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Study of characteristics of $AgGaS_2$/GaAs epilayer by hot wall epitaxy (HWE 방법에 의한 $AgGaS_2$/GaAs epilayer 성장과 특성)

  • Hong, K.J.;Jeong, J.W.;Bang, J.J.;Jin, Y.M.;Kim, S.H.;Yoe, H.S.;Yang, H.J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.08a
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    • pp.84-91
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    • 2002
  • The stochiometric composition of $AgGaS_2$/GaAs polycrystal source materials for the $AgGaS_2$/GaAs epilayer was prepared from horizontal furnace. From the extrapolation method of X-ray diffraction patterns it was found that the polycrystal $AgGaS_2$/GaAs has tetragonal structure of which lattice constant an and Co were 5.756 $\AA$ and 10.305 $\AA$, respectively. $AgGaS_2$/GaAs epilayer was deposited on throughly etched GaAs(100) substrate from mixed crystal $AgGaS_2$/GaAs by the Hot Wall Epitaxy (HWE) system. The source and substrate temperature were $590^{\circ}C$ and $440^{\circ}C$ respectively. The crystallinity of the grown $AgGaS_2$/GaAs epilayer was investigated by the DCRC (double crystal X-ray diffraction rocking curve). The optical energy gaps were found to be 2.61 eV for $AgGaS_2$/GaAs epilayer at room temperature. The temperature dependence of the photocurrent peak energy is well explained by the Varshni equation, then the constants in the Varshni equation are given by $\alpha=8.695{\times}10^{-4}$ eV/K, and $\beta=332K$. From the photocurrent spectra by illumination of polarized light of the $AgGaS_2$/GaAs epilayer, we have found that crystal field splitting ${\Delta}Cr$ was 0.28 eV at 20 K. From the PL spectra at 20 K, the peaks corresponding to free and bound excitons and a broad emission band due to D-A pairs are identified. The binding energy of the free excitons are determined to be 0.2676 eV and 0.2430 eV and the dissociation energy of the bound excitons to be 0.4695 eV.

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Effects of Multi-layer and TiCl4 Treatment for TiO2 Electrode in Dye-sensitized Solar Cell (염료감응 태양전지의 TiO2 전극의 다중층 및 TiCl4 처리에 따른 효과)

  • Kim, Gyeong-Ok;Kim, Ki-Won;Cho, Kwon-Koo;Ryu, Kwang-Sun
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.190-195
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    • 2011
  • To investigate the photon-trapping effect and scattering layer effect of $TiO_2$ multi-layer in dye-sensitized solar cell (DSSC) and the degree of recombination of electrons at the electrode treated $TiCl_4$, we formed electrodes of different conditions and obtained the most optimal electrode conditions. To estimate characteristics of the cell, IV curve, UV-Vis spectrophotometer, electrochemical impedance spectroscopy (EIS) and incident photon-to-current conversion efficiency (IPCE) were measured. As a result, we confirmed that the multi-layer's efficiency was higher than that of monolayer in the IV curve and the performance of $TiCl_4$ treated electrode was increased according to decreasing the impedance of EIS. Among several conditions, the efficiency of the cell with scattering layer is higher than that of a layer with the base electrode about 19%. Because the light scattering layer enhances the efficiency of the transmission wavelength and has long electron transfer path. Therefore, the value of the short circuit current increases approximately 10% and IPCE in the maximum peak also increases about 12%.

An Experimental Study on Concrete Bond Behavior According to Grid Spacing of CFRP Grid Reinforcement (격자형 CFRP 보강재의 격자간격에 따른 콘크리트 부착거동에 대한 실험적 연구)

  • Noh, Chi-Hoon;Jang, Nag-Seop;Oh, Hongseob
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.73-81
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    • 2022
  • Recently, as the service life of structures increased, the load-carrying capacity of deteriorated reinforced concrete, where corrosion of reinforcing bars occurs due to various causes, is frequently decreased. In order to address this problem, many studies on the bond characteristic of FRP (Fiber Reinforced Polymer) bars with corrosion resistance, light weight and high tensile strength have been conducted, however there are not many studies on the bond characteristic of grid-typed CFRP embedded in concrete. Therefore, in order to evaluate the bond characteristics of grid-typed CFRP and its usability as a substitute for steel rebar, a pull-out test is performed using the longitudinal bond length and transverse grid length of the grid-typed CFRP as variables. Through the pull-out test, the bond load-slip curve of the grid-typed CFRP is derived, and the bond behavior is analyzed. The total bond load equation is proposed as the sum of the bond force of the longitudinal bond length and the shear force of the grid in the transverse direction. Also, expressing the area of the bond load-slip curve as total work, the change in dissipated energy with respect to the slip is analyzed to examine the effect of the tranverse grid on the bond force.

Efficiency of the Hierarchical Structure for a Bus Network (시내버스 노선망 위계구조의 효율성 분석 (대전시 사례분석을 중심으로))

  • Lee, Beom-Gyu;Jang, Hyeon-Bong
    • Journal of Korean Society of Transportation
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    • v.27 no.3
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    • pp.49-58
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    • 2009
  • Four alternative plans for the bus network in Daejeon metropolitan city, which have different hierarchical structure, were proposed : Alternative 1 represents a bus network without hierarchical structure, and Alternative 2, 3, and 4 represent bus networks with primary, intermediate, and advanced hierarchical structures, respectively. Efficiency of the alternative plans were evaluated based on the evaluation index including travel time cost, waiting time cost, and transition penalty cost. The travel time cost was decreased as the level of hierarchical structure gets higher until it reaches the extremely high level. As the level of hierarchical structure get higher, the waiting time cost significantly decreased while the transition penalty cost increased. Collectively, a bus network with hierarchical structure was shown to be more efficient than without it in the light of total travel cost. For the bus network with hierarchical structure, total travel cost shows a concave curve, which implies that there exists an optimal level of hierarchical structure in a bus network.

Modeling Gamma-Ray Emission From the High-Mass X-Ray Binary LS 5039

  • Owocki, Stan;Okazaki, Atsuo;Romero, Gustavo
    • Journal of Astronomy and Space Sciences
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    • v.29 no.1
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    • pp.51-55
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    • 2012
  • A few high-mass X-ray binaries-consisting of an OB star plus compact companion-have been observed by Fermi and ground-based Cerenkov telescopes like High Energy Stereoscopic System (HESS) to be sources of very high energy (VHE; up to 30 TeV) ${\gamma}$-rays. This paper focuses on the prominent ${\gamma}$-ray source, LS 5039, which consists of a massive O6.5V star in a 3.9-day-period, mildly elliptical ($e{\approx}0.24$) orbit with its companion, assumed here to be an unmagnetized compact object (e.g., black hole). Using three dimensional smoothed particle hydrodynamics simulations of the Bondi-Hoyle accretion of the O-star wind onto the companion, we find that the orbital phase variation of the accretion follows very closely the simple Bondi-Hoyle-Lyttleton (BHL) rate for the local radius and wind speed. Moreover, a simple model, wherein intrinsic emission of ${\gamma}$-rays is assumed to track this accretion rate, reproduces quite well Fermi observations of the phase variation of ${\gamma}$-rays in the energy range 0.1-10 GeV. However for the VHE (0.1-30 TeV) radiation observed by the HESS Cerenkov telescope, it is important to account also for photon-photon interactions between the ${\gamma}$-rays and the stellar optical/UV radiation, which effectively attenuates much of the strong emission near periastron. When this is included, we find that this simple BHL accretion model also quite naturally fits the HESS light curve, thus making it a strong alternative to the pulsar-wind-shock models commonly invoked to explain such VHE ${\gamma}$-ray emission in massive-star binaries.

Effect of Deposition Temperature on Structural Properties of ZnO Thin Films on 4H-SiC Substrate (4H-SiC 기판 위에 성장된 ZnO 박막의 온도에 따른 구조적 특성 분석)

  • Kim, Ji-Hong;Cho, Dae-Hyung;Moon, Byung-Moo;Bahng, Wook;Kim, Sang-Cheol;Kim, Nam-Kyun;Koo, Sang-Mo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.120-120
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    • 2008
  • We demonstrate epitaxial growth of ZnO thin films on 4H-SiC(0001) substrates using pulsed laser deposition (PLD). ZnO and SiC have attracted attention for their special material properties as wide band gap semiconductors. Especially, ZnO could be applied to optoelectronic applications such as light emitting devices and photo detectors due to its direct wide bandgap (Eg) of ~3.37eV and large exciton binding energy of ~60meV. SiC shows a good lattice matching to ZnO compared with other commonly used substrates and in this regard SiC is a good candidate as a substrate for ZnO. In this work, ZnO thin films were grown on 4H-SiC(0001) substrates by PLD using an Nd:YAG laser with a 355nm wavelength. The crystalline properties of the films were evaluated by x-ray diffraction (XRD) $\theta-2\theta$, rocking curve and pole figure measurements using a high-resolution diffractometer. The surface morphology of the films was studied by atomic force microscopy (AFM).

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Studies on the quantitative determination of Capsaicin in various species of the genus Capsicum (고추중의 Capsaicin 정량(定量)에 관(關)한 연구(硏究))

  • Lee, Tae-Yeong;Park, Seong-O
    • Applied Biological Chemistry
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    • v.4
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    • pp.23-28
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    • 1963
  • Various species of the genus Capsicum contain in their fruits an intensively sharp and pungent substance, Capsaicin, which was first isolated in an almost pure state by Thresh. Containing the pungent principle, Capsicums are used extensively in food as a spice and in medicine as a rubefacient and carminative. Numerous methods have been proposed for the isolation, the chemical structure and the quantitative determination of Capsaicin. Modifying the several methods described before, the Capsaicin contents in various species of the genus Capsicum were determined as follows. (1) The isolation of pure Capsaicin was the essential first step for the determination of Capsaicin contents. Powdered cayenne pepper was extracted with acetone. By the method of ether alkali partition extraction slightly modified at this laboratory and by the recrystallization with light petroleum ether that was repeated ten times, the pure crystalline Capsaicin was obtained. Using this Capsaicin, the standard absorption curve was drawn with Beckman spectrophotometer model DU for the quantitative determination of Capsaicin. 92) The powdered sample was extracted in a Soxhlet extractor with ether-acetone solvent system(3:1) for 25 hours. Capsaicin in this ether-acetone extracts was efficiently separated in a pure state by paper partition chromatography using 58% methanol solution as developing agent. It was found that 58% methanol was one of the most valuable solvent to separate Capsaicin from impurities such as sterols, fatty acids, waxes and carotenoid pigments. (3) The colorimetric method modifying the Schulte-Kruger's method which consists of measuring the red color produced with diazobenzenesulphonic acid was used. Capsaicin in various species of the genus Capsicum was determined quantitatively with use of Beckman spectrophotometer model DU at $480\;m{\mu}$.

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The Effects of Magnetic Field on TLD Glow Curve (자기장이 열형광선량계의 글로우 곡선에 미치는 영향)

  • Je, Jaeyong;Kang, Eunbo
    • Journal of the Korean Society of Radiology
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    • v.7 no.6
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    • pp.415-418
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    • 2013
  • Thermoluminescent dosimeter utilizes the fact that when irradiated specimen is heated up, some part of the absorbed energy is emitted from the specimen as light with longer wavelength. This research aims at analyzing the glow curves of four TLD-100 exposed to a magnetic field and those of other four TLD-100 not exposed to one by treating them with heat and irradiating them, which are commonly used as thermoluminescent dosimeter, in the same condition. As the result of the experiment, regarding the electrons captured by irradiation, some of the electrons of lower traps were combined with positive holes of valence band through the exposure to a magnetic field, and the peak size decreased by 48%. The reduction in the size of the lower traps caused the TLD-100 exposed to a magnetic field to display a low level of dose. In addition, low traps estimated activation energies are 1.6 eV and 1.5 eV.

Alu Hypomethylation in Smoke-Exposed Epithelia and Oral Squamous Carcinoma

  • Puttipanyalears, Charoenchai;Subbalekha, Keskanya;Mutirangura, Apiwat;Kitkumthorn, Nakarin
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.9
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    • pp.5495-5501
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    • 2013
  • Background: Alu elements are one of the most common repetitive sequences that now constitute more than 10% of the human genome and potential targets for epigenetic alterations. Correspondingly, methylation of these elements can result in a genome-wide event that may have an impact in cancer. However, studies investigating the genome-wide status of Alu methylation in cancer remain limited. Objectives: Oral squamous cell carcinoma (OSCC) presents with high incidence in South-East Asia and thus the aim of this study was to evaluate the Alu methylation status in OSCCs and explore with the possibility of using this information for diagnostic screening. We evaluated Alu methylation status in a) normal oral mucosa compared to OSCC; b) peripheral blood mononuclear cells (PBMCs) of normal controls comparing to oral cancer patients; c) among oral epithelium of normal controls, smokers and oral cancer patients. Materials and Methods: Alu methylation was detected by combined bisulfite restriction analysis (COBRA) at 2 CpG sites. The amplified products were classified into three patterns; hypermethylation ($^mC^mC$), partial methylation ($^uC^mC+^mC^uC$), and hypomethylation ($^uC^uC$). Results: The results demonstrate that the $%^mC^mC$ value is suitable for differentiating normal and cancer in oral tissues (p=0.0002), but is not significantly observe in PBMCs. In addition, a stepwise decrease in this value was observed in the oral epithelium from normal, light smoker, heavy smoker, low stage and high stage OSCC (p=0.0003). Furthermore, receiver operating characteristic (ROC) curve analyses demonstrated the potential of combined $%^mC$ or $%^mC^mC$ values as markers for oral cancer detection with sensitivity and specificity of 86.7% and 56.7%, respectively. Conclusions: Alu hypomethylation is likely to be associated with multistep oral carcinogenesis, and might be developed as a screening tool for oral cancer detection.

A Study on Assessment of MTF Performance and Theoretical Analysis of Convex Trial Lenses (볼록 검안렌즈의 MTF 성능 분석 및 이론적 해석에 대한 연구)

  • Bang, Hyun Jin;Lee, Jong Ung;Son, Byung Ho;Ahn, Kyo Hoon;Choi, Eun Jung
    • Korean Journal of Optics and Photonics
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    • v.24 no.5
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    • pp.217-223
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    • 2013
  • White light MTF(Modulation Transter Function)s of biconvex trial lenses from 10 to 20 diopter (D) were represented as a function of angular frequency and visual acuity, and then they were compared with AIM(Aerial Image Modulation) curves. All of the biconvex trial lenses evaluated in on-axis mode had MTF performance that could resolve Landolt's ring up to visual acuity 2.0. However, in a half field angle of five degrees, the trial lens of 10 diopters was able to resolve Landolt's ring up to visual acuity 0.9, and that of 20 diopter only up to visual acuity 0.8. This means that the trial lenses in the case of a half field angle of five degrees do not have sufficient resolution to measure visual acuity by 1.0.