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A Study on Synthesis and Dispersion of Silver Nano Particle Using Trisodium Citrate (Trisodium Citrate을 이용한 은 나노입자의 합성 및 분산성에 관한 연구)

  • Lee, Jong Jib
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.4
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    • pp.772-779
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    • 2016
  • Silver nanoparticles were prepared by reacting silver nitrate and trisodium citrate in an aqueous solution. Their size and shape were investigated by scanning electron microscopy (SEM). The synthesis was carried with different silver nitrate concentration, addition of TSC, solvent, surfactant, ultrasonication, and dispersing agent. With higher concentration of silver nitrate or TSC, the particles became large or agglomerated. The SEM results showed that the nanoparticles have spherical and pseudospherical shape with a narrow size distribution. The hydrophobic solvent did not affect the dispersibility, but the hydrophilic solvent enhanced it. The addition of HPMC surfactant caused the size to increase (50-100 nm) with non-uniform shapes and partial agglomeration. The dispersibility was significantly improved by ultrasonication for over 3 hours after the addition of a dispersing agent. Complete dispersion was achieved by adding the dispersant, and the nanoparticle sizes were as follows: 30-40 nm (BYK-182) < 42-78 nm (BYK-192) < 51-113 nm (BYK-142). The nanoparticles were 38.45-46.28 nm after the addition of 2-4 wt% TSC in 0.002 M silver nitrate solution.

Eine Structure of Cerebral Ganglion in the Korean Planaria, Dugesia japonica (한국산 플라나리아(Dugesia japonica) 뇌신경절의 미세구조)

  • Chang, Nam-Sub
    • Applied Microscopy
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    • v.29 no.1
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    • pp.57-66
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    • 1999
  • The nervous tissue in the cerebral ganglion of Korean planaria was observed using electron microscope. The obtained results are as follows: A cerebral ganglion is composed of the nerve cells, neurosecretory cells, neuroglial cells and neuropils. The nerve cells are round or ovoidal-shaped cells (diameter, $5{\mu}m$), which has a large ellipsoidal nucleus containing the evenly developed heterochromatin. Their cytoplasms were found to be relatively simple, because of their undeveloped cell organelles. The neurosecretory cells are long and ellipsoid or spindle-shaped cells, where there were found a large ellipsoidal nucleus and cytoplasm filled with secretory granules (diameter, 60 nm). The neuroglial cells were seldom observed. They are spindle-shaped cells (size, $6\times0.8{\mu}m$), which were observed mainly among the nerve fibers. The neuropils are formed by the nerve fibers and nerve endings which are filled with mitochondria, neurotubules and secretory granules of four kinds (high electron dense granules of sizes 75 nm, 50 nm and 37 nm, and electron lucent granule of size 30 nm etc.). These granular vesicles are divided into single vesicle type and compound vesicle type in the nerve terminals, and neuronal synapses were observed to be the axo-dendritic and dendro-dendritic synapse type.

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Electrical and Optical Properties of ITO Thin Films with Various Thicknesses of SiO2 Buffer Layer for Capacitive Touch Screen Panel (정전용량식 터치스크린 패널을 위한 SiO2 버퍼층 두께에 따른 ITO 박막의 전기적 및 광학적 특성)

  • Yeun-Gun, Chung;Yang-Hee, Joung;Seong-Jun, Kang
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.6
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    • pp.1069-1074
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    • 2022
  • In this study, we prepared ITO thin films on the Nb2O5/SiO2 double buffer layer and investigated electrical and optical properties according to the change of SiO2 buffer layer thickness (40~50nm). The ITO thin film fabricated on the Nb2O5/SiO2 double buffer layer exhibited a broad surface roughness with a small value ranging of 0.815 to 1.181nm, and the sheet resistance was 99.3 to 134.0Ω/sq. It seems that there is no problem in applying the ITO thin film to a capacitive touch screen panel. In particular, the average transmittance in the short-wavelength (400~500nm) region and the chromaticity (b*) of the ITO thin film deposited on the Nb2O5(10nm)/SiO2(40nm) double buffer layer showed significantly improved results as 83.58% and 0.05, respectively, compared to 74.46% and 4.28 of ITO thin film without double buffer layer. As a result, it was confirmed that optical properties such as transmittance in the short-wavelength region and chromaticity were remarkably improved due to the index matching effect in the ITO thin film with the Nb2O5/SiO2 double buffer layer.

Photoluminescence and Electroluminescence of Carbazole-based Conjugated Dendritic Molecules

  • Cho, Min-Ju;Kim, Young-Min;Ju, Byeong-Kwon;Choi, Dong-Hoon
    • Journal of Information Display
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    • v.9 no.3
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    • pp.16-22
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    • 2008
  • A novel class of conjugated dendritic molecules bearing N-hexyl-substituted carbazoles as peripheral groups and various conjugative aromatic cores was synthesized through Heck coupling and the Horner-Emmons reaction. A multilayered structure of ITO/PEDOT:PSS (30 nm)/emitting material (50 nm)/BCP (10 nm)/$Alq_3$ (10 nm)/LiF (1 nm)/Al (100 nm) was employed to evaluate the synthesized dendritic materials. The electroluminescence spectrum of the multilayered device made of 3Cz predominantly exhibited blue emissions. Similar emissions were observed in the PL spectra of it's the device's thin film. The multilayered devices made of 3Cz, 3BCz, and 4BCz showed luminance values of 6,250 cd $m^{-2}$ at 24 V, 3,000 cd $m^{-2}$ at 25 V, and 1,970 cd $m^{-2}$ at 36 V, respectively. The smallest molecule, 3Cz, which bore three carbazole peripheral groups, exhibited a blue-like emission with CIE 1931 chromaticity coordinates of x = 0.17 and y = 0.21.

Theoretical analysis on the maximum volume ablation rate for copper ablation with a 515nm picosecond laser (515nm 피코초 레이저를 이용한 구리 어블레이션 공정의 최대 가공율에 대한 이론적 분석)

  • Shin, Dongsig;Cho, Yongkwon;Sohn, Hyonkee;Suh, Jeong
    • Laser Solutions
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    • v.16 no.2
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    • pp.1-6
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    • 2013
  • Picosecond lasers are a very effective tool for micromachining metals, especially when high accuracy, high surface roughness and no heat affected zone are required. However, low productivity has been a limit to broadening the spectrum of their industrial applications. Recently it was reported that in the micromachining of copper with a 1064nm picosecond laser, there exist the optimal pulse energy and repetition rate to achieve the maximum volume ablation rate. In this paper, we used a 515nm picosecond laser, which is more efficient for micromachining copper in terms of laser energy absorption, to obtain its optimal pulse energy and repetition rate. Theoretical analysis based on the experimental data on copper ablation showed that using a 515nm picosecond laser instead of a 1064nm picosecond laser is more favorable in that the calculated threshold fluence is 75% lower and optical penetration depth is 50% deeper.

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Fabrication and optoelectrical properties for cdSSe photoconductive cell by using print/sintering (인쇄/소결 방법에 의한 CdSSe 광전도 셀 제작과 광전기적 특성)

  • Hong, Kwang-Joon;Lee, Sang-Youl
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.46-50
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    • 2004
  • 인쇄/소결 방법으로 가시영역에서 광감도가 매우 큰 CdSSe 다결정 후막을 만들고 이를 이용하여 광전도 젤을 제작하였다. 후막의 낱알 크기는 $5{\mu}m$ 정도이였다. 광전도 셀은 소결 촉진제로 첨가한 $cucl_2$ 양이 CdSSe 1 g 당 3.06~0.10 mg 정도이변 감도, 광전류와 암전류의 비율이 각각 0.7과 $10^5$ 이상을 나타내었고, Cds 와 CdSe 의 질량비가 1:0, 9:1, 8:2, 7:3, 6:4, 5:5일 때 응답파장은 각각 500nm, 520nm, 540nm, 570nm, 620nm, 660nm였다. 또한 주파수 특성을 나타내는 응답시간은 오름시간과 감쇠시간이 각각 30관 20ms 정도 이였으며 최대허용 소비 전력은 80mw 이상이었다. 이상과 같이 인쇄/소결 방법으로 제작된 광전도 셀은 $cucl_2$ 양이 CdSSe 1g 당 0.06~0.10 mg 정도 주입되면 센서로써 좋은 특성을 나타내었다.

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Blue Organic Light-Emitting Diodes Based on Triphenylene Derivatives

  • Kim, Seul Ong;Jang, Heung Soo;Lee, Seok Jae;Kim, Young Kwan;Yoon, Seung Soo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2267-2270
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    • 2013
  • A series of blue fluorescent emitters based on triphenylene derivatives were synthesized via the Diels-Alder reaction in moderate yields. The electronic absorption and emission characteristics of the new functional materials were affected by the nature of the substituent on the triphenylene nucleus. Multilayered OLEDs were fabricated with a device structure of: ITO/NPB (50 nm)/EML (30 nm)/Bphen (30 nm)/Liq (2.0 nm)/Al (100 nm). All devices showed efficient blue emissions. Among those, a device using 1 gives the best performances with a high brightness (978 cd $m^{-2}$ at 8.0 V) and high efficiencies (a luminous efficiency of 0.80 cd/A, a power efficiency of 0.34 lm/W and an external quantum efficiency of 0.73% at 20 $mA/cm^2$). The peak wavelength of the electroluminescence was 455 nm with CIEx,y coordinates of (0.17, 0.14) at 8.0 V.

The changed diffraction efficiency depend on annealing of amorphous chalcogenide films (비정질 칼코게나이드 박막의 열처리에 따른 회절효율 변화)

  • Lee, Ki-Nam;Yeo, Cheol-Ho;Sin, Kyung;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.590-593
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    • 2004
  • 본 논문에서는 $As_{40}Ge_{10}Se_{15}S_{35}$ (300nm)박막과 $As_{40}Ge_{10}Se_{15}S_{35}$ (300nm)/Ag(20nm)박막에 홀로그래피 격자를 형성시킨 후 Tg 온도$(240^{\circ}C)$를 기준으로 하여 유리질 천이온도(Tg) 온도 이하 $(190^{\circ}C)$와 이상$(270^{\circ}C)$에서 열처리 시킨 후의 회절효율 변화를 알아보았다. $As_{40}Ge_{10}Se_{15}S_{35}$ (300nm) 박막의 경우 $190^{\circ}C$ : 50%, $240^{\circ}C$ : 약80%, $270^{\circ}C$ : 약 98%의 회절효율 감소가 일어났으며 $As_{40}Ge_{10}Se_{15}S_{35}$(300nm)/Ag(20nm)박막에서는 Tg 온도 이하 즉 $190^{\circ}C$, $240^{\circ}C$ 에서는 회절효율의 변화가 없었으나 Tg온도 이상인 $270^{\circ}C$에서는 약 1.5배 증가한 회절효율을 나타내었다.

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Rapid detection microfluidic immunosensor for food safety using static light scattering

  • Kim, Kee-Sung
    • 한국환경농학회:학술대회논문집
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    • 2009.07a
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    • pp.187-199
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    • 2009
  • We present real.time, rapid detection of Mycoplasma pneumonia in phosphate buffered saline (PBS) inside a Y.channel polydimethylsiloxane (PDMS) microfluidic device by means of optical fiber monitoring of latex immunoagglutination. The latex immunoagglutination assay was performed with serially diluted Mycoplasma pneumonia solutions using highly carboxylated polystyrene particles of 390nm and 500nm diameter conjugated with monoclonal anti. Mycoplasma pneumonia . Proximity optical fibers were located around the viewing cell of the device, which were used to measure the increase in 45${\b{o}}$ forward light scattering of the immunoagglutinated particles. The detection limit was less than 50 $pgml^{-1}$ both for 390nm and 500nm microspheres with the detection time less than 90 seconds.

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ITiO films prepared by magnetic null discharge sputtering for DSCs application (자기중성방전 스퍼터에 의한 DSCs용 ITiO 박막제작)

  • Han, Deok-Woo;Endrowednes, Kuantama;Kwak, Dong-Joo;Sung, Youl-Moon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1150-1151
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    • 2008
  • Titanium-doped indium oxide (ITiO) films were prepared on soda-lime glass substrate using a magnetic null discharge (MND) sputter source. The ITiO thin films containing 10 wt.% Ti showed the minimum resistivity of ${\rho}=5.5{\times}10^{-3}{\Omega}cm$. The optical transmittance increases from 70% at 450 nm to 80% at 700 nm in visible spectrum. The surface roughness of the sample showed a change from 10 nm to 50 nm. The ITiO film used for TCO layer of DSCs exhibited an energy conversion efficiency of about 3.8 % at light intensity of 100 $mW/cm^2$.

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