• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.6
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• pp.315-319
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• 2003

The quality, quantity, color, and characteristics were found out cultured seawater pearls and freshwater pearls. In the XRF measurement Ca chemical combinations were the main elements and Sr was detected at higher levels for the sea-water pearl and Si, S, Ca, Mn, P and other elements were found at higher levels for the fresh-water pearls. Such differences is judged to be caused by the ion diluted in sea and fresh water which affects the pearl elements. Although near similar structural peak was shown for the FT-IR measurement, the fresh-water pearl showed a lower peak for the 2344 wave. For the results of PL, the peak for fresh-water measured with Hd-Cd Laser at 455 nm was higher and with the Ar-ion Laser measurements, peaks were high at 545 nm and 570 nm for fresh-water pearl and sea-water pearls respectively.

• Journal of the Mineralogical Society of Korea
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• v.28 no.1
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• pp.9-16
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• 2015

A mineralogical analysis on the factors affecting the luster of pearls was carried out using gravity measurement, optical microscope observation, X-ray diffraction analysis, and scanning electron microscopy. We divided the seawater cultured pearls from Tongyeong into the following four types based on luster and shape; good luster and round (LR), lackluster and round (LLR), lackluster and baroque (LLB), and lackluster and two nucleus (LTN) pearls. Pearls with high-quality luster had slightly lower specific gravity as compared to pearls with low-quality luster, but both these types of pearls are within the specific gravity range of commercial pearls. Regarding the cross-sectional thickness of the mother-of-pearl layer, LR pearls showed a uniform thickness of about 0.3 mm in average. On the other hand, LLR pearls were characterized by relatively thinner, but uniform thickness. LTN and LLB pearls showed a tendency of significantly large variation in thickness even within a single pearl. For the surface of pearls, pearls with high-quality luster showed narrower and clearer growth lines of aragonite crystals as compared to pearls with low-quality luster. Pearls with high-quality luster were characterized by fewer aragonite crystal lattice defects as compared to pearls with low-quality luster, and the former showed parallel arrangement, thinner thickness, and less difference in thickness on the surface and inside. If a pearl has a prismatic layer, it is composed of aragonite with calcite in the prismatic and nacreous layer, and calcite content is very high in the lackluster pearl. Pearls without a prismatic layer were devoid of calcite irrespective of their quality of luster, and were composed of aragonite.

• 한국해양학회지
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• v.24 no.2
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• pp.69-78
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• 1989

Cultivated pearls, composed of aragonite crystals, show two distinctive layers: nacreous and conchiolin organic layers. Each aragonite crystal is surrounded by organic matrix, which probably consists of amino acids. Nucleus, surrounded by pearl layer, also consists of nacreous crystals, suggesting that there is a close mineralogical and ultrasturctural relationship between pearl and nucleus. Carbon isotopic values of cultivated pearls are within the range of marine carbonate carbon. Oxygen isotopic composition indicates that the temperature for the growth of pearl and pearl oyster ranges from 16.4 to $21.4^{\circ}C$ and from 15.5 to $24.8^{\circ}C$, corresponding to the summer temperature range of the cultivating area. Elemental composition of pearl, pearl oyster, and nucleus shows that there is a difference in chemical composition depending upon the original mineralogy and the chemical composition of water in which shells grow. Especially, a strong relationship exists between pearl and the inner layer of pearl oyster because both are composed of nacreous aragonite and formed in a shallow marine environment.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.18 no.5
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• pp.205-210
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• 2008

Pearl is the organic gemstone which does not come from mines but from the biomineralization inside mollusc. Mollusc with nacre on inner surface of the shell is inevitable to make pearl. In this paper we researched and analyzed the pearls cultured using Pen shell (Atrina pectinata) which is not used in pearl farming industry but has potential to make pearls because it has thick and beautiful nacre inside the shell. SEM analysis was conducted to reveal the pattern of nacre on the Atrina pectinata pearl. Specific characteristics as sea-water pearl are detected by further analysis with ED-XRF. Aragonite specific peaks such as $1083cm^{-1}$ and $705cm^{-1}$ were shown by Raman analysis. UV-Vis analysis of Atrina pectinata pearl showed different pattern of spectrum compared with Pinctada margaritifera pearl. The reason for this discrepancy is assumed by the metabolic difference of each species.

• The Korean Journal of Malacology
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• v.24 no.3
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• pp.243-251
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• 2008

Analyses of UV-Vis spectrum and reflectance are useful tools to identify pearls of which color was naturally made or chemically changed. Contents of some trace elements of pearls by using ED-XRF may give us the information that the pearls were originated from marine shells or freshwater shells, and may give us whether the pearls were chemically treated or not. Three types of chemically untreated pearls, freshwater cultured, Akoya cultured and Tahitian cultured, were treated with silver nitrate. UV-Vis absorbance spectrum of Ag was changed after treatment, and reflectance of pearls was decreased. Absorbance of natural black colored Tahitian cultured pearls at 400, 500 and 700 nm was observed. Natural black colored freshwater cultured pearls showed two characteristic absorption patterns in UV-Vis spectra at 380-400, 480-500 nm. Unlike naturally black colored Tahitian cultured pearls, the absorption spectrum at 700 nm could not be found from black freshwater cultured pearls. Manganese was not detected in the pearls from marine shells, and strontium content of the pearls from marine cultured shells was higher than that from freshwater cultured shells. According to ED-XRF analysis, Ag contents of silver nitrate treated pearls increased as more time passed, because silver ion invaded to nacre layer of the pearls. Since Ag content of the black pearls known as untreated ranged under 0.1%, analysis of Ag content may used to distinguish the black pearls are treated or not in marketplace.

• 한국해양학회지
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• v.19 no.2
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• pp.111-117
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• 1984

Heavy metal contents in soft tissues of mussels, Mytilus edulis, of Imweon, Banweol, Bay and Yeosu in Korea were determined during 1981∼82. The heavy metal measured were Cd, Cr, Cu, Pb, Zn, Mn and Fe. Depuration of mussel samples in clean seawater was needed adequate in the lowest levels of the complete excretion of gut contents. The 48hr depuration was adequate in the present study. Of the four study areas, Imweon showed the highest Pb, Mn and Fe contents. In Jinhae Bay, St. 9 showed the greatest Pb, Zn, Mn and Fe contents, whereas the highest levels of Cd, Cr and Cu were recorded at Sts. 7, 4 and 2, respectively. The concentrations of metals, except Cu, in mussels decreased with the growth of shell size.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.270-275
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• 2006

The cultivated pearls collected for the study were pretreated through the removal of contaminants and the surface bleaching for easy dyeing. Coloring of pearls are necessary after selecting dyes adsorbable to the Conchiolin layer, a kind of hard protein formed in the seawater, covering the surface of the pretreated pearls. Dyes adsorbable to the Conchiolin layers are mostly basic dyes such as Rhodamine 6G(R6G), Rhodamine B(RB), Methylene Blue(MB) etc. and the binary and ternary competitive adsorption were performed by mixing two or three dyes together. The multi-dye adsorption data were compared with the predictions from the ideal adsorbed solution theory(IASI) combined with the single-dye adsorption model, the Langmuir or the Redlich-Peterson(RP) model. The quality of prediction was compared by using determination coefficient($R^2$) and standard deviation(SSE) values. Predictions from the IAST were found to be in good agreement with the data for the R6G/RB binary adsorption to the pearl layers not fractionated with their size, except for the adsorption data for RB at high concentrations. Among the three binary adsorption systems, R6G/RB, R6G/MB, and MB/RB, only the RB sorption data in the R6G/RB binary system was in poor agreement with the IAST prediction. Competitive adsorption data in ternay systems were in good agreement with the predictions from the IAST except for the RB data.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.8 no.2
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• pp.61-67
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• 1975

Oceanographic conditions of the coastal water around Chungmu, one of the most important oyster farming areas in Korea, were studied from May to November in 1974 to find out the environmental influence to oyster farming. Six localities, Goseong Bay, Jaran Bay, off Saryangdo, Hansilpo, Tong-yeong Bay and Juklimpo were selected for monthly oceanographic observation and biological sampling. Flood current running westward brings saline water from the south-east and ebb current brings the low salinity water of Jinju Bay into this area. The waters in Juklimpo, Hansilpo and Tong-yeong Bay are slightly cooler and more saline than the waters in Goseong Bay, Jaran Bay and off Saryangdo. The amount of dissolved oxygen is lowest in September and Hansilpo has the least oxygen during summer. Silicate content is lower in waters of Tong-yeong Bay, Juklimpo and off Saryangdo than those of Goseong Bay, Hansilpo and Jaran Bay. Suspended matter in this area ranges from 7.4 to 16.6 mg/l and scarce in Jaran Bay, Juklimpo and off Saryangdo. Chlorophyll a shows large seasonal variation and local fluctuation. Composition of phyto-plankton reveals the difference between the waters of Goseong Bay, Jaran Bay and off Saryangdo and the waters of Hansilpo, Tong-yeong Bay and Juklimpo. The growth of oyster was good in Juklimpo, Tong-yeong Bay and Goseong Bay and worst in Hansilpo. The highest mortality was observed $82\%$ in the waters off Saryangdo.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.5 no.3
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• pp.71-75
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• 1972

The growth of the mussel, Mytilus edulis, in a salt-field reservoir was investigated at Dangjin, Choongnam, from June to October in 1970. l. Temperature, salinity, specific gravity, and pH of water were $22.5-27.5^{\circ}C,\;28.6-34.8\%$, 1.019-1.024, and 7.6 respectively in the salt-field reservoir from June 20 to July 19. 2. Three species of Gastropoda and seven species of Pelecypoda were collected. 3. The shell height of the mussel group in the highest abundance increased from 200mm($15\~25mm$) on June 15 to 40mm ($20\~50mm$) on September 26 in the salt-field reservoir, whereas the average shell heights of them were 19.80mm (June 15) and 35. 10mm (Sept. 26) respectively. 4. The daily growth of the mussel from July 10 to August 12 was 0.22 mm in shell height and highest during the experimental period. 5. The relationships between shell length (L) and shell height (H), and between shell length (L) and shell breadth (B) of the young mussel are represented by the following equations respectively : H=1.26776L+5.07978 B=35041L+3.05502 6. From the above results, it is suggested that the culture of the mussell, Mytilus edulis, in a salt-field reservoir is possible.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.22 no.4
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• pp.177-188
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• 1989

The purpose of this study was to investigate the detoxifying effect on PSP-infested sea mussel, Mytilus edulis, by heating treatment and correlation between the PSP toxicity and the environmental conditions of shellfish culture area such as temperature, pH, salinity, density of Protogonyaulax sp. and concentration of inorganic nutrients such as $NH_4-N,\;NO_3-N,\;NO_2-N\;and\;PO_4-P$. This experiment was carried out at $Suj\u{o}ng$ in Masan, Yangdo in Jindong, $Hach\u{o}ng\;in\;K\u{o}jedo\;and\;Gamch\u{o}n$ bay in Pusan from February to June in $1987\~1989$. It was observed that the detection ratio and toxicity of PSP in sea mussel were different by the year even same collected area. The PSP was often detected when the temperature of sea water about $8.0\~14.0^{\circ}C$. Sometimes the PSP fox of sea mussel was closely related to density of Protogonyaulax sp. at $Gamch\u{o}n$ bay in Pusan from March to April in 1989, but no relationship was observed except above duration during the study period. The concentration of inorganic nutrients effects on the growth of Protogonyaulax sp., then effects of $NO_3-N$ was the strongest among them. When the PSP-infested sea mussel homogenate was heated at various temperature, the PSP toxicity was not changed significantly at below $70^{\circ}C$ for 60 min. but it was proper-tionaly decreased as the heating temperature was increased. For example, when the sea mussel homogenate was heated at $100^{\circ}C,\;121^{\circ}C$ for 10 min., the toxicity was decreased about $67\%\;and\;90\%$, respectively. On the other hand, when shellstock sea mussel contained PSP of $150{\mu}g/100g$ was boiled at $100^{\circ}C$ for 30 min. with tap water, the toxicity was not detected by mouse assay, but that of PSP of $5400{\mu}g/100g$ was reduced to $57{\mu}g/100g$ even after boiling for 120 min.