• Title/Summary/Keyword: 화학섬유

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Preparation of Cellulose Diacetate/Ramie Fiber Biocomposites by Melt Processing (용융가공법을 이용한 셀룰로오스 디아세테이트/라미섬유 천연복합체의 제조)

  • Lee Sang Hwan;Lee Sang Yool;Nam Jae Do;Lee Youngkwan
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.70-74
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    • 2006
  • Plasticized cellulose diacetate(CDA) was prepared by homogenizing cellulose diacetate(CDA), triacetin(TA) and epoxidized soybean oil (ESO) in a high-speed mixer, then the CDA mixture was mixed with ramie fiber to produce a green composite material. In DMA analysis, the glass transition temperature of plasticized CDA and the composite was observed at $85\;^{\circ}C\;and\;140\;^{\circ}C$, respectively. A composite reinforced with alkali treated ramie fiber exhibited significantly higher mechanical properties, such as $15\;^{\circ}C$ increase in tensile strength as well as $41\;^{\circ}C$ increase in Young's modulus when compared with commercial polypropylene. In the SEM image analysis, much enhanced adhesion between plasticized CDA and alkali treated ramie fiber (AIRa) was observed.

An Experimental Study on the Resistance of Nylon Fiber Reinforced Concrete to Chloride Ion Penetration (나일론섬유보강 콘크리트의 염소이온 침투 저항성에 대한 실험적 연구)

  • Jeon, Joong-Kyu;Moon, Jae-Heum;You, Jin-O
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.557-560
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    • 2008
  • Fiber reinforcement has been being widely used in concrete to enhance the mechanical properties and to reduce the micro-cracking caused by plastic and drying shrinkage. While researches has been focused on the benefits of fiber reinforcement, the properties of fiber reinforced concrete are strongly dependent on the type, shape and the amount of fibers in concrete. In this study, the resistance of nylon fiber reinforced concrete against the chloride ion penetration was experimentally observed by NT Build 492. The test results showed that the addition of nylon fiber has little effect on the change of the resistivity of concrete to the chloride ion penetration.

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Dynamic Shear Behavior of the Ground-geosynthetics Interface in the Waste Landfill (폐기물 매립장 지반-토목섬유 접촉면의 동적 전단거동 특성)

  • Jang, Dong-In;Kim, Young-Jun;Kwak, Chang-Won;Park, Inn-Joon
    • Journal of the Korean Geotechnical Society
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    • v.31 no.4
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    • pp.5-12
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    • 2015
  • The construction of waste landfill sites has been increased due to recent expansion of various waste. Geotextiles are widely used for the purpose of reinforcement and protection of waste inside the landfill. Geotextile affects the shear behavior of waste landfill which forms the contact surface with soil. In this study, the effect of acidic and alkaline components in leachate has been analyzed through the laboratory experiment on the shear stress reduction of the contact surface of ground-geotextile under the cyclic load. For this purpose, a dynamic contact surface shear tester has been manufactured, and cyclic simple shear tests have been performed using geotextile and soil specimen which were immersed in chemical solutions for 60 and 840 days, respectively. Based on the Disturbed State Concept, the characteristics of shear stress on the contact surface of ground-geotextile due to chemical factors have been identified by the disturbance function.

A Study on the Strength and Drying Shrinkage Crack Control Characteristics of Polypropylene Fiber Reinforced Concrete (폴리프로필렌 섬유보강 콘크리트의 강도 및 건조수축균열 제어특성 연구)

  • 오병환;이명규;유성원;백상현
    • Magazine of the Korea Concrete Institute
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    • v.8 no.6
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    • pp.151-161
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    • 1996
  • Recently, polypropylene fiber reinforced mortar and concrete as civil and architectural materials have been used in major countries in the world. Polypropylene fiber reinforced concrete has many advantages in terms of economical aspect, chemical stability and durability. It has been reported that polypropylene fiber can control restrained tensile stresses and cracks and increase toughness, resistance to impact, corrosion, fatigue and durability. The purpose of the present study is, therefore, to investigate the strength as well as many mechanical characteristics including toughness and shrinkage control properties. A specially devjsed shrinkage test has been applied to measure the crack control characteristics of polypropylene fiber reinforced concrete. The present study indicates that the polypropylene fiber reinforced concrete curbs greatly the crack occurrence due to shrinkage and enhances toughness resistance. The present study provides a firm base for the efficient use of polypropylene fiber reinforced concrete in actual construction such as pavements and slab structures.

The Preparation of Antibacterial Activated Carbon fibers and Their Application (항균성 탄소섬유의 제조와 그의 응용)

  • 오원춘;김범수;장원철
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.1 no.1
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    • pp.43-48
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    • 2000
  • Upon the Preparation of activated carbon fiber(ACF) using chemical activation method and vapour activation method, the fiber obtained from the vapour activation method shows excellent surface Properties. The preparation of antibacterial activated carbon fiber was tried to open the new areas in application of carbon materials. The BET specific surface area and the average pore radius of the antibacterial ACFs were in the range of 844.27~1575.6 $cm^2$/g and 10.6~12.9 (equation omitted), respectively. From the adsorption studies on the antibacterial ACFs, typical Type I isotherms were obtained. And, from the SEM morphology results, it was observed that the surface of ACFs was partially coated by antibacterial materials after the treatment. Finally, from the antibacterial effects of antibacteral ACFs against E. coli, excellent antibacterial activity was shown. Concerning the above results, antibacterial ACFs can have wide application in the areas of sterilization, anti-fragrant. anti-insects.

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Influence of Carbon Fiber Direction on Mechanical Properties of Milled Carbon Fibers/Carbon Blacks/Natural Rubber Compounds (탄소섬유 방향이 미분쇄 탄소섬유/카본블랙/천연고무 복합재료의 기계적 물성에 미치는 영향)

  • Ham, Eun-Kwang;Choi, Kyeong-Eun;Ko, Jae-Kyoung;Seo, Min-Kang
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.179-184
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    • 2016
  • In this work, the influence of milled carbon fiber direction on mechanical properties of milled carbon fibers/carbon blacks/natural rubber compounds was investigated. The compounds were prepared by adding the 6 phr milled carbon fibers (MCFs) and 40 phr carbon blacks (CBs) into the natural rubber. The MCFs were aligned in a parallel and orthogonal direction in the compounds using two-roll-mill machine. Mechanical properties of compounds were studied by tensile characteristics and tearing strength. As a result, the compounds showed higher tensile strength, 100%~300% modulus, and tearing strength than those of using any other compounds due to the aligning MCFs in parallel. Mechanical properties of the compounds reinforced with non-aligned MCFs were inferior to those of others. Consequently, the parallel aligned MCFs in the compounds led to an increase of tensile properties and improvement of tearing strength, resulted from MCFs with the high elastic modulus.

Preparation of Fabric Softener Product by using Amine-functionalized Magnesium-phyllosilicates (아민기로 관능화된 마그네슘-층상규산염을 이용한 섬유유연제 제조)

  • Kim, Seong Yeol;Choi, Yoo-Sung
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.580-585
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    • 2019
  • In this study, we synthesized amine-functionalized magnesium-phyllosilicates (AF-MgP) with an octahedral and tetrahedral structure using (3-aminopropyl)triethoxysilane. The synthesis of AF-MgP, surface functionalization of amine and 1 : 2 ratio of the octahedral and tetrahedral structure were confirmed by FT-IR and XRD analysis. In addition, it was confirmed that AF-MgP was absorbed evenly on the surface of cotton fibers and coated on the cotton fibers from HR-SEM and EDX analysis. The antimicrobial activity test of cotton fibers according to KS confirmed that cotton fibers coated with AF-MgP particles show an enhanced antimicrobial activity against cutaneous microorganisms. Our results suggest that AF-MgP is not only applied as a functional nanomaterial that gives the cotton fiber antimicrobiality, but also can be used in the field of cosmetic and biomedical materials.

Application of Hierarchically Porous Fe2O3 Nanofibers for Anode Materials of Lithium-ion Batteries (계층적 다공구조를 갖는 Fe2O3 나노섬유의 리튬 이차전지 음극소재 적용)

  • Jo, Min Su;Cho, Jung Sang
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.267-273
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    • 2019
  • Hierarchically porous $Fe_2O_3$ nanofibers with meso- and macro- pores are designed and synthesized by electrospinning and subsequent heat-treatment. The macro pores are generated by selectively decomposition of polystyrene as a dispersed phase in the as-spun fibers containing $Fe(acac)_3$/polyacrylonitrile continuous phases during heat-treatment. Additionally, meso-pores formed by evaporation of infiltrated water vapor during electrospinning process interconnected the macro-pores and results in the formation of hierarchically porous $Fe_2O_3$ nanofibers. The initial discharge capacity and Coulombic efficiency of the hierarchically porous $Fe_2O_3$ nanofibers at a current density of $1.0A\;g^{-1}$ are $1190mA\;h\;g^{-1}$ and 79.2%. Additionally, the discharge capacity of the nanofibers is $792mA\;h\;g^{-1}$ after 1,000 cycles. The high structural stability and morphological benefits of the hierarchically porous $Fe_2O_3$ nanofibers resulted in superior lithium ion storage performance.

Mechanical Properties of Slag-Based Cementless Composites According to Types of Polyethylene Fibers (폴리에틸렌 섬유 종류에 따른 고로슬래그 기반 무시멘트 복합재료의 역학특성)

  • Jin, Jeong-Eon;Choi, Jeong-Il;Park, Se-Eon;Lee, Bang Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.243-251
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    • 2022
  • The purpose of this study is to investigate experimentally the effect of polyethylene fibers with different tensile strength and aspect ratio on the properties of cementless composite. Three types of mixtures according to the types of polyethylene fibers and water-to-binder ratio were prepared and density, compressive strength and tension tests were performed. Test results showed that the mixture reinforced by polyethylene fiber with a low tensile strength by 10 % and a high aspect ratio by 8.3 % had a high tensile strain capacity by 11.7 %, a high toughness by 12.4 %, and a low crack width by 9.1 %. It was also observed that high tensile strain capacity and better cracking pattern could be achieved by increasing the water-to-binder ratio of composite although its strength is low.

Effects of Fiber Surface Modification on the Flow Characteristics and Wettability in the Resin Transfer Molding Process (섬유의 표면개질이 수지이동 성형공정에서의 유동특성 및 젖음성에 미치는 영향)

  • 김세현;이건웅;이종훈;김성우;이기준
    • The Korean Journal of Rheology
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    • v.11 no.1
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    • pp.34-43
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    • 1999
  • Flow-induced voids during resin impregnation and poor fiber wetting have known to be highly detrimental to the performance of composite parts manufactured by resin transfer molding(RTM) process. In this study, in order to overcome these serious problems encountered in RTM, the effects of surface modification by using silane coupling agent as a surface modifier on the flow characteristics, the wetting between resin and fiber, and void content were investigated. For the experiments of microscopic flow visualization and curing in a beam mold, glass fiber mats having plain weaving structure and epoxy resin were used. Modifying the fiber surface was found to result in a significant decrease of dynamic contact angle between resin and fiber and increase of wicking rate. Therefore, it was confirmed that the surface modification employed in this study could improve the wettability of reinforcing fibers as well as micro flow behavior. In addition, It was revealed that high temperature and low penetration rate of the resin are more favorable processing conditions to reduce the dynamic contact angle. However, surface modified fiber mat was found to have lower permeability than the unmodified one, which may be explained in terms of the decrease of contact time between resin and fiber owing to improvement of wetting. It was also exhibited that surface modification had a significant influence on void formation in RTM process, resulting in a decrease of overall void content due to the improvement of wetting in cured composite parts.

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