the dynamic recrystallization of it. Therefore, in order to obtain successful part of magnesium alloys, it is necessary that the tool temperature is limited to the same or slightly lower temperature than sheet material.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.16 no.5
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• pp.99-104
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• 2017

Friction stir welding is a solid-state joining process and is useful for joining dissimilar metal sheets. In this study, the experimental conditions of the friction stir welding were determined by the two-way factorial design to evaluate the characteristics of the dissimilar friction stir welding of AZ31 and AZ61 magnesium alloys. The levels of rotation speed and welding speed, which are welding variables, were 1000, 2000, 3000 rpm and 100, 200, 300 mm/min, respectively. From the results, the greater the rotation speed and the lower the welding speed of the tool were, the greater the tensile strength of the welded part was. The contribution of the welding speed of the tool is larger than that of the rotation speed of the tool. In addition, the optimal conditions for tensile strength in the dissimilar friction stir joint were predicted to be the rotation speed of 3000 rpm and welding speed of 100 mm/min, and the tensile strength under the optimal conditions was estimated to be $214{\pm}6.57Mpa$ with 99% reliability.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.4
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• pp.218-224
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• 2016

The surface of Mg alloy, AZ31 and AZ91, were treated by PEO (plasma electrolytic oxidation) in Na-P system electrolyte, with different applied voltage and time. Thickness, roughness and X-ray crystallographic analysis revealed several results. The more applied time and voltage of PEO treated, the thicker oxidized surface coating layer were covered. And surface roughness increased with the thickness of oxidized layer. It was thought that when oxide layer grew, resistivity and breakdown voltage increased with the thickness of layer, and then, the energy of micro plasma need to be higher then before. So, it made craters and pores of surface become greater, which were responsible for the coarse surface.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.4
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• pp.225-230
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• 2016

Effect of electrolyte composition and concentration on PEO coating layer were investigated. Mg alloy, Surface of AZ31 and AZ91 were oxidized using PEO with different electrolyte system, Na-P and Na-Si. and applied voltage and concentration. We measured thickness, roughness, X-ray crystallographic analysis and breakdown voltage of the oxidized layer. When increasing concentration of electrolyte, the thickness of oxide layer also increased too. And roughness also increased as concentration of electrolyte increasing. Breakdown voltage of coated layer showed same behavior, the voltage goes high as increasing thickness of coating layer, as increasing concentration of electrolyte, and increasing applied voltage of PEO. $Mg_2SiO_4$ phase were observed as well as MgO.

• Proceedings of the KWS Conference
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• 2007.11a
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• pp.144-145
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• 2007

Magnesium alloys are the lightest in commercial alloys. Also, they have high damping capacity and the shielding effect of electromagnetic waves. Recently, magnesium alloys have received considerable attention from the transportation industry. Many manufacturers of cars try to increase the use of magnesium alloys in their product. In order to evaluate the weldability of magnesium alloy, gas-tungsten arc welding(GTAW) have been applied to the AZ31, AZ61 and AZ91 alloys and established the optimum welding conditions.