• Title/Summary/Keyword: 혼합면

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Study on Biodegradable Polyurethane Foam for Non-lethal Weapon (비 살상 무기 개발을 위한 생분해성 발포 폴리우레탄에 대한 연구)

  • Lee, Hyang Moo;Kim, Young Hyun;Kim, Kyung Won;Cheong, In Woo
    • Journal of Adhesion and Interface
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    • v.17 no.1
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    • pp.21-28
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    • 2016
  • Foam-type biodegradable polyurethane adhesives were developed as a non-lethal weapon against illegal fishing boats. The adhesives were prepared from a hardener of polymeric methylene diphenyl diisocyanate (MDI) and a base composed of polyester and/or polyether polyols. In order to accelerate biodegradability, starch, dextrin, and amylase were added into the base, and which present about 34% degradability within 4 weeks confirmed by OECD 301C method. For proper mixing and corresponding prompt foam reaction, viscosities of hardener and base compositions were investigated in the temperature ranges from 0 to $50^{\circ}C$. For fast completion of the foam forming and corresponding adhesion, rising time was recorded in the same temperature range, and the rising time of the adhesive was varied within around 1 minute. T-peel adhesion tests with cotton fabrics were performed which showed 20.78 N/cm and 11.95 N/cm as the maximum and the average values, respectively.

Study of Plasma Polymerization on Wood Powder/PP Composites Interface (플라즈마 처리가 목분/폴리프로필렌 복합재의 계면에 미치는 영향 연구)

  • Ha, Jong-Rok;Kim, Byung Sun;Yi, Jin Woo
    • Composites Research
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    • v.26 no.3
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    • pp.170-174
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    • 2013
  • Atmospheric glow plasma polymerization was applied to wood powder before fabricating polypropylene (PP) matrix composites. Seven different types of monomers (Oxygen, Benzene, CH4, Acrylic-acid, Hexafluoroethane, Trifluorotolune, Hexamethyl-disiloxane) were analyzed to determine the most suitable precursor for plasma polymerization. The surface energy was calculated from measured contact angle about each monomer on PP. Hexamethyl-disiloxane (HMDSO) had a highest surface energy and is selected as the most suitable monomer. Wood powder and polypropylene were mixed as pellets by twin screw extruder and then 50 wt% wood powder/PP composites were produced by an injection machine. Tensile strength and Flexural strength have improved by 7.59% and 12.43% at the maximum respectively. SEM (Scanning Electron Microscope) observation on the fracture surface revealed that the plasma polymerization have improved the interfacial bonding and the mechanical properties of the composites.

Experimental Study on Setting Time of Cement Paste Mixed Accelerating Admixtures (급결제를 혼합한 시멘트페이스트의 응결시간에 관한 실험적 연구)

  • Heo Gweon;Choi Hong-Shik;Yi Seong-Tae
    • Journal of the Korea Concrete Institute
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    • v.17 no.6 s.90
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    • pp.879-884
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    • 2005
  • The setting time is a very important factor affecting the quality of tunnel lining and reinforcement of inclined slope etc. Currently, however, the quality criteria of accelerating admixture to improve it is not established well. In this study, evaluation on setting time measuring methods of cement mixed a accelerating admixture (AA) was performed using Gillmore and Vicat needle test methods. For both test methods, the setting time for addition at a time was better than post addition regardless of initial setting and final setting. For Gillmore needle test method, two types of measuring methods were selected and it is noted that setting time with cement type under the same accelerating admixture can be different. Accordingly, manufacturing company shall develop a less sensitive accelerating admixture to cement type. For Vicat needle test method, six types of measuring methods were used and a proper measuring method of the admixture were proposed as follows: (1) the temperature of materials used shall be controlled exactly and (2) to evaluate its properties, an admixture usage of $5\%$ (ratio of cement weight) is recommended.

Fire Resistance Performance of High Strength Concrete with Fiber Types (섬유 종류에 따른 고강도 콘크리트의 내화성능에 관한 실험적 연구)

  • Kim, Jeong-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.223-229
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    • 2014
  • In this study, the fire resistance of high strength concrete with organic fibers and polymer powder (PW) was investigated. Two types of the specimens of ${\phi}100{\times}200mm$ and $300{\times}300{\times}600mm$ sizes were prepared. As a result of the test, it was found that the fiber-to-PW mixing ratio of 1:1 achieved the highest fluidity. Further, it was found that the mixing ratios of PP 0.05% + PW 0.05%, PNY 0.05% + PW 0.05% was sufficient to protect the high strength concrete from spalling. For the mock-up specimens of $300{\times}300{\times}600mm$ size, if the required amounts of fibers were added in the concrete. the concrete spalling was resisted. Likewise, in the case of the polymix (PM) together with PW, all the tested specimens were satisfactory for fire resistance performance.

A Study on the Characterization of the Mixed-Oxide Prepared from Monazite (모나자이트로부터 파생된 희토류 혼합산화물의 특성)

  • Kwon, Young Sik;Kim, Yeun Sik;Kim, Dong Su
    • Journal of the Korean Chemical Society
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    • v.39 no.12
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    • pp.946-954
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    • 1995
  • The physico-chemical nature of the rare earth oxide which was produced by the caustic fritting of monazite was studied to furnish fundamental data that are required for its efficient use and processing. It was found that the material which was mainly constituted of light rare earths and thorium was a solid solution phase of oxide whose structure was fluorite-type face centered cubic. Its density was 6.75 g/$cm^3$ and it had a uniform particle size distribution at around 1 ${\mu}m.$ The crystallinity improved by heating to elevated temperatures, whereas the solubility in HCl decreased as the crystallinity improved. Complete dissolution in conc. HCl solution in short time (30 min.) was attained by heating to 70$^{\circ}C$. The measurement of zeta potential showed its I.E.P. to be at pH 8.6 of the suspension.

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Solvolysis of Substituted Benzyl Benzenesulfonates in MeOH-MeCN Mixtures (MeOH-MeCN 혼합용매계에서 치환된 벤젠술폰산벤질의 가용매 분해반응)

  • Ikchoon Lee;Won Hee Lee;Chul Hyun Kang;Se Chul Sohn;Choong Shik Kim
    • Journal of the Korean Chemical Society
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    • v.28 no.6
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    • pp.366-373
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    • 1984
  • Methanolysis rates of benzylbenzenesulfonates, substituted both on the substrate (Y) and on the leaving group (Z), were determined in MeOH-MeCN mixtures. The results showed that the reaction proceeds via the dissociative $S_N2$ mechanism, in which bond breaking proceeds in greater degree compared to bond formation at the transition state(TS). Multiple Hammett correlation analysis showed that the cross term, ${\rho}_{YZ}$, is very small and hence the cross interaction of two substituents, Y and Z, at the TS is not important, supporting the dissociative $S_N2 $ type mechanism. While transition state variations predicted by the quantum mechanical model is shown to agree in general with the experimental results, those predicted by the potential energy surface model failed to account for the leaving group effect properly.

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Combustion Characteristics and Design of Fiber Mat Catalytic Burners (매트 형태 연소촉매를 사용하는 촉매버너의 구조와 연소특성)

  • Song, Kwang-Sup;Jung, Nam-Jo;Kim, Hee-Yeon
    • Journal of Energy Engineering
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    • v.17 no.2
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    • pp.100-106
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    • 2008
  • Flameless fiber mat catalytic burners have been known as an effective heat source in industrial drying processes since heat obtained from combustion can be transferred to absorptive body by far-infrared radiation. In order to extend the application of fiber mat catalytic burner, novel fiber mat catalytic burners were manufactured and combustion characteristics of them were investigated. For diffusive catalytic burners, the efficiency of combustion was significantly affected by the installation direction and the temperature of catalytic bed perimeter influenced on the diffusion rate of oxygen which determined the combustion efficiency of catalytic burner. It was seen in premixed catalytic combustion that air content in premixed fuel gas was optimized at slightly higher than theoretical amount of air. Combustion heat released higher than 70% by radiant heat in premixed catalytic combustion likewise diffusive catalytic combustion.

Characterization of Thermo-Plastic Vulcanized (TPV) Composite Prepared by the Waste Tire and Plastic Powder (폐타이어 분말과 재생PP로 제조한 열가소성 고무 플라스틱(TPV)의 물성평가)

  • An, Ju-Young;Park, Jong-Moon;Bang, DaeSuk;Kim, Bong-Suk;Oh, Myung-Hoon
    • Resources Recycling
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    • v.23 no.4
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    • pp.30-36
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    • 2014
  • 300,000 tons of waste tires are annually being produced with development of the automotive industry in Korea. Landfill and incineration treatment system are causing the economic problem through secondary environmental pollution and waste. Therefore, as one of the ways to take advantage of this, Thermo-Plastic Vulcanized (TPV) composite was prepared by the ground waste tire and plastic powders. The waste tire powder was gained by mechanical fracturing through crushers. The waste tire powder was ground by a shear crushing method and a 2-stage disk mill method instead of cutting crushing one. The waste tire powder of 50 mesh was mixed with Polypropylene(PP) in various proportions. TPVs were prepared by an extrusion, and tensile and impact tests were performed. In addition, the same experiments were repeated in 40, 80, 140 mesh conditions in order to observe size effect of waste tire powders.

Application of Blended learning for effective anatomic education of sports science students (체육전공 학생들의 효과적인 해부학 교육을 위한 혼합강의의 적용)

  • Kim, Jee-Hee;Moon, Tae-Young;Kim, Kyeong-Uoon;Roh, Sang-Gyun;Park, Jeong-Hyun
    • Proceedings of the KAIS Fall Conference
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    • 2011.12a
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    • pp.166-169
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    • 2011
  • 체육전공에서 해부학을 통해 스포츠 상해, 운동역학적 적용, 인체의 병리나 생리적인 지식을 습득할 수 있는 바탕이 된다. 그러므로 해부학적 기초가 없이 운동생리학, 생체역학, 측정평가, 운동처방 등 여러 응용학문에 대한 이해가 불가능하다. 대부분 체육전공에서 해부학을 전공필수로 지정하여 그 중요성을 강조하고 있다. 체육전공학과는 학과특성 및 교육시설 등 여러 가지 문제로 인해 해부학 실습교육이 어렵고, 특히 체육 특기생 경우 잦은 시합으로 수업의 결손이 많다. 또한 체육학과 전공교수는 학과특성상 대부분이 체육전공자로서 최근 의과대학에서 해부학을 포함한 기초의학전공 교수들의 감소되는 현상으로 건강-의료-보건관련 학과의 기초의학강의의 수요를 충족시키는데 어려움이 존재하여 학과 내 해부학강의도 체육전공교수들이 직접하고 있는 실정이다. 기초의학전공자가 아닌 교원의 해부학강의는 깊이 있는 해부학지식을 전달하는데 제한적이며 교수의 강의에 대한 부담도 존재한다. 따라서 본 연구는 2007년부터 2009년 동안 강원대학교 스포츠과학부 학생들을 대상으로 자체 제작한 가상강의 컨텐츠와 해부실습, 그리고 면대면 강의를 병행한 혼합강의를 실시한 후 설문조사를 통해 체육전공학생들의 효과적인 해부학지식전달의 방식으로 그 도입을 제시하고자 한다.

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Experimental studies on surface resistance method of levee based on bio-polymer (바이오폴리머 기반 제방 표면 강화 공법에 대한 실험적 연구)

  • Ko, Dongwoo;Kang, Joongu
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.50-50
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    • 2019
  • 최근 국지성 호우 및 하천 제방의 노후화로 인한 제방 붕괴 피해가 빈번히 발생하면서 제방의 안정성 및 표면 보강을 위한 다양한 연구가 시도되고 있다. 본 연구에서는 제방 붕괴에 따른 피해 최소화 및 대책을 수립하기 위한 방법으로 시멘트와 같은 지구온난화를 야기시키는 물질이 아닌 친환경 신소재 바이오폴리머를 흙과 혼합한 재료를 활용하여 제방의 내구성을 강화하기 위한 연구가 수행되고 있다. 이에 안동하천실증연구센터에서는 현장토를 사용하여 높이 1 m, 폭 3 m, 사면경사 1 : 2, 총 길이 5 m 의 중규모 제방모형을 제작하였으며, 공동연구기관인 카이스트에서 개발된 바이오폴리머와 흙을 적정 비율로 혼합한 바이오-소일을 제방 전면에 일정 두께로 피복하여 월류 발생에 따른 제방 안정성 평가 실험을 수행하였다. 1차 실험은 흙 제방 조건이며, 2 3차 실험은 제방 표면에 5 cm 두께로 신소재가 피복된 조건으로 안정된 결과 도출을 위해 반복 실험을 수행하였다. 제방 천단면 및 사면에서의 유속분포를 측정하기 위해 드론 및 비디오카메라를 활용한 LSPIV 기법을 적용하여 실험조건에 따른 표면유속과 월류 흐름이 제방 붕괴에 미치는 영향에 대해 비교분석하였다. 또한 그래픽 소프트웨어를 이용한 픽셀기반 영상분석 기법을 적용하여 시간에 따른 제방사면의 붕괴면적을 산정하여 신소재 피복에 따른 붕괴 지연효과 분석을 통한 신소재 활용 제방의 현장 적용가능성 및 안정성을 평가하였다. 본 연구결과, 흙 제방의 경우 월류 흐름 발생 직후 침식현상이 전개되어 유속분포가 집중되고 있었으며, 이후 발생하는 강한 수직흐름으로 인해 입자추적을 통한 분석이 더 이상 불가능하였다. 신소재 제방의 경우 월류 흐름 발생 직후 침식은 발생하지 않았으며 일정시간동안 유속분포가 유지되었다. 지속적인 월류 흐름으로 인해 제방 끝단에서 침식이 발생하였으며 이때 최대 유속은 3.3 m/s 로 나타났다. 또한 픽셀기반 분석을 통해 30초 단위로 표면손실률을 산정한 결과, 신소재 활용 제방(2, 3차)의 경우 같은 실험조건에도 불구하고 최종 붕괴시간은 약 3배의 차이를 보였으며, 양생 과정에서의 크랙 발생을 최소화한다면 월류 발생 시 상당한 붕괴지연효과가 있는 것으로 판단된다.

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