• 제목/요약/키워드: ADS 1.2

검색결과 218건 처리시간 0.029초

1-Chlorobutadiene-Butadiene Copolymer의 수가교반응(水架橋反應)에 관한 연구(硏究)(II) (A Study on Curing Reaction of 1-Chlorobutadiene-Butadiene Copolymer by Moisture)

  • 유종선;백남철
    • Elastomers and Composites
    • /
    • 제22권4호
    • /
    • pp.305-313
    • /
    • 1987
  • In this study, as one of the developing ways of the functional elastomer, improvement of the functionality of 1-Chlorobutadiene-Butadiene Copolymer(CB-BR) was attempt through curing reaction by moisture. The curing reaction of CB-BR was determined an use of $\gamma$-Aminopropyltriethoxysilane(APS) and $\gamma$-Aminopropylmethyldiethoxysilane(ADS) as a crosslinking agent with filler at so the uncrosslinked elastomer was exposured in the air and curing reaction by moisture in the air was studied. The results obtained are as follows. 1. APS was more efficient than ADS as a crosslinking agent for CB-BR 2. Optimum amount of APS for moisture cured elastomer was r=1.5(at the ratio of $[APS]/[Cl^*]$) also in case(r=1.5), elastomer formed after soaking $T_{72}$ had similar physical properties with elastomer crosslinked by sulfur and it was very good. 3. Uncrosslinked elastomer(CB-BR+APS+Silica) was easily crosslinked by exposure to the air, and the physical properties was also satisfactory.

  • PDF

다결정 Pt 전극계면에서 음극 H2 발생반응을 위한 전착된 수소의 Langmuir 흡착등온식에 관한 위상이동 방법 (The Phase-Shift Method for the Langmuir Adsorption Isotherms of Electroadsorbed Hydrogens for the Cathodic H2 Evolution Reactions at the Poly-Pt Electrode Interfaces)

  • 천장호;전상규;이재항
    • 전기화학회지
    • /
    • 제5권3호
    • /
    • pp.131-142
    • /
    • 2002
  • 순환전압전류 및 교류임피던스 기법을 이용하여 다결정 Pt/0.5M $H_2SO_4$ 및 0.5M LiOH수용액 계면에서 저전위 수소흡착(UPD H) 과 전위 수소흡착(OPD H)에 관한 Langmuir 흡착등온식 $({\theta}\;vs.\;E)$ 을 연구조사 하였다. 계면에서 치적중간주파수일 때 위상이동$(0^{\circ}{\leq}{-\phi}{\leq}90^{\circ})$ 거동은 표면피복율$(1{\geq}{\theta}{\geq}0)$ 거동에 정확하게 상응한다. 위상이 동 방법 즉 최적중간주파수일 때 위상이동 변화$({-\phi}\;vs.\;E)$는 계면에서 음극 $H_2$ 발생 반응에 관한 UPD H와 OPDH의 Langmuir흡착등온식을 결정할 수 있는 새로운 전기화학적 방법으로 사용할 수 있다 다결정 Pt/0.5M $H_2SO_4$ 수용액 계면에서 OPD H의 흡착평형상수(K)와 표준자유에너지$({\Delta}G_{ads})$는 각각 $2.1\times10^{-4}$와 21.0kJ/mol 이다. 다결정 Pt/0.5M LiOH 수용액 계면에서 K는 음전위(E)에 따라 2.7 (UPD H)에서 $6.2\times10^{-6}$ (OPD H) 또는 $6.2\times10^{-6}$(OPD H)에서 2.7 (UPD H)로 전이한다. 유사하게 ${\Delta}G_{ads}$는 E에 따라 -2.5kJ/mol (UPD H)에서 29.7kJ/mol (OPD H)또는 29.7kJ/mol (OPD H)에서 -2.5kJ/mol (UPD H)로 전이한다. K와 ${\Delta}G_{ads}$의 전이는 다결정 Pt전극 표면의 상이한 UPD H와 OPD H의 흡착부위에 기인한다. 다결정 Pt전극 계면에서 UPD H와 OPD H는 음극 $H_2$ 발생 반응에 따른 순차적 과정이 아니라, 수소 흡착부위 자체에 따른 독립적 과정이다. UPD H와 OPD H의 기준은 음극 $H_2$발생 반응과 전위가 아니라, 수소 흡착부위와 과정이다. 수용액에서 음극 $H_2$발생 반응에는 다결정 Pt선 전극이 단결정 Pt(100)원반 전극보다 더 효율적이고 유용하다 위상이동 방법은 열역학적 방법과 상충적이 아니라, 보완적이다.

산화 전처리가 고강도 질소폐수의 막증류 공정에 미치는 영향 (The Effect of Acidification on Membrane Distillation Process for Strong Nitrogenous Wastewater)

  • ;정다운;배효관
    • 한국물환경학회지
    • /
    • 제36권2호
    • /
    • pp.137-147
    • /
    • 2020
  • A direct contact membrane distillation (DCMD) was applied to treat strong nitrogenous wastewater of anaerobic digestion supernatant (ADS) and human urine (HU). The ammonia transfer was evaluated in terms of specific ammonia transfer (SAT) value, which is the ratio of total ammoniacal nitrogen divided by the amount of water transferred. The acidification resulted in low SAT values and high quality of produced water. The ammonia transfer control in the acidic condition was stronger for HU than ADS due to higher alkalinity (pH 8.8) and ammonia concentration (5700 mg-N/L) of HU. Acidified HU at pH 4 exhibited a SAT value of 1.64 × 10-5, which was significantly smaller than the SAT value of 3.00 × 10-3 for the original HU. The low pH enhanced the water flux for ADS, but HU showed a steep decrease in water flux due to enhanced fouling. It was considered that the fouling intensity in acidic conditions depends on the characteristics of the wastewater source. The major foulants on the MD membrane were NaCl, CaCO3 and CuSO4 as recognized by the SEM-EDS. Acidified ADS and HU at pH 4 showed relatively high N content of 8.18 % and 28.03 %, respectively, as organic fouling.

생체모방공학을 이용한 bovine carbonic anhydrase를 SBA-15에 고정화하여 이산화탄소분리와 재구성된 $CaCO_3$ 연구 (Biomimetic sequestration of $CO_2$ and reformation to $CaCO_3$ using bovine carbonic anhydrase immobilized on SBA-15)

  • ;김대훈;임경수;정순관
    • 한국산학기술학회:학술대회논문집
    • /
    • 한국산학기술학회 2010년도 추계학술발표논문집 1부
    • /
    • pp.495-499
    • /
    • 2010
  • The biocatalytic capture of $CO_2$, and its precipitationas $CaCO_3$, over bovine carbonic anhydrase (BCA) immobilized on a pore-expanded SBA-15 support was investigated. SBA-15 was synthesized using TMB as a pore expander, and the resulting porous silica was characterized by XRD, BET, IR, and FE-SEM analysis. BCA was immobilized on SBA-15 through various approaches, including covalent attachment (BCA-CA), adsorption (BCA-ADS), and cross-linked enzyme aggregation (BCA-CLEA). The immobilization of BCA on SBA-15 was confirmed by the presence of zinc metal in the EDXS analysis. The effects of pH, temperature, storage stability, and reusability on the biocatalytic performance of BCA were characterized by examining para-nitrophenyl acetate (p-NPA) hydrolysis. The $K_{cat}/K_m$ values for p-NPA hydrolysis were 740.05, 660.62, and $680.11M^{-1}s^{-1}$, respectively, where as $K_{cat}/K_m$ for free BCA was $873.76M^{-1}s^{-1}$. The amount of $CaCO_3$ precipitate was measured quantitatively using anion-selective electrode and was found to be 12.41, 11.82, or 11.28 mg $CaCO_3$/mg for BCA-CLEA, BCA-ADS, or BCA-CA, respectively. The present results indicate that the immobilized BCA-CLEA, BCA-ADS, and BCA-CA are green materials, and are tunable, reusable, and promising biocatalysts for $CO_2$ sequestration.

  • PDF

임베디드 교육용 라우터 실습장비의 구현 (Implementation of Embedded Educational Router System)

  • 박균득;정중수;정광욱
    • 한국컴퓨터정보학회논문지
    • /
    • 제18권5호
    • /
    • pp.9-17
    • /
    • 2013
  • 본 논문에서는 교육용 임베디드 라우터 실습장비 설계를 제시하였다. 교육용 임베디드 라우터 실습장비는 사용자가 인터넷 환경에서네트워크 구성과 임베디드 라우터 프로그래밍 실습 교육을 할 수 있도록 설계 및 구현되었다. 정적 및 동적 라우팅 프로토콜과 방화벽을 지원하는 라우터 기술 교육용 시스템 설계를 임베디드 환경에서 이더넷 인터페이스를 바탕으로 제시하였다. 개발 환경으로는 CPU는 PXA255, 디버깅 환경은 ADS 1.2, RTOS는 uC/OS-ii, 개발 언어는 C 언어를 사용하였다. 교육 과정으로는 제공된 정적 및 동적 라우팅 프로토콜과 방화벽 프로그램을 컴파일 및 로딩이후 데모 동작의 ping 처리과정으로 이들 기능의 점검 후 ping 패킷 처리의 성능도 살펴보았다. 이후 데모 기능과 유사하게 동작하는 프로그래밍을 하도록 기술 교육을 단계별로 진행시키도록 하였다. 즉, 정적 및 동적 라우팅 프로토콜과 패킷 필터링에 따른 프로그래밍의 완성 및 이의 검증을 수행하도록 하였다.

부정적 소구 광고의 효과 -사회문제를 주제로 한 잡지 의류광고를 중심으로- (The effectiveness of Advertising with Negrative Appeal -concentrating on magazine apparel ads taking social problems as their themes-)

  • 변상은;김인숙
    • 한국의류학회지
    • /
    • 제23권7호
    • /
    • pp.953-964
    • /
    • 1999
  • The purpose of this study was to analyze the effectiveness of negative appeal ads taking social problems as their themes. Two social problem ad themes concerning abortion and drug addiction were selected as stimulus. Questionnaires consisted of questions about affective response cognitive evaluation consumer's characteristics(sex, clothing involvement social problem involvement) and the ad and brand attitudes They were distributed to 200 high school students in Seoul. Results were : 1 The affective response consisted of 4 dimensions(negative inactivating activating positive) and the cognitive evaluation had 3 dimensions(utility·persuasive power creativity awareness) 2. Creativity and awareness dimensions and the ad attitude had positive influence on the brand attitude for the abortion theme ad,. Creativity dimension and consumer's clothing involvement had positive influence on the brand attitude for the drug addiction theme ad . Especially the affective response had no significant influence on the brand attitude. This result suggests that in case of negative appeal ads the affective response does not necessarily degrade the brand attitude while positive cognitive evaluation on creativity and awareness of the could influence the brand attitude favorably through raising attention to the brand resulting in high effectiveness of the ad.

  • PDF

Acoustic Variation Conditioned by Prosody in English Motherese

  • Choi, Han-Sook
    • 말소리와 음성과학
    • /
    • 제2권1호
    • /
    • pp.41-50
    • /
    • 2010
  • The current study exploresacoustic variation induced by prosodic contexts in different speech styles,with a focus on motherese or child-directed speech (CDS). The patterns of variation in the acoustic expression of voicing contrast in English stops, and the role of prosodic factors in governing such variation are investigated in CDS. Prosody-induced acoustic strengthening reported from adult-directed speech (ADS)is examined in the speech data directed to infants at the one-word stage. The target consonants are collected from Utterance-initial and -medial positions, with or without focal accent. Overall, CDS shows that the prosodic prominence of constituents under focal accent conditions variesin the acoustic correlates of the stop laryngeal contrasts. The initial position is not found with enhanced acoustic values in the current study, which is similar to the finding from ADS (Choi, 2006 Cole et al, 2007). Individualized statistical results, however, indicate that the effect of accent on acoustic measures is not very robust, compared to the effect of accent in ADS. Enhanced distinctiveness under focal accent is observed from the limited subjects' acoustic measures in CDS. The results indicate dissimilar strategies to mark prosodic structures in different speech styles as well as the consistent prosodic effect across speech styles. The stylistic variation is discussed in relation to the listener under linguistic development in CDS.

  • PDF

소구유형별 내의류 광고에 대한 소비자 태도-성적.비성적 소구유형을 중심으로- (Consumer's Attitudes toward Underwear Advertisements by Appeal Types-with or without Sex Appeal-)

  • 홍성순;황춘섭
    • 복식
    • /
    • 제39권
    • /
    • pp.283-299
    • /
    • 1998
  • The present study is to analyze the dimensions of affective responses according to the types of appeal in underwear advertisements and to find out the influences of affective res-ponses on the attitudes toward advertisement and brands. The research has been made by normative-descriptive survey method with the sample of 654 consumers residing in Seoul and Incheon. The data gaathered was analyzed by the methods of means, standard deviation, ANOVA, factor analysis and regression. The result are as follows : 1. There are 4 dimensions of affective responses ; Emotional dimension, Negative dimen-sion, Upbeat-activation dimension and Sexual activation dimension. 2. Affective responses to the advertising were different according to the characteristics of the consumers. According to the consumer's sex, there are significant differences in each dimension of their affective responses. To the sex appeal advertisement, man show higher degree of affective responses in Emotional, Upbeat-activation and Sexual-activation dim-ensions, while women show higher degree of affective responses in Negative dimension. 3. In case of female consumers, there are significant differences in affective responses to the both appeal type of advertisements according to consumer's age. As the age is increasing. Emotional dimension and Sexual-activation dimension are increasing, but Negative dimension is decreasing in the Ads with sex appeal. In particular, the 19∼24s age group shows strong responses in the Emotional dimension, Upbeat-activation dimension and Sexual-activation dimension to Ads with sex appeal, while it shows the lowest affective responses in Negative dimension. It represents the 19-24s age group is the most positive one to the under-wear advertisements with sex appeal. Consequently, it is proved that the Ads with sex appeal focusing on this age group can be one of the most effective advertising plans. 4. The involvement gets higher, Upbeat-ac-tivation dimension and Sexual-activation dimension are increasing both in males and female groups. But Negative dimension is in-creasing in the female consumer group of low involvement. 5. The attitudes toward advertisements and brands are comparatively stronger in the advertisements using sex appeal type. Regardless of types of appeal in the advertisements, there is a significant difference in their attitudes tow-ard Ads between male and female consumer groups. When Ads are sexual, attitudes toward Ads and Brands are stronger in the female consumer group. But males consumers show com-paratively strong attitudes toward the advertis-ements and brands in both types of appeal. 6. The age of consumers doesn't make any significant difference in their attitudes toward advertisements and brands in both types of appeal. 7. According to the involvement level of the consumers, there are significant differences in their attitudes toward advertisements. In the groups of low involvement, the female consumers show more favorite attitudes toward the advertisements with sex appeal, while the male group show more favorite attitudes toward the non-sex appeal advertisement. But there is no significant difference in consumer's attitude toward brands according to the types of appeal of the advertisement. 8. The affective responses of the consumers caused by the underwear advertisements have a respectable influence on their attitudes toward the advertisements and brands. This research represents that the advertisers should try to arise consumer's positive affective responses such as pleasant, happy, cheerful and warm-hearted emotions by the advertisements. Based on the above results of the research, it can be said that the consumer's affective responses have a strong effect not only on their attitudes toward adver-tisements but on those toward attitude toward the brands.

  • PDF

유튜브 인플루언서 마케팅: 사회적 거리, 지각된 진정성 및 광고태도의 관계에서 제품-인플루언서 일치성의 역할 (Influencer Marketing: The Role of Product-Influencer Congruence between Social Distance, Perceived Authenticity and Attitude toward Ads)

  • 최건;양병화
    • 미래기술융합논문지
    • /
    • 제1권2호
    • /
    • pp.27-35
    • /
    • 2022
  • 본 연구는 소셜미디어 인플루언서 마케팅의 효과성을 알아보기 위한 것으로 유튜브 인플루언서에 대한 지각된 사회적 거리, 진정성 및 광고태도의 관계를 분석하였다. 지각된 진정성은 인플루언서의 활동에 중요한 요소로서 협찬광고의 노출에 따른 소비자의 태도에 영향을 줄 것이며, 특히 지각된 진정성의 효과는 제품과 인플루언서 활동 간의 일치성에 의해 조건부 간접효과를 보일 것으로 가정되었다. 이를 알아보기 위해, 364명의 대학생을 대상으로 설문조사를 실시하였고 무응답 및 불성실 응답을 제외하고 340명의 데이터를 타당하게 분석하였다. 분석 결과, 인플루언서와의 사회적 거리는 지각된 진정성과 광고태도에 긍정적 영향을 주었고, 지각된 진정성은 광고태도에 직접 영향을 주는 것으로 나타났다. 특히 지각된 진정성은 사회적 거리와 광고태도의 관계성을 부분매개하는 효과를 보였고, 이러한 매개효과는 낮은 수준의 제품-인플루언서 일치성에서 나타나는 반면 높은 수준의 일치성에서는 발견되지 않았다. 이러한 결과에 기초하여, 인플루언서 마케팅에 대한 전략적 시사점을 논의하였다.

Silkworm (Bombyx mori) Response to Differently Formulated Artificial Diets

  • Mottaghitlab, M.;Pourali, M.
    • International Journal of Industrial Entomology and Biomaterials
    • /
    • 제8권2호
    • /
    • pp.207-210
    • /
    • 2004
  • Artificial diet (AD) has shown with different advantages over mulberry leaves (ML). Various types of such feed for silkworm have been developed and proposed. The aims of this study were possibility rearing whole instar of silkworm on AD and to find some economic formulation for rearing silkworm, compare to that ML. Eleven ADs (D$_1$ to D$_{11}$) were prepared with different percentage of mulberry leaf powder, and other ingredients such as soybean meal, cellulose, potato starch, agar, wheat flour, rice bran, etc. Five formulated diets (D$_1$ D$_2$, D$_{5}$, D$_{10}$ and D$_{11}$) appeared to have similar response to that ML (D$_{m}$). There were no significant differences for duration period between ADs, all of which recorded with higher duration than mulberry leaves. Compared to other died used in the present study D$_1$ and D$_{10}$ showed better growth development and survival rate. Larvae fed D$_1$, D$_2$, D$_{5}$, D$_{10}$ and D$_{11}$ grew faster and produced heavier and more useful cocoons.coons.coons.coons.