• 센서학회지
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• 제21권2호
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• pp.96-102
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• 2012

This paper addresses photometric distortion problems of a compact 3D scanning sensor which is composed of a micro-size and inexpensive camera-projector system. Recently, many micro-size cameras and projectors are available. However, erroneous 3D scanning results may arise due to the poor and nonlinear photometric properties of the sensors. This paper solves two inherent photometric distortions of the sensors. First, the response functions of both the camera and projector are derived from the least squares solutions of passive and active calibration, respectively. Second, vignetting correction of the vision camera is done by using a conventional method, however the projector vignetting is corrected by using the planar homography between the image planes of the projector and camera, respectively. Experimental results show that the proposed technique enhances the linear properties of the phase patterns that are generated by the sensor.

• 대한화학회지
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• 제42권2호
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• pp.197-202
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• 1998

1-(2-Pyridylazo)-2-Naphthol (PAN)은 많은 금속이온들과 착색된 착물을 형성함으로 분광시약 또는 금속지시약으로 널리 사용된다. 본 연구는 PAN을 이동상에 첨가하여 Cu(II), Ni(II) , Zn(II), Co(II) , 및 Fe(III)이온들과 착물을 형성시켜 역상 액체크로마토그래피법으로 분리하였다. 이들 금속착물들은 570nm에서 분광광도 검출기로 검출되었고, 이들 금속이온의 머무름을 조사하기 위하여 이동상의 pH, 이온세기 및 유기용매 조성의 변화에 따른 크로마토그램과 용량인자를 측정하였다. 이상의 실험결과에서 얻은 최적조건하에서 금속이온을 분리한 결과 좋은 크로마토그램을 얻었으며, 검출한계(S/N)도 ppb단위까지 검출이 가능함을 알 수 있었다.

• 분석과학
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• 제35권2호
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• pp.82-91
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• 2022

Grayanotoxin-contaminated honey exhibits toxicity. In this study, a reliable and sensitive liquid-chromatography-tandem-mass-spectrometric method (LC-MS/MS) was developed and validated for the quantitation of grayanotoxin I and grayanotoxin III in honey. The grayanotoxins were extracted from honey via solid phase extraction and separated on a biphenyl column with a mobile phase consisting of 0.5 % acetic acid in water and methanol. Mass spectrometric detection was performed in the multiple-reaction monitoring mode with positive electrospray ionization. The calibration curve covered the range 0.25 to 100 ㎍/g. The intra- and inter-day deviations were less than 10.6 %, and the accuracy was between 94.3 and 114.0 %. The validated method was successfully applied to the determination of grayanotoxins in mad honey from Nepal. The concentrations of grayanotoxin I and grayanotoxin III in 33 out of 60 mad honey samples were 0.75 - 64.86 ㎍/g and 0.25 - 63.99 ㎍/g, respectively. The method established herein would help in preventing and confirming grayanotoxin poisoning.

• Journal of Pharmaceutical Investigation
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• 제22권1호
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• pp.63-68
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• 1992

An HPLC procedure with UV detection has been developed for the quantitation of flurbiprofen released into isopropyl myristate used as the receptor phase in an in vitro membraneless drug diffusion cell. The drug and the internal standard (oxaprozin) were extracted from isopropyl myristate with a mixture of dimethylsulfoxide:methanol:water (2:1:1) and quantitated using a reverse phase $C_{18}$ column. The chromatograms were completely free from interfering peaks, and the relative retention times of flurbiprofen and the internal standard were 4.9 and 6.8 min, respectively. Calibration plots were linear over the concentration range of $1-200\;{\mu}g/ml$ of flurbiprofen with correlation coefficients, all higher than 0.99. The mean intra-day precision and accuracy among three replicate sets of the assay in a day were 4.26 and 4.52%, respectively, whereas the mean inter-day precision and accuracy were 3.35 and 3.64%, respectively. The mean recovery of the drug was 92.5% over the calibration range. The method was simple, reliable and accurate for the quantitation of flurbiprofen in unpurified isopropyl myristate.

• Bulletin of the Korean Chemical Society
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• 제23권3호
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• pp.488-496
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• 2002

SPME techniques have proven to be very useful tools in the analysis of wide VOCs in the air. In this study, we estimated VOCs in ambient and workplace air using a Tedlar ba /SPME/GC/MS system. The calibration curve was set to be linear over the range of 1-30 ppbv. The detection limits ranged from 10 pptv to 0.93 ppbv for all VOCs. Reproducibility of TO-14 target gas mixtures by SPME/GC/MS averaged at 8.8 R.S.D (%). Air toxic VOCs (hazardous air pollutants, HAPs) containing a total of forty halohydrocarbons, aromatics, and haloaro-matic carbons could be analyzed with significant accuracy, detection limit and linearity at low ppbv level. Only reactive VOCs with low molecular weight, such as chloromethane, vinylchloride, ethylchloride and 1,2-dichloro-ethane, yielded relatively poor results using this technique. In ambient air samples, ten VOCs were identified and quantified after external calibration. VOC concentration in ambient and workplace air ranged from 0.04 to 1.85 ppbv. The overall process was successfully applied to identify and quantify VOCs in ambient/workplace air.

• 대한기계학회논문집B
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• 제29권6호
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• pp.671-686
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• 2005

The transient nature and complex geometries of two-phase gas-liquid flows cause fundamental difficulties when measuring flow velocity using an electromagnetic flowmeter. Recently, a current-sensing flowmeter was introduced to obtain measurements with high temporal resolution (Ahn et al.). In this study, current-sensing flowmeter theory was applied to measure the fast velocity transients in slug flows. The velocity fields of axisymmetric gas-liquid slug flow in a vertical pipe were obtained using Volume-of-Fluid (VOF) method, and the virtual potential distributions for the electrodes of finite size were also computed using the finite volume method for simulating slug flow. The output signal prediction for slug flow was carried out from the velocity and virtual potential (or weight function) fields. The flowmeter was numerically calibrated to obtain the cross-sectional liquid mean velocity at an electrode plane from the predicted output signal. Two calibration parameters are proposed for this procedure: a flow pattern coefficient and a localization parameter. The flow pattern coefficient was defined by the ratio of the liquid resistance between the electrodes for two-phase flow with respect to that for single-phase flow, and the localization parameter was introduced to avoid errors in the flowmeter readings caused by liquid acceleration or deceleration around the electrodes. These parameters were also calculated from the computed velocity and virtual potential fields. The results can be used to obtain the liquid mean velocity from the slug flow signal measured by a current-sensing flowmeter.

• 한국통신학회논문지
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• 제29권2C호
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• pp.306-314
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• 2004

배열 안테나를 사용하고 있는 CDMA 기반의 이동 통신 기지국은 효율적인 빔 형성을 위해서 배열 안테나 시스템을 이루고 있는 송수신기 모듈의 정확한 성능을 필요로 하며 이를 위해 오차 보정이 반드시 필요하다. 일반적으로 오차 보정은 internal 오차 보정과 external 오차 보정으로 크게 구분 할 수 있다. 특히 internal 오차 보정은 수신기 모듈을 이루고 있는 RF/IF 회로 소자들의 특성이 변하기 때문에 정기적으로 오차 보정이 필요하다고 알려져 있다. 본 논문에서는 비동기 CDMA 시스템에서 안테나 배열 소자들 간의 진폭 이득과 위상 응답에 오차가 생길 때 온라인으로 보정 할 수 있는 알고리듬을 제안한다. 부공간(subspace) 기반의 알고리듬의 성능 평가와 분석 결과를 제시하기 위해 실험으로 측정한 데이터를 이용하였고, simulated annealing이라는 최적화 방법을 사용하여 부공간(subspace) 기반의 알고리듬에서 발생하는 초기값 문제를 해결하고 모의실험을 통해 확인하였다.

• 항공우주기술
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• 제13권2호
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• pp.142-149
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• 2014

저궤도위성은 발사 이후 초기 운영[1] 및 검보정 단계를 거쳐 정상 운영 단계로 진입한다. 정상 운영 단계에서는 이상 현상에 대한 대응조치[2], 궤도조정 작업 이외의 대부분 기간 동안 지상국으로부터 임무 명령을 수신하고 영상 촬영 및 전송 임무를 수행하게 된다. 저궤도위성과 지상국 시스템이 모두 관여된 임무수행능력은 저궤도위성 프로그램 성공 판단의 핵심 지표이고, 저궤도위성 프로그램 추진 목적과 일치하는 항목이기 때문에 지상 시험 단계에서 철저한 검증을 통해 신뢰성을 확보해야 한다. 지상 시험단계에서 지상국과 위성의 역할을 검증함으로써 임무수행능력에 대한 신뢰성을 확보하기 위해서는 저궤도위성의 실제 운용 상황과 유사한 시나리오를 작성하고 이를 바탕으로 명령을 생성하여 위성에 전달하며, 영상과 건강상태 텔레메트리(Telemetry) 데이터를 수신하는 등의 임무수행 전체 주기에 대한 검증이 필요하다. 이 논문은 저궤도위성과 지상국간 접속 환경을 활용해 수행된 임무수행능력 지상 검증 시험 설계 및 수행 결과에 대해 다룬다. 시험 설계시 고려되어야 할 항목과 이를 바탕으로 설계된 시험에 대해 상세히 서술하고 결과에 대해 정리하였다.

• 약학회지
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• 제31권5호
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• pp.315-321
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• 1987

A high performance liquid chromatographic method was developed for the determination of glycyrrhetinic acid contained in licorice powder. Glycyrrhetinic acid which is hydrolysate of glycyrrhizin extracted from licorice powder, was determined with good result by HPLC using 2-bromoacetyltriphenylene labeling reagent. The glycyrrhetinic acids were labeled with 2-bromoacetyltriphenylene in acetonitrile using 18-crown-6-ether and KOH as a catalyst. Derivatized glycyrrhetinic acids were separated from the extracted licorice powder on a reversed-phase column (chemopak $C_{18}$) using 100% acetonitrile as a mobile phase and monitored by an UV-detector at 268nm. Linearity of calibration curve was obtained between 5 ng and 20 ng, and the lower limit of detection was 2 ng. The recovery of glycyrrhetinic acid to licorice powder was about 99.3%. This method was sensitive, reliable and useful for, determination of glycyrrhetinic acid.

• Natural Product Sciences
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• 제19권2호
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• pp.145-149
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• 2013

A simple reversed phase HPLC method was established for quantitative determination of liquiritigenin (1), genistein (2), isoliquiritigenin (3), and 7-hydroxyflavanone (4) from stems of Spatholobus suberectus Dunn (Leguminosae) using a binary gradient of $H_2O$ and MeOH as a mobile phase with UV detection at 280 nm. All calibration curves showed good linear regression ($r^2$ > 0.998) within test ranges. The detection limits of the four compounds were $0.43{\sim}1.63{\mu}g/mL$. The contents of four flavonoids (1 - 4) from the stem of S. suberectus were 6.54 mg/g, 1.66 mg/g, 6.65 mg/g, and 1.93 mg/g, respectively.