• Title/Summary/Keyword: 혼합 산화제

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A Study on the Oxide CMP Characteristics According to the $CeO_2$ Abrasive Adding (세리아 연마제 첨가에 따른 산화막 CMP 특성 연구)

  • Han, Sang-Jun;Lee, Young-Kyun;Park, Sung-Woo;Seo, Yong-Jin;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.542-542
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    • 2008
  • 본 논문에서는 기존에 상용화된 슬러리에 비해 새로운 혼합 연마제 슬러리의 우수성을 입증하고, 최적화 된 공정기술을 연구의 기반으로 활용하고자 Silica slurry에 $CeO_2$ 연마제를 혼합하여, 어떠한 연마 특성을 나타내는지 알아보았고, AFM, EDX, XRD, TEM 분석을 통해 그 가능성을 비교 분석하였다.

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A Comparative Study on Characteristics of Nanofluids Using Carbon NanoTubes (탄소 나노튜브를 이용한 나노유체의 특성 비교 연구)

  • An, Eoung-Jin;Park, Sung-Seek;Kim, Nam-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.74.1-74.1
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    • 2011
  • 탄소나노튜브는 높은 전기 전도성과 열 전도성을 가지며, 이러한 특성 때문에 21세기를 주도해 나갈 수 있는 차세대 첨단 소재로서 각광을 받고 있다. 또한 최근에는 나노공학기술의 발달로 인하여 획기적으로 높은 열전도도를 나타내는 다중벽 탄소나노튜브(Multi-walled Carbon Nanotubes, MWCNTs)의 대량 생산이 가능하게 되면서 다중벽 탄소나노튜브의 높은 열전도도 특성을 이용하여 탄소나노튜브를 기본 유체 및 기능성 유체에 안정하게 분산 시킨 후 이를 이용하고자 하는 연구가 활발히 진행되고 있으며, 탄소나노튜브를 유체에 안정하게 분산시키기 위한 방법으로는 기계적 분산법, 물리적 흡착에 의한 분산법, 화학적 개질에 의한 분산법이 있다. 따라서 본 연구에서는 이들 분산 방법과 탄소나노튜브 입자의 물성치에 따른 나노유체의 특성을 알아보기 위하여 나노유체의 열전도도와 점도 특성을 비교 분석하였다. 모든 물성치는 같지만 탄소나노튜브의 길이만 다른 두 종류의 다중벽 탄소나노튜브에 각각 계면 활성제(Sodium Dodecyl Sulfate, SDS) 100 wt%와 고분자 화합물(Polyvinyl Pyrrolidone, PVP) 300 wt%를 첨가하여 나노유체를 제조하였으며, 산화처리 된 다중벽 탄소나노튜브(Oxidized Multi-Walled Carbon Nanotubes, OMWCNTs)를 증류수에 초음파 분산하여 산화나노유체를 제조하였다. 나노유체의 열전도도는 전기 전도성 유체의 비정상 열선법(Transient Hot-wire Method)을 이용하여 측정하였고, 나노유체의 점도는 회전형 디지털 점도계를 이용하여 측정하였다. 실험 결과, 상온에서 동일 혼합비의 나노유체를 비교했을 때, 산화나노유체가 SDS 100 wt%, PVP 300 wt%를 혼합한 다른 나노유체보다 높은 열전도도 특성을 보였으며 점도 특성 또한 가장 낮은 것으로 측정되었다. 특히 상온에서 0.1vol%의 산화 CM-100 나노유체는 증류수보다 열전도도가 8.34%가 증가하였고, $10^{\circ}C$의 저온에서는 상온에서 증류수와 비교하여 측정된 열전도도 값보다 0.36%가 감소한 7.98%가 증가함을 보였다. 본 연구를 통하여 얻어진 결과는 높은 열전도도를 필요로 하는 열교환기의 작동유체나 기타 활용 분야에 대한 기초 자료로써 유용한 정보를 제공할 것이라 판단된다.

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Effects of Antioxidants and Packaging Methods on the repression of Lipid Oxidation in Plain Dried Large Anchovy (소건 대멸치 지질의 산화억제에 미치는 항산화제와 포장의 병행효과)

  • CHO Young-Je;KIM Tae-Jin;SHIM Kil-Bo;CHOI Young-Jun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.3
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    • pp.238-242
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    • 2000
  • The antioxidants and packaging methods affecting on lipid oxidation of the plain dried large anchovy were investigated. Antioxidants resulted in decrease of lipid oxidation of dried large anchovy. The addition of BHT remarkably repressed lipid oxidation during storage of the dried large anchovy at $37^{\circ}C$, followed by ${\alpha}-tocopherol$, rosemary extract and sage extract. The addition of rosemary extract mixed with 0.1{\%} {\alpha}-tocopherol$ showed similar effect to BHT during storaBe at $25^{\circ}C\;in\;0.1{\%}$ rosemary extract mixed with $0.1{\%}\;{\alpha}-tocopherol$. When the dried anchovy were packed in polyethylene film after treatment with antioxidants, the vacuum package increased the antioxidative effect in repression of lipid oxidation during storage of dried large anchovy.

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Spray Characteristics of a Liqud-Liquid Swirl Coaxial Injector (액체-액체 스월 동축형 인젝터의 분무특성)

  • Kim Dong-Jun;Im Ji-Hyuk;Han Poong-Gyoo;Yoon Young-Bin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.147-150
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    • 2006
  • The influences of injection conditions and recess configuration of liquid-liquid swirl coaxial injector on spray characteristics were investigated. The characteristics of the coaxial spray in internal mixing injection region were mai y controlled by the merging phenomenon and momentum balance between two liquid sheets, but those in internal mixing injection region were influenced by the impingement phenomenon as well as momentum balance between two liquid sheets.

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Spray Characteristics of a Liquid-Liquid Swirl Coaxial Injector Part I : Effect of Injection Condition (액체-액체 스월 동축형 인젝터의 분무특성 Part I : 분사조건에 따른 특성)

  • Kim, Dong-Jun;Im, Ji-Hyuk;Han, Poong-Gyoo;Yoon, Young-Bin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.10 no.3
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    • pp.1-8
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    • 2006
  • The influences of injection conditions and recess configuration of liquid-liquid swirl coaxial injectors on spray characteristics were investigated. The characteristics of the coaxial spray in internal mixing injection region were mainly controlled by the merging phenomenon and momentum balance between two liquid sheets, but those in internal mixing injection region were influenced by the impingement phenomenon as well as momentum balance between two liquid sheets.

Study on Discharge Coefficient Variations of Bi-Swirl Injectors with Working Conditions (작동 조건에 따른 이중 와류 분사기 유량 계수 변화 연구)

  • Seo, Seong-Hyeon;Ahn, Kyu-Bok;Han, Yeoung-Min;Choi, Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.05a
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    • pp.177-180
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    • 2010
  • It has been studied the effect of mixture ratio and chamber pressure on variations of discharge coefficients. Combustion experiments of bi-liquid swirl coaxial injectors were conducted at fuel-rich conditions with liquid oxygen and kerosene. Using two types of injectors for the experiments, characteristics of the discharge coefficient have been identified from variations in a diameter of the fuel nozzle and a momentum ratio along with the change of a LOx spray angle. It is concluded that discharge coefficients do not vary because of no change of flame structures from the fact that the fuel swirl chamber is completely filled up with fuel flow.

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Study on Thermodynamic Properties of Sulfidization for Uranium and Rare Earth Oxides (우라늄 및 희토류(稀土流) 산화물(酸化物)의 황화반응(黃化反應)에 대한 열역학적(熱力學的) 고찰(考察))

  • Lee, Jung-Won;Lee, Jae-Won;Kang, Kweon-Ho;Park, Geun-Il
    • Resources Recycling
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    • v.21 no.1
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    • pp.66-74
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    • 2012
  • In order to evaluate the feasibility of selective sulfidization of uranium and rare-earth(RE) oxides, an analysis on thermodynamic data, such as $M-O_2-S_2$ phase stability diagram and changes of Gibbs free energy for sulfidization of uranium and rare-earth oxides were carried out. Comparing $RE-O_2-S_2$ with $U-O_2-S_2$ phase stability diagram at wide range of sulfur potential, $UO_2$ remains unreacted, while RE oxides are sulfidized. The Gibbs free energy change(${\Delta}G^{\circ}$) of sulfidization of RE oxides is lower than that of uranium oxides. Thus, the selective formation of RE sulfides is possible during sulfidization of RE and uranium oxides at lower temperature. $CS_2$ was selected as a sulfidizing agent, because it is a stronger sulfidizing agent than other agents and reacts at lower temperature.

Study of Injector Damage on Fuel-rich Gas Generator (연료 과농 가스발생기의 분사기 손상에 관한 연구)

  • Moon Il-Yoon;Lee Kwang-Jin;Lim Byoung-Jik;Seo Seong-Hyeon;Han Yeoung-Min;Choi Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.197-201
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    • 2006
  • In the development process of a fuel-rich gas generator using kerosene and LOx for a 30 tonf class liquid rocket engine, a heat damage occurred at the LOx post of swirl coaxial injectors used in the gas generator and the problem has been examined. To prevent the heat damage, injectors are redesigned to have an increased recess while maintaining internal mixing, which minimizes recirculation region to prevent anchoring of the flame in the recirculation region. The combustion test results of the sub-scale gas generator showed that this scheme can prevent heat damage of the LOx post in the swirl coaxial injectors of the fuel-rich gas generator.

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Hot-firing Test Results of Subscale Gas Generator for 75 ton-class Liquid Rocket Engine (75톤급 액체로켓엔진 축소형 가스발생기 연소시험 결과)

  • Kim, Mun-Ki;Ahn, Kyu-Bok;Lim, Byoung-Jik;Kim, Jong-Gyu;Seo, Seong-Hyeon;Choi, Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.726-728
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    • 2010
  • A subscale gas generator was designed and manufactured to investigate the effect of design parameters on discharge coefficients of injectors for a 75 ton-class gas generator and hot-firing tests were successfully performed. The test results showed that discharge coefficients of fuel and liquid oxygen injectors remained nearly constant irrespective of variations of a mixture ratio and a chamber pressure. When the post diameter of the liquid oxygen injector was reduced, the discharge coefficient was increased as the pressure drop of the injector was decreased.

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The Patterns of Streamwise Vortex on the Fuel Surface in Hybrid Rocket Combustion (하이브리드 로켓 모터 연소 중 발생하는 streamwise 와류 특성)

  • Shin, Kyung-Hoon;Park, Kyung-Su;Mon, Khin Oo;Lee, Chang-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.649-652
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    • 2011
  • A series of hybrid rocket combustion experiments were carried out with PMMA/GOx changing diameter and length of the disk installed at pre-chamber. The disk can generate vortex shedding flow and change flow conditions prior to entering the fuel grain which could also alter the combustion characteristics and pressure oscillations. Isolated dimple-like surface roughness patterns distributed all over the fuel surface, which can be thought of as a realization of the inherent flow instability. It is very likely that the formation of cell structures is originated from the modification of boundary layer characteristics of an entering oxidizer flow caused by a blowing effect mainly taking place near the wall. This coincided with our LES results. It would be a meaningful basis to understand combustion instability of hybrid rocket motor.

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