• Title/Summary/Keyword: 환경폐기물

Search Result 2,200, Processing Time 0.033 seconds

Corrosion Behavior of $Y_2O_3$ Coating in an Electrolytic Reduction Process (전해환원공정에서 $Y_2O_2$ 코팅층의 부식거동)

  • Cho, Soo-Haeng;Hong, Sun-Seok;Kang, Dae-Seung;Jeong, Myeong-Soo;Park, Byung-Heong;Hur, Jin-Mok;Lee, Han-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.8 no.1
    • /
    • pp.33-39
    • /
    • 2010
  • The electrolytic reduction of a spent oxide fuel involves a liberation of the oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is too corrosive for typical structural materials. Accordingly, it is essential to choose the optimum material for the processing equipment that handles the high molten salt. In this study, hot corrosion studies were performed on bare as well as coated superalloy specimens after exposure to lithium molten salt at $675^{\circ}C$ for 216 h under an oxidizing atmosphere. The IN713LC superalloy specimens were sprayed with an aluminized NiCrAlY bond coat and then with an $Y_2O_3$ top coat. The bare superalloy reveals an obvious weight loss due to spalling of the scale by the rapid scale growth and thermal stress. The chemical and thermal stability of the top coat has been found to be beneficial for increasing to the corrosion resistance of the structural materials for handling high temperature lithium molten salts.

Chemical Composition of Maize Germs Separated in the Manufacture of Cornstarch (옥수수전분 제조공정의 부산물인 maize germ의 지질 및 아미노산 조성)

  • Cho, Sung-Hwan;Kim, Ze-Uook;Choi, Jong-Duck
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.15 no.1
    • /
    • pp.15-21
    • /
    • 1986
  • This study was conducted to research the industrial utilizaion of the maize germs separated in the manufacture of the cornstarch. The maize germs contained crude protein (25.3%) and crude fat (19.2%), with the 512 Kcal/100g of determined food energy values. It was found to have the valuable amounts of essential minerals, such as the content of calcium and phosphorus were low (53.0, 12.3mg%), while those of potassium (495.4mg%), magnesium (95.0mg%), zinc (48.3ppm) and manganese (45.2ppm) were plentiful. It was noted that the iodine value was 44.0, saponification value 292.3, acid value 1.5 and peroxide value about 3.3. The lipid fractions obtained by silicic acid column chromatography were mainly composed of neutral lipid, whereas, the contents of glycolipid and phospholipid were scarcely. The major fatty acids in total lipids were linoleic $(60{\sim}62.5%)$, oleic $(20{\sim}22.5%)$ and palmitic $(10{\sim}13.5%)$ acids. The content of the unsaturated fatty acids was more predominant than that of the saturated fatty acids. The content of the insoluble proteinous nitrogen (32.5%) was the most abundant. whereas, the contents of soluble proteinous nitrogen (12.7%) and peptide proteinous nitrogen (3.3%) were low. The major amino acids of the maized germs were glutamic, glycine, alanine and aspartic. It has been identified by the SDS-disc electrophoresis that the protein of maized germs had $5{\sim}6$ bands. Compared with standard substances, the molecular weight of the main protein was estimated to be $14,500{\sim}24,500$.

  • PDF

Implementation of Monitoring System of the Living Waste based on Artificial Intelligence and IoT (AI 및 IoT 기반의 생활 폐기물 모니터링 시스템 구현)

  • Kim, Sang-Hyun;Kang, Young-Hoon;Yoon, Dal-Hwan
    • Journal of IKEEE
    • /
    • v.24 no.1
    • /
    • pp.302-310
    • /
    • 2020
  • In this paper, we have implemented the living waste analysis system based on IoT and AI(Artificial Intelligence), and proposed effective waste process and management method. The Jeju location have the strong point to devise a stratagem and estimate waste quantization, rather than others. Especially, we can recognized the amount variation of waste to the residence people compare to the sightseer number, and the good example a specific waste duty. Thus this paper have developed the IoT device for interconnecting the existed CCTV camera, and use the AI algorithm to analysis the waste image. By using these decision of image analysis, we can inform their deal commend and a decided information to the map of the waste cars. In order to evaluate the performance of IoT, we have experimented the electromagnetic compatibility under a national official authorization KN-32, KN61000-4-2~6, and obtained the stable experimental results. In the further experimental results, we can applicable for an data structure for precise definition command by using the simulated several waste image with artificial intelligence algorithm.

Precipitation behaviors of Cs and Re(/Tc) by NaTPB and TPPCl from a simulated fission products-$(Na_2CO_3-NaHCO_3)-H_2O_2$ solution (모의 FP-$(Na_2CO_3-NaHCO_3)-H_2O_2$ 용액으로부터 NaTPB 및 TPPCl에 의한 Cs 및 Re(/Tc)의 침전 거동)

  • Lee, Eil-Hee;Lim, Jae-Gwan;Chung, Dong-Yong;Yang, Han-Beum;Kim, Kwang-Wook
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.8 no.2
    • /
    • pp.115-122
    • /
    • 2010
  • In this study, the removal of Cs and Tc from a simulated fission products (FP) solution which were co-dissolved with U during the oxidative-dissolution of spent fuel in a mixed carbonate solution of $(Na_2CO_3-NaHCO_3)-H_2O_2$ was investigated by using a selective precipitation method. As Cs and Tc might cause an unstable behavior due to the high decay heat emission of Cs as well as the fast migration of Tc when disposed of underground, it is one of the important issues to removal them in views of the increase of disposal safety. The precipitation of Cs and Re (as a surrogate for Tc) was examined by introducing sodium tetraphenylborate (NaTPB) and tetraphenylphosponium chloride (TPPCl), respectively. Precipitation of Cs by NaTPB and that of Re by TPPCl were completed within 5 minutes. Their precipitation rates were not influenced so much by the temperature and stirring speed even if they were increased by up to $50^{\circ}C$ and 1,000 rpm. However, the pH of the solution was found to have a great influence on the precipitation with NaTPB and TPPCl. Since Mo tends to co-precipitate with Re at a lower pH, especially, it was effective that a selective precipitation of Re by TPPCl was carried out at pH of above 9 without co-precipitation of Mo and Re. Over 99% of Cs was precipitated when the ratio of [NaTPB]/[Cs]>1 and more than 99% of Re, likewise, was precipitated when the ratio of [TPPCl]/[Re]>1.

Porous Media Modelling and Verification of Thermal Analysis for Inlet and Outlet Ducts of Spent Fuel Storage Cask (사용후핵연료 저장용기 유로입출구의 다공성매질 모델링 및 열해석 검증평가)

  • Lee, Ju-Chan;Bang, Kyung-Sik;Choi, Woo-Seok;Seo, Ki-Seog;Ko, Sungho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.16 no.2
    • /
    • pp.223-232
    • /
    • 2018
  • Bird screen meshes are installed at the air inlet and outlet ducts of spent fuel storage casks to inhibit the intrusion of debris from the external environment. The presence of these screens introduces an additional resistance to air flow through the ducts. In this study, a porous media model was developed to simplify the bird screen meshes. CFD analyses were used to derive and verify the flow resistance factors for the porous media model. Thermal analyses were carried out for concrete storage cask using the porous media model. Thermal tests were performed for concrete casks with bird screen meshes. The measured temperatures were compared with the analysis results for the porous model. The analysis results agreed well with the test results. The analysis temperatures were slightly higher than the test temperatures. Therefore, the reliability and conservatism of the analysis results for the porous model have been verified.

Study on Characteristics of Change of Physical/Chemical property of Refined Fuel Oil(Reduced-pressure) by Mixing with By-product Fuel Oil(No. 2) (부생연료유(2호) 혼합에 따른 정제연료유(감압)의 물성 변화 특성 연구)

  • Doe, Jin-woo;Lim, Tae-yun;Yim, Eui-soon;Lee, Joung-min;Kang, Hyung-kyu
    • Journal of the Korean Applied Science and Technology
    • /
    • v.35 no.4
    • /
    • pp.1349-1358
    • /
    • 2018
  • In addition to responding to the environmental pollution caused by fossil fuels, the enforcement of Renewable Fuel Standard(RFS) system has increased the utilization of renewable energy such as refined fuels oil. The by-product fuel oil(No. 2) and the refined fuel oil(reduced-pressure) are strictly regulated by the domestic legislation and the chemical property changes of the refined fuel oil(reduced-pressure) mixed with the by-product fuel oil(No. 2) were analyzed. As a result of analyzing the physical properties of refined fuel oil(reduced pressure) obtained by mixing 1 : 1 of by-product fuel oil(No. 2), it satisfied the quality standards stipulated by the domestic Enforcement Decree of the Wastes Control Act. However, the results of the additional tests related to the fuel showed a high aromatic content. The high content of aromatic in a fuel is likely to cause the soot and ehaust emission gas during the combustion of the used equipment.

Combustion Characteristics of Bio Emulsion Fuel (바이오에멀젼 연료의 연소 특성)

  • Kim, Moon-Chan
    • Journal of the Korean Applied Science and Technology
    • /
    • v.35 no.4
    • /
    • pp.1421-1432
    • /
    • 2018
  • Water soluble oil was obtained from the pyrolysis of coconut waste as a biomass at $600^{\circ}C$. It was studied that the combustion characteristics of bio-emulsion fuel by mixing and emulsifying 15~20% of water soluble oil which obtained from pyrolysis of coconut waste as a biomass and MDO(marine diesel oil) as a marine fuel. Engine dynamometer was used for detecting emissions, temperature, and power. The temperature of combustion chamber was decreased because the moisture in bio-emulsion fuel deprived of heat of evaporation in combustion chamber. While combustion, micro-explosion took place in the combustion chamber by water in the bio-emulsion fuel, MDO fuel scattered to micro particles and it caused to smoke reduction. The temperature reduction of combustion chamber by using bio-emulsion fuel reduced the NOx emission. The increasing of bio-oil content caused increasing water content in bio-emulsion fuel so total calorific value was reduced. So the characteristics of power was decreased in proportion to using the increasing amount of bio-emulsion fuel. Heavy oil as a marine fuel exhausts a lot of smoke and NOx. We expect that we can reduce the exhaust gas of marine engine such as smoke and NOx by using of bio-emulsion fuel as a marine fuel.

A Study on Penetration Effect of Penetrating Hardener for Prevention of Scattering of Asbestos Building Materials (석면 건축자재의 비산 방지를 위한 침투성 경화제 침투 효과에 관한 연구)

  • Song, Tae-Hyeob;Park, Ji-Sun;Shin, Hyun-Gyoo
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.6 no.4
    • /
    • pp.324-330
    • /
    • 2018
  • In accordance with the amendment of the Industrial Safety and Health Act of 2007, Korea completely prohibited the import, distribution and manufacture of asbestos like Europe and Japan. Accordingly, the current problem of asbestos is the safe maintenance and disposal of asbestos construction material, the disposal of asbestos, and the final disposal of asbestos building materials. In the past, Korea used 100,000 tons of asbestos every year, and the building materials using it exceeded 1 million tons per year. These asbestos building materials continued to be used until 2006, and the Ministry predicted that these materials would continue to be maintained until 2044. When the permeable hardening agent is applied to the asbestos building material installed in the pre-pretreatment step for the harmless treatment of the asbestos waste and the dismantling is carried out, the scattering of the asbestos is suppressed in the disassembling step, detoxification treatment conditions can be improved. Therefore, permeable hardeners should be stably penetrated into asbestos building materials. In this study, it is suggested that pre - pretreatment methods for the harmlessization of waste asbestos building materials with medium density level can be presented. In order to efficiently perform pre - treatment for chemical harmlessness in the future, the mixing ratio of permeable hardener and middle water Optimization is the most important factor.

A Preliminary Study on the Evaluation of Internal Exposure Effect by Radioactive Aerosol Generated During Decommissioning of NPPs by Using BiDAS (BiDAS를 적용한 원전 해체 공정 시 발생되는 방사성 에어로졸의 내부피폭 영향평가 사전 연구)

  • Song, Jong Soon;Lee, Hak Yun;Kim, Sun Il
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.16 no.4
    • /
    • pp.473-478
    • /
    • 2018
  • Radioactive aerosol generated in cutting and melting work during the NPP decommissioning process can cause internal exposure to body through workers' breath. Thus, it is necessary to assess worker internal exposure due to the radioactive aerosol during decommissioning. The actually measured value of the working environment is needed for accurate assessment of internal exposure, but if it is difficult to actually measure that value, the internal exposure dose can be estimated through recommended values such as the fraction of amount of intake and the size of particles suggested by the International Committee on Radiological Protection (ICRP). As for the selection of particle size, this study applied a value of $5{\mu}m$, which is the size of particles considering the worker recommended by the ICRP. As for the amount of generation, the amount of intake was estimated using data on the mass of aerosol generated in a melting facility at a site in Kozloduy, Bulgaria. In addition, using these data, this study calculated the level of radioactivity in the worker's body and stool and conducted an assessment of internal exposure using the BiDAS computer code. The internal exposure dose of Type M was 0.0341 mSv, that of Type S was 0.0909 mSv. The two types of absorption showed levels that were 0.17% and 0.45% of the domestic annual dose limit, respectively.

Durability Performance Evaluations on Resistance to Chloride Attack for Concrete Using LCD Waste Glass Powder (LCD 폐유리 미분말을 사용한 콘크리트의 염해내구성 평가)

  • Kim, Seong-Kyum;Lee, Kwang-Woon;Song, Jae-Ho;Jang, Il-Young
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.6 no.4
    • /
    • pp.289-296
    • /
    • 2018
  • In this study, we evaluated the feasibility and performance of LCD waste glass as a replacement for cement by using LCD waste glass powder which is generated from manufacturing process due to development of LCD industry. Experiments were carried out by replacing 10% and 20% cement of LCD waste glass with particle size of $12{\mu}m$ of LCD waste glass with OPC and particle size of $5{\mu}m$, respectively. Through experiments, basic properties, mechanical properties and durability of concrete were evaluated. Experimental results show that the compressive strength is high at 10% replacement ratio compared to 20%. The lower the particle size, the higher the strength. The durability test evaluated the chloride penetration performance through the chloride ion diffusion coefficient. The higher the substitution rate and the smaller the particle size, the lower the chloride ion diffusion coefficient and the better the OPC than the all substitution rate. As a result, LCD waste glass concrete with low granularity and proper replacement ratio is considered to be advantageous for durability under salt environment.