• Journal of Ginseng Research
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• v.19 no.1
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• pp.45-50
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• 1995

(20S)- and (20R)-protopanaxadiol were prepared from crude ginseng saponin by chemical treatment. The $^{1}H$- and $^{13}C$-NMR signals of these compounds were fully assigned by various NMR techniques such as DEPT, 1H-1H COSY, HMQC, HMBC and NOESY.

• Journal of the Korean Magnetic Resonance Society
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• v.25 no.2
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• pp.17-23
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• 2021

High mobility group protein B1 (HMGB1) is a highly conserved, non-histone, chromatin associated nuclear protein encoded by HMGB1 gene. HMGB1 proteins may be general co-factors in Hox-mediated transcriptional activation that facilitate the access of Hox proteins to specific DNA targets. It is unclear that the exact binding interface of Hoxc9DBD and HMGB1. To identify the interface and binding affinity of Hoxc9DBD and HMGB1 A-box, the paramagnetic probe, MTSL was used in NMR titration experiment. It is attached to the N-terminal end of HMGB1 A-box by reaction with thiol groups. The backbone assignment of HMGB1 A-box was achieved with 3D NMR techinques. The ¹⁵N-labeled HMGB1 A-box was titrated with MTSL-labeled Hoxc9DBD respectively. Based on the chemical shift changes we can identify the interacting residues and further map out the binding sites on the protein structure. The NMR titration result showed that the binding interface of HMGB1 A-box is around loop-1 between helix-1 and helix-2. In addition, the additional contacts were found in N- and C-terminus. The N-terminal arm region of Hoxc9DBD is the major binding region and the loop between helix1 and helix2 is the minor binding region.

• The KIPS Transactions:PartD
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• v.14D no.2
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• pp.217-224
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• 2007

In order to determine the value and type statically. CTOC uses the SSA Form which separates the variable according to assignment. The SSA Form is widely being used as the intermediate expression of the compiler for data flow analysis as well as code optimization. However, the conventional SSA Form is more associated with variables rather than expressions. Accordingly, the redundant expressions are eliminated to optimize expressions of the SSA From. This paper defines the partial redundant expression to obtain a more optimized code and also implements the technique for eliminating such expressions.

• Archives of Pharmacal Research
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• v.14 no.2
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• pp.160-164
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• 1991

The existence in nature of two isomers of 28-nortriterpenes is known. One is normal D/E cis form and the other is $17\alpha$-hydrogen D/E trans form. Since the latter cannot exist with ring D in the chair conformation, the chiroptical method is not applicable to determination of the absolute configuration. The stereochemical assignment would now be made by NMR data. Confirmation of this view could be provided by the synthesis of $3\beta, 21\beta-{dihydroxy-16-keto-28-nor-17}\alpha, \;18\beta-{olean-12-ene}$ as a model compound.

• Journal of the Korean Magnetic Resonance Society
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• v.4 no.2
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• pp.125-132
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• 2000

The detailed $^1$H and $^{13}$ C NMR assignments of a novel sucrose isovaleryl ester isolated from the seed of Euphorbia Lathyris L., were achieved by one-and two-dimensional techniques. The new sucrose ester was characterized as an $\alpha$-D-glucopyranoside, 3,4,6-tris-O-(3-methyl-1-oxobutyl)-$\beta$-D-fructofuranosyl, 2,6-bis(3-methylbutanoate); sucrose 4,7,8,11,12-pentaisovalerate by MS and NMR experiments.

• Journal of the Korean Magnetic Resonance Society
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• v.27 no.2
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• pp.10-15
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• 2023

The Strain-Promoted Azide-Alkyne Cycloaddition (SPAAC) is a powerful method for synthesizing triazoles, even under physiological conditions, without a copper catalyst. This technique provides an efficient means for everyone to synthesize complex triazole derivatives rapidly. In order to investigate the configuration of triazole derivatives using bicyclo[6.1.0.]-nonyne (BCN) and chiral azide, it is necessary to employ the 2D NMR. Both 1D and 2D NMR (COSY, HSQC, ¹⁵N HMBC) are used to analyze the complex triazole product containing cyclooctyne, a diastereomeric product. The stereometric difference of the proton bonded to the same carbon is determined through the HSQC assignment. The intriguing splitting pattern of carbon resonances also reveals their diastereomeric configuration and will aid in further research based on physiological knowledge.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.29 no.9
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• pp.668-676
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• 2018

In satellite communications, a modulation technique with a low peak-to-average power ratio, high transmission efficiency, and low bit error rate(BER) is required, and differential amplitude and phase shift keying(DAPSK) modulation technique has been appraised as a technology that meets these requirements. However, because conventional DAPSK modulation uses a regular constellation diagram, the Euclidean distance between the symbols in the inner concentric circles of the constellation are quite short. Such a characteristic degrades the BER. In this paper, we propose a DAPSK system that uses an efficient constellation assignment to improve the performance of existing DAPSK systems and evaluate the performance of the proposed scheme. From the simulation results, we confirm that the proposed 16-DAPSK system achieves an signal-to-noise ratio gain of 0.8 dB over the conventional approach at a BER condition of $10^{-4}$ when the number of symbols used in the symbol detector of the receiver is 2.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.40 no.9
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• pp.1719-1721
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• 2015

In this paper, we investigate a frequency assignment problem from graph theory for military communications. We propose an algorithm based on the graph coloring theory and confirm that we utilize 0.77 times lower number of frequencies. We also propose a hybrid algorithm that facilitates a trade-off between the range and the spectrum utilization gain.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.9 no.8
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• pp.2797-2820
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• 2015

In order to accommodate huge number of antennas in a limited antenna size, a large scale antenna array is expected to have a three dimensional (3D) array structure. By using the Active Antenna Systems (AAS), the weights of the antenna elements arranged vertically could be configured adaptively. Then, a degree of freedom (DOF) in the vertical plane is provided for system design. So the three-dimension MIMO (3D MIMO) could be realized to solve the actual implementation problem of the massive MIMO. However, in 3D massive MIMO systems, the pilot contamination problem studied in 2D massive MIMO systems and the inter-cell interference as well as inter-vertical sector interference in 3D MIMO systems with vertical sectorization exist simultaneously, when the number of antenna is not large enough. This paper investigates the interference management towards the above challenges in 3D massive MIMO systems. Here, vertical sectorization based on vertical beamforming is included in the concerned systems. Firstly, a cooperative joint vertical beams adjustment and pilot assignment scheme is developed to improve the channel estimation precision of the uplink with pilots being reused across the vertical sectors. Secondly, a downlink interference coordination scheme by jointly controlling weight vectors and power of vertical beams is proposed, where the estimated channel state information is used in the optimization modelling, and the performance loss induced by pilot contamination could be compensated in some degree. Simulation results show that the proposed joint optimization algorithm with controllable vertical beams' weight vectors outperforms the method combining downtilts adjustment and power allocation.

• Journal of the Korean Magnetic Resonance Society
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• v.5 no.1
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• pp.29-36
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• 2001

The structures of two VBS (viral binding site) RNAs, SL1 and SL2, of Yeast Saccharomyces cerevisiae vims have been studied by 2D and 3D NMR experiments. VBSs play a crucial role in viral particle binding to the plus strand and packaging of the RNA. The secondary structures of the two VBS RNAs share a common feature of the stem-internal loop-stem-hairpin loop structure although the size of the internal loops of SL1 and SL2 differs. 2D experiments were sufficient for fill assignments of SL1. However, isotope labeling of the sample and multidimensional experiments were required for 28-nucleotide-long SL2 due to the spectral overlap. Several 3D HCCH experiments have accomplished full assignment of SL2 RNA.