• 한국자기학회지
• /
• 제7권5호
• /
• pp.250-257
• /
• 1997

Ar+N$_{2}$ 가스분위기에서 반응성 스퍼터링법으로 제조된 Fe-Nb-B-N 박막의 미세구조 및 자기적 특성을 조사하였다. 질소첨가한 적정조성의 Fe-Nb-B-N 박막은 우수한 고주파 연자기 특성을 보였는데, 그 특성은 다음과 같다. 포화자화(4 .pi. M$_{s}$ )는 16.5 kG, 보자력(H$_{c}$)은 0.13 Oe, 1 MHz에서의 실효투자율은 약 5,000의 값을 나타내었다. 특히 실효투자율은 10 MHz까지 겨의 변화가 없었으며, 100 MHz에서도 약 2,000의 값을 보여 매우 우수한 고주파 특성을 가진 재료로 판단된다. 한편, 이러한 우수한 특성을 지닌 Fe-Nb-B-N 박막의 미세구조를 TEM으로 관찰한 결과, 적정 열처리온도인 590 .deg. C에서 열처리한 Fe-Nb-B-N 박막은 약 5 ~ 10 nm의 .alpha. -Fe phase, Nb-nitride의 석출물과 Nb-B rich 비정질상 등으로 이루어져 있음을 알 수 있었다. 반면에 N이 첨가되지 않은 Fe-Nb-B 박막의 경우에는 약 10 nm정도의 .alpha. -Fe결정립과 Nb-B rich 비정질상의 두가지 상으로 이루어져 있다. 따라서 N을 첨가한 경우에 더욱 미세한 .alpha. -Fe 결정립을 얻을 수 있음이 확인되었다. 이는 N 첨가로 인한 결정립의 미세화 효과 와 Nb-nitride 형성으로 인한 결정립 성장의 억제효과에 의한 것으로 생각된다. 따라서 Fe-Nb-B-N 박막의 우수한 연자기 특성은 결정립 미세화에 기인하는 것으로 판단된다.

• 한국결정성장학회지
• /
• 제5권2호
• /
• pp.109-121
• /
• 1995

SiC/Co 반응커플을 Ar/4 vol% $H_2$분위기하에서 $950^{\circ}C$에서 $1250^{\circ}C$ 범위에서 4시간에서 100시간까지 열처리하였다. $950^{\circ}C$ 이상의 온도에서의 고상반응으로 여러 가지 규소화물과 탄소석출이 형성되었다. 이 반응 zone에 있어서의 전형적인 반응층의 순서는 $SiC/CoSi + C/Co_2Si + C/Co_2Si/Co_2Si + C/{\cdots\cdots}/Co_2Si/Co$이었다. 그리고 탄소 석출거동을 동반한 주기적인 띠구조의 형성기구가 반응운동학과 열역학적인 고찰을 통하여 조사되어졌고 논하여졌다. 이 반응의 zone의 서장은 시간의 함수관계를 가지며 이러한 반응운동학이 반응상수의 측정을 통하여 제시되어진다. 또한 microhardness 측정을 통하여 반응 zone의 기계적인 물성이 조사되어졌다.

• 한국자기학회지
• /
• 제7권1호
• /
• pp.7-12
• /
• 1997

회전형 볼밀을 이용하여 Ar 분위기에서 기계적 합금화 방법으로 Fe$_{50}$Zr$_{50}$ 비정질을 제조하고 이들의 구조 및 자기적 성질을 투과전자현미경과 SQUID 자력계를 이용하여 조사하였다. 기계적합금화법으로 제조된 분말로 부터 얻은 제한시야 회절도형은 두개의 인접한 halo ring 도형을 나타내며, 이것은 비정질이 Fe rich 한 비정질과 Zr rich 한 두 비정질로이 공존하기 때문이다. 기계적 합금화한 Fe$_{50}$Zr$_{50}$ 비정질 분말에서 비정질상의 큐리온도로 부터 추정된 강자성 Fe-Zr계 비정지상의 Fe 조성은 100시간 합금화한 경우 65 at% 로서, 이것은 비정질의 상분리가 일어났기 때문이며, 이 결과는 회절도형의 분석결과와 일치한다. 기계적 합금화한 Fe$_{50}$Zr$_{50}$ 분말의 스핀파 탄성계수는 100시간 합금화한 경우에는 52.2 meV .angs. 이고, 200시간 합금화 한 경우에는 63.8 meV .angs. 으로 합금화시간이 증가함에 따라 증가하였다. 이것으 200시간 합금화한 경우 부분 결정화에 의하여 .alpha. -Fe가 일부 석출하였기 때문이다.

• 한국수자원학회:학술대회논문집
• /
• 한국수자원학회 2016년도 학술발표회
• /
• pp.203-203
• /
• 2016

The linkage between climate change and water security, i.e., the response of water resource to the future climate change, have been of great concern to both scientific community and policy makers. In this study, the impact of future climate on water resources in Yellow River Basin in North of China has been investigated using the Coupled Land surface and Hydrology Model System (CLHMS) and IPCC AR5 projected future climate change in the basin. Firstly, the performances of 14 IPCC AR5 models in reproducing the observed precipitation and temperature in China, especially in North of China, have been evaluated, and it's suggested most climate models do show systematic bias compared with the observation, however, CNRM-CM5、HadCM5 and IPSL-CM5 model are generally the best models among those 14 models. Taking the daily projection results from the CNRM-CM5, along with the bias-correction technique, the response of water resources in Yellow river basin to the future climate change in different emission scenarios have been investigated. All the simulation results indicate a reduction in water resources. The current situation of water shortage since 1980s will keep continue, the water resources reduction varies between 28 and 23% for RCP 2.6 and 4.5 scenarios. RCP 8.5 scenario simulation shows a decrease of water resources in the early and mid 21th century, but after 2080, with the increase of rainfall, the extreme flood events tends to increase.

• 한국수자원학회:학술대회논문집
• /
• 한국수자원학회 2008년도 학술발표회 논문집
• /
• pp.299-303
• /
• 2008

In this study, an uncertainty assessment for surface air temperature(T2m) and precipitation(PCP) over East Asia is carried out. The data simulated by the intergovermental Panel on Climate Change (IPCC) Fourth Assessment Report (AR4) Atmosphere-Ocean coupled general circulation Model (AOGCM) are used to assess the uncertainty. Examination of the seasonal uncertainty of T2m and PCP variabilities shows that spring-summer cold bias and fall warm bias of T2m are found over both East Asia and the Korea peninsula. In contrast, distinctly summer dry bias and winter-spring wet bias of PCP over the Korea peninsula is found. To investigate the PCP seasonal variability over East Asia, the cyclostationary empirical orthogonal function(CSEOF) analysis is employed. The CSEOF analysis can extract physical modes (spatio-temporal patterns) and their undulation (PC time series) of PCP, showing the evolution of PCP. A comparison between spatio-temporal patterns of observed and modeled PCP anomalies shows that positive PCP anomalies located in northeastern China (north of Korea) of the multi-model ensemble(MME) cannot explain properly the contribution to summer monsoon rainfalls across Korea and Japan. The uncertainty of modeled PCP indicates that there is disagreement between observed and MME anomalies. The spatio-temporal deviation of the PCP is significantly associated with lower- and upper-level circulations. In particular, lower-level moisture transports from the warm pool of the western Pacific and corresponding moisture convergence significantly contribute to summer rainfalls. These lower- and upper-level circulations physically consistent with PCP give a insight of the reason why differences between modeled and observed PCP occur.

• 한국재료학회지
• /
• 제18권4호
• /
• pp.187-192
• /
• 2008

Multi-walled carbon nanotube (MWNT)/$SnO_2$ nano-composite (MSC) for the anode electrode of a Li-ion battery was prepared using a homogeneous precipitation method with $SnCl_2$ precursors in the presence of MWNT. XRD results indicate that when annealed in Ar at $400^{\circ}C$, $Sn_6O_4(OH)_4$ was fully converted to $SnO_2$ phases. TEM observations showed that most of the $SnO_2$ nanoparticles were deposited directly on the outside surface of the MWNT. The electrochemical performance of the MSC electrode showed higher specific capacities than a MWNT and better cycleability than a nano-$SnO_2$ electrode. The electrochemical performance of the MSC electrode improved because the MWNT in the MSC electrode absorbed the mechanical stress induced from a volume change during alloying and de-alloying reactions with lithium, leading to an increase in the electrical conductivity of the composite material.

• 열처리공학회지
• /
• 제8권3호
• /
• pp.236-243
• /
• 1995

Since amorphous alloys have been known to have better mechanical and chemical properties than crystalline alloys of the same composition, a great number of studies on the formation of Al-based amorphous alloys have been carried out actively. However, little has been obtained about the effect of Rare-Earth metal and Transition metal addition on amorphous phase formed by melt spinning method. This study included fabrication of amorphous alloy $Al_{85}Ce_5Ni_{10}$ by melt spinning methods and DTA, XRD, TEM analysis to determine crystalization behavoir. Annealing treatments were carried out in Ar atmosphere under isothermal and nonisothermal conditions. The diffraction pattern of non-heated ribbons showed broad form characteristic of glass metallic alloy. The crystallization of amorphous $Al_{85}Ce_5Ni_{10}$ takes place eutedtoidly by homogeneous formation of Al and MS-1, followed by precipitation of the $Al_{11}Ce_3$ and later $MS-1{\rightarrow}Al_3Ni$ transformation.

• 물과 미래
• /
• 제9권1호
• /
• pp.86-100
• /
• 1976

To study influences on the downstream, and the Gunsan harbor by setting up estuary of the Gumgang, available data which were collected from the measuring stations which were established within the river basin of which results attained are as follows: 1. The discharge can be calculated as the relationship between the discharge and precipitation in the basin is $R=4{\times}10^{-4}p^2$ or R=P-600 2. The discharge flow in to small resevoirs in the basin can be estimated as $QR=QS\frac{PR-600}{PS-600}(\frac{AR}{AS})$ 3. This daily average discharge at Kongju is 31% less than the during maximum probable discharge and that in Okcheon is 48% less than the daily maximum probable flood. 4. The maximum probable flood from the small stream in the basin can be estimated by a $Q=82.45A^{0{\cdot}464}$ 5. Sediments can be computed with Qs (suspended load)=1.41 $Q^{1{\cdot}42}$ and Qb (bed load)=165.2 $Q^{0{\cdot}705}$. 6. By setting up the specific estuary the tidal movement will be reduced to 93.6% on the average and the sedimentation is reduced to 96.0%. Upon review of overall analysis, the dead wate level of estuary of Gumgang will completely sedimented in next 30 years, therefore, the dredging work at Gunsan harbor is reduced to 73.6%, it is considered that life length will be extended about 52years taking account the existing condition.

• 한국동물학회지
• /
• 제37권1호
• /
• pp.76-87
• /
• 1994

High density lipophorin-L (HDLP-L) was purified from the hemolymph of Bombyx modi using KBr density gradient ultracentrifugation and gel permeation chromatographv (Sephadex G-2001. Lipophorin has native molecular weight of 730 Nd and consists of Apo-Lp I and Apo-Lp II with molecular weights of 250 Kd and 90 Kd, respectively. Lp contains large amounts of glutamine & glutamic acid, threonine, leucine but small amounts of cysteic acid & oxidized cystine, tyrosine, methionine. Lp also contains diacylglycerol, cholesterol, phosphatidylcholine, and phosphatidylethanolamine. Anti-lipophorin showed positive reaction with fat body and ovarial extracts and also revealed immunological identity with lipophorin of Fall webworm, Hyphantria cunea. Lipophorin maintains constant level during larval and pupal stapes but greatlv increases during adult stage in both male and female. Apo-Lp III was purified from adult hemolymph. Hemolymph was subjected to KBr ultracentrifusation and Lp-free fraction was submitted to cation exchange chromatosraphy after ammonium sulfate precipitation. Apo-Lp III has molecular weight of 17 Kd, and similar amino acid composition ar those of other species Lp but contains high amounts of tryptophan which other are tacking in.

• Elastomers and Composites
• /
• 제55권4호
• /
• pp.321-328
• /
• 2020

Zinc nitrate hexahydrate (Zn(NO3)2·6H2O) and sodium hydroxide (NaOH) were dissolved in distilled water and stirred for 30 min. The resulting solution was sonicated by an ultrasonic wave for 45 min. This solution was washed with distilled water and ethanol after centrifugation; next, it was placed in an electric furnace at 200℃ for 1 h under the flow of Ar gas to obtain zinc oxide nanoparticle. A zinc oxide nanoparticle-(C60) fullerene nanowhisker composite was synthesized using the zinc oxide nanoparticle solution, C60-saturated toluene, and isopropyl alcohol via the liquid-liquid interfacial precipitation method. The zinc oxide nanoparticle and zinc oxide nanoparticle-(C60) fullerene nanowhisker composite were characterized using X-ray diffraction, scanning electron microscopy, and Raman spectroscopy, and they were used for the catalytic degradation of methyl orange (MO) under ultraviolet (at 254 and 365 nm) and ultrasonic irradiation. In addition, the catalytic degradation of MO over the zinc oxide nanoparticle and zinc oxide nanoparticle-(C60) fullerene nanowhisker composite was evaluated using ultraviolet-visible spectroscopy.