• Title/Summary/Keyword: 55%Al-Zn

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A Study on the Erosion Behavior of the Ceramic Sprayed Coating Layer in the Molten 55% Al-Zn (용융 55%Al-Zn 중에서 세라믹 용사 피막의 침식 거동에 관한 연구)

  • 강태영;임병문;최장현;김영식
    • Journal of Welding and Joining
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    • v.18 no.3
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    • pp.51-59
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    • 2000
  • Sink roll has been used in molten 55%Al-Zn alloy bath of continuous galvanizing line for sinking and stabilizing working steel strip in molten metal bath. In the process, the sink roll body inevitably build up dross compounds and pitting on the sink roll surface during 55%Al-Zn alloy coated strip production, and the life time of the sink roll is shorten by build up dross compounds and pitting. The present study examined the application of thermally sprayed ceramic coatings method on sink roll body for improving erosion resistance at molten 55% Al-Zn pool. In this experiment, the stainless steels such as STS 316L and STS 430F were used as the substrate materials. The CoNiCr and WE-Co powder were selected as bond coating materials. Moreover $Al_2O_3-ZrO_2-SiO_2 and ZrO_2-SiO_2$ powders selected as the top coating materials. Appearances of the specimens before and after dipping to molten 55%Al-Zn pool were compared and analyzed. As a result of this study, STS430F of substrate, WC-Co of bond spray coatings, $ZrO_2-SiO_2$ power of top spray coatings is the best quality in erosion resistance test at molten 55%Al-Zn pool

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Corrosion Behavior of Zn and Zn-AI Alloy Coated Steels under Cyclic Wet-dry Environments

  • Nishikata, Atsushi;Yadav, Amar Prasad;Tsutsumi, Yusuke;Tsuru, Tooru
    • Corrosion Science and Technology
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    • v.2 no.4
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    • pp.165-170
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    • 2003
  • Atmospheric corrosion behaviors of Zn, Zn-5%Al and Zn-55%A l coated steels have been investigated under cyclic wet-dry environments containing chloride ions. The wet-dry cycle was carried out by alternate exposure to immersion in 0.5 M (or 0.05 M) NaCl solutions and drying at $25^{\circ}C$ and 60 %RH. The polarization resistance $R_p$ and solution resistance $R_s$ were monitored by AC impedance technique. From the obtained $1/R_p$ and $1/R_s$ values, the corrosion rate of the coatings and the Time of Wetness (TOW) were estimated, respectively. Effects of chloride ions and TOW on the corrosion rates of Zn, Zn-5%Al, Zn-55%Al coatings and appearance of red rust (onset of underlying steel corrosion) under wet-dry cycles are discussed on the basis of the corrosion monitoring data.

Formation and Progression of Intermetallic phase on Iron Base Alloy PTA weld overlay in Molten Zn Alloys (용융 Zn 합금에서 Fe합금의 PTA 오버레이 용접 금속간 상의 형성과 진행)

  • Zulkarnain, Zulkarnain;Baek, E.R.
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.95-95
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    • 2009
  • Zinc coatings provide the most effective and economical way of protecting steel against corrosion. There are three types of galvanizing lines typically used in production line in galvanizing industries,Galvanize (GI) coating (Zn-0.1-0.3%Al), Galfan coating (Zn-5%Al), Galvalume(GL) coating (45%Zn-Al). In continuous Galvanizing lines, the immersed bath hardware (e.g. bearings, sink, stabilizer, and corrector rolls, and also support roll arms and snout tip) are subjected to corrosion and wear failure. Understanding the reaction of these materials with the molten Zn alloy is becomes scientific and commercial interest. To investigate the reaction with molten Zn alloys, static immersion test performed for 4, 8, 16, and 24 Hr. Two different baths used for the static immersion, which are molten Zn and molten Zn-55%Al. Microstructures characterization of each of the materials and intermetallic layer formed in the reaction zone was performed using optical microscope, SEM and EDS. The thickness of the reaction layer is examined using image analysis to determine the kinetics of the reaction. The phase dominated by two distinct phase which are eutectic carbide and matrix. The morphology of the intermetallic phase formed by molten Zn is discrete phase showing high dissolution of the material, and the intermetallic phase formed by Zn-55wt%Al is continuous. Aluminum reacts readily with the materials compare to Zinc, forming iron aluminide intermetallic layer ($Fe_2Al_5$) at the interface and leaving zinc behind.

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Codoped ZnO films by a co-spray deposition technique for photovoltaic applications

  • Zhou, Bin;Han, Xiaofei;Tao, Meng
    • Advances in Energy Research
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    • v.2 no.2
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    • pp.97-104
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    • 2014
  • A co-spray deposition technique has been developed to bypass a fundamental limitation in the conventional spray deposition technique, i.e., the deposition of metal oxides from incompatible precursors in the starting solution. With this technique, ZnO films codoped with F and Al have been successfully synthesized, in which F is incompatible with Al. Two starting solutions were prepared and co-sprayed through two separate spray heads. One solution contained only the F precursor, $NH_4F$. The second solution contained the Zn and Al precursors, $Zn(O_2CCH_3)_2$ and $AlCl_3$. The deposition was carried out at $500^{\circ}C$ on soda-lime glass in air. A minimum sheet resistance, $55.4{\Omega}/{\square}$, was obtained for Al and F codoped ZnO films after vacuum annealing at $400^{\circ}C$, which was lower than singly-doped ZnO with either Al or F. The transmittance for the codoped ZnO samples was above 90% in the visible range. This co-spray deposition technique provides a simple and cost-effective way to synthesize metal oxides from incompatible precursors with improved properties for photovoltaic applications.

Production of Heavy Gauged HY-GALUME in Hyundai HYSCO

  • Park, S.J.;Koh, H.S.;Kim, J.G.;Moon, M.B.
    • Corrosion Science and Technology
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    • v.10 no.5
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    • pp.157-161
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    • 2011
  • HY-Galume is a brand name of 55%Al-Zn coated steel sheets produced by Hyundai HYSCO. Heavy gauged HY-Galume having thickness around 2 millimeters is used as a steel casing for the electrical distribution panel in the construction market. It requires a strict surface quality because it is used indoors. In this paper, several troubleshooting experiences in producing heavy gauged HY-Galume are proposed.

Numerical Simulation of Flow and Dross Particle Transfer in a 55% Al-Zn Pot

  • Kim, Hwang Suk;Kim, Jong Gi;Yoon, Seung Chae;Im, Hee Joong;Moon, Man Been
    • Corrosion Science and Technology
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    • v.11 no.3
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    • pp.71-76
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    • 2012
  • Computational fluid dynamics (CFD) is nowadays a powerful and reliable tool for simulating different flow processes and temperature. CFD is used to analyze the various pot geometries and operative variables in 55% Al-Zn pot of CGL. In this research, different strip velocities were assumed and then shown the flow pattern in the pot that was similar in the different strip velocities. Temperature distribution in the pot depended on inductors and inlet strip temperature at the steady condition. Generation of dross particles and transport models were considered to describe dross particles evolution inside the pot. In order to observe dross influence by scrap location, dross particles were generated upon the sink roll. Floating time of dross particles is different by scraper locations above the sink roll.

ZnO/Cu/Al2O3 transparent heaters fabricated by magnetron sputtering (마그네트론 스퍼터링법으로 제조된 ZnO/Cu/Al2O3 투명 면상 발열체 연구)

  • Min, Changheum;Choi, Dooho
    • Journal of Surface Science and Engineering
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    • v.55 no.5
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    • pp.284-291
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    • 2022
  • Herein, we studied ultrathin Cu-layer-based transparent heaters embedded between a ZnO underlayer and an Al2O3 overlayer. The anti-reflecting functions for the ZnO and Al2O3 layers by independently varying the layer thicknesses, with the Cu layer thickness fixed at 8.5 nm. The smallest visible light transmittance of 11.1% was achieved when the overlayer and underlayer thicknesses were 90 and 30 nm, respectively. We conducted electrically driven Joule heating test for the Cu layers having thicknesses of 8.5 nm (Rs: 14.7 Ohm/sq.) and 19 nm (Rs: 3.4 Ohm/sq.). External voltages were increased with an interval of 2 V until irreversible failures occurred at temperatures of ~390 ℃ and 550 ℃, respectively. At each voltage increase before heater failures, the heater exhibited superior thermal response with the heater temperatures reaching over 90% of the final temperatures. The heaters also showed excellent reproducibility when turning on and off the heater repeatedly.

Cut Edge Corrosion of Painted Zn and 55%Al-Zn Coated Steels under Alternate Wetting and Drying

  • Nishikata, A.;Tsuda, T.;Tsuru, T.
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.34-38
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    • 2010
  • Electrochemical study on cut edge corrosion of prepainted Zn coated (GI) and 55%Al-Zn coated (GL) steels has been performed in wet-dry cyclic conditions. Maximum width of delaminated polymer coating from the cut edge for GI and GL specimens was evaluated under wet-dry cyclic conditions. The cyclic tests were carried out for 1000 h by changing of relative humidity, where the salt of NaCl was deposited on the specimen every 48 h. The cut edge corrosion test under NaCl deposit indicated that the delamination of the GL specimen progresses at a higher rate than the GI. The electrochemical corrosion monitoring was also performed under condition of alternate exposure to immersion in NaCl solution and drying at 60%RH and $25^{\circ}C$. On the basis of the results of the delamination tests and electrochemical measurements, the mechanism of cut edge corrosion for GI and GL were discussed.