• Bulletin of the Korean Chemical Society
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• 제28권11호
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• pp.1996-2002
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• 2007

The redox behavior of a [Ni6(μ3-Se)2(μ4-Se)3(Fe(η 5-C5H4P-Ph2)2)3] (= [Ni-Se-dppf], dppf = 1,1-bis(diphenylphosphino) ferrocene) cluster was studied using platinum (Pt) and glassy carbon electrodes (GCE) in nonaqueous media. The cluster showed electrochemical activity at the potential range between +1.6 and ?1.6 V. In the negative region (0 to ?1.6 V), the cluster exhibited two-step reductions. The first step was one-electron reversible, while the second step was a five-electron quasi-reversible process. On the other hand, in the positive region (0 to +1.6 V), the first step involved one-electron quasi-reversible process. The applicability of the cluster was found towards the electrocatalytic reduction of CO2 and was evaluated by experiments using rotating ring disc electrode (RRDE). RRDE experiments demonstrated that two electrons were involved in the electrocatalytic reduction of CO2 to CO at the Se-Ni-dppf-modified electrode.

• 한국실내디자인학회논문집
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• 제3호
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• pp.58-63
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• 1994

As following four steps, we can make a development about Model-Curriculum of Interior Architecture by an approach of occupational cluster in a College. Step. 1.Selecting of an occupational cluster in which students want to get a job. Step 2. Abstracting and analyzing about occupation , job and task of occupational cluster. Step.3. Selecting of courses by the systematization of occupation, job and task. Step.4. Selecting the goals of instruction in Interior Architecture. Through the above steps, the change of occupation has been promoted among occupational cluster by the development of curriculum based on the planning of Interior Architecture which has the widest range of job and task.

• 한국지역사회생활과학회지
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• 제21권4호
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• pp.619-631
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• 2010

The purpose of this study is to segment and examine urban farmers behavior by applying a two-step cluster analysis and multi-nominal logit model. The data were collected by a telephone survey with two-staged stratified random sampling in the cities around the country for the purpose of acquiring representative data. Respondents were asked to describe their awareness of urban agriculture, their agricultural activity, and sociodemographic characteristics. Among 2,000 cases, 381 cases(19.1%) which were of participants in urban agriculture were analysed in SPSS. From the findings, 27.3% of respondents had heard the word 'urban agriculture', and 25.5% of them regarded themselves as urban farmers. Four different clusters were derived from two-step clusters based on motive, place, companion, area and hours. They were 'Large scale hobby farming(cluster 1)', ‘Weekend farm/ hobby farming(cluster 2)', 'Land/ Self-supporting farming(cluster 3)', and 'Small scale hobby farming(cluster 4)'. The result of multinomial logistic regression showed that there were significant differences among these four segmented groups in terms of age, city size and housing type. In other words, there is quite a possibility that urbanites select different urban farming types according to their socio-demographic profiles. Therefore, the urbanite profiles can be used as the basis for promoting policy of several urban agriculture types. According to the result, policy directions for facilitating urban agriculture were presented.

• 응용통계연구
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• 제20권1호
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• pp.23-38
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• 2007

세분화는 크게 목적변수의 유무에 따라 분석방법이 달라지게 된다. 본 논문은 특수법인의 경영지표를 바탕으로 목적변수가 존재하지 않을 경우의 세분화를 통해 전략방향을 도출하는 사례 연구를 제안하고자 한다. 군집분석을 통한 세분화의 경우, 많은 변수를 사용하여 분류를 하게 되면 군집별 특성화가 어렵게 된다. 따라서 군집의 특성을 잘 반영할 수 있는 대표적 요인변수를 요인분석을 통해 추출하고 이 대표요인을 바탕으로 2단계 군집분석을 통한 세분화를 고려하였다. 이를 통해 총 6개의 세분화 군집을 도출하고 각 군집 별 강점요인을 강화하고 약점요인을 보완하는 방향으로 전략방향을 설정하여 제안하고자 한다.

• 한국자기학회지
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• 제2권2호
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• pp.91-98
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• 1992

$Co_{67}Fe_{4.5}Nb_{2}Si_{10}B_{15}$ 비정질합금리본에서 2단 어닐링이 자기특성에 미치는 영향을 조사 하였다. 고온인 $480^{\circ}C$ 이상에서 20분간 1단 어닐링한 리본을 저온인 $310^{\circ}C$에서 2시간 동안 2단으로 진공어닐링한 결과 보자력과 각형비는 1단 어닐링한 경우와 거의 비슷한 값들을 나타내었으나, 직류 및 교류투자율은 1단 어닐링에 비해 현저히 높아졌다. 2단 어닐링시 직류 및 1 kHz에서의 교류투자율의 최대치는 각각 약 290,000과 41,000으로서 1단 어닐링에 비해 30% 이상 증가하였다. 어닐링온도에 따른 자성의 변화는 3단계로 나누어 내부응력, 자구크기, cluster 및 결정상의 변화를 주요 요인으로 하여 고찰하였다.

• 응용통계연구
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• 제13권2호
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• pp.343-352
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• 2000

K-평균 군집화(K-means clustering)는 비계층적 군집화 방법이 하나로서 큰 자료에서 개체 군집화에 효율적인 것으로 알려져 있다. 그러나 종종 비교적 균일한 대군집의 일부를 소군집에 떼어주는 오류를 범하기도 한다. 이 연구에서는 그러한 현상을 정확히 인지하고 이에 대한 대책으로서 ‘이중 K-평균 군집화(double K-means clustering)’방법을 제시한다. 또한 실증적 사례에 새 방법론을 적용해보고 토의한다.

• Journal of Microbiology and Biotechnology
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• 제18권10호
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• pp.1672-1677
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• 2008

IscR (iron-sulfur cluster regulator) has been reported to be a repressor of the iscRSUA operon, and in vitro transcription reactions have revealed that IscR has a repressive effect on the iscR promoter in the case of [$Fe_{2}S_{2}$] cluster loading. In the present study, the iscR gene from A. ferrooxidans ATCC 23270 was cloned and successfully expressed in Escherichia coli, and then purified by one-step affinity chromatography to homogeneity. The molecular mass of the IscR was 18 kDa by SDS-PAGE. The optical and EPR spectra results for the recombinant IscR confirmed that an iron-sulfur cluster was correctly inserted into the active site of the protein. However, no [$Fe_{2}S_{2}$] cluster was assembled in apoIscR with ferrous iron and sulfide in vitro. Therefore, the [$Fe_{2}S_{2}$] cluster assembly in IscR in vivo would appear to require scaffold proteins and follow the Isc "AUS" pathway.

• 전기전자학회논문지
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• 제24권4호
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• pp.1022-1027
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• 2020

본 논문에서는 GMM-supervector를 특징 파라미터로 하는 SVM 기반 화자 분류에 대해서 실험하였다. 실험을 위한 화자 클러스터를 생성하기 위해서 기존의 SNR 기반 가중치를 반영한 KL거리 기반 화자변화검출을 실행하였다. SVM 기반 화자 분류는 2단계로 이루어져있다. 1단계는 UBM과 화자 모델들간의 SVM 기반 분류를 시행하여 각 클러스터에 화자 정보를 인덱싱한 다음 화자별로 그룹핑한다. 2단계는 화자 클러스터 그룹에 UBM과 화자모델들간의 SVM 기반 분류를 시행한다. SVM의 커널 함수로는 Linear와 RBF를 사용하였다. 실험결과, 1단계에서는 Linear 커널이 화자 클러스터 148개, MDR 0, FAR 47.3, ER 50.7로 좋은 성능으로 보였다. 2단계 실험결과도 Linear 커널이 화자 클러스터 109개, MDR 1.3, FAR 28.4, ER 32.1로 좋은 성능을 보였다.

• 국토계획
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• 제54권1호
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• pp.40-51
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• 2019

The ultimate aim of this study is to diagnose the process stage and look at the step change of transition process to see how the step changes. Therefore, in this study, cluster analysis was conducted by examining four types of commercial characteristics such as Retail Homogeneity, Share of Neighbourhood store, Share of chain store, and Share of cafe & Western food store. Through the cluster analysis, three types have been identified. Type1 is the first step which can explain the time before gentrification occurs and when the ratio of neighborhood facilities is the highest. Type2 is the second step that can explain boutique stage where the gentrification occurs. At this time, the ratio of Cafes & Western food restaurant increased and the proportion of neighborhood shops decreased. And Type3, third step is when the mature gentrification occurs. In the analysis of the transition period, it is necessary to monitor the change of the industry in the period from the first stage to the second stage. In the transition period from the second stage to the third stage, It is necessary to constantly monitor such factors as the increase of shops.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.111-111
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• 2016

Two step PEO ceramic coatings were formed on AZ91 magnesium alloy in $ZrO_2$ nanoparticles and $K_2ZrF_6$ based colloidal electrolyte solution for various voltages. Surface and layers tructure of the coatings was analyzed using SEM (ScanningElectronMicroscope). Structure analysis revealed that surface of the coating was transferred from individual pancake or craters-based structure to cluster-based structure with increasing the voltage of the secondary step process. Further, it was confirmed that the cluster zone was richin Zr-based complexes and formed due to high intensives parks. Increase in the Zr contents as discovered from the EDS analysis confirmed the rise in amorphous form of the Zr-based species, which justified the results of XRD where no increase in the intensity of Zr-based species was observed with increase in voltage. Potentiodynamic polarizariotion and impedance spectroscopy techniques were used to evaluate the corrosion performance of the coatings. The highest corrosion resistance was found for coatings prepared at 240V. The same specimen was found having highest and uniform vickers hardness ~1070.5 HV. The superior mechanical and electrochemical properties of the said coating can be attributed to the defect-less microstructure and the optimal role of $ZrO_2$ nanoparticles in the secondary PEO process at 240V.