• 제목/요약/키워드: 2D Materials

검색결과 6,149건 처리시간 0.037초

Constitutive Equations Based on Cell Modeling Method for 3D Circular Braided Glass Fiber Reinforced Composites

  • Lee, Wonoh;Kim, Ji Hoon;Shin, Heon-Jung;Chung, Kwansoo;Kang, Tae Jin;Youn, Jae Ryoun
    • Fibers and Polymers
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    • 제4권2호
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    • pp.77-83
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    • 2003
  • The cell modeling homogenization method to derive the constitutive equation considering the microstructures of the fiber reinforced composites has been previously developed for composites with simple microstructures such as 2D plane composites and 3D rectangular shaped composites. Here, the method has been further extended for 3D circular braided com-posites, utilizing B-spline curves to properly describe the more complex geometry of 3D braided composites. For verification purposes, the method has been applied for orthotropic elastic properties of the 3D circular braided glass fiber reinforced com-posite, in particular for the tensile property. Prepregs of the specimen have been fabricated using the 3D braiding machine through RTM (resin transfer molding) with epoxy as a matrix. Experimentally measured uniaxial tensile properties agreed well with predicted values obtained for two volume fractions.

Magneto-transport Properties of La0.7Sr0.3Mn1+dO3-Manganese Oxide Composites Prepared by Liquid Phase Sintering

  • Kim, Hyo-Jin;You, Jae-Hyoung;Choi, Soon-Mi;Yoo, Sang-Im
    • Journal of Magnetics
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    • 제19권3호
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    • pp.221-226
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    • 2014
  • Significantly enhanced low-field magnetoresistance (LFMR) and maximum dMR/dH {$(dMR/dH)_{max}$} values were successfully achieved from $La_{0.7}Sr_{0.3}MnO_3$(LSMO)-manganese oxide composite samples prepared by liquid phase sintering, compared with those of the same composites prepared by solid state reaction. For this study, pure LSMO and LSMO-manganese oxide composites with various nominal compositions of (1-x)LSMO-$xMn_2O_3$ (x = 0.1, 0.2, 0.3, 0.4, and 0.8) were sintered at $1450^{\circ}C$, above the eutectic temperature of $1430^{\circ}C$, for 1 h in air. The highest LFMR value of 1.28% with the highest $(dMR/dH)_{max}$ value of 21.1% $kOe^{-1}$ was obtained from the composite sample with x = 0.3 at 290 K in 500 Oe. This enhancement of LFMR and $(dMR/dH)_{max}$ values is ascribed to efficient suppression of magnetic disorder at the LSMO grain boundary, by forming a characteristic LSMO-manganese eutectic structure.

Fabrication of a Porous Copper Current Collector Using a Facile Chemical Etching to Alleviate Degradation of a Silicon-Dominant Li-ion Battery Anode

  • Choi, Hongsuk;Kim, Subin;Song, Hayong;Suh, Seokho;Kim, Hyeong-Jin;Eom, KwangSup
    • Corrosion Science and Technology
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    • 제20권5호
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    • pp.249-255
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    • 2021
  • In this work, we proposed a facile method to fabricate the three-dimensional porous copper current collector (3D Cu CC) for a Si-dominant anode in a Li-ion battery (LiB). The 3D Cu CC was prepared by combining chemical etching and thermal reduction from a planar copper foil. It had a porous layer employing micro-sized Cu balls with a large surface area. In particular, it had strengthened attachment of Si-dominant active material on the CC compared to a planar 2D copper foil. Moreover, the increased contact area between a Si-dominant active material and the 3D Cu could minimize contact loss of active materials from a CC. As a result of a battery test, Si-dominant active materials on 3D Cu showed higher cyclic performance and rate-capability than those on a conventional planar copper foil. Specifically, the Si electrode employing 3D Cu exhibited an areal capacity of 0.9 mAh cm-2 at the 300th cycles (@ 1.0 mA cm-2), which was 5.6 times higher than that on the 2D copper foil (0.16 mAh cm-2).

유도결합 플라즈마 화학기상증착법을 이용한 Ni/SiO2/Si 기판에서 그라핀 제조 (Synthesis of Graphene on Ni/SiO2/Si Substrate by Inductively-Coupled Plasma-Enhanced Chemical Vapor Deposition)

  • 박영수;허훈회;김의태
    • 한국재료학회지
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    • 제19권10호
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    • pp.522-526
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    • 2009
  • Graphene has been effectively synthesized on Ni/SiO$_2$/Si substrates with CH$_4$ (1 SCCM) diluted in Ar/H$_2$(10%) (99 SCCM) by using an inductively-coupled plasma-enhanced chemical vapor deposition. Graphene was formed on the entire surface of the 500 nm thick Ni substrate even at 700 $^{\circ}C$, although CH$_4$ and Ar/H$_2$ gas were supplied under plasma of 600 W for 1 second. The Raman spectrum showed typical graphene features with D, G, and 2D peaks at 1356, 1584, and 2710 cm$^{-1}$, respectively. With increase of growth temperature to 900 $^{\circ}C$, the ratios of the D band intensity to the G band intensity and the 2D band intensity to the G band intensity were increased and decreased, respectively. The results were strongly correlated to a rougher and coarser Ni surface due to the enhanced recrystallization process at higher temperatures. In contrast, highquality graphene was synthesized at 1000 $^{\circ}C$ on smooth and large Ni grains, which were formed by decreasing Ni deposition thickness to 300 nm.

잉크젯 프린팅을 이용한 연속 조성 세라믹 화합물 구조체 형성 (Additive Manufacturing of Various Ceramic Composition Using Inkjet Printing Process)

  • 박재현;최정훈;황광택;김진호
    • 한국재료학회지
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    • 제30권11호
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    • pp.627-635
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    • 2020
  • 3D printing technology is a processing technology in which 3D structures are formed by fabricating multiple 2D layers of materials based on 3D designed digital data and stacking them layer by layer. Although layers are stacked using inkjet printing to release various materials, it is still rare for research to successfully form a product as an additive manufacture of multi-materials. In this study, dispersion conditions are optimized by adding a dispersant to an acrylic monomer suitable for inkjet printing using Co3O4 and Al2O3. 3D structures having continuous composition composed of a different ceramic material are manufactured by printing using two UV curable ceramic inks whose optimization is advanced. After the heat treatment, the produced structure is checked for the formation and color of the desired crystals by comparing the crystalline analysis according to the characteristics of each part of the structure with ceramic pigments made by solid phase synthesis method.

2-D Braided Textile 금속복합재료의 성형과 특성 해석 (Fabrication and Analytical Characterization of 2-D Braided Textile Metal Matrix Composites)

  • 이상관;김효준;변준형;홍순형
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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    • pp.38-41
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    • 2001
  • A new 2-D braided textile metal matrix composite was developed and characterized. The constituent materials consist of PAN type carbon fiber as reinforcements and pure aluminum as matrices. The braided preforms of different braider yarn angles were fabricated. For a fixed bundle size of 12K, three braider yarn angles was selected: $30^{\circ}$, $45^{\circ}$, and $60^{\circ}$. The braided preforms were infiltrated with pure Al by vacuum assisted squeeze casting. Through the investigation of melt pressing methods and the effects of process parameters such as applied pressure, and pouring temperature, the optimal process conditions were identified as follows: applied pressure of 60MPa, pouring temperature of $800^{\circ}C$. Using the measured geometric parameters, 3-D engineering constants of metal matrix composites have been determined from the elastic model, which utilizes the coordinate transformation and the averaging of stiffened and compliance constants based upon the volume of each reinforcement and matrix material.

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카본블래랙과 탄소섬유를 포함하는 에폭시 복합체의 마이크로파 흡수 특성 (Microwave Absorbing Characteristics of Epoxy Composites Containing Carbon Black and Carbon Fibers)

  • Lv, Xiao;Yang, Shenglin;Jin, Junhong;Zhang, Liang;Li, Guang;Jiang, Jianming
    • 폴리머
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    • 제33권5호
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    • pp.420-428
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    • 2009
  • In this study, the composites containing carbon black (CB) or carbon fibers were prepared, and the microwave absorbing properties and the absorption mechanism of them were investigated and discussed in the frequency range of 2-18 GHz, respectively. The optimum mass fraction of CB has been found as 6%, and the carbon fibers were discovered to absorb radar wave either under parallel or vertical polarization, the suitable gap distance between each bundle of which was 5 mm. According to the results of the single constitute absorber samples, the structured composites with the two kinds of absorbers combination were fabricated and studied at 2-18 GHz. The top layer absorbers affect the absorption performance a lot; the maximum reflection loss of composites with CB as top layer absorbers was -31.8 dB with the frequency range of 2.4 GHz below -10 dB, and the other type with CFs as the top layer absorbers obtained the reflection loss peak value of -31.4 dB with 2 GHz below-10 dB.

Warm Tensile Deformation Behavior and Constitutive Equation of Supersaturated Solid-Solutionized Al-9Mg Extruded Alloy

  • Seung Y. Yang;Bong H. Kim;Da B. Lee;Kweon H. Choi;Nam S. Kim;Seong H. Ha;Young O. Yoon;Hyun K. Lim;Shae Kim;Young J. Kim
    • Archives of Metallurgy and Materials
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    • 제66권4호
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    • pp.1013-1018
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    • 2021
  • In this paper, as a purpose to apply the supersaturated solid-solutionized Al-9Mg alloy to the structural sheet parts of automotive, tensile tests were conducted under the various conditions and a constitutive equation was derived from the tensile test results. Al-9Mg alloy was produced using a special Mg master alloy containing Al2Ca during the casting process and extruded into the sheet. In order to study the deformation behavior of Al-9Mg alloy in warm temperature forming environments, tensile tests were conducted under the temperature of 373 K-573 K and the strain rate of 0.001/s~0.1/s. In addition, by using the raw data obtained from tensile tests, a constitutive equation of the Al-9Mg alloy was derived for predicting the optimized condition of the hot stamping process. Al-9Mg alloy showed uncommon deformation behavior at the 373 K and 473 K temperature conditions. The calculated curves from the constitutive equation well-matched with the measured curves from the experiments particularly under the low temperature and high strain rate conditions.