• Title/Summary/Keyword: 1,4-Addition

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Increase of Cell Concentration by the Automatic Addition of Glucose and Ammonium to an Alcohol distillery Wastewater Reutilized for Cultivating a Baker's Yeast : Automatic Addition of Ammonium with pH-stat (알콜증류폐액을 이용한 빵효모배양에서 Glucose와 Ammonium의 자동첨가에 의한 종균 : pH-stat 방법에 의한 Ammonium의 자동첨가)

  • 이형춘
    • KSBB Journal
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    • v.15 no.2
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    • pp.134-138
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    • 2000
  • Addition of carbon and nitrogen source to an alcohol distillery wastewater was tried to increase the cell concentration of a b baker's yeast cultivated in that wastewater. Carbon was found to be primary limiting nutrient and nitrogen secondary limiting o one. Glucose addition increased the cell concentration 1.3 times higher than no addition, and both glucose and $(NH_4)_2S0_4$ a addition did 5.8 times. A fed-batch cultivation by the automatic addition of glucose and ammonium was executed. Added g glu$\infty$se was automatically controlled to low concentration by a method using DO as control parameter. Ammonium was a automatically added as NH40H used as pH $\infty$ntrol agent after initiating glucose addition. By this simple cultivation method t the cell concentration $\infty$내d be efficiently increased from 2.6g/L to 12.0g/L, and maximum specific growth rate and biomass y yield to glu$\infty$se were $0.18hr^{-1}$ and about 0.54g/g respectively. By increasing cell concentration, COD of the wastewater m media could be additionally reduced by about 22%.

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Quality Characteristics of Chicken Sausage added with Jubak Powder (주박분말을 첨가한 닭고기 소시지 품질특성)

  • Jong-Pil Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.27 no.1
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    • pp.97-106
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    • 2024
  • This study aimed to quality characteristics date for the industrialization of sausage prepared from chicken meat. The sausages were prepared by chicken meat and Jubak powder of CJ1(0%), CJ2(5%), CJ3(10%), CJ4(15%). In the proximate composition of the crude fat content of CJ4 was high and was increased according to Jubak powder addition ratios. Crude protein of CJ1 showed the highest. pH was increased but TBA, WHC, total cell counts were decreased according to Jubak powder addition ratios. WHC was decreased from the initial 46.77% to the final 38.81% according to Jubak powder addition ratios. TBA was increased from initial 0.16-0.19 to 0.2-0.59 at 15 days. Total cell counts in CJ2, CT3 and CJ4 showed the trend to be decreased according to Jubak powder addition ratios. Number of total cell counts of CJ1, CJ4 were increased from initially 2.2 to 8.9, 6.2 at 15 days. Elasticity, hardness, gumminess and cohesiveness of CT4 showed high value. L, a, b were increased according to Jubak powder addition ratios. In the sensory evaluation, Preference for color, overall of CJ1 showed high value. Preference for appearance flavor, taste of CJ2 showed high value. This result can be applied in storage property of chicken meat sausage added with Jubak powder.

Regioselective Addition Reactions of the Organoindium Reagents onto α,β-Unsaturated Ketones

  • Lee, Phil-Ho;Kim, Hyun;Lee, Koo-Yeon;Seomoon, Dong;Kim, Sun-Dae;Kim, Hee-Chul;Kim, Hyun-Seok;Lee, Mi-Ae;Shim, Eun-Kyong;Lee, Seok-Ju;Kim, Mi-Sook;Han, Mi-Jeong;Noh, Kwang-Hyun;Sridhar, Madabhushi
    • Bulletin of the Korean Chemical Society
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    • v.25 no.11
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    • pp.1687-1691
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    • 2004
  • Regioselectivity on the reactions of ${\alpha},{\beta}$--enones with organoindium such as in situ generated allylindium and allenylindium was systematically studied in the presence of TMSCl as an additive. Treatment of 2-cyclohexen-1-one, carvone, 2-cyclohepten-1-one, and chalcone with allylindium reagent produced 1,4-addition products in good yields, while 2-cyclopenten-1-one, 2-methyl-2-cyclopenten-1-one, 4,4-dimethylcyclohexen-1-one, 3-nonen-2-one, 4-hexen-3-one, and 4-phenyl-3-buten-2-one afforded 1,2-addition products. Indium reagent derived from indium and propargyl bromide in Grignard type gave addition products in good yields, under which the successive addition of ${\alpha},{\beta}$-enone and TMSCl were necessary. Although organoindium reagent derived from propargyl bromide produced propargylated compound in Grignard type except 2-cyclohepten-1-one, indium reagent obtained from 1-bromo-2-butyne having ${\gamma}$-methyl group gave allenylated product inBarbier type.

MO Theoretical Studies on Stereoelectronic Control in the Addition Reaction of 1, 4-Benzoquinone-4-(O-methyloxime)$^*$

  • Ik-Choon Lee;Eun-Sook Han
    • Bulletin of the Korean Chemical Society
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    • v.4 no.1
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    • pp.41-44
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    • 1983
  • The chlorine addition and Diels-Alder cycloaddition of cyclopentadiene to 1, 4-benzoquinone-4-(O-methyloxime) have been studied MO theoretically. It has been shown that the reactions occur predominantly to the quinone ring double bond which is oriented anti to the nitrogen lone pair due to an n-${\sigma}^*$ interaction between the nitrogen lone pair, n, and the app. vicinal bond, causing the ${\pi}$ bond to be weakened and destabilized due to the less conjugation from reduced delocalization.

Effects of Inlet-Manifold Water Addition on the Performance of Kerosene Engines (석유(石油)엔진의 흡기관내(吸氣管內)의 물 부가(附加)가 엔진성능(性能)에 미치는 영향(影響))

  • Yi, Chun Woo;Ryu, Kwan Hee
    • Journal of Biosystems Engineering
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    • v.8 no.1
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    • pp.38-46
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    • 1983
  • This study was carried out to investigate the possibility of improving the performance of a kerosene engine with water addition. The engine used in this study was a single-cylinder, four-cycle kerosene engine with the compression ratio of 4.5. Water could be successfully added into the inlet manifold by an extra carburetor for the volumetric ratios of 5, 10, 20, and 30 percents. Variable speed tests at wide-open throttle were performed for five speed levels in the range of 1,000 to 2,200rpm for each fuel type. Volumetric efficiency and brake specific fuel consumption were determined, and brake thermal efficiency based on the lower heats of combustion of kerosene was calculated. To examine variation in fuel consumption, CO concentration, and cooling water temperature, part load tests were also performed. The results obtained are summarized as follow. (1) Brake torque increased almost in proportion to volumetric efficiency. But the ratio of increase in torque was greater than that of volumetric efficiency. Mean torque over the speed range of 1,000 to 2,200rpm increased 1, 3, 7, and 2 percents for 5, 10, 20, and 30 percents water addition, respectively. The increase in brake torque with water addition was greater at lower speeds. (2) Mean brake specific fuel consumption over the speed range of 1,000 to 2,200rpm decreased 1, 2, 3, and 3 percents for 5, 10, 20, and 30 percents water addition, respectively. (3) Mean temperature of cooling water over the speed range of 1,000 to 2,200rpm decreased 2, 4, 8, and 12 percents for 5, 10, 20, and 30 percents water addition, respectively. (4) The effects of decreasing CO concentration in the exhaust emissions with water addition were significant. At the speed range of 1,000 to 2,200rpm, CO concentration in the exhaust emissions decreased 2, 10, 23, percents for 5, 10, and 20 percents water addition, respectively. (5) Deposits were not discovered in the combustion chamber during the experiment. However, a little rust was formed in the water-supply carburetor.

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A Study on the Microstructural Control of LAS Ceramics (III) : Influence of Li2O.4B2O3 Frit Addition on the Microstructure and Thermal Expansion of $\beta$-Spodumene made from Kaolinite (LAS계 내열충격성 재료의 미세구조 제어(III): Li2O.4B2O3 첨가가 카올린을 공급원으로하여 합성한 $\beta$-Spodumene의 미세구조 및 열팽창특성에 미치는 영향)

  • 박정현;김현민;이화선
    • Journal of the Korean Ceramic Society
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    • v.29 no.8
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    • pp.646-650
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    • 1992
  • Effect of Li2O.4B2O3 frit addition on microstructural and thermal expansion behaviour of the $\beta$-spodumene ceramics made from kaolinite was investigated. With 2.0~4.0 wt% frit addition, the densification by liquid phase sintering caused low water absorption below 3% and enhancement of beding strength. As the amount of frit addition was increased, thermal expansion coefficient was increased to large scale, but in 2 wt% frit addition, its thermal expansion coefficient was constrained to 1.92$\times$10-6$^{\circ}C$-1.

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Kinetic Studies on the Nucleophilic Addition of Thiophenol Derivatives to 4'-[N- (9-Acridinyl) ]-1'-( N- methanesulfonyl) -3'-methoxyquinonediimide

  • 김태린;정동인;변상용
    • Bulletin of the Korean Chemical Society
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    • v.18 no.4
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    • pp.374-379
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    • 1997
  • The rate constants for the nucleophilic addition of thiophenol derivatives (p-OCH3, H, p-CH3, m-CH3, p-Br and p-NO2) to 4'-[N-(9-acridinyl)]-1'-(N-methanesulfonyl)-3'-methoxyquinonediimide (AMQD) were determined by ultraviolet spectrophotometer in water at 5 ℃, and rate equations which can be applied over a wide pH range were obtained. On the basis of pH-rate profile, Bronsted plot, adduct analysis, general base catalysis and substituent effect, a plausible mechanism of this addition reaction was proposed: Below pH 2.5, the reaction proceeded by the addition of thiophenol molecule to 6'-position of quinonoid after protonation at the acridinyl nitrogen. Above pH 6.2, the addition of sulfide anion to 6'-position of quinonoid was rate controlling. However, in the range of pH 3.0-6.0, these two reactions occured competively.

The Function of Halogen Additive in $CH_4/O_2/N_2$ Flames ($CH_4/O_2/N_2$ 화염에서 할로겐 첨가제의 역할)

  • Lee, Ki-Yong;Shin, Sung-Su
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.209-214
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    • 2003
  • Numerical simulations are performed at atmospheric pressure in order to understand the effect of additives on flame speed, flame temperature, the radical concentration, the NOx formation in freely propagating $CH_4/O_2/N_2$ flames. The additives used are carbon dioxide and hydrogen chloride which have a combination of physical and chemical behavior on hydrocarbon flame. In the flame established with the same mole of methane and additive, $CO_2$ addition significantly contributes toward the reduction of flame speed and flame temperature by the physical effect, whereas addition of HCl mainly does by the chemical effect. The impact of HCl addition on the decrease of the radical concentration is about 1.6-1.8 times as large as $CO_2$ addition. Hydrogen chloride addition is higher on the reduction of EINO than $CO_2$ addition because of the chemical effect of HCl.

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Synthesis of Nucleophilic Adducts of Thiols (Ⅰ). Addition of Cysteine to $\beta$-Nitrostyrene Derivatives

  • Kim, Tae-Rin;Choi, Sung-Yong
    • Bulletin of the Korean Chemical Society
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    • v.2 no.4
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    • pp.125-129
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    • 1981
  • The addition reactions of cysteine without blocking amino and carboxyl groups to substituted and unsubstituted ${\beta}$-nitro-styrene derivatives were investigated. ${\beta}$-Nitrostyrene(1a), p-methyl-${\beta}$-nitrostyrene(1b), 3,4,5-trimethoxy-$[\beta}$ -nitrostyrene(1c), $[\varpi}$-3,4-methylenedioxy-${\beta}$ -nitrostyrene(1d), o-, m- and p-chloro-${\beta}$ -nitrostyrene (1e, 1f, 1g) and o-, m- and p-methoxy-${\beta}$-nitrostyrene (1h, 1i, 1j) easily undergo addition reactions with cysteine to form S-(2-nitro-1-phenylethyl)-L-cysteine(3a), S-[2-nitro-1-(p-methyl)phenyl-ethyl]-L-cysteine(3b), S-[2-nitro-1-(3',4',5'-trimethoxy) phenylethyl]-L-cysteine(3c), S-[2-nitro-1-($[\vatpi}$ -3',4'-methylenedioxy)phenylethyl]-L-cysteine(3d), S-[2-nitro-1-(o-chloro)phenylethyl]-L-cysteine(3e), S-[2-nitro-1-(m-chloro)-phenylethyl]-L-cysteine(3f), S-[2-nitro-1-(p-chloro)phenylethyl]-L-cysteine(3g), S-[2-nitro-1-(o-methoxy)phenylethyl]-L-cysteine(3h), S-[2-nitro-1-(m-methoxy)phenylethyl]-L-cysteine(3i) and S-[2-nitro-1-(p-methoxy)phenylethyl]-L-cysteine(3j), respectively. The structure of adducts were confirmed by means of UV-spectrum, IR-spectrum, molecular weight measurement and elemental analysis. The various factors effecting the yield of cysteine adducts to ${\beta}$-nitrostyrene derivatives were also studied.

Photo-electronic Properties of Cd(Cu)S/CdS Thin Films and Diodes Prepared by CBD

  • Cho, Doo-Hee;Kim, Kyong-Am;Song, Gi-Bong
    • Journal of the Korean Ceramic Society
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    • v.45 no.1
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    • pp.30-35
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    • 2008
  • In this paper, CdS/Cd(Cu)S thin films and diodes were manufactured via a chemical bath deposition (CBD) process, and the effects of $NH_4Cl$ and TEA(triethylamine) on the properties of the films were examined. The addition of $NH_4Cl$ significantly increased the thickness of the CdS and Cd(Cu)S films, however, the addition of TEA decreased the thickness in both cases slightly. The addition of $NH_4Cl$ along with TEA increased the film thickness more effectively compared to the addition of only $NH_4Cl$. The thickness of the CdS film prepared from an aqueous solution of 0.007 M $CdSO_4$, 1.3 M $NH_4OH$, 0.03 M $SC(NH_2)_2$, 0.0001 M TEA and 0.03 M $NH_4Cl$ was 310 nm. Dark resistivity of the CdS film was $1.2{\times}10^3\;{\Omega}cm$ and the photo resistivity with $500\;W/cm^2$ irradiation of white light was $20{\Omega}cm$. The Cd(Cu)S/CdS thin film diodes prepared by CBD showed good rectifying characteristics.