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Hydrogen Storage Characteristics of Melt Spun Mg-23.5Ni-xCu Alloys and Mg-23.5Ni-2.5Cu Alloy Mixed with $Nb_{2}O_{5}$ and $NbF_{5}$

  • Hong, Seong-Hyeon;Kwon, Sung-Nam;Song, Myoung Youp
    • Korean Journal of Metals and Materials
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    • v.49 no.4
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    • pp.298-303
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    • 2011
  • Mg-23.5 wt%Ni-xwt%Cu (x = 2.5, 5 and 7.5) samples for hydrogen storage were prepared by melt spinning and crystallization heat treatment from a Mg-23.5 wt%Ni-5 wt%Cu alloy synthesized by the gravity casting method. They were then ground under $H_2$ to obtain a fine powder. Among these samples the Mg-23.5Ni-2.5Cu sample had the highest hydriding and dehydriding rates after activation. The Mg-23.5Ni-2.5Cu sample absorbed 3.59 and 4.01 wt%H for 10 and 60 min, respectively, at 573K under 12 bar $H_{2}$. The activated 88(87.5Mg-10Ni-2.5Cu)-$5Nb_{2}O_{5}-7NbF_{5}$ sample absorbed 2.93 wt%H for 10 min, and 3.14 wt%H for 60 min at 573K under 12 bar $H_{2}$.

Reaction of Nitrous Acid on 5-Aminopyrimidine (Ⅳ) The Synthesis of 5-Cyano-and 5-Carboxypyrimidines (5-Aminopyrimidine에 대한 아질산의 반응 (Ⅳ) 5-Cyano 및 5-CarboxyPyrimidine 유도체의 합성)

  • Chang Sae Hee;Kim Jae Soon;Huh Tae Soung
    • Journal of the Korean Chemical Society
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    • v.13 no.2
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    • pp.177-180
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    • 1969
  • 5-Cyanopyrimidine derivatives were synthesized starting from 5-aminopyrimidine derivatives through the extended Sandmeyer reaction, and then these compounds were hydrolyzed to obtain pyrimidine-5-carboxylic acids. According to this procedure, 5-cyanopyrimidine derivatives and pyrimidine-5-carboxylic acid derivatives have been prepared in 62% and 65% yields, respectively, without any difficulties in removing impurities.

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Research on the Trend in Private 5G Introduction in a Foreign Country (해외 주요국의 Private 5G 도입 동향)

  • Min, Dae Hong;Shin, Yong Hee;Ahn, Jee Young
    • Electronics and Telecommunications Trends
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    • v.35 no.5
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    • pp.139-150
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    • 2020
  • Fifth-generation (5G) wireless communication supports low latency of up to 1 ms or less, 20 Gbps of data rate, and more than 1 million connections. With these technical advantages, machines and equipment can be precisely adjusted, allowing 5G to be applied to industrial applications. To expand the industrial application of 5G wireless communications, major countries have introduced dedicated 5G, allowing specific companies to build and use 5G directly. Germany, UK, and Japan allocate 100 MHz, 416 MHz, and 1,200 MHz, respectively, of bandwidth dedicated to 5G. Companies with local licenses from the government are expected to accelerate the application of 5G at a low cost and low-frequency range. Therefore, Korea should introduce private 5G to foster 5G-related industrial ecosystems and successfully implement the fourth industrial revolution.

5-axis machining with selective three-axis controlled CNC machine (선택적 3축 제어기를 이용한 5축 가공연구)

  • 김성구;서석환;이정재
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.11a
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    • pp.683-689
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    • 1996
  • 5축 가공기는 가공중의 공구자세 변화를 요구하는 복잡한 산업형상의 가공, 혹은 경사 가공을 통한 표면조도 향상등의 목적으로 채용되는 첨예의 공작기계로서 이를 지원하는 CAM연구가 활발히 이루어지고 있다. 그러나, 산업현장에서 흔히 5축 가공기로 일컬어지는 상당수의 5축 가공기는 기구축은 5축을 가지나, 동기제어 축수는 3측인 “선택적 3/5축 가공기”의 형태로서 진정한 의미의 5축가공기와는 근본적으로 다르다. 5축 동기제어를 지원하는 CAM연구는 부분적으로 연구 개발된 상태이나, 선택적 3/5축을 지원하는 CAM 이론은 연구된 바 없으며, 이에 따라 현장에서는 공작물의 셋업을 변경시키는 소위 자동 인덱싱 방식으로 활용하고 있는 실정이다. 본 연구팀에서는 선택적 3/5축 가공기에서 5축 가공을 실현할 수 있는 공구경로 산출 및 제어알고리즘을 개발하고 있으며, 본 논문에서는 (5축 가공 대비) 선택적 3/5축 가공문제의 이론적 특성과 경사가공을 수행하기 위한 알고리즘을 소개하고 시뮬레이션을 통하여 유효성을 보인다.

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Evaluation of Microwave Dielectric Properties in $(Pb_{0.5}Ca_{0.5})(Fe_{0.5}Ta_{0.5})O_3$ Ceramics by the Dielectric Mixing Rule (유전체 혼합 법칙을 이용한 $(Pb_{0.5}Ca_{0.5})(Fe_{0.5}Ta_{0.5})O_3$세라믹스의 마이크로파 유전특성 평가)

  • 박흥수;윤기현;김응수
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.240-246
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    • 2000
  • The microwave dielectric properties of the complex perovskite (Pb0.5Ca0.5)(Fe0.5Ta0.5)O3 ceramics were investigated with the porosity and the dielectric mixing rule. Assuming that the specimens were mixtures of real dielectrics and pores, with 3-0 connectivity, the ionic polarizabilities modified by Maxwell's equation were more close to the theoretical values rather than those modified by Wiener's equation in porous specimens. The theoretical dielectirc loss were obtained with the infrared reflectivity spectra from 50 to 4000cm-1, which were calculated by Kramers-Kronig analysis and classical osciallator model. The relative tendency of dielectric loss calculated from the theoretical value and Maxwell's equation in the specimens with different porosities was in good agreement with the one by the post resonant method.

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Development of Frequency Converter for 2.5/3.5/5.5 GHz m-WiMAX System Wireless Measurement using WiBro Network (WiBro 망을 이용한 2.5/3.5/5.5 GHz m-WiMAX 시스템 무선 측정용 주파수 변환기 개발)

  • Kim, Se-Hwan;Chun, Kuk-Jin
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.48 no.2
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    • pp.1-5
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    • 2011
  • For measuring quad-band module system using WiBro network, frequency converter was developed. The size of the fabricated frequency converter is $3.1cm{\times}3.1cm{\times}0.4cm$. Noise figure of the receiver part of the frequency converter was 2.62 ~ 3.45 dB, EVM of that is -37.5 dB ~ -34.5 dB. And EVM of the transmission part was -42.5 ~ -35.5 dB. Quad-band module was fabricated with the developed frequency converter. Testing the quad-band module in 2.3 GHz WiBro network results the excellent internet connection for 2.5 GHz, 3.5 GHz and 5.5 GHz band.

A Study on Anthropometric Data of 5 th Grade Students II. Comparisons Between Underweight and Overweight Group by BMI (국교 5년생의 성장발달에 관한 조사 연구 II. BMI 에 따른 저체중과 과체중의 요인분석)

  • 문현경
    • Journal of Nutrition and Health
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    • v.20 no.6
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    • pp.405-410
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    • 1987
  • Study population was described at the previously published paper(23). Body Mass Index of 10751, 5th grade students from nation-wide were calculated . From this distribution lowest 10% and highest 10% were selected as group 1 and group 5, respectively. In this paper, between group 1 and group 5 anthropometric data, demographic data and other health related factors were compared. 1) Using Japanese criteria for obesity, the prevalence for obesity at 5 th grade was 5.8% at nation wide and 7.8% at urban area. 2) The proportion of students who skipped breakfasts everyday was 5.8% of whole student surveyed and 8.4% for group 5. The proportion of students who took medicine for health was 29.4% for group and 22.5% for group 5. 3) The students who are at group 5 had larger height and weight velocity than other groups. Group 5 had large increase of BMI by increasing grade, but group 1 had almost no change. 4) In physical fitness examination, group 3 who mean BMI was in the highest class than other groups 5 was in low class.

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Mechanical Properties and Thermal Stability of Ti0.5Al0.5N/CrN Nano-multilayered Coatings (Ti0.5Al0.5N/CrN 나노 다층 박막의 기계적 성질과 열적 안정성)

  • Ahn, Seung-Su;Park, Jong-Keuk;Oh, Kyung-Sik;Chung, Tai-Joo
    • Journal of Powder Materials
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    • v.27 no.5
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    • pp.406-413
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    • 2020
  • Ti0.5Al0.5N/CrN nano-multilayers, which are known to exhibit excellent wear resistances, were prepared using the unbalanced magnetron sputter for various periods of 2-7 nm. Ti0.5Al0.5N and CrN comprised a cubic structure in a single layer with different lattice parameters; however, Ti0.5Al0.5N/CrN exhibited a cubic structure with the same lattice parameters that formed the superlattice in the nano-multilayers. The Ti0.5Al0.5/CrN multilayer with a period of 5.0 nm exceeded the hardness of the Ti0.5Al0.5N/CrN single layer, attaining a value of 36 GPa. According to the low-angle X-ray diffraction, the Ti0.5Al0.5N/CrN multilayer maintained its as-coated structure up to 700℃ and exhibited a hardness of 32 GPa. The thickness of the oxidation layer of the Ti0.5Al0.5N/CrN multilayered coating was less than 25% of that of the single layers. Thus, the Ti0.5Al0.5N/CrN multilayered coating was superior in terms of hardness and oxidation resistance as compared to its constituent single layers.

Iodine Sorption Complexes of Partially Cobalt(II) Exchanged Zeolite A. Two Crystal Structures of $Co_{3.5}Na_5Si_{12}Al_{12}O_{48}\cdot2.5I_2\;and\;Co_{3.5}Na_5Si_{12}Al_{12}O_{48}\cdot5.0I_2$

  • Kim, Yang;Lee, Suk-Hee;Seff, Karl
    • Bulletin of the Korean Chemical Society
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    • v.10 no.5
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    • pp.426-430
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    • 1989
  • Two crystal structures of iodine sorption complexes of dehydrated partially Co(Ⅱ )-exchanged zeolite A, $Co_{3.5}Na_5-A{\cdot}xI_2$, x = 2.5 and 5.0, have been determined by single crystal X-ray diffraction techniques. Both structures were solved and refined in cubic space group, Pm3m at $21(1)^{\circ}C$. The structures of $Co_{3.5}Na_5-A{\cdot}2.5I_2$(a = 12.173(1) ${\AA}$) and $Co_{3.5}Na_5-A{\cdot}5.0I_2$(a = 12.130(1) ${\AA}$) were refined to the final error indices, $R_1$ = 0.081 and $R_2$ = 0.077 with 261 reflections and $R_1$ = 0.103 and $R_2$ = 0.112 with 225 reflections, respectively, for which I>3${\sigma}$(I). In both structures, 3.5 $Co^{2+}$ ions and 4.5 $Na^+$ ions per unit cell lie at two crystallographically different 6-ring positions. 0.5 $Na^+$ ion lines in an 8-oxygen ring plane. Dehydrated $Co_{3.5}Na_5$-A sorbs 2.5 iodine molecules per unit cell at $70^{\circ}C$ (vapor pressure of $I_2$ is ca. 8.3 torr) within 30 minutes and 5 iodine molecules per unit cell at $80^{\circ}C$ (vapor pressure of $I_2$ is ca. 14.3 torr) within 24 hours. Each iodine molecule makes a close approach, along its axis to framework oxygen atom with I-I-O = $175^{\circ}$.

Factor Structure of the Korean-Child Behavior Checklist 1.5-5 Dysregulation Profile in Infants and Toddlers With Mental Disorders and the Difference Among Mental Disorders (정신장애 영유아에 대한 K-CBCL 1.5-5 (Korean-Child Behavior Checklist 1.5-5) 조절곤란 프로파일의 요인구조와 정신장애 간 차이검증)

  • Kyung, Hye Min;Ha, Eun Hye
    • Therapeutic Science for Rehabilitation
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    • v.12 no.1
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    • pp.37-49
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    • 2023
  • Object : This study aimed to identify the factor structure of Korean-Child Behavior Checklist 1.5-5 Dysregulation Profile (K-CBCL 1.5-5 DP) in infants and toddlers with mental disorders and verify differences in K-CBCL 1.5-5 DP among the diagnosis groups. Methods : The participants were 265 mothers of infants and toddlers with mental disorders who completed K-CBCL 1.5-5 DP. The data was analyzed using AMOS 25.0 and SPSS 25.0. Results : First, the bifactor model was the most suitable for the factor structure of the K-CBCL 1.5-5 DP. Second, there were significant differences among the diagnosis groups, such as communication disorders, pervasive developmental disorders, emotional disorders, and developmental delays. It was confirmed that the pervasive developmental disorder and emotional disorder groups showed significantly higher dysregulation compared with the communication disorder group. Conclusion : This study confirmed that infants and toddlers had dysregulation problems. Using the bifactor model, the multidimensional nature of the K-CBCL 1.5-5 DP was assessed. It was also meaningful that dysregulation could contribute to onset and deepening of symptoms of pervasive developmental disorders and emotional disorders in infancy.