• Title/Summary/Keyword: 30% 농도의 산소

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Changes in Free Amino Acids by Lipid Deterioration in the Biological System of Rice Bran (미강지방질의 산패에 따라 생성된 산화 지방실이 유리아미노산의 변화에 미치는 영향)

  • 송영옥;최홍식;변재형
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.3
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    • pp.214-219
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    • 1991
  • The damaging effect of peroxidized lipid on amino acid was studied in rice bran by determining the free amino acid content in abiological system. The content of free amino acid in the rice bran stored in the controlled atomsphere of $35^{\circ}C$ with relative humidity of 65% for 180 days, increased during the first 60 days of storage, and then decreased as the lipid peroxidation proceeded. The content of free amino acid in the sample exposed to the air of $25-30^{\circ}C$ with relative humidity of 70-90% for 100 days decreased rapidly in the beginning period of the storage. The lipid oxidation developed much faster in the rice bran exposed to the air than in the rice bran stored in the controlled atmosphere. The correlation coefficients between the total content of free amino acid and degree of peroxidation for the samples of both conditions were above -0.8, which is significant(p<0.05). The changes in the concentration of serine, glutamic acid, proline, methionine, lysine, histidine, and arginine were significantly correlated with the degree of lipid oxidation(p<0.05) for the samples stored in the controlled atmosphere and the open air. It was observed that peroxidized lipid has damaging effects on protein in the bilogical system of rice bran.

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Experimental Study on the Flame Spread Characteristics under Reduced Atmospheric Pressures and Elevated Oxygen Concentrations (저기압 고산소 환경에서 화염 전파특성에 관한 실험적 연구)

  • Yang, Ho-Dong;Kwon, Hang-June;Park, Seul-Hyun
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.78-83
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    • 2016
  • The characteristics of flame spread under similar atmospheric conditions to those inside the first stage of launch vehicles were investigated to provide fundamental knowledge to prevent fires and explosions of vehicles during launching operations. To this end, the rate of flame spread on the solid fuel was measured at elevated oxygen concentrations and reduced atmospheric pressures. A 0.18 mm diameter optical fiber was used as a solid fuel. The experimental results indicated that elevated oxygen concentrations can increase the rate of flame spread while increasing the atmospheric pressures to 1 atm can lead to decreases in the rate of flame spread. The increases in the rate of flame spread with pressure is due mainly to reductions in the convective heat loss that are clarified through an analysis of the pressure dependence on the convective heat transfer coefficient.

Theoretical Studies on the Cationic Polymerization Mechanism of Oxiranes (산촉매하의 옥시란 공중합에 관한 분자궤도론적 연구)

  • Young-Gu Cheun
    • Journal of the Korean Chemical Society
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    • v.35 no.5
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    • pp.461-468
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    • 1991
  • The cationic polymerizations of substituted oxiranes which have pendant energetic groups such as azido, and nitrato, are investigated theoretically using the semiempirical MNDO, and $AM_1$ methods. The nucleophilicity and basicity of substituted oxiranes can be explained by the negative charge on oxygen atom of oxiranes. The reactivity of propagation in the polymerization of oxiranes can be represented by the positive charge on carbon atom and the low LUMO energy of active species of oxiranes. Ring opening of the complexed cyclic oxonium ion to the open chain carbenium ion is expected computational stability of the oxonium and carbenium ion by 30∼40 kcal/mol favoring the carbenium ion. The relative equilibrium concentration of cyclic oxonium and open carbenium ions will be a major determinant of mechanism. The chain growth $SN_1$, mechanism will be at least as fast as that for $SN_2$ mechanism.

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A Study Based on Molecular Orbital Theory of Polymerization of Oxolane High Explosives (Oxolane 고폭 화약류의 중합반응에 관한 분자 궤도론적 연구)

  • Kim, Joon-Tae
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.278-283
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    • 2010
  • The cationic polymerization of oxolane high explosives which have pendant explosive groups such as azido, nitrato and hydrazino is investigated theoretically using the semiempirical MINDO/3, MNDO and AM1 methods. The nucleophilicity and basicity of oxolane high explosives can be explained by the negative charge on oxygen atom of oxolane. The reactivity of propagation in the polymerization of oxolane can be represented by the positive charge on carbon atom and the low LUMO energy of active species of oxolane. The reaction of the oxolane high explosives in oxonium ion form to the open chain carbenium ion form is expected by computational stability energy (17.950~30.197 kcal/mol) of the oxonium ion and carbenium ion favoring the carbenium ion. The relative equilibrium concentration of cyclic oxonium ion and carbenium ion is found to be a major determinant of mechanism, owing to the rapid equilibrium of these catoinic forms. Based on calculation, in the prepolymer propagation step, $S_N1$ mechanism will be at least as fast as that for $S_N2$ mechanism.

The Preliminary Study of Odorant Induced fMRI using an Apparatus of Smell Stimulation Controller (후취자극 제어장치를 이용한 후각 fMRI의 기초연구)

  • 강원석;백문영;이현용;신운재;정순철;민병찬;김재형;은충기;문치웅
    • Journal of Biomedical Engineering Research
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    • v.22 no.2
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    • pp.157-163
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    • 2001
  • 본 논문에서는 후취자극 제어장치를 이용하여 후각자극에 대한 인간의 뇌의 활성화 영역을 뇌기능자기공명영상(functional magnetic resonance imaging : fMRI)장치로 측정 또는 가시화하고 이의 임상적용에 대한 기초자료를 마련하고자 하였다. 우선 후각에 이상이 없고 코 수술 경험이 없는 오른손잡이 피험자 4명을 대상으로 5번에 걸쳐 Echo Plannar Imaging(EPI)에 의한 혈액산소농도의존(blood oxygen level dependent : BOLD)법을 이용하여 후각자극에 의한 뇌기능자기공명영상 실험을 수행하였다. 후각자극은 MRI 장치에서 사용할 수 있도록 제작된 후취제어장치를 사용하였으며, 제시된 향은 천연 향의 일종인 lavender-like fragrance를 사용하였다. 향의 제시는 후각의 피로도를 감안하여 3회의 휴식기관과 2회의 자극기간을 각 30초씩 번갈아 시행하였으며, 동시에 5초 간격으로 각 절편 당 30 영상을 연속적으로 획득하였다. Correlation법으로 0.4∼0.7의 문턱치(threshold)범위에서 통계 처리된 뇌의 활성화 영상은 EPI영상과 같은 부위의 T1 강조영상에 overlapping 시켰다. 호흡에 의한 artifact를 제거하기 위해 실험실에 만든 장치로 호흡을 측정하여 post-processing 할 때 반영하였다. 이렇게 얻어진 fMRI 영상의 신호변화를 관찰하여 활성 영역의 위치를 분석하였다. 그 결과 후각자극에 의해 뇌의 전두엽 피질(frontal cortex), 소뇌(cerebellum), 그리고 뇌교(pons)에서 활성화된 신호를 발견할 수 있었다. 또한, 측두엽(temporal lobe)과 뇌섬(insula)에서도 의미 있는 신호가 관찰되었다. 그러나, 일차 후각영역인 piriform cortex와 entorhinal cortex, amygdaloid complex, 그리고 이차후각영역인 orbitofrontal cotex에서는 그다지 많은 빈도로 신호가 발견되지 않았다. 결론적으로 BOLD법을 이용한 fMRI에 의하여 후각자극에 대한 뇌의 활성화영역을 관찰할 수 있었으며, 후각자극에 대한 뇌의 기능을 연구하는데 있어서 중요한 정량적 자료를 제공할 수 있다는 점을 확인할 수 있었다.

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Release Characteristics of Phosphorus in Nakdong Estuary Barrage (낙동강 하구호에서의 인의 용출특성)

  • YANG Jin-Woo;SONG Kyo-Ouk;LEE Suk-Mo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.3
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    • pp.192-197
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    • 1990
  • The study of characteristics of phosphorus release in Nakdong Estuary Barrage was conducted in June and July, 1989. Batch type reactor was designed for evaluating of release flux. The fractional composition of organic phosphorus and inorganic phosphorus in sediment were $34.7\%,\;66.7\%$, respectively. Inorganic phosphorus was fractionated into three types; Adsorbed-P, Non Apatite Inorganic-P, Apatite-P. The major forms of inorganic phosphorus were Non Apatite Inorganic-P($61.1\%$) and apatite-P($30.0\%$). Release rates of phosphorus from sediment were $-4.4mg/m^2/d$ in aerobic condition, and $39.4mg/m^2/d$ in anaerobic condition. According to the result of this study, sediment plays an important role in Nakdong Estuary Barrage as an internal load source of phosphorus.

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Effect of PE film thickness on MA storage or kiwifruit(Actinidia chinensis Planch.) during storage (PE 필름 두께에 따른 한국산 양다래(Actinidia chinensis Planch.)의 MA 저장에 관한 연구)

  • Lee, Se-Eun;Kim, Dong-Man;Kim, Kil-Whan
    • Applied Biological Chemistry
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    • v.35 no.2
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    • pp.126-131
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    • 1992
  • For the development of kiwifruit storage method applicable to farm level, several quality indicator of kiwifruit(Actinidia chinensis Planch.) were measured during storage at modified atmosphere(MA) conditions(0.04, 0.06, 0.08 and 0.10 mm PE Film). The results obtained from the experiment were as follows. The highest firmness was marked by the kiwifruit kept in 0.06 mm thick film bag and the lowest weight loss was shown in 0.10 mm thick film bag. The largest production of respiratory rate was occured after storage for 30 days. The concentration of $O_2\;and\;CO_2$ in 0.06 mm thick film bag was 2.6% and 3.2% after storage for 60 days, respectively. It could be concluded that the optimum PE film thickness for MA storage of kiwifruit was 0.06 mm.

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The Limnological Survey of a Coastal Lagoon in Korea (2): Lake Hyangho (동해안 석호의 육수학적 조사(2): 향호)

  • Kwon, Sang-Yong;Lee, Jae-Il;Kim, Dong-Jin;Kim, Bom-Chul;Heo, Woo-Myung
    • Korean Journal of Ecology and Environment
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    • v.37 no.1 s.106
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    • pp.1-11
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    • 2004
  • The limnological characteristics of a coastal lagoon were studied in Lake Hyangho, one of a series of brackish lagoons along the eastern coast of Korea. Phytoplankton community structure, physical factors, and chemical factors were surveyed from May 1998 through November 2002 on a two-month interval basis. Temperature, salinity, Secchi disc transparency, TN, TP, organic matter content of sediment, chlorophyll a concentration, dominant phytoplankton species, and phytoplankton cell density were measured. Salinity gradient was formed between the overlying freshwater stream water and the permeated seawater at the bottom. The chemocline was persistent at the depth of 2 ${\sim}$ 5 m that caused discontinuities of salinity, DO, and temperature profiles. The inversion of vertical temperature profiles with higher temperature in deeper layer was observed in early winter. Secchi disc transparency was very low with the range of 0.1 to 1.1m. TP, TN, and Chl. a concentration in the epilimnion was 0.011 ${\sim}$ 0.238 mgP $L^{-l}$, 0.423 ${\sim}$ 2.443 mgN $L^{-l}$, and 0.7 ${\sim}$ 145.2 mg $m^{-3}$, respectively. Sediment was composed of silt and coarse silt. COD, TP, and TN content of dry sediment were 19.7 ${\sim}$ 73.3 mg$O_2\;g^{-1}$, 0.61 ${\sim}$ 1.32 mgP $g^{-l}$ and 0.64 ${\sim}$ 0.88 mgN $g^{-l}$, respectively. Dominant phytoplankton species were chlorophytes (Ankistrodesmus falcatus) and cyanobacteria (Oscillatoria sp. and Merismopedia tennuissima). The total cell density was in the range of 560 ${\sim}$ 35,255 cells $mL^{-l}$.

Initial Analysis of the Underground Air Among Jeju Lava Forest(Sumgol) and its Healing Effect on the Human Body (제주 현무암 '숲' 지하 공기(숨골: Sumgol)의 분석과 인체에 미치는 치유 효과)

  • Sin, SBangsik;Kim, Hyek Nyeon;Lee, Deok Hee;Kim, Tae Seung;Kim, Yong Hwan;Kang, Chang Hee;Song, Kyu Jin;Lee, Hyung H.
    • Journal of Naturopathy
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    • v.11 no.1
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    • pp.18-30
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    • 2022
  • Background: It was to develop an air purification system (APS) using an underground air purification layer to verify the effect of basalt forest's underground air (sumgol) on a volcanic Jeju. Finally, it is necessary to analyze these purified air components and their usefulness to the human body in an air experience center. Purpose: It was to collect basalt forest air, analyze its composition, and explore its effect on the human body. Methods: We APS devices installed at four points in the Papaville area of Jeju. The air discharged from the APS was collected and analyzed the recycling components. An installed experience room filled with negative ions is about 5,000 ions/m3. After allowing the participants to stay for 60 to 120 minutes, we investigated the state of blood vessels. Results: In the analysis of the underground air, the O2 concentration was 21.18%, which was higher than the average oxygen concentration of 20.94% in the atmosphere. However, Formaldehyde was not detected, and the CO2 was 419 ppm, which was lower than that of indoor air. The PM2.5 concentration was less than 24 ㎍/m3 and detected anions over 5.000 /m3. The experiencer's vascular states improved, and the increase in pulse rate and stress relief were high. Conclusions: The valuable ingredients identified by analyzing the air were precious for natural healing. The experience results showed that it effectively improved the pulse rate, blood vessels, and stress. These conditions may be highly beneficial as a new area for expanding the basalt lava forest in the Jeju area into the natural healing and wellness industry.

Antioxidative Activity of Smilax china L. Leaf Teas Fermented by Different Strains (균주에 따른 청미래덩굴잎 발효차의 항산화 활성)

  • Lee, Sang-Il;Lee, Ye-Kyung;Kim, Soon-Dong;Kang, Yun Hwan;Suh, Joo Won
    • The Korean Journal of Food And Nutrition
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    • v.25 no.4
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    • pp.807-819
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    • 2012
  • To evaluate the functional characteristic and availability for drinking of the fermented Smilax china leaf tea by using different microbial species, various fermented leaf tea was prepared by non-fermentation (C), or the fermentation of Saccharomyces cerevisiae (S), Bacillus sp. (B), Bifidobacterium bifidus (L), Monascus pilosus (M) and Aspergilus oryzae (A), and sensory and antioxidant parameter of each brewed tea was observed. The color of the A tea was red, but the other teas were yellow in color. Furthermore, the aesthetic quality of the A and M tea was 3.95 and 3.30 point, respectively, and other teas (2.55~2.28) were similar to that of the C tea. TP of fermented tea water extract was lower than that of the C, although TF was not significantly different between the fermented and non-fermented tea. Especially, TF of the A tea was significantly lower than those of the other teas. The range of EDA ($1mg/m{\ell}$) of water and ethanol extracts of tea C and the fermented teas was 19.25~22.48%; however, tea A was only 8.04~12.49%. In addition, FRAP, FICA and LPOIA of teas were not significantly different between the fermented and non-fermented teas. On the other hand, XOIA and AOIA of tea ethanol extracts were slightly higher than those of water extracts. XOIA of water extract derived from the teas was 4.83~9.20%, while ethanol extract of these was 9.00~19.00%. However, XOIA of B and L teas water extract was not detected. Furthermore, AOIA of fermented tea water extract (30.17~48.52%) were lower than those of ethanol extract (44.09~66.93%). In this study, interestingly, antioxidant parameters, such as FRAP, FICA, LPOIA and AOIA, of the A tea water extract (0.1%) was higher than that of the other tea in spite of high decreasing rate in the contents of TP and TF. Therefore, above results imply the possibility of fermented Smilax china leaf tea as a functional food.