• Journal of the Mineralogical Society of Korea
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• v.22 no.4
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• pp.343-352
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• 2009

High-resolution Solid-state NMR provides element specific and quantitative information and also resolves, otherwise overlapping atomic configurations in multi-component non-crystalline silicates. Here we report the preliminary results on the effect of composition on the structure of CMAS (CaO-MgO-$Al_2O_3-SiO_2$) silicate glasses, as a model system for basaltic magmas, using the high-resolution 1D and 2D solid-state NMR. The $^{27}Al$ MAS NMR spectra for the CMAS silicate glasses show that four-coordinated Al is predominant, demonstrating that $Al^{3+}$ is network forming cation. The peak position moves toward lower frequency about 4.7 ppm with increasing $X_{MgO}$ due to an increase in $Q^4$(4Si) fraction with increasing Si content, indicating that Al are surrounded only by bridging oxygen. $^{17}O$ MAS NMR spectra for $CaAl_2SiO_6$ and $CaMgSi_2O_6$ glasses qualitatively suggest that NBO fraction in the former is smaller than that in $CaMgSi_2O_6$ glasses. As $^{17}O$ 3QMAS NMR spectrum of model quaternary aluminosilicate glass resolved distinct bridging and non-bridging oxygen environments, atomic structure for natural magmas can also be potentially probed using high-resolution 3QMAS NMR.

• The Korean Journal of Rheology
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• v.9 no.4
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• pp.133-139
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• 1997

PC(polycarbonate), SAN(styren-acrylonitrile)공중합체, 그리고 충격 보강제를 근간 으로 하는 다성분계 고분자 블렌드에 대하여 고정된 사출조건에서 블렌드의 조성에 따른 weldline강도의 변화를 조사하였다. 블렌드의 전체적인 함량에 있어서 PC가 그함량이 높아 연속상이 되는 경우가 비교적 높은 weldline강도를 나타내지만 PC함량이 감소함에 따라서 급격한 저하가 발생하여 채-continuity의 성향이 강한 50%부근에서 최소 값을 보였다. PC 함량이 고정되었을 때에는 분산상의 점도가 증가할수록 weldline 강도가 향상되었는데 이는 weldline의 형성 시에 발생하는 분수형 흐름장에 의한 분산상의 배향이 억제되어 외부 응력 에 대하여 균일하게 대응할수 있는 형태학을 유지하는 효과로 설명된다. 충격보강제의 변경 과 상용화제의 적용으로부터 얻은 결과를 종합하여 볼 때 다성분계 고분자 블렌드의 weldline강도는 구성성분간의 상용성 뿐만 아니라 유변학적인 조건이 만족되어야 효과적으 로 향상될수 있다.

• Journal of the Korea Concrete Institute
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• v.20 no.4
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• pp.439-449
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• 2008

Mineral admixtures are used to improve the quality of concrete and to develop sustainability of concrete structures. Supplementary cementitious materials (SCM), such as silica fume (SF), granulated blast furnace slag (GGBS) and pulverized fly ash (PFA), are gradually recognized as useful mineral admixture for producing high performance concrete. The study on ternary blended concrete utilizing mainly three major mineral admixtures is limited and the study on durability and chloride induced corrosion resistance of ternary blended concrete is very few. This study examines the durability characteristics of the ternary blended concrete composed of different amount of the SCM with ordinary Portland concrete and the study experimentally focuses on corrosion resistance evaluation of ternary blended concrete subjected to chloride attack. In this study, 50% replacement ratio of mineral admixture to OPC was used, while series of combination of $20{\sim}40%$ GGBS, $5{\sim}15%$ SF and $10{\sim}45%$ PFA binder were used for chloride corrosion resistance test. This study concerned the durability properties of the ternary blended concrete including the corrosion resistance, chloride binding, chloride transport and acid neutralization capacity. It was found that the ternary blended concrete utilizing the SCM densified the pore structures to lower the rate of chloride transport. Also, increased chloride binding and buffering to acid were observed for the ternary blended concrete with chlorides in cast.

• KSBB Journal
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• v.17 no.2
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• pp.148-152
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• 2002

The extraction of volatile essential oil using supercritical carbon dioxide with 2%(v/v) ethanol and non-ethanol was performed in a semi-continuous flow extractor at the range of pressures and temperatures 6.9 to 17.2 MPa and 30 to 45$^{\circ}C$, respectively. When ethanol was added to the co-solvent, the solubility of volatile essential oils was increased up to 90% over the neat CO$_2$ value. The most efficiency of extraction of the voilatile essential oils was achieved at 13.8㎫ and 40$^{\circ}C$ by supercritical carbon dioxide with entrainer from Citrus junos peel.

• Journal of the Korean Society of Food Science and Nutrition
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• v.22 no.5
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• pp.543-551
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• 1993

This study was designed to observe the effects of the feeding mixed with the sardine oil containing n-3 EPA, DHA and the safflower oil in which rich n-6 linoleic acid on the improvement of the lipids and on the fatty acid matabolism of serum lipoprotein in the dietary hyperlipidemic rats. Experimental oils mixed with 16% butter(control group) and 8% butter+8% olive oil, 8% butter and various level of sardine and safflower oils were administered to the male rats of the Sprague Dawley for 4 weeks. Concentrations of total cholesterol in serum lipoproteins were highest in the LDL, followed by VLDL, HDL and chylomicron components. in the triglyceride concentrations, chylomicron were highest, and much VLDL, LDL, HDL components. There were highest in the HDL, followed by LDL, VLDL and chylomicron in phospholipid concentrations of serum lipoproteins. Concentrations of total cholesterol, triglyceride and phospholipid in serum lipoprotein were lower in the other groups than in the control groups, and particularly, lowest in the group 5(4% sardine oil+4% safflower oil). From this results, the feeding equal quantity mixed oil with n-3 PUFA rich sardine oil and n-6 PUFA rich safflower oil were effective on the improvement of the lipid composition in the serum lipoprotein. It might be due to the effects of appropriate rations of P/S, 0.85 and n-6/n-3P, 2.85 in the test lipids. In the fatty acid composition of serum lipoprotein, ratio of P/S and n-3/n-6P were influenced from the fatty acid compositions of the mixed test lipids. And EPA contents were higher in the chylomicron components.

• Journal of the Korean Wood Science and Technology
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• v.43 no.4
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• pp.494-503
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• 2015

This study was focused on the comparison of the variations in the yield and chemical composition of Chamaecyparis obtusa leaf oil obtained under different pressure conditions of the supercritical carbon dioxide extraction (SCE), and by hydro-distillation. SCE was carried out varying the pressure in the range of 100~400 bar at $40^{\circ}C$. The chemical composition of C. obtusa leaf oils was determined by gas chromatography-mass spectroscopy (GC-MS) analysis. The maximum yield of 4.4% (relative to the initial mass of oven dry mass) was obtained in the extraction under 300 bar pressure, which was higher than that of the hydro-distillation method (1.9%). The contents of sesquiterpenes in the extracts obtained by the SCE were higher than those of the essential oils of C. obtusa by the hydro-distillation. The sesquiterpenes in the SCE extracts made up approximately 39%~46% of the total, followed by monoterpenes, diterpene, and lignan. The contents of each constituent in the supercritical carbon dioxide extracts were varied on the extraction pressure. Therefore, these results showed that the extraction condition of SCE had significant effect on the yield of C. obtusa oils and its chemical composition.

• Conservation Science in Museum
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• v.28
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• pp.89-108
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• 2022

Among about 500,000 characters in metal types in National Museum of Korea, this study conducts a statistical analysis of 62 metal types from the early Joseon Dynasty, including 33 gabinja (甲寅字) types and 29 eulhaeja (乙亥字) Hangeul types by examining the shape, measuring the specific gravity, and identifying the components based on previously-studied Joseon metal types. Among them, 33 gabinja types and 24 eulhaeja types were made of two-component bronze (copper and tin) (Group A), and four eulhaeja types were produced with three-component bronze (copper, tin and lead). (Group B), and one eulhaeja type was created with two-component bronze (copper and tin) with a high tin content (Group C). By comparing with imjinja (壬辰字) types of the late Joseon Dynasty based on multiple statistical analyses of type components, this study confirms that late-Joseon types have low copper content and high zinc and lead content, and therefore it may be possible to distinguish between the types of early and late Joseon Dynasty.

• 발명특허
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• v.14 no.1 s.155
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• pp.26-27
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• 1989

일본 횡하전기㈜는 각종 공업계기$\cdot$계측기$\cdot$정보기기$\cdot$분석계$\cdot$성분계 등 항공기기의 제조 및 판매 업체로서 자본금 137억7천8백만엔에 종업원 6천3백명의 대기업. 특허부문은 기술개발부문산하 특허부이다. 특허부원은 30명으로 특허부장 산하에 기술 1$\cdot$2팀 18명, 정보팀 4명, 사무팀 7명 등이 있다. 또 기술팀은 주로 연구개발담당팀과 사무부 기술담당팀으로 구성되어 있다.

• 발명특허
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• v.14 no.6 s.160
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• pp.72-73
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• 1989

일본 횡하전기㈜는 각종 공업계기$\cdot$계측기$\cdot$정보기기$\cdot$분석계$\cdot$성분계 및 항공기기의 제조 및 판매 업체로서 자본금 137억 7천8백엔에 종업원 6천3백명의 대기업, 특허부문은 기술개발부문 산하특허부이다. 특허부원은 30명으로 특허부장 산하에 기술 1.2팀 18명, 정보팀 4명, 사무팀 7명 등이 있다. 또 기술팀은 주로 연구개발담당 팀과 사무부 기술담당 팀으로 구성되어 있다.

• Journal of the Korea Concrete Institute
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• v.25 no.4
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• pp.457-465
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• 2013

This study discussed the influence of mixtures and curing conditions on the development of strength and microstructure of RPC using ternary pozzolanic materials. Through pilot experiment, various RPC was manufactured by adding single or mixed ternary pozzolanic materials such as silica fume, blast furnace slag and fly ash by mass of cement, up to 0~65%, and cured by using 4 types of method which are water and air-dried curing at $20^{\circ}C$, steam and hot-water curing at $90^{\circ}C$. The results show that the use of ternary pozzolanic materials and a suitable curing method are an effective method for improving development of strength and microstructure of RPC. The unit volume of cement was greatly reduced in RPC with ternary pozzolanic materials and unlike hydration reaction in cement, the pozzolanic reaction noticeably contributes to a reduction in hydration heat and dry shrinkage. A considerable improvement was found in the flexural strength of RPC using ternary pozzolanic materials, and then the utilization of a structural member subjected to bending was expected. The X-ray diffractometer (XRD) analysis and Scanning Electronic Microscope (SEM) revealed that the microstructure of RPC was denser by using the ternary pozzolanic materials than the original RPC containing silica fume only.