• Title/Summary/Keyword: 화학적 특성

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Fault Detection Method for Multivariate Process using Mahalanobis Distance and ICA (마할라노비스 거리와 독립성분분석을 이용한 다변량 공정 고장탐지 방법에 관한 연구)

  • Jung, Seunghwan;Kim, Sungshin
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.14 no.1
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    • pp.22-28
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    • 2021
  • Multivariate processes, such as chemical and mechanical process, power plants are operated in a state where several facilities are complexly connected, the fault of a particular system can also have fatal consequences for the entire process. In addition, since process data is measured in an unstable environment, outlier is likely to be include in the data. Therefore, monitoring technology is essential, which can remove outlier from measured data and detect failures in advance. In this paper, data obtained from dynamic and multivariate process models was used to detect fault in various type of processes. The dynamic process is a simulation of a process with autoregressive property, and the multivariate process is a model that describes a situation when a specific sensor fault. Mahalanobis distance was used to remove outlier contained in the data generated by dynamic process model and multivariate process model, and fault detection was performed using ICA. For comparison, we compared performance with and a conventional single ICA method. The proposed fault detection method improves performance by 0.84%p for bias data and 6.82%p for drift data in the dynamic process. In the case of the multivariate process, the performance was improves by 3.78%p, therefore, the proposed method showed better fault detection performance.

ITZ Analysis of Cement Matrix According to the Type of Lightweight Aggregate Using EIS (EIS를 활용한 경량골재 종류별 시멘트 경화체의 계면특성 분석)

  • Kim, Ho-Jin;Jung, Yoong-Hoon;Bae, Je-Hyun;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.498-505
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    • 2020
  • Aggregate occupies about 70-85% of the concrete volume and is an important factor in reducing the drying shrinkage of concrete. However, when constructing high-rise buildings, it acts as a problem due to the high load of natural aggregates. If the load becomes large during the construction of a high-rise building, creep may occur and the ground may be eroded. Material costs increase and there are financial problems. In order to reduce the load on concrete, we are working to reduce the weight of aggregates. However, artificial lightweight aggregates affect the interface between the aggregate and the paste due to its higher absorption rate and lower adhesion strength than natural aggregates, affecting the overall strength of concrete. Therefore, in this study, in order to grasp the interface between natural aggregate and lightweight aggregate by type, we adopted a method of measuring electrical resistance using an EIS measuring device, which is a non-destructive test, and lightweight bone. The change in the state of the interface was tested on the outside of the material through a blast furnace slag coating. As a result of the experiment, it was confirmed that the electric resistance was about 90% lower than that in the air-dried state through the electrolyte immersion, and the electric resistance differs depending on the type of aggregate and the presence or absence of coating. As a result of the experiment, the difference in compressive strength depending on the type of aggregate and the presence or absence of coating was shown, and the difference in impedance value and phase angle for each type of lightweight aggregate was shown.

Rating Evaluation of Fire Risk for Combustible Materials in Case of Fire (화재 시 연소성 물질에 대한 화재 위험성 등급 평가)

  • Chung, Yeong-Jin;Jin, Eui
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.75-82
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    • 2021
  • This study investigated the fire risk assessment of woods and plastics for construction materials, focusing on the fire performance index-III (FPI-III), fire growth index-III (FGI-III), and fire risk index-IV (FRI-IV) by a newly designed method. Japanese cedar, red pine, polymethylmethacrylate (PMMA), and polyvinyl chloride (PVC) were used as test pieces. Fire characteristics of the materials were investigated using a cone calorimeter (ISO 5660-1) equipment. The fire performance index-III measured after the combustion reaction was found to be 1.0 to 15.0 with respect to PMMA. Fire risk by fire performance index-III increased in the order of PVC, red pine, Japanese cedar, and PMMA. The fire growth index-III was found to be 0.5 to 3.3 based on PMMA. Fire risk by fire growth index-III increased in the order of PVC, PMMA, red pine, and Japanese cedar. COpeak concentrations of all specimens were measured between 106 and 570 ppm. In conclusion, it is understood that Japanese cedar with a low bulk density and PMMA containing a large amount of volatile organic substances have a low fire performance index-III and high fire growth index-III, and thus have high fire risk due to fire. This was consistent with the fire risk index-IV.

A Study on the Microstructure Formation of Sn Solder Bumps by Organic Additives and Current Density (유기첨가제 및 전류밀도에 의한 Sn 솔더 범프의 미세조직 형성 연구)

  • Kim, Sang-Hyeok;Kim, Seong-Jin;Shin, Han-Kyun;Heo, Cheol-Ho;Moon, Seongjae;Lee, Hyo-Jong
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.1
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    • pp.47-54
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    • 2021
  • For the bonding of smaller PCB solder bumps of less than 100 microns, an experiment was performed to make up a tin plating solution and find plating conditions in order to produce a bump pattern through tin electroplating, replacing the previous PCB solder bumps process by microballs. After SR patterning, a Cu seed layer was formed, and then, through DFR patterning, a pattern in which Sn can be selectively plated only within the SR pattern was formed on the PCB substrate. The tin plating solution was made based on methanesulfonic acid, and hydroquinone was used as an antioxidant to prevent oxidation of divalent tin ions. Triton X-100 was used as a surfactant, and gelatin was used as a grain refiner. By measuring the electrochemical polarization curve, the characteristics of organic additives in Triton X-100 and gelatin were compared. It was confirmed that the addition of Triton X-100 suppressed hydrogen generation up to -1 V vs. NHE, whereas gelatin inhibited hydrogen generation up to -0.7 V vs. NHE. As the current density increased, there was a general tendency that the grain size became finer, and it was observed that it became finer when gelatin was added.

Changes in Leaf and Reproductive Traits of Mountain Ash (Sorbus alnifolia) as Urban Flourisher in the Seoul Metropolitan, South Korea (한국 서울 식생의 번성자로서 팥배나무의 형질 변화 양상)

  • Jung, Song-Hie;Cho, Yong-Chan;Lee, Chang-Seok
    • Korean Journal of Environment and Ecology
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    • v.35 no.6
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    • pp.644-658
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    • 2021
  • Understanding the functional traits of dominant species in urban ecosystems provides insight into species' trait adaptation and ecosystem function in response to fragmented and isolated urban vegetation and reduced biological interactions. This study compared means and variances of environmental factors (geographic, meteorological, and soil attributes) and 4 leaf traits (leaf area, specific leaf area, leaf dry mass content, and leaf shape index) and 7 reproductive traits (fruit width, fruit length, fruit shape, fruit dry weight, fruit dry matter content, seed weight, and seed ratio) measured of 40 Sorbus alnifolia individuals in four mountainous areas south of Seoul downtown, South Korea. We then performed the multivariate analysis of trait combinations. While the measured environmental factors indicated the individuality of the survey sites, the urban vegetation was drier and had a longer growth period. The leaves of S. alnifolia in the urban areas were smaller and heavier, and the fruits produced longer and lighter seeds, showing the traits affected by long urbanization. The study confirmed changes in the growth and reproduction mechanism of the S. alnifolia population under the urban environment, indicating reduced biological interaction due to vegetation fragmentation and isolation. This study provides limited but distinct ecological information about the function and persistence of key species in cities with a reduced scale of biological interactions and many negative environmental factors such as air pollution.

Preparation of High Energy Density Lithium Anode for Thermal Batteries and Electrochemical Properties Thereof (열전지용 고에너지 밀도 리튬 음극 제조 및 이의 전기화학적 특성)

  • Im, Chae-Nam;Yu, Hye-Ryeon;Yoon, HyunKi;Cho, Jang-Hyeon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.4
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    • pp.398-406
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    • 2022
  • In order to increase the electrochemical performance of thermal battery anode, LIFT anode having the same weight but a larger lithium content in electrodes was fabricated by mixing lithium, iron and titanium. By applying these electrodes, a single cell and a thermal battery were prepared, and the effect of LIFT anode on electrochemical performance was evaluated. The LIFT-applied single cell presented a better cell performance than LIFe-applied single cell at 500℃ and 550℃. The discharge performance of LIFT-applied single cell, which included the operating time (787s), specific capacity (1,683 Asg-1), and electrode utilization (80.7%), was improved collectively compared to the LIFe applied single cell (736s, 1,245 As g-1, and 74.6%) at 500℃. As the discharge progressed, the internal resistance of LIFT anode decreased, because the lithium migration path was formed due to the presence of large titanium particles among iron particles. These results were analyzed in terms of the microstructure of electrode using SEM. Energy density of LIFT-applied single cell also increased by 10% to 142.1 Wh kg-1 compared to that of LIFe-applied single cell (127.4 Wh kg-1). In addition, the LIFT-applied single cell presented a stable discharge performance for 6,500s without a short circuit which could occur by molten lithium under an open circuit voltage condition with a high pressure (4 kgf cm-2). As observed in the high temperature thermal battery performance tests, the voltage and specific capacity of LIFT-applied thermal battery are superior to those of LIFe-applied thermal batteries, indicating that the energy density of LIFT-applied thermal batteries should remarkably increase.

Antibacterial and Antiviral Activities of Multi-coating Polyester Textiles (다중 코팅 폴리에스터 섬유 여재의 항균 및 항바이러스 특성)

  • Ko, Sangwon;Lee, Jae-Young;Park, Duckshin
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.444-450
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    • 2022
  • The effect of coated polyester (PET) textiles with metal oxide, chitosan, and copper ion on the antibacterial and antiviral activities was evaluated to investigate the applicability of multi-coated PET textiles as antiviral materials. Compared to coated PETs with a single agent, multi-coated PETs reduced the loading amount of coating materials as well as the contact time with bacteria for a bacterial cell number of < 10 CFU/mL, which was not detectable with the naked eyes. Metal oxides generate reactive oxygen species (ROS) such as free radicals by a catalytic reaction, and copper ions can promote contact killing by the generation of ROS. Chitosan not only enhanced antibacterial activities due to amine groups, but enabled it to be a template to load copper ions. We observed that multi-coated PET textiles have both antibacterial activities for E. coli and S. aureus and antiviral efficiency of more than 99.9% for influenza A (H1N1) and SARS-CoV-2. The multi-coated PET textiles could also be prepared via a roll-to-roll coating process, which showed high antiviral efficacy, demonstrating its potential use in air filtration and antiviral products such as masks and personal protective equipment.

Growth and Yield Response of Perilla Plants Grown under Different Substrates in Hydroponic System (잎들깨 수경재배에서 배지 종류에 따른 식물 생육 및 수량의 반응)

  • Shin, Minju;Jeong, Ho Jeong;Roh, Mi Young;Kim, Jin Hyun;Song, Kwan Jeong
    • Journal of Bio-Environment Control
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    • v.31 no.4
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    • pp.292-299
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    • 2022
  • This study was conducted to analyze physical and chemical properties of horticultural substrates and response of hydroponically grown two cultivars of 'Namcheon' and 'Somirang' perilla by four different substrates: coir (chip:dust = 5:5), perlite, granular rockwool, and commercial mixed substrate (cocopeat:peatmoss:vermiculite:perlite: zeolite = 50:25:10:10:5). There were no significant differences in EC and pH according to substrates. Container capacity was the greatest in granular rockwool, and it showed appropriate levels in mixed substrate and coir. Air space was higher in coir and perlite than the other treatments. Bulky density reached a proper standard in all substrates excepting coir. The leaf length and width of 'Namcheon' indicated the most in mixed substrate, though the value of 'Somirang'was greatest in coir substrate. The leaf weight of both cultivars was highest in mixed substrate, and relatively low in coir and perlite. The total yield of leaves was separated by two groups: higher group, which are mixed substrate and granular rockwool, and lower group, which are coir and perlite. There was a large gap by 28% between these two groups. Therefore, this study suggests that substrates with high water holding capacity such as mixed substrate or granular rockwool are most suitable for the hydroponic cultivation of perilla, which require sufficient moisture supply to the root zone.

A Study on the Electrical Characteristics of Ge2Sb2Te5/Ti/W-Ge8Sb2Te11 Structure for Multi-Level Phase Change Memory (다중준위 상변환 메모리를 위한 Ge2Sb2Te5/Ti/W-Ge8Sb2Te11 구조의 전기적 특성 연구)

  • Oh, Woo-Young;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.1
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    • pp.44-49
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    • 2022
  • In this paper, we investigated current (I)- and voltage (V)-sweeping properties in a double-stack structure, Ge2Sb2Te5/Ti/W-doped Ge8Sb2Te11, a candidate medium for applications to multilevel phase-change memory. 200-nm-thick and W-doped Ge2Sb2Te5 and W-doped Ge8Sb2Te11 films were deposited on p-type Si(100) substrate using magnetron sputtering system, and the sheet resistance was measured using 4 point-probe method. The sheet resistance of amorphous-phase W-doped Ge8Sb2Te11 film was about 1 order larger than that of Ge2Sb2Te5 film. The I- and V-sweeping properties were measured using sourcemeter, pulse generator, and digital multimeter. The speed of amorphous-to-multilevel crystallization was evaluated from a graph of resistance vs. pulse duration (t) at a fixed applied voltage (12 V). All the double-stack cells exhibited a two-step phase change process with the multilevel memory states of high-middle-low resistance (HR-MR-LR). In particular, the stable MR state is required to guarantee the reliability of the multilevel phase-change memory. For the Ge2Sb2Te5 (150 nm)/Ti (20 nm)/W-Ge8Sb2Te11 (50 nm), the phase transformations of HR→MR and MR→LR were observed at t<30ns and t<65ns, respectively. We believe that a high speed and stable multilevel phase-change memory can be optimized by the double-stack structure of proper Ge-Sb-Te films separated by a barrier metal (Ti).

Electrical Characterization of Lateral NiO/Ga2O3 FETs with Heterojunction Gate Structure (이종접합 Gate 구조를 갖는 수평형 NiO/Ga2O3 FET의 전기적 특성 연구)

  • Geon-Hee Lee;Soo-Young Moon;Hyung-Jin Lee;Myeong-Cheol Shin;Ye-Jin Kim;Ga-Yeon Jeon;Jong-Min Oh;Weon-Ho Shin;Min-Kyung Kim;Cheol-Hwan Park;Sang-Mo Koo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.4
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    • pp.413-417
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    • 2023
  • Gallium Oxide (Ga2O3) is preferred as a material for next generation power semiconductors. The Ga2O3 should solve the disadvantages of low thermal resistance characteristics and difficulty in forming an inversion layer through p-type ion implantation. However, Ga2O3 is difficult to inject p-type ions, so it is being studied in a heterojunction structure using p-type oxides, such as NiO, SnO, and Cu2O. Research the lateral-type FET structure of NiO/Ga2O3 heterojunction under the Gate contact using the Sentaurus TCAD simulation. At this time, the VG-ID and VD-ID curves were identified by the thickness of the Epi-region (channel) and the doping concentration of NiO of 1×1017 to 1×1019 cm-3. The increase in Epi region thickness has a lower threshold voltage from -4.4 V to -9.3 V at ID = 1×10-8 mA/mm, as current does not flow only when the depletion of the PN junction extends to the Epi/Sub interface. As an increase of NiO doping concentration, increases the depletion area in Ga2O3 region and a high electric field distribution on PN junction, and thus the breakdown voltage increases from 512 V to 636 V at ID =1×10-3 A/mm.