• Title/Summary/Keyword: ACID property

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Three-Dimensional Analysis of the Collapse of a Fatty Acid at Various Compression Rates using In Situ Imaging Ellipsometry

  • Hwang, Soon Yong;Kim, Tae Jung;Byun, Jun Seok;Park, Han Gyeol;Choi, Junho;Kang, Yu Ri;Park, Jae Chan;Kim, Young Dong
    • Journal of the Optical Society of Korea
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    • v.18 no.4
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    • pp.350-358
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    • 2014
  • The collapse of Langmuir monolayers of arachidic acid (AA) on water at various rates of molecular area compression has been investigated in situ by imaging ellipsometry (IE). The thickness of the collapsed AA molecules, which are inherently inhomogeneous, was determined by IE with a spatial resolution of a few microns. For the analysis, we determined the dielectric function of AA monolayers from 380 to 1690 nm by conventional spectroscopic ellipsometry. Compression rates ranged from 0.23 to $0.94{\AA}^2/min$. A change of multilayer domains was observed in the in situ IE images. Lower compression rates resulted in more uniform collapsed films. Our experimental results correspond with previous theoretical simulations.

Surface coating and characterizations of non-swelling property mica (비팽윤성 운모의 표면코팅 및 특성평가)

  • Park, Ra-Young;Seok, Jeong-Won;Park, Sun-Min;Kim, Pan-Chae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.3
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    • pp.131-135
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    • 2008
  • This study is to establish the coating technique for synthetic mica and to prepare synthetic mica with the non-aqueous property. The surface coating of synthetic mica is prepared with stearic acid using the high speed stirrer. The characterizations for mica powders coated the stearic acid are carried out by the deposition test, XRD and SEM. The results of research could be coated the stearic acid on the mica by 1600 rpm/min at $70^{\circ}C$ for 10 min. From the observation of SEM was found that the non-aqueous property mica could obtained by mixture ratios for stearic acid and mica, the inner temperature and rotation speed of the stirrer but treated time be unrelated.

Preparation and Properties of Rust-Removing Polymer Gel (녹제거 폴리머겔의 제조 및 특성)

  • Kang, Young-Goo;Kim, Jeong-Hun
    • Journal of the Korean Society of Safety
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    • v.19 no.2
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    • pp.41-46
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    • 2004
  • The formation of rust on metallic substrate is known to cause the damages and destructions of raw materials, which is one of the leading reasons of sturctural collapses and many kind of hazards in modern industry. Polymer gels with rust removing effects were compounded in this study by employing various kinds of acids like hydrochloric acid, phosphoric acid, gluconic acid, oxalic acid as the rust removing ingredients. TEA(Triethanolamine) as dispersant and hydrophilic chemical were used for effective gelation of acids. Also corrosion inhibitor was added to enable the coating effect and to improve rust removing effect on metallic surface. In order to investigate the rust properites on metallic substrate, artificial rusts were prepared in salt solution, using iron, copper, aluminium and brass as the base metals. The properties of gel compounds were checked by gelation, pH, viscosity, morphology property and rust removing test. Developed gel compounds in this study have a good rust removing property, showing a strong adhesion on horizontal and vertical metallic surface, and can be easily rinsed off by water.

Synthesis and Lubrication Properties of Semi-Fluorinated Polyol Esters (불소계 폴리올에스테르의 합성과 윤활 특성)

  • 백진욱;정근우;김영운
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.149-155
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    • 2001
  • New semi-fluorinated polyol esters were synthesized by condensation reaction of polyols (NPG and TMP) and carboxylic acids such as 2-ethylhexanoic acid, stearic acid and perfluorooctanoic acid. The structures of polyol esters were confirmed by FT-IR and H-NMR etc. And, the fluorinated polyol esters were insoluble in several oils, however, the semi-fluorinated polyol esters were soluble in several oils depended on the structure of polyol esters. The physical properties such as 4-ball wear property and extreme-pressure (EP) properties were characterized by measuring wear scar diameter through ASTM D2266 and by determining the load-carrying through ASTM D2783 method, respectively. As the results, wear scar diameters of oils in which the semi-fluorinated polyol esters were added were not changed compared to those of not added oils. While extreme-pressure properties remarkably Increased with fluorine contents of the esters depended on the structure of acid moiety and polyol moiety. Also, the extreme-pressure property of semi-fluorinated NPG polyol ester in gasoline engine oil was better than that of commercial Teflon coating additive.

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A Study on the Property Improvement of a Lead-Acid Battery by Inhibitor Addition (인히비터 첨가에 의한 연축전지의 성능 향상에 관한 연구)

  • Park, Gyeong-Hwa;Kim, Seong-Jong;Mun, Gyeong-Man
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.34 no.1
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    • pp.96-103
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    • 1998
  • Lead-acid battery is being most widely used with secondary battery because of its low price, and long life cycles. But According to using for a long time, its voltage, capacity, and recovery ability is decreased gradually. Therefore there are many papers about improving the property of a lead-acid battery. One of them is to slow down sulfation due to formation of inner PbSO sub(4) by adding inhibitor to electrolyte, however it was not well known what is inhibitor's composition and its role acting on both cathodic and anodic electrode because of its know-how of every country and companies. The purpose of this paper is to study about improvement of property of lead-acid battery by adding one of the inhibitor to H sub(2) SO sub(4) electrolyte.

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Inorganic Salt Doped Soluble Polyimide Type Alignment Layer for Improving Panel Reliability and DC Image Sticking Properties

  • Lee, Tae-Rim;Roh, Seung-Kwang;Lim, Young-Nam;Kim, Kyeong-Jin;Shin, Hyun-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.672-676
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    • 2009
  • Polymide is widely used alignment material of recent commercial LCD panel structure. Generally, polyimide alignment material is classified soluble polyimide type and polyamic acid type with their main bond structure of solution state. specially, compared to polyamic acid alignment layer, soluble polyimide type alignment layer have excellent reliability during long term LCD driving cause of their high imidazation ratio(%), high voltage holding ratio(%) and low ion density. The other side, this type alignment materials has significant DC image stickicng side effect for using in-plane switching mode lcd structure cause of their slow DC discharging property. we applied inorganic salt to usual soluble polyimide type alignment layer and found out this technique had good DC image sticking property without any loss of reliability property in inplane switching LCD cell structure. This approach leads excellent DC image sticking property with maintaining high reliability property this approach confirmed improves an image sticking and a reliability simultaneously from the horizontality aligned LCD mode whose relatively bad image sticking property.

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Investigation of cultivation and FAME composition isolated Phaeodactylum tricornutum from Youngheung island (영흥도에서 분리된 Phaeodactylum tricornutum의 증식 및 Monounsaturated fatty acid 관련 지방산 조성 분석)

  • Lee, SangMin;Cho, Yonghee;Shin, ong-Woo;Jeon, Hyonam;Ryu, YoungJin;Lim, Sang-Min;Lee, Choul-Gyun
    • Journal of Marine Bioscience and Biotechnology
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    • v.6 no.2
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    • pp.47-52
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    • 2014
  • Oxidation stability and cold fuid property are considered as the most important factors for determining biodiesel quality. Among the fatty acids, monounsaturated fatty acid satisfy both oxidation stability and cold flow property of biodiesel quality standards. Microalgae with high monounsaturated fatty acid contents is have some benefit for producing to produce biodiesels with satisfying quality standards. In this study, monounsaturated fatty acid contents of a isolated microalga from Youngheung island was analyzed. Phaeodactylum tricornutum was isolated by streaking, and growth rate and fatty acid composition of the algae were investigated. Total FAME contents were consisted of 26% of saturated fatty acids, 43% of monounsaturated fatty acids, and 18% of polyunsaturated fatty acids. The contents of monounsaturated fatty acid were especially high in the Phaeodactylum species. This result implies that the FAMEs from P. tricornutum may contribute to improve the oxidation stability and cold flow property of biodiesel.

Preparation of Yogurt Added with Aloe vera and Its Quality Characteristics (Aloe vera가 첨가된 요구르트의 제조와 그 품질 특성)

  • 신용서;이갑상;이정성;이철호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.2
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    • pp.254-260
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    • 1995
  • Yogurt base were prepared from milk added with skim milk powder or Aloe vera powder and femented with lactic acid bacteria(the single or mixed strain of Lactobacillus bulgaricus and Streptococcus thermophilus). The yogurt product were evaluated for acid production(pH, titratable acidity), number of viable cell, viscosity, sensory property and quality-keeping property. The composition of organic acid were also analyzed by HPLC. Addition of Aloe vera remarkably accelerated acid production, and titratable acidity of Aloe vera yogurts(1.293∼1.407%) after 24 hours incubation was higher than that of yogurts added with only skim milk powder(9.98∼1.110%). Yogurt fermented with the mixed strain of L. bulgaricus and Sc. thermophilus was more acidic than that of single strains. The propagation of lactic acid bacteria was stimulated by Aloe vera and the number of viable cell after 24 hours incubation were above 9.87log CFU/ml. Viscosity of Aloe vera yogurt(3,860∼4,300CPS) was higher than that of yogurt with only skim milk powder(2,402∼2,604CPS). The overall sensory score of Aloe vera yogurt femented by mixed strain was the best of tested yogurt. When yogurt with Aloe vera was kept at 5℃ for 15 day, it's quality-keeping property was relatively good. The major organic acid of Aloe vera yogurt was lactic acid and lactic acid content of yogurt increased by addition of Aloe vera powder. The citric acid content decreased wtih fermentation and malonic acid, pyroglutaric acid and α-ketoglutaric acid were analyzed out a little.

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Studies on the Destructible Surfactants(2);Surface-Active Properties of Cleavable Surfactant with 1, 3-Dioxolane Ring (분해성 계면활성제에 관한 연구(제2보);1, 3-Dioxlane고리를 갖는 분해성계면활성제의 합성)

  • Kim, J.H.;Ha, J.H.;Jeong, N.H.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.101-107
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    • 1995
  • As the surfactants that were used in micellar reaction, emulsion polymerization and phase-transfer reaction etc. have the problems, the cleavable surfactant was converted to inactive compound after such as the reaction in the condition. Because 1, 3-dioxolane ring by ketal or acetal reactioc is lack of stability in acid condition, it is easily made to acid-hydrolysis. And cmc value of the surfactant is assumed $1.0{\times}10^{-5}mol/L$ and surface tension in cmc is 31 dyne/cm. Compared with other surfactant, this surfactant foam property is not better. But emulsion property was relatively good. According as acid-hydrolysis property was observed the interface tension change between aqueous solution and benzene by the variation of pH and time, this surfactant was made to hydrolysis within about 300minutes in pH 1${\sims}$4. Therefore this surfactant is expected to be a good emulsifier that has the bad foam property and the acid-hydrolysis property in acid condition.

Effects of Stearic Acid on the Watertightness Properties of the Cementitious Materials (시멘트 재료의 수밀성에 대한 스테아르산의 영향)

  • Na, Seung-Hun;Kang, Hyun-Ju;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.46 no.4
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    • pp.365-371
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    • 2009
  • It is well known that the properties of concrete such as the compressive strength, water permeability, water tightness and durability are affected by micro-structure in hardened cement paste. Especially, for durability of concrete, watertightness of cementitious materials is the most critical property among various properties. Recently, many types of materials as organic and/or inorganic materials are used for watertightness of concrete. In this study, The effect of Stearic Acid at $0.5\;wt%{\sim}3.0\;wt%$ adding ratios on the hydration and watertightness property of cement were investigated. And we also discussed the changing of microstructure in hardened cement paste by addition of Stearic Acid. Cement paste with Stearic Acid showed improvement of watertightness by reducing of cement total pore volume and decomposition of Stearic Acid.