• Bulletin of the Korean Chemical Society
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• 제28권9호
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• pp.1467-1471
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• 2007

The green-emitting CeMgAl11O19:Tb (CMAT) phosphor has been prepared at 1200 °C by the simple solid-state reaction using AlF3 as a self-flux. This preparation temperature is much lower than those (1500-1700 °C) for conventional solid-state reaction and spray pyrolysis method. In particular, the complete process to produce high-quality phosphor particles was carried out through the single-step heat treatment of the mixture of corresponding oxide-type metal sources. An addition of AlF3 as a self-flux significantly decreased the crystallization temperature of CMAT with plate-like shape. The particle morphology could be controlled from plate-like to spherical by using H3BO3 as an additional flux. Thus, an optimal morphology and luminescence characteristics of CMAT were achieved when both AlF3 and H3BO3 fluxes were simultaneously used. Compared with conventional solid-state process, which is accompanied by the calcination step(s), and other alternative liquid solution techniques such as sol-gel method and spray pyrolysis, no use of active precursors and liquid media that are harmful to the environment is a distinctive advantage for the industrial purpose.

• Progress in Superconductivity
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• 제8권2호
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• pp.186-192
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• 2007

High $J_c\;YBa_2Cu_3O_{7-x}$ superconducting films have been fabricated $LaAlO_3(100)$ substrate by MOD method using dichloroacetic acid(DCA) as chelating solvent for preparing precursor solution. Heating rate was varied in order to optimize the calcination heat treatment condition in DCA-MOD method. Coated films were calcined at lower temperature up to $500^{\circ}C$ in flowing humid oxygen atmosphere. The heating rate was calcined from $13.3^{\circ}C/min\;to\;0.28^{\circ}C/min$. Conversion heat treatment was performed $800^{\circ}C$ for 2 h in flowing Ar gas containing 1000 ppm oxygen with a humidity of 9.45%. Surface and cross sectional SEM microstructures showed that particle sizes were increased with heating rate at a calcination step. The amount of pores was increased with heating rate in the calcined films. Dense microstructure and sharp texture were developed in an YBCO films after conversion heat treatment. A high critical current density (Jc) of $1.26MA/cm^2$ (@77 K and self-field) was obtained for the YBCO film which was prepared with a heating rate of $0.28^{\circ}C/min$.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
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• pp.3-5
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• 2001

ZnO thin films are deposited on $SiO_2$/Si (111) substrate by RF magnetron sputtering. The two-step deposition method is proposed to enhance both the c-axis orientation and the resistivity of ZnO films. This method consists of the following two procedures: the 1 st-deposition for 30 min without oxygen at l00W and the 2nd-deposition with oxygen added in the range of $O_2/(Ar+O_2)=10{\sim}50%$. Effects of thermal treatment on the properties of ZnO films are systematically investigated.

• 열처리공학회지
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• 제10권1호
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• pp.1-9
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• 1997

The variation of the mechanical properties and the formation of retained austenite with heat treatment conditions in austempered Si bearing carbon steels has been investigated. In the case of a steel containing 0.35C-1.48Si-0.95Mn, it has been found that a feather shape bainite structure of lath are obtained under a isothermal treated condition at just below the Ms temperature, and the martensite, bainitic ferrite and retained austenite of second phase particles on the ferrite matrix for a isothermal treated steels after intercritical annealing are precipitated in a linked shape. The retained austenite with $2{\mu}m$ size induced as TRIP is found to increase with increasing the formation rate of retained austenite for the intercritical annealing and high Si containing steels. The tensile strength is increased as austempering temperature increases in all isothermal treatment temperature, whereas the elongation is shown to roughly decrease as the tensile strength increases. The values of tensile strength-elongation balance have showed a marked dependence upon the elongation rather than the tensile stregth, and their values are increased for high Si containing steels and intercritical annealing condition. The most optimum result has been shown to be the tensile stregth-elongation balance of $2882.4kgf/mm^2.%$ and the elongation of 33.3% for a "B" steel in the heat treating temperature range of $780{\sim}370^{\circ}C$.

• 대한금속재료학회지
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• 제46권12호
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• pp.800-808
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• 2008

Heat treatment is an important step for tool manufacture, but unavoidably generates dimensional distortion. This study investigated the continuous dimensional change and the anisotropic behavior of STD11 tool steel during austenitizing and tempering heat treatment especially using quenching dilatometer. Dilatometric results represented that the dimensional change along longitudinal direction was larger than that along transverse direction. Anisotropic phase transformation strain was produced in forged STD11 tool steel during heat treatment. Anisotropic dimensional change increased with increasing austenitizing temperature. After tempering, anisotropic distortion was partially reduced. FactSage thermodynamic equilibrium phase simulation and microstructural observation (FE-SEM, TEM) showed that large ($7{\sim}80{\mu}m$) elongated $M_7C_3$ carbides could be formed along rolling direction. The resolution of elongated carbides during austenitizing was found to be related with the change of martensite transformation temperature after heat treatment. Anisotropic size change of STD11 tool steel was mainly attributed to large elongated carbides produced during rolling process. Using dilatometric and metallographic examination, the possible mechanism of the anisotropic size change was also discussed.

• 한국식품영양과학회지
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• 제39권1호
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• pp.154-158
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• 2010

본 연구에서는 현미 발아 시 침지 및 발아 조건에 따른 GABA 함량의 변화를 분석하고 효과적으로 GABA 함량을 증가시키기 위한 처리조건을 살펴보았다. 발아 현미의 GABA 함량 증가를 위해 침지 전 열처리를 실시하였으며, 한약재로 널리 쓰이는 오미자와 용안육, 구릿대, 천마를 침지수와 발아수로 이용하였을 때의 GABA 함량의 변화를 확인하였다. 실험 결과 $45^{\circ}C$에서의 열처리군이 3977.3 nmol/g로 무처리군에 비해 약 1.4배 정도의 증가 효과를 나타내었다. 또한 한약재를 침지 및 발아수로 이용한 결과 용안육은 3% 추출물을 발아수로 이용하였을 경우가 가장 높은 증가율을 보여주었으며, 오미자는 5% 추출물을 발아수로 이용한 경우가 대조군보다 2.1배로 가장 높은 GABA 함량을 나타내었다. 천마 추출물의 경우는 5% 추출물을 침지수와 발아수로 이용했을 경우 약 2.5배의 증가율을 보여 실험한 한약재 중 가장 높은 효과를 보여주었다. 본 연구 결과는 점차 관심이 높아지고 있는 발아현미 연구에 있어서 기초자료가 될 것으로 예상되며, 쌀 소비촉진에 영향을 미칠 것으로 기대된다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.251-254
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• 1999

A new multi-seeding process for the growth of YBa$_2$Cu$_3$Oxx single crystals was developed. This process introduces an additional heating step to peritectic temperature and a subsequent slow cooling step to the growth temperature following the point when the crystals contacted. The crystal growth was resumed thereafter. The results obtained with this new process were compared with those of the conventional growth process, in which materials were only kept at the growth temperature. It was observed that the liquid phase between crystals were almost completely eliminated, but that Y2ll grains were grown during this new process. There was no significant improvement in trapped magnetic field over the conventional process, which is believed to be due to the cracks generated during the oxygen heat treatment or to the growth of YBa$_2$Cu$_3$Ox grains.

• 대한금속재료학회지
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• 제50권5호
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• pp.345-351
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• 2012

A three-point bending test was performed on roll-bonded Mg/Al/STS clad-metal plates under two different testing conditions (Mg layer in tension, or STS in tension) and their mechanical response and fracture behavior were investigated. Bending strength was found to be greater under the condition of Mg layer in tension. Heat treatment at $200^{\circ}C$ increased the bending formability, suggesting the interfacial strength increased at $200^{\circ}C$. Under the condition of Mg in tension, the clad heat-treated at $300^{\circ}C$ and $400^{\circ}C$ fractured in two steps, with the first step associated with the interfacial fracture between Mg and Al, and the second the fracture of the Mg layer. STS/Al layers were found to be bent without complete fracture. Under the condition of STS in tension, the clad heat-treated at $300^{\circ}C$ and $400^{\circ}C$ exhibited a very small load drop at the displacement, which is similar to that of the first load drop associated with the interfacial fracture under the condition of Mg in tension. In this case, no interfacial cracks were found and the complete cut-through fracture of clad was observed at low temperature heat treatment conditions, suggesting excellent interfacial strength. When the heat treatment temperature was higher than $300^{\circ}C$, interfacial cracks were observed. The local stress condition and the position of the interface with respect to the surface were found to have a great influence on the fracture behaviors of clad metals.

• 한국전기전자재료학회논문지
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• 제24권9호
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• pp.766-772
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• 2011

Amorphous Si (a-Si) thin films of $p^+/p^-/n^+$ were deposited on $Si_3N_4$/glass substrate by using a plasma enhanced chemical vapor deposition (PECVD) method. These films were annealed at various temperatures and for various times by using a rapid thermal process (RTP) equipment. This step was added before the main thermal treatment to make the nuclei in the a-Si thin film for reducing the process time of the crystallization. The main heat treatment for the crystallization was performed at the same condition of $600^{\circ}C$/18 h in conventional furnace. The open-circuit voltages ($V_{oc}$) were remained about 450 mV up to the nucleation condition of 16min in the nucleation RTP temperature of $680^{\circ}C$. It meat that the process time for the crystallization step could be reduced by adding the nucleation step without decreasing the electrical property of the thin film Si for the solar cell application.

• 열처리공학회지
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• 제25권3호
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• pp.138-145
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• 2012

An ${\alpha}$-Ferrite (Fe) powder dispersed with 4 vol.% of $Al_2O_3$ was successfully produced by a simple miling at 210 K with a mixture of $Fe_2O_3$, Fe and Al ingredient powders, followed by 2 step high temperature consolidation: Hot Pressing (HP) at 1323 K and then Hot Isostatic Pressing at 1423 K. The microstructure of the consolidated material was characterized by standard metallographic techniques such as XRD (X-ray Diffraction), TEM and STEM-EDS. The results of STEM-EDS analysis showed that the HIPed materials comprised a mixture of pure Fe matrix with a grain size of ~20 nm and $Al_2O_3$ with a bimodal size distribution of extremely fine (~5 nm) and medium size dispersoids (~20 nm). The mechanical properties of the consolidated materials were characterized by compressive test and micro Vickers hardness test at room temperature. The results showed that the yield strength of the ODS (Oxide Dispersion Strengthened) Fe alloy are as much as $674{\pm}39$ MPa and the improvement of the yield strength is attributed to the presence of the fine $Al_2O_3$ dispersoid.