• Journal of the Korean Wood Science and Technology
• /
• v.20 no.4
• /
• pp.21-30
• /
• 1992

An activation energy equation for moisture diffusion in wood was developed with an assumption that activation energy is directly proportional to wood specific gravity. Theoretical activation energies obtained from the activation energy equation were revealed to be always lower than actual activation energies, which implies that activation energy isn't affected only by wood specific gravity. The other affecting factors are possibly anatomical structures of wood which determine a ratio of vapor diffusion to bound water diffusion in wood. For the convenience of estimating actual activation energy by using the activation energy equation, thirteen kinds of species were categorized into three groups according to their anatomical structures.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2002.10a
• /
• pp.81-84
• /
• 2002

Activation energy value is different according to cement, admixture and water-cement ratio also the relation of age-temperature is as non-linear as activation energy value is large. So to make accurate explanation for the effect of temperature on concrete strength development property, it is necessary to investigation for activation energy value. This study compares activation energy value recommended by Freiesleben and ASTM with activation energy value obtained by consequence of mortar examination according to ASTM C 1074-93. As the result of this study, activation energy value obtained by the study is 37.19KJ/mol, and in case of activation energy value obtained by the study explain temperature's influence about concrete strength development more accurate than activation energy value recommend by Freiesleben and ASTM.

• Journal of Applied Reliability
• /
• v.13 no.2
• /
• pp.117-127
• /
• 2013

In this paper, we studied the correlation between the activation energy($E_a$) of the raw materials and the structural characteristics of the White LED PKGs. The samples used in the study were composed of low power LED 3type and high power LED 5type. To calculate the activation energy($E_a$) of the White LED PKGs conducted three conditions of high temperature operation test based on the Arrhenius model. The number of samples used in the experiment is 10, respectively. The $T_j$ of Conditions and target specifics expressed $T_{j1}$, $T_{j2}$, $T_{j3}$. The activation energy ($E_a$) of the samples was calculated based on the value of the actually measured lifetime. We investigated the correlation between the activation energy ($E_a$) of the raw materials and the structural characteristics of the White LED PKGs. As a result, White LED PKGs activation energy($E_a$) value was confirmed that the material properties affected more than the structural characteristics of the LED PKGs and we found that activation energy of each LED Model has difference. Normally, The activation energy of phosphor of YAG type was indicated from 0.21 to 0.25[eV] and Silicate type was indicated from 0.12 to 0.16[eV]. According to the results, we confirmed that the activation energy of phosphor of YAG type is higher more than The activation energy of phosphor of Silicate type.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2003.11a
• /
• pp.13-16
• /
• 2003

There is no study that application of the maturity using H.B.C and H.S.C. Also activation energy has different values according to the cement, admixture and water-cement ratio. Therefore to make accurate explanation for the effect of temperature on concrete strength development properties, it is necessary that activation energy value according to the kind of cement is reviewed. This study compares and estimates equivalent age using activation energy value obtained by this experiment and Freiesleben activation energy value with compressive strength of concrete. As the result of this study, activation energy value obtained by this study has more accurate explanation of temperature's influence on concrete strength development than Freiesleben activation energy value.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2003.05a
• /
• pp.13.1-16
• /
• 2003

There is no study that application of the maturity using H.S.C and H.S.C. Also activation energy has different values according to the cement, admixture and water-cement ratio. Therefore to make accurate explanation for the effect of temperature on concrete strength development properties, it is necessary that activation energy value according to the kind of cement is reviewed. This study compares and estimates equivalent age using activation energy value obtained by this experiment and Freiesleben activation energy value with compressive strength of concrete. As the result of this study, activation energy value obtained by this study has more accurate explanation of temperature's influence on concrete strength development than Freiesleben activation energy value.

• Journal of the Semiconductor & Display Technology
• /
• v.18 no.2
• /
• pp.82-86
• /
• 2019

The reliability of 3D NAND flash memory cell is affected by the charge migration which can be divided into the vertical migration and the lateral migration. To clarify the difference of two migrations, the activation energy of the charge loss is extracted and compared in a conventional square device pattern and a new test pattern where the perimeter of the gate is exaggerated but the area is same. The charge loss is larger in the suggested test pattern and the activation energy is extracted to be 0.058 eV while the activation energy is 0.28 eV in the square pattern.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.91-91
• /
• 2011

박막태양전지의 높은 효율개선을 위해 TCO층과 p-layer 사이에 buffer layer를 넣어 Voc와 FF를 개선하는 연구가 진행되고 있다. 이에 buffer layer의 활성화 정도를 높이기 위해 p-layer을 최적화 시키고자한다. 이 실험에서 a-Si:B에 N2O를 도핑시켜 Bandgap Energy 2.0 eV, Activation Energy 0.4 eV인 a-SiOx:B 막을 제작하여 buffer layer로 사용하였고 이 buffer layer에 의한 cell의 효율 향상을 최적화 하기위해 ASA simulation을 이용해 p-layer의 Bandgap Energy와 Activation Energy를 가변 하여 보았다. 실험결과 p-layer의 Bandgap Energy 1.95 eV에서 buffer layer와 p-layer사이에서의 barrier가 최소가 됨을 확인 할 수 있었고 Actication Energy 0.5 eV에서 가장 높은 Voc를 가짐을 알 수 있었다. 본 연구를 통해 p-layer의 Bandgap Energy 1.95 eV, Activation Energy 0.5 eV에서 buffer layer를 활성화시키기 위한 p-layer의 최적화 조건을 구현해 볼 수 있었다.

• Bulletin of the Korean Chemical Society
• /
• v.19 no.7
• /
• pp.733-737
• /
• 1998

Using an atom superposition and electron delocalization molecular orbital (ASED-MO) method, we have compared adsorption properties of adsorbates on the Pt(Ill) surface with the Pt(lll)/γ-Al203 surface in the ethylene hydrogenation reaction. In two-layer thick model systems, the calculated activation energy of the hydrogenation by the surface platinum hydride is equal to the energy by the hydride over supported platinum/γ-alumina. The transition structure on platinum is very close to the structure on the supported platinum/γ-alumina surface. Hydrogenation by the surface hydride on platinum can take place easily because the activation energy is about 0.5 eV less than hydrogenation by ethylidene. On supported platinum/,y-alumina the activation energy of the hydride mechanism is about 0.61 eV less than that of ethylidene mechanism. In one-layer thick model systems, the activation energy of hydrogenation by ethylidene is about 0.13 eV less than the activation energy of hydride reaction. The calculated activation energy by the hydride over the supported platinum y-alumina is 0. 24 eV higher than the platinum surface. We have found from this result that the catalytic properties of one-layer thick model systems have been influenced by the support but the two-layer thick model systems have not been influenced by the support.

• Journal of Hydrogen and New Energy
• /
• v.34 no.2
• /
• pp.178-186
• /
• 2023

Three activation methods (constant voltage, current cycling, and hydrogen pumping) were applied to investigate the effects on the performance of the membrane electrode assembly (MEA) loaded with PtCo/C catalyst. The current cycling protocol took the shortest time to activate the MEA, while the performance after activation was the worst among the all activation methods. The constant voltage method took a moderate activation time and exhibited the best performance after activation. The hydrogen pumping protocol took the longest time to activate the MEA with moderate performance after activation. According to the distribution of relaxation time analysis, the improved performance after the activation mainly comes from the decrease of charge transfer resistance rather than the ionic resistance in the cathode catalyst layer, which suggests that the existence of water on the electrode is the key factor for activation.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2001.05a
• /
• pp.947-952
• /
• 2001

The prediction model is proposed to estimate the variation of compressive strength of fly ash concrete with aging. After analyzing the experimental result with the model, the regression results are presented according to fly ash replacement content and water/cement ratio. Based on the regression results, the influence of fly ash replacement content and water/cement ratio on apparent activation energy was investigated. According to the analysis, the model provides a good estimate of compressive strength development of fly ash concrete with aging. As the fly ash replacement content increases, the limiting relative compressive strength and initial apparent activation energy become greater. The concrete with water/cement ratio smaller than 0.40 shows that the limiting relative compressive strength and apparent activation energy are nearly constant according to water/cement ratio. But, the concrete with water/cement ratio greater than 0.40 has the increasing limiting relative compressive strength and apparent activation energy with increasing water/cement ratio.