• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2003.05a
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• pp.418-421
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• 2003

경량ㆍ고강도 기능성 Composite는 경량구조재료로 차량, 항공기, 선박 및 각종 설비의 안전구조재로 그 용도가 다양하게 사용되고 있다. 특히 폐플라스틱을 이용한 경량구 조재는 가격 경쟁력이 높고 또한 환경 및 자원 재활용 측면에서 관심이 고조되고 있다. 고강도, 안전성 확보를 위해 사용가능한 폐플라스틱 소재로는 가공성이 용이한 폐Polyethylene(PE), 폐Polypropylene(PP), 폐Polyethyleneterephthalate(PET) 등을 주원료로 가공되나, 기계적 특성이 저하되어 이의 개선을 위해 여러 가지 형태의 충진재의 혼합을 통해 개선하고자 하는 연구가 진행되어 왔다.(중략)

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2004.05a
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• pp.123-127
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• 2004

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.191-198
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• 2008

The thermal degradation characteristics of high molecular components obtained from pyrolysis of mixed waste plastics have been studied by thermogravimetric analysis (TGA) and gas chromatography spectrometry (GC-MS). The kinetics of thermal degradation has been studied by a conventional nonisothermal thermogravimetric technique at several heating rates between 10 and $50^{\circ}C/min$. The dynamic thermogravimetric analysis curve and its derivative have been analyzed using a variety of analytical methods reported in the literature to obtain information on the kinetic parameters such as activation energies and reaction orders. The yields of liquid products have been monitored by batch pyrolysis reactor under various reaction temperatures and reaction times. And the characteristic of liquid products with the increase in reaction temperature has been performed by GC-MS.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2006.05a
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• pp.159-163
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• 2006

본 연구는 국제환경규제에 따라 폐자동차의 재활용율 향상을 위한 재활용 부품 우선순위를 도출하고, 폐시트 등 부품 재활용에 의한 환경성을 평가하기 위하여 폐차 해체시스템 전과정평가를 수행하였다. 연구결과 차피의 고철을 재활용 할 경우에는 지구온난화와 오존층파괴에 큰 환경이득을 얻을 수 있으나 폐시트를 폴리올 원료로 재활용할 경우에는 많은 자원의 사용으로 오히려 소각으로 인한 환경부하보다 지구온난화와 오존층파괴, 광화학산화물생성 등의 부하를 증가시키는 것으로 나타났다. 그러나 폐차의 95% 이상을 재활용 및 회수하기 위해서는 분해시간 및 시장성, 기술현황 등을 종합하여 고려하여야 하며 재활용이 곤란한 유리와 같은 다른 부품과 함께 시트의 물질재활용도 반드시 포함되어야 될 것으로 사료된다. 처리와 재활용에 따른 환경성을 비교한 결과 재활용이 필요한 부품은 시트와 유리가 가장 시급하며, 배터리, 혼합플라스틱도 재활용시 환경친화적 공정개발이 필요한 것으로 도출되었다.

• Prospectives of Industrial Chemistry
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• v.24 no.2
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• pp.10-21
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• 2021

최근 폐플라스틱의 사용량 증가와 미세플라스틱으로 인한 해양 오염 및 생태계 축적 등의 부정적인 영향으로 인해 플라스틱 업사이클링(upcycling) 및 리파이너리(refinery) 기술에 대한 관심이 증가하고 있다. 화학적 재활용 방법 중의 하나로, 폐플라스틱의 열분해를 통해서 재생 연료 및 화학물질을 생산하는 연구는 90년도에 활발히 진행된 바 있고, 최근의 환경오염에 대한 대응으로서 다시 많은 관심을 받고 있다. 폐플라스틱을 효율적으로 분해하기 위해서는 촉매를 사용하여 분해 속도를 제어해 주어야 하며, 사용된 촉매의 특성에 따라 최종 생성물의 성상이 크게 달라진다. 본 기고문에서는 폐플라스틱의 촉매 열분해를 통해 가솔린, 디젤유 및 항공유와 같은 수송용 연료, 발전용 연료 혹은 방향족 화학 물질을 생산하는 기술들의 최신 연구 동향을 다루고 향후 전망에 대해 기술하고자 한다. 아울러 최근 몇 년간 많은 연구가 있었던 바이오매스와 폐플라스틱의 혼합열분해를 통한 하이브리드 촉매 공동 열분해 기술에 대해서도 다루고자 한다.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.3
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• pp.55-61
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• 2018

This study evaluated if the selected samples meets the Solid Refuse Fuel quality criteria in Korea. Biomass and plastic wastes generated in D City were mixed in diverse ratio. When the biomass content was about 40%, the moisture content was close to the SRF criteria and was measured to be 9.8%. The ash contents were analyzed up to 4.19%, and the lower calorific values based on Steuer, Dulong Equation and Bomb Calorimeter were at least 4,851, 4,181 and 3,847 kcal/kg, respectively. As a result of the elemental analysis, sulfur and chloride content were measured up to 0.05%. Those values satisfied the SRF criteria. Also, heavy metals(Hg, Cd, Pb, As) were analyzed to be below the SRF criteria. This makes it possible to use efficiently the wood byproducts abandoned in the woods, and the physical properties of wood being weak to moisture can be supplemented with plastics. Consequently, if plastic and biomass were well mixed and made into SRF, it would overcome the problem of shortening the life span of incineration facilities due to the high temperature of plastic wastes in the incinerator.

• Resources Recycling
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• v.22 no.6
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• pp.33-40
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• 2013

Due to the environmental problem caused by plastics largely used in various fields, the importance of recycling is being emphasized. A research on material separation of ABS and PS mixed plastic waste, using a triboelectrostatic separator, was carried out for recovery the ABS. As a results of research on charging characteristic for choosing charging material, it was confirmed that ABS was optimum charging material for a tribo-charger in the material separation of ABS and PS. In the material separation using ABS charger, ABS grade of 99.5% and recovery of 92.5% were achieved at 20 kV, splitter position +2 cm from the center and 30% relative humidity. Therefore, material separation technique for recycling ABS and PS mixed plastic waste was established.

• Resources Recycling
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• v.22 no.4
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• pp.70-80
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• 2013

Waste refrigerator is the most large amount of item being recycled and the recycling process is the most complicated in WEEE (Waste Electrical and Electronic Equipment) because refrigerator is biggest product and consists of various parts and materials such as ferrous, non-ferrous, and plastics. Recently, recycling process of waste refrigerator has been being more complex since large capacity 2 door refrigerators and standing Kimchi refrigerators with various material are distributed on custom market. In addition, recycling of valuable resource from waste refrigerator is mandatory by WEEEs recycling legislation; therefore, high efficiency recycling enough for economic and environment-friendly recovery of valuable resource through present technical situation analysis and comparison of recycling technologies of waste refrigerator with advanced country.

• Resources Recycling
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• v.12 no.4
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• pp.58-64
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• 2003

A study on the preparation of RDF with ASR materials from shredder line of end-of-life vehicles has been peformed by using hot molding method. ASR materials used in the work were plastics, fibers and sponge which were cut by less than 10 mm in size prior to hot molding and 40, 60 and 80 mm mold in diameter were employed for RDF forming. It was found that heating temperature, heating time and mixing ratio of materials played an important role in the hot molding of ASR materials. Density of RDF samples Prepared in the work was in the range of 0.5∼0.9gr/ml depending on the hot molding conditions and it was decreased with increase in the content of sponge. Breaking strength of RDF samples was observed to 0.8∼3.0MPa and it was also increased with increase in density of RDF samples. Finally, when heating temperature was elevated, density of RDF was increased due to Increase in molten part of ASR materials which resulted in the enhancement of breaking strength of RDF.

• Resources Recycling
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• v.23 no.5
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• pp.44-54
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• 2014

A standard plastic garbage bag which was discarded from Incheon Metropolitan City was composed of 4.5% recyclable resources (aluminum cans 0.2%, steel cans 2.5%, glass 1.8%), 92.5% resources with recoverable energy (papers 23.0%, plastics 15.5%, combustible etc. 54.0%) and 3.0% non-combustible etc. Recycling is more effective than landfilling for aluminum cans, steel cans, and glass. The energy recovery process using solid refuse fuel (SRF) is more effective than incineration for papers and plastics. Incineration is more effective than recycling for combustible etc. 2,068,948 Million Btu of total energy savings and 21,008 $MTCO_2E$ of total GHG reductions were obtained by the application of the proposed scheme. The total energy savings were equivalent to an economic benefit of 422 billion won per year. The total GHG reductions were equivalent to a GHG benefit of 4,119 passenger cars not running per year. The lower calorific value of the combustible materials was obtained to be 1,936 kcal/kg of papers, 5,079 kcal/kg of plastics and 2,462 kcal/kg of combustible other resources, respectively. If papers and plastics are properly mixed, the mixture can be used as SRF. The lower calorific value of combustible other resources does not meet the quality criteria for refuse derived fuel, therefore its components are inappropriate to used as solid refuse fuel.