• KOMUNHWA
• /
• no.57
• /
• pp.195-210
• /
• 2001

One kiln site of Koryo Earthenware in Hwakok-ri, Ansung was excavated from March 15, 1999 to May 15, 1999 by Museum Team of Ehwa Women's University, and also other one earthenware kiln site was confirmed as exposed figure on the ground. In this study, the

• Korean Chemical Engineering Research
• /
• v.52 no.1
• /
• pp.126-132
• /
• 2014

A pilot-scale electrokinetic (EK) separation field test ($2{\times}3{\times}0.2m^3$, $W{\times}L{\times}D$) was performed in a greenhouse to remove salts from saline soil. Initially, the greenhouse soil had high electrical conductivity (EC), about 9 dS/m, and contained mainly $Ca^{2+}$, $Cl^-$ and $SO_4^{2-}$ ions. After 2 weeks of EK treatment, the soil EC was reduced to 52% compared with its initial value. The EC reduction was mostly achieved within the first week (47%) due to removal of $Na^+$ and $Cl^-$ ions, but ions with a high adsorption capacity such as $Ca^{2+}$ and $SO_4^{2-}$ ions were difficult to be removed. During the EK test, the soil temperature increased and it reached around $50^{\circ}C$ at some regions. For in situ application to soils in cultivation, the current should be controlled to limit increases in temperature, especially near the cathodes. In conclusion, the in situ EK technique is feasible for the restoration of saline greenhouse soils in or no cultivation and an appropriate strategy is necessary for more effective remediation.

• Journal of the KSME
• /
• v.21 no.1
• /
• pp.21-31
• /
• 1981

원자력발전소의 원자로냉각재 압력경계의 건전성과 안정성을 확보하기 위하여 법적 요구조건을 설정함에 있어 파괴역학이 어떻게 적용되었는 가를 설명하였다. 이를 요약하면 다음과 같다. 1) 압력경계에 사용되는 재료의 $RT_{NDT}$를 정의하였다. 이는 무연성천이온도와 같은 개 념의 것으로, 앞으로 재료의 파괴인성은 이 $RT_{NDT}$에 대한 상대온도의 함수로 주어진다. 2)비연성파괴를 방지하기 위한 설계조건으로서 선형탄성 파괴역학에 근거한 조건식을 인용하였다. 여기서 조건식이란 능력확대계수의 합계가 어떠한 조건에서도 이러한 조건식을 만족한다는 것을 해석적으로 확인하고 규제당국의 승인을 받아야 한다. 3) 가동중검사에 발견된 결함으로 합격수준을 초과하는 것은 파괴역학적으로 해석하여 구조적 으로 안전하다는 것은 파괴역학적으로 해석하여 구조적으로 안전하다는 것을 입증하여야 한다. 이때 결함은 원자로의 가동과 더불어 성장하므로 수명기간중 피로파괴에 이를 것인지의 여부도 평가하여야 한다. 이때의 대조균열성장률은 Paris의 power law에 따른다. 4) 고속중성자 (E>1. 0MeV)에 의한 조사취화를 감시하기 위하여 감시시험계획을 사전에 수립 하고 이에 따라 감시시험을 수행하여 조사에 수립하고 이에 따라 감시시험을 수행하여 조사에 의한 원자로용기 재료의 파괴인성의 저하를 평가하여 이를 고려한 충분한 안전여유를 갖는 운 전조건 즉, 압력-온도 한계곡선을 산출하여야 한다. 이때의 취화 정도는 DELTA. $RT_{NDT}$ 와 Upper Shelf Energy의 감소로 나타낸다. 또한, 압력-온도 한계곡선은 선형관성 파괴역학에 입각한 조건식을 이용하여 해당 온도에서의 압력을 산출한다. System을 개발 사용하기 위하여 기존 전자계산소를 이용하는 방법이 바람직하며 System의 도입은 자체운영을 결정하기 전에 경제적인 여건 등 여러가지 문제를 검토하여야 한다. 특히 Turn Key Base로 System를 도입할 경우에는 System의 도입목 적과 사용빈도, 앞으로의 확장성 현재 설계및 생산 과정과의 마찰가능성, 유지보수문제 등을 신 중히 검토하여야 한다. 이제 기계공업도 전자계산기를 이해하고 사용하므로 서 발전할 수 있는 단계가 되었다. 예로부터 좋은 공구를 개발하여 적절히 사용하는 것이 기계공업 발전의 첩경이 었다. 전자계산기는 현대 기술이 개발한 가장 강력하고 사용하기 좋은 공구이다.점에서 피로구열의 안정성장을 논하고, 과거 10여년간의 피로 crack문제에 대한 연구방법, 실험방법 등을 소개하는 방향으로 고 를 진행시켜 나가겠다.에 그 효과가 증대됨을 알 수 있었다.적용한 임상실험이 수행되어야 할 것이다. 또한 위치결정에서 획득한 좌표값의 정확성을 알아보기 위해서 팬톰을 이용한 방사선조사 실험이 추후에 실행되어져야 할 것이다. 그리고 제작된 프레임에 Rotating X선 시스템과 내부 장기의 움직임을 계량화하고 PTV에서의 최적 여유폭을 설정함으로써 정위 방사선수술 및 3 차원 업체 방사선치료에 대한 병소 위치측정과 환자의 자세에 대한 setup 오차측정 결정에 도움이 될 수 있을 것이라고 사료된다. 상대적으로 우수한 것으로 나타났으며, 혼합충전재는 암모니아의 경우 코코넛과 펄라이트의 비율이 7：3인 혼합 재료 3번과 소나무수피와 펄라이트의 비율이 7：3인 혼합 재료 6번에서 다른 혼합 재료에 비하여 우수한 것으로 나타났다. 4. 코코넛과 소나무수피의 경우 암모니아 가스에 대한 흡착 능력은 거의 비슷한 것으로 사료되며,

• The Korean Journal of Ecology
• /
• v.28 no.5
• /
• pp.335-345
• /
• 2005

A study on changes on the distribution of vascular hydrophytes and the growth pattern of Schenoplectus triqueter (Scirpus triqueter) was undertaken at the Nakdong River estuary from 2002 to 2004. The change was due to physical alteration of the estuary for the past 25 years. These plant species are the major food sources for winter waterfowl. A total of 32 species of vascular hydrophytes from 17 families were found in the West Nakdong River (freshwater), the main channel of Nakdong River (freshwater) and the Nakdong River Estuary (brackish water). After the construction of the barrage on the estuary in 1987, the number of hydrophytes has remarkably increased to 17 species (5 species in 1985) in the main channel of the River. In particular, a community of Eurale ferox was found at the backwater wetland of the Daejeo side of the main channel. The introduced species of Eichhornia crassipes and Pistia stratiotes that were epidemic in 2001 at West Nakdong River was not found any more. The other species such as Nymphoides indica, Myriophyllum spicatum, Ruppia spp. were rediscovered. The large area (about 1,300ha) of Zostera spp. was the main sources of food for swans, but disappeared because of direct and indirect impacts of reclamation in the River estuary. Currently, there remains a small patch of Zostera spp. and about 250ha of S. triqueter. Schenoplectus triqueter grew mostly between April-September and tuber formed, between September-October. The growth of S. triqueter up to $60\sim80cm$ in length was observed in 5 sites out of the 7 sites in brackish area. Tubers of S. triqueter were eaten by waterfowls such as swans as winter food. In five sites, tubers took $44\sim57%$ of total biomass in October. Tubers were found in deep layers; $5\sim15cm$ (9%), $15\sim25cm$ (28%), $25\sim40cm$ (55%), below 40cm $(6\sim7%)$. The distribution of vascular hydrophytes has remarkably changed in the Nakdong River Estuary due to the reclamation of the area. In order to determine the extent of changes of the distribution of these plants and the carrying capacity of the area for waterfowl, an intensive research is urgently needed.

• Korean Journal of Mineralogy and Petrology
• /
• v.33 no.3
• /
• pp.251-258
• /
• 2020

Single crystal of fully dehydrated and partially Ca²⁺-exchanged zeolites A (|Ca₄Na₄|[Si₁₂Al₁₂O₄₈]-LTA) was brought into contact with Se in fine pyrex capillary at 523 K for 5 days. Crystal structure of Se-sorbed |Ca₄Na₄|[Si₁₂Al₁₂O₄₈]-LTA has been determined by single-crystal X-ray diffraction techniques at 294 K in the cubic space group $Pm{\bar{3}}m$ (a = 12.2787(13) Å). The crystal structure of yellow |Ca₄Na₄Se₄|[Si₁₂Al₁₂O₄₈]-LTA has been refined to the final error indices of R₁/wR₂ = 0.0960/0.3483 with 327 reflections for which F_o > 4s(F_o). In this structure, 4 Na⁺ and 4 Ca²⁺ ions fill every 6-ring site: These ions are all found at three crystallographic positions, on 3-fold axes equipoints of opposite 6-rings. Selenium atoms are found at three crystallographically distinct positions: 2 Se atoms per unit cell at Se(1) are located opposite 6-rings in the sodalite cavity (Se(1)-Na(1) = 2.53(5) Å) and 1 at Se(2) opposite 4-rings (Se(2)-O(1) = 2.76(10) Å) and 1 at Se(3) opposite 6-rings in the large cavity (Se(3)-Na(1) = 2.48(5) Å). Two molecular of Se₂ (Se(1)-Se(1) = 2.37(7) or 2.90(8) Å and Se(2)-Se(3) = 2.91(5) ) Å) are found in all sodalite cavity and large cavity. Other clusters such as Se₄ and Se₈ could be existed in large cavity. The inter-selenium distances turned out to be longer that of gases Se₂ molecule.

• Journal of Korean Society of Environmental Engineers
• /
• v.28 no.11
• /
• pp.1186-1191
• /
• 2006

Removal efficiency of As(III) through oxidation and adsorption in column reactors was investigated at different ratios of manganese-coated sand(MCS) and iron-coated sand(ICS) : MCS-alone, ICS-alone and both of ICS and MCS. The breakthrough of arsenic immediately occurred from a column reactor with MCS-alone. However, most of the arsenic present in the effluent was identified as As(V) due to the oxidation of As(III) by MCS. While five-times delayed breakthrough of arsenic was observed from a column reactor with ICS-alone. At a complete breakthrough of arsenic, the removed As(III) was 36.1 mg with 1 kg ICS. To find an optimum ratio of ICS and MCS in the column packed with both ICS and MCS, the removal efficiency of As(III) was investigated at three different ratios of ICS/MCS with a fixed amount of ICS. The breakthrough time of arsenic was quite similar in the different ratios ICS/MCS. However, much slower breakthrough of arsenic was observed as the ratio of ICS/MCS decreased. As the ratio of ICS/MCS decreased the concentration of As(III) in the effluent decreased and then showed below 50 ppb at an equal amount of ICS and MCS, suggesting more efficient oxidation of As(III) by greater amount of MCS. When a complete breakthrough of arsenic occurred, the removed total arsenic with an equal amount of ICS and MCS was 68.5 mg with 1 kg of filter material.

• Economic and Environmental Geology
• /
• v.56 no.6
• /
• pp.847-870
• /
• 2023

The safe disposal of high-level radioactive waste requires accurate predictions of the long-term geochemical behavior of radionuclides. To achieve this, the present study was conducted to model geochemical behaviors of uranium (U), plutonium (Pu), and palladium (Pd) under different hydrogeochemical conditions that represent deep groundwater in Korea. Geochemical modeling was performed for five types of South Korean deep groundwater environment: high-TDS saline groundwater (G1), low-pH CO₂-rich groundwater (G2), high-pH alkaline groundwater (G3), sulfate-rich groundwater (G4), and dilute (fresh) groundwater (G5). Under the pH and Eh (redox potential) ranges of 3 to 12 and ±0.2 V, respectively, the solubility and speciation of U, Pu, and Pd in deep groundwater were predicted. The result reveals that U(IV) exhibits high solubility within the neutral to alkaline pH range, even in reducing environment with Eh down to -0.2 V. Such high solubility of U is primarily attributed to the formation of Ca-U-CO₃ complexes, which is important in both G2 located along fault zones and G3 occurring in granitic bedrocks. On the other hand, the solubility of Pu is found to be highly dependent on pH, with the lowest solubility in neutral to alkaline conditions. The predominant species are Pu(IV) and Pu(III) and their removal is predicted to occur by sorption. Considering the migration by colloids, however, the role of colloid formation and migration are expected to promote the Pu mobility, especially in deep groundwater of G3 and G5 which have low ionic strengths. Palladium (Pd) exhibits the low solubility due to the precipitation as sulfides in reducing conditions. In oxidizing condition, anionic complexes such as Pd(OH)₃^-, PdCl₃(OH)₂^-, PdCl₄^2-, and Pd(CO₃)₂^2- would be removed by sorption onto metal (hydro)oxides. This study will improve the understanding of the fate and transport of radionuclides in deep groundwater conditions of South Korea and therefore contributes to develop strategies for safe high-level radioactive waste disposal.

• Parasites, Hosts and Diseases
• /
• v.33 no.4
• /
• pp.289-296
• /
• 1995

The surface ultrastructure of metacercariae and adults of Gymnophallokles seoi, the only known gymnophallid infecting humans, was observed by scanning electron microscopy. Metacercariae were ovoid or pyriform in shape and slightly concave ventrally. The oral sucker had two sizes of type I papillae, small and large, encircling its lip. Type I papillae were arranged in a row on both side oi the body. The ventral pit had several type I papillae on its inner surface. The ventral sucker was covered with cobble-stone like cytoplasmic processes and had 6 type I papillae on its lip. The surface of the body was covered with the tegumental spines except for the ventromedian area between the two suckers. The spines at anterior body were digitated into 3-5 points, and their size decreased at posterior one third or the body. Adult worms were rhomboid or ellipsoid in shape and covered with tegumental spines except for the ventromedian area. The shape and distribution of the tegumental spines and sensory papillae were similar to those of metacercariae. However, sensory papillae arranged in a row on the ventral surface of metacercariae were not observed in adults. The ventral pit became larger and more prominent as the fluke grew. It is suggested that the ventral pit function as an additional adhesive organ to the host tissue.

• Journal of the Korean GEO-environmental Society
• /
• v.8 no.2
• /
• pp.5-9
• /
• 2007

This study carried out to investigate the removal capacity of heavy metals such as Cu (II), Zn (II) and Cd (II) dissolved in aqueous solution in the soils collected from Hyeon-Dong (HD), San-seong (SS), Keum-chon (KC) and Keum-Hac (KH) located in the upper Banbyun stream. The pH of all the soils was weak alkali such as 8.8 9.2. According to the analysis of chemical composition of the soils, the amount of $SiO_2$, $AlO_2$ and CaO were similar in all tested soils. However, the amount of $K_2O$, $FeO_3$ and MgO were different from each soil. The XRD measurement with these soils showed that quartz and feldspar were presented in all tested soils, and the distribution of kaoline, illite, montmorillonite, vermiculite and calcite were different from each soil. The results of the removal capacity of heavy metals indicated that all the soils had more than 98% of the removal efficiency of Cu (II), Zn (II) and Cd (II), and among the heavy metals, Cu (II) was removed the most effectively. These results suggested that the soils collected from the upper Banbyun stream have the high removal capacity of heavy metals, and these soils could be used for the banking a river around the abandoned mine area, containing the higher concentrations of heavy metals than the usual stream.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.224.2-224.2
• /
• 2010

연료개질기는 연료전지 시스템의 핵심 구성요소 중의 하나로 도시가스로부터 수소를 생산하는 역할을 담당한다. 연료개질기는 주로 탈황, 수증기 개질, 수성가스 전이, 선택적 산화 반응의 4단계로 구성되어 있으며 이 중 상온 탈황부분을 제외한 나머지 부분은 일체화 설계를 통해 제작된다. 탈황의 경우 도시가스에 포함된 부취제인 황화합물를 제거하여 후단에 위치한 촉매층이 황에 의해 피독되는 것을 막는 역할을 하며 주로 상온흡착식 탈황제를 사용한다. 황이 제거된 도시가스는 물과 함께 연료개질기로 도입되어 수증기 개질반응을 통하여 수소, 일산화탄소, 이산화탄소 및 소량의 메탄과 미반응 수증기로 구성된 개질가스로 전환된다. 이후의 수성가스 전이반응에서는 일산화탄소가 물과 반응하여 수소 생산량을 늘리며 동시에 일산화탄소의 농도를 낮추게 된다. 또한 고분자 전해질 연료전지에 공급되는 개질가스는 선택적 산화반응을 통하여 일산화탄소의 농도를 10ppm이하로 유지하게 된다. 이러한 기능의 연료개질기 개발의 주요 이슈로는 컴팩트화 및 고효율화이며 이 두가지 요소를 고려하여 연료개질기를 설계하여야 한다. 연료전지 시스템의 전체부피를 줄이기 위한 노력의 일환으로 연료개질기의 컴팩트화가 요구되는데 가정용 연료전지 기술 선진국인 일본 제품의 경우 $1Nm^3/h$급 연료개질기의 부피는 20L정도로 알려져 있다. 또한 연료전지 시스템의 효율은 연료개질기의 개질효율과 연료전지 스택의 발전효율의 곱으로 계산되기 때문에 연료개질기의 연료개질 효율은 전체 시스템의 효율에 직접적으로 영향을 미치게 된다. 한국에너지기술연구원에서는 수소생산량 기준 $1Nm^3/h$급 연료개질기의 개발을 완료하였으며 크기 및 효율면에서 선진국 제품과 비교하여 동등 또는 우위의 수준을 달성하였다. 연료개질기 내부의 혼합 및 분배 구조를 개선하고 각 촉매층의 최적 배치를 통해 연료개질기의 부피를 최소화 하였으며 연료개질기 내부에서 고온부위와 저온부위 사이의 최적 열교환을 통해 열효율을 극대화 시켰다. 현재 개발된 $1Nm^3/h$급 개질기의 단열 후 부피는 13.5L 그리고 단독운전 시 열효율은 80%(LHV)로 측정되었다. 또한 $1Nm^3/h$급의 연료개질기의 스케일-업 설계를 통하여 수소생산량 3, $5Nm^3/h$ 규모의 연료개질기를 개발하였으며 성능평가가 진행 중이다.