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Photodegradation of Pyrene, Chrysene and Benzo[a]pyrene in Water (II) (수중의 Pyrene, Chrysene 및 Benzo[a]pyrene의 광분해(II))

  • 감상규;김지용;주창식;이민규
    • Journal of Environmental Science International
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    • v.12 no.7
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    • pp.775-782
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    • 2003
  • The photodegradations of pyrene, chrysene and benzo[a]pyrene that were similar in structure among polycyclic aromatic hydrocarbons (PAHs) were investigated with a low-pressure mercury lamp(the wavelength of 253.7 nm and UV output of 1.35${\times}$10$\^$-3/J/s). The optimum concentrations of TiO$_2$ and H$_2$O$_2$ on the photodegradation of pyrene, chrysene and benzo[a]pyrene were 1 g/L and 1.5${\times}$10$\^$-3/ M, respectively. By these optimum concentrations, their rates increased with increasing the concentration of TiO$_2$ and H$_2$O$_2$ because the amounts of OH radical formed increased, but for the higher concentrations than the optimum, their rates decreased with increasing those concentrations because the white turbidity phenomena occurs in case of TiO$_2$ and H$_2$O$_2$ acts as an OH radical inhibitor. The photodegradation rates among the photodegradation processes such as UV, UV/TiO$_2$, UV/H$_2$O$_2$, and UV/H$_2$O$_2$/TiO$_2$ decreased in the following sequences.: UV/H$_2$O$_2$/TiO$_2$> UV/H$_2$O$_2$> UV/TiO$_2$> UV.

A Study on Spray and Mixing Characteristics of Unlike Impinging Triplet Injector (F-O-F, O-F-O) (충돌형(F-O-F, O-F-O) 실물형 분사기의 분무특성 및 혼합특성에 관한 연구)

  • 김종규;김승한;문일윤;이광진;서성현;한영민
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2003.10a
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    • pp.195-203
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    • 2003
  • Spray and Mixing characteristics of the unlike impinging triplet injectors (F-O-F, O-F-O) were investigated with the variation of the momentum ratio of oxidizer to fuel. The spray pattern was measured using a backlit stroboscopic photography technique, and mixing efficiency was measured using a mechanical patternator. Kerosene/water were used as a propellant simulant. From the experimental results, it is found that a O-F-O type injector has a good atomization. And as the momentum ratio increases, the mixing efficiency decreases rapidly.

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A Study on the Intention of Continuous Usage of O2O Service: Focusing on the Moderating Effect of User Innovation (O2O 서비스의 지속이용의도에 관한 연구 : 이용자 혁신성의 조절효과를 중심으로)

  • Lee, Og;Lee, MoonBong
    • The Journal of Information Systems
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    • v.29 no.2
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    • pp.51-69
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    • 2020
  • Purpose Today, the increasing of internet use and the expansion of internet range provide us with many opportunities. Therefore, this study examine relation of perceived ease of use, perceived playfulness, perceived risk, perceived usefulness based on previous studies. And we examine the effect of O2O service satisfaction on continuous use intention. Also, we studied the relationship between perceived ease of use, perceived playfulness, perceived risk, perceived usefulness according to user innovation. Design/Methodology A Structural Equation Model(SEM) method was used to test the theoretical framework based on a sample of 451 respondents who have experienced the O2O service. Factor analysis and confirmation factor analysis was conducted to check the reliability, convergency validity and discriminant validity. To test moderating effect of the user innovation, multi group analysis was conducted. Findings First, perceived ease of use, perceived playfulness, perceived risk have significant effects on perceived usefulness. Second, perceived usefulness of O2O service have a positive effect on satisfaction. Third, satisfaction of O2O service have a positive effect on continuous use intention. The relationship that perceived ease of use, perceived playfulness, perceived risk affect perceived usefulness is differ depending on user innovation. Based on these findings, this study suggested to marketing practitioners the need for different approach by a user innovation.

Characterization of ZnO/TiO2 Nanocomposites Prepared via the Sol-Gel Method

  • Hellen, Nalumaga;Park, Hyun;Kim, Kyung-Nam
    • Journal of the Korean Ceramic Society
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    • v.55 no.2
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    • pp.140-144
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    • 2018
  • $ZnO/TiO_2$ nanocomposites were synthesized via a modified sol-gel technique by incorporating 30 and 70 wt% $TiO_2$ nanopowder into a ZnO sol-gel matrix. Zinc acetate dihydrate was used as the ZnO precursor and de-ionized water as the solvent, while titanium oxysulfate was employed for the synthesis of $TiO_2$ nanopowder. The synthesized $ZnO/TiO_2$ nanocomposites were characterized by x-ray diffraction, UV-vis spectroscopy, scanning electron microscopy, and transmission electron microscopy. The $ZnO/TiO_2$ nanocomposites showed both the ZnO (wurtzite) and $TiO_2$ (anatase) phases. The average ZnO crystallite size of the $ZnO/TiO_2$ nanocomposites was found to be about 26.3 nm. The TEM results confirmed that spherical $TiO_2$ particles were embedded in the ZnO matrix. $TiO_2$ particles attached onto the rod-like ZnO particles were also observed. The $ZnO/TiO_2$ nanocomposites exhibited optical absorption properties superior to those of pure ZnO and $TiO_2$.

Properties of the Powders of the System Al2O3-ZrO2-Y2O3 Prepared by Precipitation Method (침전법으로 제조한 Al2O3-ZrO2-Y2O3계 분말의 특성)

  • 김준태;홍기곤;이홍림
    • Journal of the Korean Ceramic Society
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    • v.25 no.2
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    • pp.117-124
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    • 1988
  • The properties of the powders of the system Al2O3-ZrO2-Y2O3 prepared by precipitation method were investigated. Al2(SO4)3$.$18H2O3, ZrOCl2$.$8H2O and YCl3$.$6H2O were used as starting materials. Amorphous aluminum hydrate prepared by precipitation method was completely transformed to alpha Al2O3 as a result of calcining at 1100$^{\circ}C$ for 1 hr and gamma, delta and theta phases appeared as transition phases. In ZrO2-Y2O3 system prepared by co-precipitation method, the crystallization temperature of ZrO2 was increase with Y2O3 contents. The coupled crystallization occured in coprecipitated Al2O3-ZrO2-Y2O3 system, therefore the formation temperature of alpha Al2O3 and ZrO2-Y2O3 system. In this ternary system, the powder morphology showed a particular shape which was composed of large Al2O3 grains having small spherical ZrO2 particles within large Al2O3 grain and relatively large ZrO2 particles along the grian boundaries.

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Geochemical Characteristics of A-type granite in Dongcheondong, Gyeongju (경주 동천동 일대에 분포하는 A-형 화강암의 지화학적 특성)

  • Myeong, Bora;Ju, Jiwon;Kim, Junghoon;Jang, Yundeuk
    • The Journal of the Petrological Society of Korea
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    • v.26 no.3
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    • pp.271-280
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    • 2017
  • The Dongcheondong granite is alkali feldspar granite in Dongcheondong, Gyeongju. The granite is coarse grained and consists of alkali feldspar, quartz, amphibole, and biotite. Alkali feldspar is perthitic orthoclase and quartz often shows undulatory extinction. Plagioclase often shows albite twins, and biotite and amphibole emplace as interstitial minerals. The Dongcheondong granite is plotted in A-type area having high ($Na_2O+K_2O)/Al_2O_3$ and low (MgO+CaO)/FeOT ratio. The Dongcheondong A-type granite has higher $SiO_2$, $Na_2O$, $K_2O$, Zr, Y, and REE contents (except for Eu) and lower $TiO_2$, $Al_2O_3$, CaO, MgO, Sr, Ba, and Eu contents than I-type granites in Gyeongsang Basin. These results show that the geochemical characteristics of the Dongcheondong A-type granite are distinguished from I-type granite in Gyeongsang Basin. A-type granite in the Dongcheondong is thought to has been generated by partial melting of I-type tonalite or granodiorite.

A study on the Microstructure and electrical characteristics of ZnO varistors for arrester (피뢰기용 ZnO 바리스터 소자의 미세구조 및 전기적 특성에 관한 연구)

  • 김석수;조한구;박태곤;박춘현
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.489-494
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    • 2001
  • In this thesis, the microstructure and electrical properties of ZnO varistors were investigated according to ZnO varistors with various formulation. A∼E's ZnO varistor ceramics were exhibited good density, 95% of theory density and low porosity, 5%, wholly. The average grain size of A-E's ZnO varistor ceramics exhibited 11.89$\mu\textrm{m}$, 13.57$\mu\textrm{m}$, 15.44$\mu\textrm{m}$, 11.92$\mu\textrm{m}$, 12.47$\mu\textrm{m}$, respectively. Grain size of C's ZnO varistor is larger and grain size of A and D's are smaller than other varistors. In the microstructure, A∼E's ZnO varistor ceramics sintered at l130$^{\circ}C$ was consisted of ZnO grain(ZnO), spinel phase(Zn$\sub$2.33/Sb$\sub$0.67/O$_4$), Bi-rich Phase(Bi$_2$O$_3$) and inergranular phase, wholly. Reference voltage of A∼E's ZnO varistor sintered at 1130$^{\circ}C$ decreased in order D, E > A > B > C's ZnO varistors. Nonlinear exponent of varistors exhibited high characteristics, above 30, wholly. Consequently, C's ZnO varistor exhibited good nonlinear exponent, 68. Lightning impulse residual voltage of A, B, C and E's ZnO varistors suited standard characteristics, below 12kV at current of 5kA.

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Characteristic Analysis of Chemical Compositions for Ancient Glasses Excavated from the Sarira Hole of Mireuksaji Stone Pagoda, Iksan (익산 미륵사지 석탑 사리공 내 출토 고대 유리 유물의 성분특성 분석)

  • Han, Min Su
    • Journal of Conservation Science
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    • v.33 no.3
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    • pp.215-223
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    • 2017
  • The purpose of this study is to reveal the characteristics, correlations, and colorant materials of those using the chemical compositions of 30 glasses excavated from the Sarari hall of the Mireuksaji stone pagoda, and to determine the correlations between them and other glass excavated from the Wanggungri site. The results of the chemical analysis of the 11 glass beads show that they are a soda glass group with high contents of $SiO_2$ and $Na_2O$; these can be further subdivided into soda-alumina groups ($Na_2O-Al_2O_3-CaO-Si_2O$). The characteristics of the stabilizer are classified as being of the high alumina glass group (LCHA), except for two glasses. It was concluded that colorant materials affected the coloring for glass beads by various components including Ti, Mn, Fe, Cu and Pb. In addition, we examined six lead glasses which are glass plate and unknown fragments that are of a common lead glass system ($PbO-SiO_2$) with respect to the average contents of PbO (70wt.%) and $SiO_2$ (30wt.%). As a result of comparing these relics with those of the glass beads excavated by Wanggungri, there is a similarity in that they belong to the soda glass group. However, the contents of $Na_2O$ are relatively higher than that of the glass beads in the Mireuksaji pagoda, and most of relics include glasses with a low content of $K_2O$ and CaO. In addition, the PbO and $SiO_2$ contents are slightly different in the lead glass. It seems that the glass relics made at two different sites may have used different raw materials or techniques.

Growth of ε-Ga2O3 film and fabrication of high quality β-Ga2O3 films by phase transition (ε-Ga2O3 박막의 성장과 상전이를 이용한 고품질 β-Ga2O3 박막의 제조)

  • Lee, Hansol;Kim, Soyoon;Lee, Jungbok;Ahn, Hyungsoo;Kim, Kyounghwa;Yang, Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.1
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    • pp.1-7
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    • 2021
  • ε-Ga2O3, a metastable phase of Ga2O3, has excellent compatibility with substrates having a hexagonal structure or a quasi-hexagonal structure, so that a film having a relatively lower surface roughness and defect density than β-Ga2O3 can be obtained easily. Accordingly, we attempted to fabricate a high-quality β-Ga2O3 film with a low surface roughness and defect density using the property of phase transition to β-Ga2O3 when ε-Ga2O3 is annealed at a high temperature. For this, the growth of high-quality ε-Ga2O3 films must be preceded. In this study, the optimal flow rate was investigated by analyzing the structural and morphological characteristics of the ε-Ga2O3 film according to the supplied precursor ratio. In addition, the annealing condition and the effect of β-Ga2O3 mixed in the ε-Ga2O3 film on the crystallinity of β-Ga2O3 after phase transition were also investigated.

A study on the characteristic of hydration reaction in $CaO-Al_2O_3-SiO_2$ system glass ($CaO-Al_2O_3-SiO_2$계 유리의 수화반응특성)

  • 조재우;김승진;김영근;손진군
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.289-292
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    • 1999
  • The charateristic of hydration reaction was studied in CaO-Al2O3-SiO2 system glass. As a result, the rate of heat liberation curves of synthestized glass becomes fixed after having increased by degrees. And it is decreasing after having increased suddenly. It was found that the total heat liberation with hydration for synthesized glass has a close relationship with the formation amount of ettringite.

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