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Improvement of external quantum efficiency of EL devices with PVK/P3DoDT blends using as a emitting layer (PVK/P3DoDT 블랜드를 발광층으로 사용한 EL 소자의 발광효율 향상에 관한 연구)

  • Kim, Ju-Seung;Seo, Bu-Wan;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.96-99
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    • 2000
  • We fabricated electroluminescent(EL) devices which have a blended single emitting layer containing poly(N-vinylcarbazole)[PVK] and poly(3-dodecylthiophene)[P3DoDT]. The molar ratio between P3DoDT and PVK changed with 1:0, 2:1 and 1:1. To improve the external quantum efficiency of EL devices, we applied insulating layer, LiF layer, between polymer emitting layer and Al electrode. All of the devices emit orange-red light and its can be explained that the energy transfer occurs from PVK to P3DoDT. In the voltage-current and voltage-light power characteristics of devices applied LiF layer, current and light power drastically increased with increasing applied voltage. In the consequence of the result, the external quantum efficiency of the devices that have a molar ratio 1:1 with LiF layer was 35 times larger than that of the device without LiF layer at 6V.

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The Characteristics of the Oxide Layer Produced on the Plasma Nitrocarburized Compound Layer of SCM435 Steel by Plasma Oxidation (플라즈마 산질화처리된 SCM435강의 표면경화층의 미세조직과 특성)

  • Jeon Eun-Kab;Park Ik-Min;Lee Insup
    • Korean Journal of Materials Research
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    • v.14 no.4
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    • pp.265-269
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    • 2004
  • Plasma nitrocarburising and post oxidation were performed on SCM435 steel by a pulsed plasma ion nitriding system. Plasma oxidation resulted in the formation of a very thin ferritic oxide layer 1-2 $\mu\textrm{m}$ thick on top of a 15~25 $\mu\textrm{m}$ $\varepsilon$-F $e_{2-3}$(N,C) nitrocarburized compound layer. The growth rate of oxide layer increased with the treatment temperature and time. However, the oxide layer was easily spalled from the compound layer either for both oxidation temperatures above $450^{\circ}C$, or for oxidation time more than 2 hrs at oxidation temperature $400^{\circ}C$. It was confirmed that the relative amount of $Fe_2$$O_3$, compared with $e_3$$O_4$, increased rapidly with the oxidation temperature. The amounts of ${\gamma}$'-$Fe_4$(N,C) and $\theta$-$Fe_3$C, generated from dissociation from $\varepsilon$-$Fe_{2-3}$ /(N,C) phase during $O_2$ plasma sputtering, were also increased with the oxidation temperature.e.

A Study on Permeability of Stratified soil in the Close State Under Existence of Stagnant Water. (담수상태에 있어서 성층토양의 물의 침투에 관한 연구)

  • 조경용
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.16 no.3
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    • pp.3477-3491
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    • 1974
  • Following are the results of the study on the property of falling permeation of stratified soil in the close state under existence of stagnant water on a soil layer. 1. When on the stratified soil a least permeating layer was put on the soil layer the load Pressure was present owing to appearance of saturation close state driving decrease of the pressure in the lower layer, on the other hand when the least permeating layer was placed under the layer the lower least permeating layer pressure was decreased. 2. In the case of least permeating layer the variation of current gradient according to the respective level after treating the layer was enormous and due to usal storage phenomena for the Kl layer which was coarse that was trifle. 3. The permeability of the respective layer of stratified soil in the close state died not always coincide with that of single layer. 4. Generally Zunker's equation of average permeability was valid but actually calculated permeating velocity after treating the layer of stratified soil was seriously differ from the measured value owing to the variation of current gradient, especially when the pressure head at the layer boundany was discontinuous the validity of the equation of average permeability was seemed to be doubtful. 5. The permeating velocity of stratified soil was regulated by the least permeating layer, i.e. it is thought to be rational to estimate the value by calculating the current gradient with its proper permeability, pressure headon the layer and its thickness.

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Enhancement of Emission Efficiency of Multilayer White Light Organic Electroluminescent Device (다층구조를 적용한 백색 전계발광소자의 발광효율 향상)

  • Kim, Ju-Seung;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05a
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    • pp.27-31
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    • 2001
  • We fabricated organic electroluminescent(EL) devices with mixed emitting layer of poly(N-vinylcarbazole)(PVK), 2,5-bis(5'-tert-butyl-2-benzoxazoly)thiophene(BBOT), N,N'-diphenyl-N,N'-(3-methyphenyl)-1,1'-biphenyl-4, 4'-diarnine(TPD) and poly(3-hexylthiophene)(P3HT). To improve the external quantum efficiency of EL devices, we added the functional layer to the devices such as LiF insulating layer, carrier confinement layer(BBOT) and hole injection layer(CuPc). In the ITO/emitting layer/Al device, the maximum quantum efficiency at 15V was $1.88{\times}10^{-5}%$. And then, it is increased by a factor of 27 to $5.2{\times}10^{-3}%$ in ITO/CuPc/emitting layer/BBOT/LiF/Al device at 15V.

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Hydroxyapatite Formation on Fluoride Bioactive Glasses coated on Alumina (알루미나에 코팅된 불화물 생체유리에의 수산화 아파타이트 형성)

  • 안현수;이은성;김철영
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1087-1093
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    • 1999
  • Bioglass which is one of the surface active bionmaterials has a good biocompatibility but a poor mechanical strength, In the present work therefore two types of fluoride-containing bioglasses were coated on an alumina to improve mechanical strength. Crystallization of the coating layer and the hydroxyapatite formation on the bioactive glass coatings in tris-buffer solution were studied. When bioactive glass coated alumina was heat-treated Na2CaSi3O8 crystal was formed on the layer at lower temperature while wollastonite(CaSIO3) was obtained at higher temperature. Hydroxyapatite forming rate on the coating layer with Na2CaSi3O8 crystal was delayed with SiO2 contents in glass composition. However the hydroxyapatite was developed in 20minutes regardless SiO2 contents when the coating layer crystallized into wollastonite. More amount of P3+ ions were leached out of the coating layer with wollastonite than that with Na2CaSi3O8 crystal while Na+ and Ca2+ ions were leached out more easily from the Na2CaSi3O8 crystal containing coating layer.

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Synthesis of Conjugated Copolymers with phenothiazine and Azomethine Units and their Electro-Optic Properties

  • Seo, Hyeon-Jin;Jang, Byeung-Jo;Chang, Jin-Gyu;Park, Lee-Soon
    • Journal of Information Display
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    • v.2 no.4
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    • pp.8-14
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    • 2001
  • Three types of conjugated polymers, poly(PZ-Pi), poly(PZ-BPI) and poly(PZ-NPI) were synthesized by Schiff-base reaction. These new conjugated polymers exhibited improved solubility in common organic solvents due to the presence of alkyl side chains as well as azomethine groups, Double layer LEDs made with the synthesized polymers as emitting layer and $Alq_3$, as electron transporting layer exhibited enhanced EL emission and efficiency compared to those of single layer LEDs. Double layer LEDs exhibited gradual shift in the emission peak th the single layer LED, made of only $Alq_3$ as the emitting layer as the thickness of $Alq_3$ layer increased.

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Electrical Properties of Ba0.66Sr0.34TiO3 Thin Films Fabricated by a Seed-layer Process (Seed-layer 공정을 이용한 Ba0.66Sr0.34TiO3박막의 제조 및 전기적 특성 연구)

  • 최덕영;박철호;손영국
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.198-205
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    • 2003
  • $Ba_{0.66}Sr_{0.34}TiO_3$ thin films and seed-layers were deposited on $Pt/Ti/SiO_2/Si$substrate by R.F. magnetron sputtering method. Effects of various substrate temperature conditions on electrical properties (such as capacitance and leakage current) of BST thin films were studied. The effect of seed-layer was also studied. When seed-layer was inserted between BST and Pt, the crystallization of the BST thin films was considerably improved and the processing temperature was lowered. Compared to the pure BST thin films, dielectric constant, dielectric loss, and leakage current of BST thin films deposited on the seed-layer were considerably improved. It could be revealed that electrical properties are influenced by the substrate temperatures of BST thin films and are enhanced by the seed-layer.

Multi-layer Coating for Improvement Anti-wear Property of Graphite (흑연의 내마모성 증진을 위한 다층 코팅)

  • Suh, Im-Choon;Kim, Dong-Il;Yeh, Byung-Hahn;Jung, Bahl;Park, Chong-Ook
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.874-878
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    • 1994
  • To increase the anti-oxidation and anti-wear properties of graphite for the propellant-burning environment, SiC, Pt and Al2O3 multi-layer coatings were conducted succesisvely and the optimum condition was researched. The SiC layer was produced by pack cementation and SiC layer in thickness of 30 ${\mu}{\textrm}{m}$ coating was produced after coating for 6 hours. Pt layer was coated by sputtering, and the Al2O3 layer was coated by reactive sputtering. the thickness of Pt layer and Al2O3 layer was less than one-tenth of that of SiC layer. The pack coated specimens and multi-layer coated specimens were made using above conditions and test-fired. The test result showed that the wear rate of SiC layer is approximately 1/10 compared to that of uncoated graphite.

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RP model decomposition algorithm for making 3D layer (3D layer 생성을 위한 RP 모델 분할 알고리즘)

  • 이재호;박준영
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2000.04a
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    • pp.724-727
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    • 2000
  • Rapid Prototyping(RP)이란 3차원 솔리드 모델을 단면화한 뒤 하나씩 적층하는 가공방식을 총칭한다. 이때 단면화하는 방법에 따라서 uniform, adaptive slicing으로 나뉘며, 입력 모델에 따라서 direct slicing과 STL을 이용한 방식으로 나뉜다. 적층 방법에 따라서는 연속된 2D 윤곽을 기반으로 적층하는 vertical layer 방식과 인접한 두 개의 2D 윤곽들을 연결하며 만들어진 3D layer를 기반으로 가공하는 sloping layer방식으로 나뉠 수 있다. 현재 상용 RP 시스템들에서는 거의 모든 경우 vertical layer 방식이 채택되어 사용되고 있다. RP와 절삭 공정, 예를 들면 CNC 밀링의 장점을 효율적으로 결합하기 위해서는 임의의 복잡한 형상을 갖는 솔리드 모델을 정밀도에 제한이 없이 제조할 수 있어야 한다. 그러나 절삭 공정은 특별한 전문적 지식들을 필요로 한다 또한 상용 RP에서 사용하는 순차적인 적층 작업으로는 가공할 수 없는 형상들이 많다. 대표적인 것으로 지지대를 필요로 하는 형상들이 있다. 이러한 형상들을 지원하기 위해서는 복잡한 3D 형상을 절삭 가능한 형식으로 분할하는 것과 적층 가능한 순서대로 공정 계획하는 것이 필요하게 된다. 본 연구에서는 SDM에서 제시된 3D 분할 방법이 솔리드 모델을 기반으로 전개되어 STL file과 같은 삼각다면체 형식으로 근사화된 모델에 적용하기 어렵다는데 착안하여 STL file에서 읽어들인 삼각 다면체 모델을 가공 가능한 3D 형상으로 분할하는 알고리즘을 제시하고자 한다.

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Effect of $Al_2O_3$ capping layer on properties of MgO protection layer for plasma display panel

  • Eun, Jae-Hwan;Lee, Jung-Heon;Kim, Soo-Gil;Kim, Hyeong-Joon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.628-631
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    • 2002
  • $Al_2O_3$ capping layer and MgO protective layer were deposited by electron beam evaporation method using single crystal source. Thickness of the capping layer, $Al_2O_3$, was varied from 5 nm to 10 nm. Surface morphology was observed by SEM and AFM before and after hydration. And microstructure of deposited $Al_2O_3$ layer and chemical shift of electron binding energy were also observed by high resolution TEM and XPS, respectively, after hydration. From these results, it was found that Mg atoms diffused into $Al_2O_3$ layer, reacted with moisture and formed $Mg(OH)_2$ during hydration. As thickness of $Al_2O_3$ increased, extent of hydration increased. $Al_2O_3$ capped MgO thin films and uncapped MgO thin films were deposited on AC-PDP test panel to characterize discharge properties. Although $Al_2O_3$ has poor discharge properties rather than MgO, because of many hydrated species on the surface of MgO, similar discharge properties were observed.

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