• Title/Summary/Keyword: 3D FE

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Test of Superoxide Dismutase Characteristics and Antioxidant Activity in Perilla Leaves (들깨잎에 함유된 Superoxide Dismutase의 특성 및 항산화 활성 검정)

  • Chung, Ill-Min;Yun, Song-Joong;Kim, Jung-Tae;Gwag, Jae-Gyun;Sung, Jae-Duck;Suh, Hyung-Soo
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.4
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    • pp.504-511
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    • 1995
  • This study was conducted to investigate the superoxide dismutase (SOD) characteristics and antioxidant activity by nonenzymatic(Fe$^{2+}$/Ascorbate) and Fe$^{3+}$-ADP/NADPH method in perilla(Perilla frutescens var. japonica Hara.) and jaso(Perilla frutescens Briton var. acuta Kudo.) leaves. The characteristics were evaluated by the nitro blue tetrazolium reduction method. Perilla leaves contained three or four major SODs depending on the varieties. The inhibitor test indicated that the Perilla leaves contained two Cu /ZnSODs and one or two FeSODs, but Jaso leaves have only Cu/ZnSOD. However, no varietal differences were detected in the Cu /ZnSOD isozyme patterns. FeSODs, however, showed different varietal isozyme patterns through the different combinations of the two FeSOD isozymes. Among MeOH extractes, "mil yang 2" showed very strong antioxidant activity. Relatively large differences in the levels of SOD and antioxidant activity detected in the Perilla varietites. There was significantly different in the comparison between perilla leaves and red jaso leaves.s.etween perilla leaves and red jaso leaves.

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Robust and Efficient 3D Model of an Electromagnetic Induction (EMI) Sensor

  • Antoun, Chafic Abu;Perriard, Yves
    • Journal of international Conference on Electrical Machines and Systems
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    • v.3 no.3
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    • pp.325-330
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    • 2014
  • Eddy current induction is used in a wide range of electronic devices, for example in detection sensors. Due to the advances in computer hardware and software, the need for 3D computation and system comprehension is a requirement to develop and optimize such devices nowadays. Pure theoretical models are mostly limited to special cases. On the other hand, the classical use of commercial Finite Element (FE) electromagnetic 3D models is not computationally efficient and lacks modeling flexibility or robustness. The proposed approach focuses on: (1) implementing theoretical formulations in 3D (FE) model of a detection device as well as (2) an automatic Volumetric Estimation Method (VEM) developed to selectively model the target finite elements. Due to these two approaches, this model is suitable for parametric studies and optimization of the number, location, shape, and size of PCB receivers in order to get the desired target discrimination information preserving high accuracy with tenfold reduction in computation time compared to commercial FE software.

High-temperature Oxidation of Fe-2%Ni Alloys (Fe-2%Ni 합금의 고온 산화)

  • Lee, Dong Bok;Jung, Jae Ok;Park, Soon Yong;Cho, Gyu Chul;Xiao, Xiao;Kim, Min Jung
    • Journal of Surface Science and Engineering
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    • v.51 no.2
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    • pp.104-109
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    • 2018
  • Fe-2 wt.%Ni alloys were fabricated by metal powder injection molding, and their oxidation behavior at $600-700^{\circ}C$ for 30 h in air was studied in order to find the effect of the small addition of Ni in the iron matrix on the high-temperature oxidation. Oxide scales that formed after oxidation consisted primarily of $Fe_2O_3$, where microscopic voids were scattered. Nickel was segregated initially at the scale/matrix interface, and later at the lower part of the $Fe_2O_3$ scale. At $600^{\circ}C$, Fe-2wt.%Ni alloys oxidized parabolically initially, and linearly after 15 h. At $650-700^{\circ}C$, they oxidized linearly from the initial period. Although Fe-2wt.%Ni alloys oxidized slower than pure iron, their oxidation rates were relatively fast.

Temperature Dependent Cation Distribution in Tb2Bi1Ga1Fe4O12

  • Park, Il-Jin;Park, Chu-Sik;Kang, Kyoung-Soo;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.13 no.3
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    • pp.110-113
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    • 2008
  • In this study, heavy rare earth garnet $Tb_2Bi_1Ga_1Fe_4O_{12}$ powders were fabricated by a sol-gel and vacuum annealing process. The crystal structure was found to be single-phase garnet with a space group of Ia3d. The lattice constant $a_0$ was determined to be 12.465 ${\AA}$. From the analysis of the vibrating sample magnetometer (VSM) hysteresis loop at room temperature, the saturation magnetization and coercivity of the sample are 7.64 emu/g and 229 Oe, respectively. The N$\acute{e}$el temperature($T_N$) was determined to be 525 K. The M$\ddot{o}$ssbauer spectrum of $Tb_2Bi_1Ga_1Fe_4O_{12}$ at room temperature consists of 2 sets of 6 Lorentzians, which is the pattern of single-phase garnet. From the results of the M$\ddot{o}$ssbauer spectrum at room temperature, the absorption area ratios of Fe ions on 24d and 16a sites are 74.7% and 25.3%(approximately 3:1), respectively. These results show that all of the non-magnetic Ga atoms occupy the 16a site by a vacuum annealing process. Absorption area ratios of Fe ions are dependent not only on a sintering condition but also on the temperature of the sample. It can then be interpreted that the Ga ion distribution is dependent on the temperature of the sample. The M$\ddot{o}$ssbauer measurement was carried out in order to investigate the atomic migration in $Tb_2Bi_1Ga_1Fe_4O_{12}$.

High Pressure X-ray Diffraction Study of LiFePO4/C-olivine-like Phase (LiFePO4/C-유사 감람석 결정구조에 대한 고압 X-선회절연구)

  • Hwang, Gil-Chan;Kim, Young-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.1
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    • pp.35-44
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    • 2013
  • Synthetic carbon-coated olivine-like structured lithium iron phosphate ($Li^+Fe^{2+}(PO_4)^{3-}/C$) powder composites were compressed up to 35.0 GPa in the symmetrical diamond anvil cell at room temperature. Bulk modulus of $LiFePO_4/C$ was determined to be $130.1{\pm}10.3$ GPa. New peak appears at the d-spacing of 3.386 ${\AA}$ above 18 GPa, and another new one at 2.854 ${\AA}$ around 35 GPa. The crystallographic symmetry of the sample (i.e. orthorhombic) is apparently retained up to 35 GPa as no clear evidence for the phase transition into spinel structure has been observed. The pressure-induced volume change in the M1 site ($Li^+O_6$) is more significant than those in M2($Fe^{2+}O_6$) and $PO_4$ tetrahedral sites.

Correlation Effect on the Electronic Structures of {Li, Na}FeAs ({Li, Na}FeAs 물질의 강상관계 전자 구조)

  • Ji, Hyo-Seok;Lee, Geun-Sik;Shim, Ji-Hoon
    • Progress in Superconductivity
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    • v.14 no.1
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    • pp.11-16
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    • 2012
  • Based on fully self-consistent dynamical mean field theory (DMFT) method, we investigate electronic structure and Fermi surface nesting property of LiFeAs and NaFeAs, focusing on the correlation effect of iron 3d orbital. For LiFeAs, good nesting property by density functional theory (DFT) method is much suppressed by DFT+DMFT method due to the orbital-dependent renormalization magnitude. NaFeAs shows a similar behavior, but a better nesting is obtained than LiFeAs from DFT+DMFT Fermi surfaces. Our result is consistent with the observed superconducting (spin density wave) ground state of LiFeAs (NaFeAs).

Effects of Vanadium Doping on Magnetic Properties of Inverse Spinel Fe3O4 Thin Films (역스피넬 Fe3O4 박막의 바나듐 도핑에 따르는 자기적 성질 변화)

  • Kim, Kwang-Joo;Choi, Seung-Li;Park, Young-Ran;Park, Jae-Yun
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.18-22
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    • 2006
  • Effects of V substitution of Fe on the magnetic properties of $Fe_3O_4$ have been investigated by x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), conversion electron Mossbauer spectroscopy (CEMS), and vibrating sample magnetometry (VSM) measurements on sol-gel-grown films. XRD data indicates that the $V_xFe_{3-x}O_4$ films maintain cubic structure up to x=1.0 with little change of the lattice constant. Analyses on V 2p and Fe 2p levels of the XPS data indicate that V exist as $V^{3+}$ mostly in the $V_xFe_{3-x}O_4$ films with the density of $V^{2+}$ ions increasing with increasing V content. Analyses on the CEMS data indicate that $V^{3+}$ ions substitute tetrahedral $Fe^{3+}$ sites mostly, while $V^{2+}$ ions octahedral $Fe^{2+}$ sites. Results of room-temperature VSM measurements on the films reveal that the saturation magnetization for the x=0.14 sample is larger than that of $Fe_3O_4$, while it becomes smaller than that of $Fe_3O_4$ for $x{\geq}0.5$. The coercivity of the $V_xFe_{3-x}O_4$ films is found to increase with x, attributed to the increase of anisotropy by the substitution of $V^{2+}(d^3)$ ions into the octahedral sites.

석류석과 녹염석간의 철-알루미늄 교환에 관한 실험암석학적 연구

  • 김형식;김진섭;김기영;이설경;신의철;권용완
    • The Journal of the Petrological Society of Korea
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    • v.3 no.3
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    • pp.185-195
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    • 1994
  • An experimental study of iron-aluminium partitioning between synthetic garnet and synthetic epidote was carried out, as equilibrium was maintained in the exchange reaction expressed as follows : $Ca_3Fe_2Si_3O_12\+\2\Ca_2Al_2AlSi_3O_12$(0H) = $Ca_3Al_2Si_3O_12\+\Ca_2Al_2FeSi_3O_12$(0H) Temperature has a pronounced effect on the distribution of Fe and A1 between the minerals. However, the pressure effect is not so drastic as in the exchange reaction. With increasing temperature, $Fe^{+3}$ becomes redistributed from garnet into epidote, whereas A1 becomes redistributed from epidote into garnet. This is in line with the general principle of phase correspondence, as the temperature increases the more electropositive metal aluminium redistributes from epidote into garnet. The agreement between the experimental results of this study and the natural samples suggests that $K_D=X^{Ep}_{Fe}/X^{Gr}_{Fe}$ may be a useful geothermometer for metamorphic rocks containing garnet and epidote that are close to binary Fe-A1 compounds.

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The Magnetic Properties and Microstrostrures for FeMX(M=Mo, Ta, X=N, C) Films. (FeMX(M=Mo, Ta, X=N, C) 박막의 자기 특성 및 미세구조 변화)

  • Shin, D.H.;Choi, W.;Kim, H.J.;Nam, S.Y.;Ahn, D.H.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.874-879
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    • 1995
  • Magnetic properties of FeMoN, FeMoTaN, FeTaN and FeTaC films deposited by DC magnetron reactive sputter were investigated, and correlated with their microstructure. FeMoN films were not showen the soft magnetic prop¬erties, because of generated $Fe_{2}Mo$, $Fe_{3-2}N$ and $Fe_{4}N$ phases. Ta added films, however, effectivly retarded the $\alpha$-Fe grain growth and suppressed the generation of Fe nitrides or carbides during heat treatement. The soft magnetic properties of $B_{s}:15\;kG,\;H_{e}:0.25\;Oe,\;\mu':4000(at\;5\;MHz),\;and\;B_s:14.5\;kG,\;He:0.25\;Oe,\;\mu':2700(5MHz)$ were observed in $Fe_{78.8} Ta_{8.5}N_{12.7}\;and\;Fe{75.6}Ta_{8.1}C_{16.3}$ films, respectively.

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Piezoelectric and Dielectric Properties of (Na,K,Li)(Nb,Sb,Ta)O3 Ceramics as a Function of Fe2O3 Addition (Fe2O3첨가에 따른 (Na,K,Li)(Nb,Sb,Ta)O3계 세라믹스의 압전 및 유전 특성)

  • Lee, Gwang-Min;Shin, Sang-Hoon;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.9
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    • pp.555-560
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    • 2014
  • In this paper, in order to develop outstanding Pb-free composition ceramics, the $Fe_2O_3$-doped ($Na_{0.525}K_{0.443}Li_{0.037}$)($Nb_{0.883}Sb_{0.08}Ta_{0.037}$)$O_3$ + 0.3 wt% $Bi_2O_3$ + x wt% $Fe_2O_3$ (x= 0~1.0 wt%)(abbreviated as NKL-NST) lead-free piezoelectric ceramics have been synthesized using the ordinary solid state reaction method. The effect of $Fe_2O_3$-doping on their microstructure and electrical properties were investigated. XRD diffraction pattern studies confirm that $Fe_2O_3$ completely diffused into the NKL-NST lattice to form a new stable soild solution with $Fe^{3+}$ entering the $Nb^{5+}$, $Sb^{5+}$ and $Ta^{5+}$ of B-site. And, phase structure of all the ceramics exhibited pure perovskite phase and no secondary phase was found in the ceramics. The ceramics doped with 0.6 wt% $Fe_2O_3$ have the optimum values of piezoelectric constant($d_{33}$), planar piezoelectric coupling coefficient($k_p$) and mechanical quality factor($Q_m$) : $d_{33}$ = 233 [pC/N], $k_p$= 0.44, $Q_m$= 95. These results indicate that the ($Na_{0.525}K_{0.443}Li_{0.037}$)($Nb_{0.883}Sb_{0.08}Ta_{0.037}$)$O_3$ +0.3 wt% $Bi_2O_3$ + 0.6 wt% $Fe_2O_3$ ceramic is a promising candidate for lead-free piezoelectric ceramics.