• Title/Summary/Keyword: 혼합면

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Metal 첨가물질에 따른 비정질 IGZO 투명전극 특성 연구

  • Sin, Han-Jae;Hwang, Do-Yeon;Lee, Jeong-Hwan;Lee, Dong-Ik;Park, Seong-Eun;Park, Jae-Seong;Kim, Seong-Jin;Lee, Yeong-Ju;Seo, Chang-Taek
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.368-370
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    • 2013
  • 투명 전극은 전기전도도를 갖는 동시에 가시광선을 투과하는 소재를 말하며, 구체적으로는 빛의 파장이 400~700 nm 영역대의 가시광선을 80% 이상 투과하며 전기전도도가 비저항으로 $10^{-3}{\Omega}cm$이하이거나 면저항이 $10^3{\Omega}$/${\Box}$소재를 의미한다. 투명 전극은 전기전도도에 따라 사용되는 용도가 다양하다. LCD, PDP, OLED 와 같은 평판디스플레이 및 3D 디스플레이의 투명전극으로 사용되는 핵심재료일 뿐만 아니라 터치스크린, 투명필름, 대전방지막, 열반사막, EMI 방지막, 태양전지 분야에 광범위하게 이용되고 있다. 일반적으로, 투명전극 박막에 가장 많이 사용되고 있는 소재는 ITO (indium tin oxide)이나, 주성분인 In의 사용량 증가로 상용 ITO 타겟 가격이 급등하고 있음으며, 고가의 ITO 타겟을 대체하기 위한 저가의 투명전극 소재 개발이 절대적으로 요구되며, 신규 소재 개발을 통한 기술력 우위 선점이 필수적으로 요구되는 상황이다. 본 연구에서는 기존에 디스플레이 분야에서 널리 활용되는 고가의 ITO를 대체하기 위한 다성분 금속산화물 투명전극 스퍼터링 타겟 제조기술을 개발하기 위한 연구로서, Metal이 첨가된 In-Ga-Zn-O기반의 3성분계 투명도전성 소재를 조성설계, 고밀도 균질 타겟 제조 및 투명전극 박막을 형성하는 연구를 실시하였다. 고체산화물 산화인듐(In2O3)분말, 산화갈륨(Ga2O3) 분말그리고 산화아연(ZnO)분말과 Metal을 몰비로 칭량한 후 분말을 폴리에틸렌제 포트에 넣고 에탄올을 충분히 채운 후 지르코니아(ZrO2) 볼(ball)을 이용하여 24 h 동안 볼 밀링(ball milling) 방법으로 혼합한 뒤, $120^{\circ}C$의 플레이트위에서 마그네틱 바로 stirring하면서 건조하였다. 이 분말을 건조기에서 완전히 건조한 후 알루미나 유발을 이용해서 pulverizing한 후 sieving기를 이용하여 분말의 조립화를 하였다. 이 분말을 금형에 넣고 300 kg/$cm^2$의 압력으로 press하여 성형한 뒤 대기중에서 소결하였다 소결을 위한 승온 온도는 $10^{\circ}C$/min이었고 소결은 $1,450^{\circ}C$에서 6 h 동안 하였다. IGZO target의 조성 비율은 1:1:12 (mol%)를 사용하였으며, 첨가한 Metal은 Boron (B), Germanium (Ge), Barium (Ba)을 사용하여 타겟을 제작하였다. M-IGZO 박막은RF magnetron Sputter를 이용하여 증착하였으며, 앞선 실험에서 제작한 타겟을 사용하여 M-IGZO박막을 투명전극으로 사용하기 위한 각각의 특성을 파악하였다. 모든 박막은 상온에서 증착을 하였으며, 증착된 박막두께를 측정하기 위해 ${\alpha}$-step IQ를 사용하였고, 광학적 특성을 분석하기 위해 UV-Visible spectrophotometer 로 투과율을 측정하였다. 그리고 전기적 특성을 측정하기 위해 Hall effect measurement 및 4-probe를 사용하였으며, 결정성 분석을 위하여 XRD를 이용하여 분석하였다. 표1은 M-IGZO타겟을 사용하여 증착시간에 따른 면저항 특성을 나타내었다. Ge, B, Ba이 첨가된 IGZO 박막은 증착시간이 증가할수록 면저항이 낮아짐을 알 수 있었다. 또한, Ge이 첨가된 IGZO 박막이 다른 금속이 첨가된 IGZO 박막의 면저항보다 현저히 낮음을 알 수 있었다. Fig. 1(a), (b), (c)는 각 타겟을 동일한 조건으로 증착을 하여 광학적특성을 나타내는 그래프이다. GZO 박막의 광학적 특성을 보면 가시광 영역에서 평균 투과율은 모두 80% 이상으로 우수한 광투과 특성을 보여 투명전자소자로 사용가능하다. 특히, 자외선 영역을 모두 차단하는 UV cut 능력이 우수함을 알 수 있었다. 따라서, 금속이 첨가된 IGZO 박막을 태양전지용 투명전극으로 사용할 경우, 자외선에 의하여 수명이 단축되는 현상을 줄여줄 수 있음을 기대할 수 있으며 내구성 향상에 크게 기여할 것으로 보인다. Fig. 2는 Ge=0, 0.5, 5%인 IGZO 투명전극을 총 40회 반복하여 증착을 실시한 후 각각의 면저항을 측정한 결과이다. 실험결과에 따르면 Ge가 0%, 5%인 IGZO 투명전극은 증착을 거듭할수록 면저항이 증가하는 결과를 나타내었으며, 0.5%인 IGZO 투명전극은 점차 안정화되어가는 결과를 나타내었다. 따라서 안정화 되었을 때 평균 면저항은 26ohm/sq.로 나타났으며, 광투과율은 Fig. 3과 같이 가시광영역에서 평균 80%이상의 결과를 보였으며, 550 nm에서는 86.36%의 우수한 특성을 나타내었다. 본 연구에서는 Metal이 첨가된 In-Ga-Zn-O기반의 3성분계 투명도전성 소재 target을 제작하여 RF magnetron sputter로 박막을 형성한 후 특성을 비교하였다. M-IGZO target 중 Ge (0.5%)을 첨가한 IGZO 타겟을 사용한 투명전극이 가장 우수한 특성을 보였으며, 제작된 M-target의 In 비율이 30% 정도로 기존의 ITO (90%) 대비하여 투명전극 제작 단가를 절감할 수 있다.

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MICROLEAKAGE OF THE CLASS V CAVITY ACCORDING TO RESTORATION SITE AND CAVITY SIZE USING SEM AND THREE-DIMENSIONAL RECONSTRUCTION TECHNIQUES (SEM과 3차원 재구성법을 이용한 수복면의 위치와 와동 크기에 따른 미세누출도 분석)

  • Yang, In-Seo;Shin, Dong-Hoon
    • Restorative Dentistry and Endodontics
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    • v.30 no.2
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    • pp.112-120
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    • 2005
  • This study was done to evaluate whether there were any differences in microleakage of class V composite restorations according to restoration site and cavity size. Total sixty-four restorations were made in molar teeth using Esthet-X. Small ($2\;{\times}\;2\;{\times}\;1.5\;mm$) and large ($4{\times}2{\times}1.5\;mm$) restorations were made at the buccal/lingual surface and the proximal surface each. After 1,000 times of thermocycling ($5^{\circ}\;-\;55^{\circ}C$), resin replica was made and the percentage of marginal gap to the whole periphery of the restoration was estimated from SEM evaluation. Thermocycled tooth was dye penetrated with $50\%$ silver nitrate solution. After imbedding in an auto-curing resin, it was serially ground with a thickness of 0.25 mm. Volumetric microleakage was estimated after reconstructing three dimensionally. Two-way ANOVA and independent T-test for dye volume, Mann-Whitney U test for the percentage of marginal gap, Spearman's rho test for the relationship between two techniques were used, The results were as follows : 1. The site and size of the restoration affected on the microleakage of restoration. Namely, much more leakage was seen in the proximal and the large restorations rather than the buccal/lingual and the small restorations. 2. Close relationship was found between two techniques (Correlation coefficient = 0.614/ P = 0.000). Within the limits of this study, it was noted that proximal and the large restorations leaked more than buccal/lingual and the small restorations. Therefore, it should be strictly recommended large exposure of margins should be avoided by reducing unnecessary tooth reduction.

Quality and Antioxidant Activity of Wet Noodles Supplemented with Brown Rice and Sorghum Powders (현미 및 수수 첨가에 따른 생면의 품질특성과 항산화 효과)

  • Cheng, Li;Kim, Sin-Joung;Kil, Jeung-Ha;Park, Kun-Young
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.4
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    • pp.530-536
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    • 2014
  • In this study, we investigated the quality and antioxidant activity of wet noodles fortified by adding brown rice and sorghum powders. Wet noodles were divided into four groups: WN-p (wheat flour 100%, purified salt 2%), WBN-b (wheat flour 80%, brown rice powder 20%, bamboo salt (${\times}1$) 2%), WBSN-b (wheat flour 80%, brown rice powder 10%, sorghum powder 10%, bamboo salt (${\times}1$) 2%), and WSN-b (wheat flour 80%, sorghum powder 20%, bamboo salt (${\times}1$) 2%). The wet noodles were evaluated for their quality characteristics and capacities to scavenge free radicals. The weight, volume, capacity to absorb water, and turbidity of cooked WBSN-b were close to those of cooked WN-p. Springiness, cohesiveness, and chewiness of cooked WBSN-b were the highest among all cooked noodles added with brown rice or sorghum powders and textural properties of cooked WBSN-b were not significantly different from WN-P. In the sensory evaluation, the overall acceptance of WBSN-b received the highest score of 6.4 points, which was higher than the score for WN-p. DPPH and hydroxyl radical scavenging activities increased significantly with addition of brown rice and sorghum powder, and radical scavenging activities of WBSN-b and WSN-b were the highest. In conclusion, wet noodles added with 10% brown rice powder, 10% sorghum powder, and 2% bamboo salt (${\times}1$) exhibited the same quality properties of WN-p. Addition of 10% brown rice powder, 10% sorghum powder, and 2% bamboo salt (${\times}1$) increased the sensory and antioxidant activities of wheat flour noodles.

Development of the Optimal Composting Condition for the High Quality of Pig manure compost (고품질의 돈분 퇴비를 위한 합리적인 퇴비화 조건 개발)

  • Chang, Ki-Woon;Yu, Young-Seok;Min, Kyoung-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.4
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    • pp.112-117
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    • 2002
  • This study was conducted to induce the optimal composting conditions of pig manure mixed with sawdust and dried paper-mill sludge in the composting for production of high quality compost. Pig manure contains high water content and How C/N ratio because of comparatively high nitrogen content than sawdust and dried paper-mill sludge. Therefore the addition of dried paper-mill sludge and sawdust to the raw materials helps controlling the C/N and the water content of compost pile. The composting system used in the experiment was agitated static bed system. The physical properties of the mixed raw materials was not good at the working conditions in the early stage of composting. The temperature of compost heap reaches at $60^{\circ}C$within 5 day after starting composting in P-2 treatment mixed with pig manure and sawdust(56.6 : 43.4). Then the water content of P-2 was 58%. The pH in all treatments were slowly decreased as the composting was proceeded. Although the changes of T-C and T-N were not extended because of the short composting experiment period. Reduction rates of T-C in treatments were 5-12% without special difference. By considering the efficiency of composting in each of five treatments with pig manure the optimal water contents was about 57% level. Mixing a sawdust as a bulking agent was more positive than dried paper-mill sludge from a viewpoint of compost quality.

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Processing Techniques of Layer Channel Image for 3D Image Effects (3D 영상 효과를 위한 레이어 채널 이미지의 처리 기법)

  • Choi, Hak-Hyun;Kim, Jung-Hee;Lee, Myung-Hak
    • The Journal of the Korea Contents Association
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    • v.8 no.1
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    • pp.272-281
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    • 2008
  • A layer channel, which can express effects on 3D image, is inserted to use it on application rendering effectively. The current method of effect rendering requires individual sources in storage and image processing, because it uses individual and mixed management of images and effects. However, we can save costs and improve results in images processing by processing both image and layer channels together. By changing image format to insert a layer channel in image and adding a hide function to conceal the layer channel and control to make it possible to approach image and layer channels simultaneously during loading image and techniques hiding the layer channel by changing image format with simple techniques, like alpha blending, etc., it is developed to improve reusability and be able to be used in all programs by combining the layer channel and image together, so that images in changed format can be viewed in general image viewers. With the configuration, we can improve processing speed by introducing image and layer channels simultaneously during loading images, and reduce the size of source storage space for layer channel images by inserting a layer channel in 3D images. Also, it allows managing images in 3D image and layer channels simultaneously, enabling effective expressions, and we can expect to use it effectively in multimedia image used in practical applications.

Characterization of Flowable Fill with Ferro-Nickel Slag Dust (페로니켈 슬래그 미분말을 이용한 유동성 뒤채움재 특성)

  • Lee, Kwan-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.5
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    • pp.16-21
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    • 2017
  • The aim of this study was to utilize ferronickel slag produced in the manufacture of stainless steel as a flowable backfill material for underground use using crushed fine powder. Experimental combinations were made using two components: Case A (sand) and Case B (soil). The optimal mixing ratio of Case A was sand (58.4%), ferronickel slag fine powder (21.6%), cement (1.8%), and water (18.2%). In the case of B, the optimal mixing ratio was determined to be soil (53.0%), ferronickel slag fine powder (20.0%), cement (1.7%), and water (25.3%). The uniaxial compressive strength of case A, which is a mixture of ordinary sand and ferronickel slag powder, was relatively larger than that of case B using soil. In addition, the strength of the specimen increased with increasing curing time. The uniaxial compressive strength tended to increase with increasing curing time. In addition, the unconfined compression strength of the fluid backfill material using common sand as the main material was relatively larger than that of the mixed material using soil as the main material. In case A, the uniaxial compressive strength ranged from 0.17-0.33 MPa, 0.21-0.39 MPa, and 0.19-0.40 MPa, respectively, at curing times of 7, 14, and 28 days. From the experimental results, it was concluded that the ratio of FNS powder and cement mixture was the most appropriate for Case A3. Case B, which used soil as the main material, showed a similar tendency to Case A. As a result of the dissolution test for evaluating the environmental harm of the FNS fine powder, there was no dissolution of substances harmful to the environment.

Quality characteristics and antioxidant activities of aronia jams added with apple (사과를 첨가한 아로니아 혼합잼의 품질특성 및 항산화활성)

  • Park, Seong-Hoon;Park, Jae-Ho;Noh, Jae-Gwan;Shin, Hyunman;Lee, Sung-Hee;Kim, Youngho;Eom, Hyun-Ju
    • Food Science and Preservation
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    • v.23 no.2
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    • pp.180-187
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    • 2016
  • The objective of this study was to investigate the quality characteristics and antioxidant activities of aronia jam prepared with different content of mashed apple. To analyze the quality characteristics pH, texture, color, antioxidant activity, total polyphenol content, and sensory property were investigated. As aronia amounts decreased, the pH of aronia jam level increased from 3.97 to 4.40, while its total acidity decreased from 0.39 to 0.27. In color, the L-, a-, and b- values increased with decreases in aronia contents when compared with 100% aroma jam. Texture evaluation revealed that the hardness, springiness, gumminess, and chewiness of 100% aronia jam were markedly higher than those of the control and other samples (p<0.05). As the aronia content decreased, both the antioxidant activity and total polyphenol content significantly decreased (p<0.05) and the total anthocyanin content gradually decreased. In the sensory evaluation, the jams containing 50% and 70% aronia showed higher values than those of other samples in overall acceptability. Taken together, aronia jam with 30% apple could be the best in order to meet the taste and functional requirements for consumers.

Characteristics of Planting Design according to Parking Lots Type in Multi-family Housing Complex (공동주택단지의 주차장 유형에 따른 식재특성)

  • Hong, Seong-Rae;Jeong, Dae-Young;Shim, Sang-Ryul
    • Journal of the Korean Institute of Landscape Architecture
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    • v.37 no.1
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    • pp.43-49
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    • 2009
  • The number of registered vehicles increased to one million in 1985 and ten million in 1997, and the parking lots in multi-family housing complex that had been mainly constructed on the ground level began to be constructed in underground levels. Therefore, planting design in such complex were greatly changed. This study classifies the parking lots in multi-family housing complexes located in Cheongju into three categories: above-ground, mixture of above-ground and underground, and underground. The characteristics of planting design in each were then analyzed. The rate of parking per family increased by two or more in the type of mixture when compared to in the type of above-ground. As underground parking lots became dominant, the rate of parking per family increased to one car or more. The green area ratio did not change considerably when above-ground parking was combined with underground parking, but the green area per total floor space was reduced, which indicates the quality of green area became lower. Most of the parking lots in multi-family housing complexes since 2000 have been constructed underground, and the green area became larger. As for the species of trees used in planting design, trees that are vulnerable to damage by blight and harmful insects and may be repugnant have been reduced and replaced by trees whose shapes are beautiful and whose flowers and fruits can be appreciated, such as Chionanthus retusa, Malus floribunda, Styrax japonicus, Prunus mume, Lagerstroemia indica. Pine trees are variously planted with diversified standards, and, in particular, tall pine trees are being utilized as focal points. Herbaceous flowers began to be planted in underground parking lots constructed since 2000, and they are expected to be planted even more due to the appreciation of their flowers and their splendid appearance.

Eliminating Color Mixing of Projector-Camera System for Fast Radiometric Compensation (컬러 보정의 고속화를 위한 프로젝터-카메라 시스템의 컬러 혼합 성분 제거)

  • Lee, Moon-Hyun;Park, Han-Hoon;Park, Jong-Il
    • Journal of Broadcast Engineering
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    • v.13 no.6
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    • pp.941-950
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    • 2008
  • The quality of projector output image is influenced by the surrounding conditions such as the shape and color of screen, and environmental light. Therefore, techniques that ensure desirable image quality, regardless of such surrounding conditions, have been in demand and are being steadily developed. Among the techniques, radiometric compensation is a representative one. In general, radiometric compensation is achieved by measuring the color of the screen and environmental light based on an analysis of camera image of projector output image and then adjusting the color of projector input image in a pixel-wise manner. This process is not time-consuming for small sizes of images but the speed of the process drops linearly with respect to image size. In large sizes of images, therefore, reducing the time required for performing the process becomes a critical problem. Therefore, this paper proposes a fast radiometric compensation method. The method uses color filters for eliminating the color mixing between projector and camera because the speed of radiometric compensation depends mainly on measuring color mixing between projector and camera. By using color filters, there is no need to measure the color mixing. Through experiments, the proposed method improved the compensation speed by 44 percent while maintaining the projector output image quality. This method is expected to be a key technique for widespread use of projectors for large-scale and high-quality display.

Physico·Chemical Properties of Organic and Inorganic Materials Used as Container Media (혼합배지 조제에 이용되는 유·무기 물질들의 물리·화학적 특성)

  • Choi, Jong Myung;Chung, Hae Joon;Choi, Jong Seung
    • Horticultural Science & Technology
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    • v.18 no.4
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    • pp.529-535
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    • 2000
  • Organic materials such as composted rice-hull, saw dust, and pine bark, and inorganic materials such as vermiculite, perlite, and recycled rockwool were commonly employed as container media in domestic greenhouse industry. The objective of this research was to get informations in soil physico chemical properties of those materials. Composted dry-peeling bark and wet-peeling bark had 72.1% and 69.1%, respectively, in particles larger than 1.0 mm, which were much higher than 34.7% of composted rice-hull and 33.7% of composted saw dust. Imported vermiculite had 89.9%, but domestic vermiculite had 25.7% in particles larger than 1 mm. In soil physical properties, Russian peat had the highest container capacity of 79.3%, and wet-peeling bark had the lowest container capacity of 58.2%. However, Russian peat and composted saw-dust had 4.1% in air space indicating that possible problems could occur in soil aeration when those are employed for container grown crops. Saw dust had $2.3mS{\cdot}cm^{-1}$ in electrical conductivity, while other composted organic materials had less than $0.25mS{\cdot}cm^{-1}$. Imported vermiculite had 64.0 meq/100 g in cation exchange capacity, which was 2.4 times higher than those of domestic vermiculite, 27.2 meq/100 g. Domestic vermiculite had higher Ca and Mg and less Na contents than those of imported vermiculite.

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