• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1464-1469
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• 2004

In this study, micro square heaters having dimensions of $65{\times}65{\mu}m^2$and $100{\times}100{\mu}m^2$ were fabricated and bubble nucleation experiments on the heaters were performed. Bubble nucleation temperature was also measured using a bridge circuit and the photographs of bubble nucleation and subsequent growth were taken by a camera with a flash unit. Measured bubble nucleation temperatures were found to be closer to the superheat limit of working fluid (FC-72). Also quasi-1D analyses for the square heaters were performed. The quasi-1D analysis yielded proper temperature distribution of the square heater at steady state, however failed to predict the temperature rise up to the steady state. Similar time dependent temperature can be obtained with proper value of thermal diffusivity. For the $100{\times}100{\mu}m^2$ square heater, nucleation of several bubbles was observed while only one bubble was observed to be nucleated on $65{\times}65{\mu}m^2$ heater.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.2
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• pp.227-232
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• 1998

Diamond crystallization and discontinuous deposit phenomena depend on the process of hydrocarbon deposition, nucleation and growth. Then, it is investigated the concentration of methane, flow rate, structure and the growth process of $CH_4-H_2$ system in hot filament assisted C.V.D. There is a limited value of temperature, pressure, flow rate and the mole fraction of methane-hydrogen gas. Diamond nucleation occurs on substrate selectively and surface diffusion of species on the substrate plays an important role in the early stages of nucleation and growth.

• Journal of Electrochemical Science and Technology
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• v.9 no.3
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• pp.202-211
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• 2018

In this work, Fe-Pd alloy films have been electrodeposited on different substrates using an electrolyte containing $[Pd(NH_3)_4]^{2+}$ (0.02 M) and $[Fe-Citrate]^{2+}$ (0.2 M). The influences of substrate and overpotential on chemical composition, nucleation and growth kinetics as well as the electrodeposited films morphology have been investigated using energy dispersive X-ray spectroscopy (EDS), current-time transients, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD) patterns. In all substrates - brass, copper and sputtered fluorine doped tin oxide on glass (FTO/glass) - Fe content of the electrodeposited alloys increases by increasing the overpotential. Also the cathodic current efficiency is low due to high rate of $H_2$ co-reduction. Regarding the chronoamperometry current-time transients, it has been demonstrated that the nucleation mechanism is instantaneous with a typical three dimensional (3D) diffusion-controlled growth in the case of brass and copper substrates; while for FTO, the growth mode changes to 3D progressive. At a constant overpotential, the calculated number of active nucleation sites for metallic substrates is much higher than that of FTO/glass; however by increasing the overpotential, the number of active nucleation sites increases. The SEM micrographs as well as the XRD patterns reveal the formation of Fe-Pd alloy thin films with nanostructure arrangement and ultra-fine grains.

• Korean Journal of Materials Research
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• v.2 no.6
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• pp.443-451
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• 1992

Effects of various pretreatments on the nucleation of CVD-W deposited on the reactively sputter-deposited TiN was investigated. Incubation period of nucleation and deposition rate decreased by the pretreatment of Ar rf-sputter etching for the depth below 300k, but they increased for the etchig depth over 200A. The preteatment of Ar ion implantation decreased the incubation period of nucleation, but increased deposition rate. Also Si$H_4$flushing pretreatment decreased the incubation period of nucleation slightly due to the absorption of Si by TiN surface.

• Journal of the Korean Ceramic Society
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• v.31 no.3
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• pp.249-256
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• 1994

By surface structure and X-ray topographic observation, growth mechanism of NAB single crystal grown by TSSG technique using a BaB4O7 flux was studied. Surface structure of grown crystals were investigated by optical microscope. Growth history and crystal defects included within grown crystal were investigated using X-ray topography. The {001} faces were grown by 2-D nucleation growth. As decreasing cooling rate, growth mechanism of {111} and {11} was changed from 2-D nucleation growth to the growth by screw dislocation. Only surface striations developed parallel to a-axis were observed on {010} faces. Growth sector of NAB crystals were divided into {001}, {111}, {010}, {021}, {11}. The inclusion which was usually trapped between {001} faces was investigated.

• Journal of the Korean Applied Science and Technology
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• v.24 no.3
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• pp.219-232
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• 2007

In T-mixer crystallization, supersaturation is generated by mixing of another solvent or non-solvent in order to reduce the solubility of the compound. Also, T-mixer is a type of continuous crystallization. In order to induce micro-mixing, two solutions were mixed rapidly by T-mixer, which formed high supersaturation. As the results, mean size of HMX crystals decreased with increasing de-supersaturation rate $(R_s)$. Eventually, HMX particles ranging from 0.5 to $5{\mu}m$ can be obtained by T-mixer crystallization. Mixing efficiency in T-mixer increased with increasing $R_s$ values. In T-mixer crystallization without surfactants, homogeneous nucleation was formed when S and $R_s$ was over 54 and $1.6{\times}10^3/sec$. In T-mixer crystallization with surfactants, homogeneous nucleation was formed when S and $R_s$ was over 26 and 7.4/sec.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08a
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• pp.224-227
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• 2007

The reconstruction characteristics of MgO (111) textured protective layer by over-frequency accelerated discharge in AC-PDP were investigated and correlated to the variations of electronic structures. The reconstruction process and exaggerated grain growth (EGG) were explained by defect-assisted 2-D nucleation and growth mechanism combined with charged cluster model.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.8 no.3
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• pp.131-150
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• 1979

Recently only a few correlations between various factors due to the different grades of surface roughness for the nucleate pool boiling have been proposed. The main purpose of this work is to test the validity of these types of correlations between related factors to nucleate pool boiling phenomena. The boiling experiments using distilled water were carried out at the heat flux ranging from $7.4\times10^4\;to\;2.4\times10^5kcal/m^2h$ on the sintered porous metal surface with the cavity diameter of 10, n, 40, 70, $100{\mu}$, respectively, at the atmospheric pressure, To determine the bubble sizes, number of nucleation sites, delay and growth time, frequency of bubble emission and rising velocities of bubbles, the high speed motion picture technique was employed. In the correlation $f{\propto}D_b^n$, where f denotes frequency of bubble emission and $D_b$ departure diameter, n, the power factor of $D_b$, have been found to be from -2 to -10/3. The correlation C in the correlation between heat flux q and density of nucleation sites $\frac{N}{A}$, $q=C(\frac{N}{A})^n$, was appeared to be more crucial than the power factor n. The correlation of the heat flux q to the temperature difference ${\Delta}T$ and the density of nucleation sites$\frac{N}{A}$, was proposed to be $$q-460{\Delta}T^{\frac{5}{4}}=K{\Delta}T{\frac{5}{3}}(\frac{N}{A})^{\frac{2}{3}}$$. The values of heat transfer coefficient obtained in this experiments for the porous sintered metal surface appeared to be very high in comparison with the formerly obtained results for the other surfaces.

• Bulletin of the Korean Chemical Society
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• v.33 no.5
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• pp.1541-1546
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• 2012

The early stages of bismuth (Bi) electrodeposition on glass carbon electrode from alkaline electrolyte were studied by cyclic voltammetry, chronoamperometry, scanning electron microscopy, atomic force microscopy and X-ray diffraction. The CV analysis showed that the electrodeposition of Bi was determined to be quasireversible process with diffusion controlled. The current transients for Bi electrodeposition were analyzed according to the Scharifker-Hills model and the Heerman-Tarallo model. It can be concluded that the nucleation and growth mechanism was carried out under a 3D instantaneous nucleation, which was confirmed by SEM analysis. The kinetic growth parameters were obtained through a nonlinear fitting. In addition, the Bi film obtaining at -0.86 V for 1 hour was of compact and uniform surface with good smoothness, small roughness and a very high purity. The Bi film were indexed to rhombohedral crystal structure with preferred orientation of (0 1 2) planes to growth.

• Proceedings of the Korean Ceranic Society Conference
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• 2003.04a
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• pp.162.1-162
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• 2003