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A Study on Synthesis of Mayenite by Using Recycled Aluminium Resource for Application in Insulating Material (알루미늄 재활용 소재를 이용한 내화재용 Mayenite 합성 연구)

  • Im, Byoungyong;Kang, Yubin;Joo, Soyeong;Kim, Dae-Guen
    • Resources Recycling
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    • v.29 no.6
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    • pp.65-72
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    • 2020
  • Black dross is a dark gray dross generated during the aluminum recycling process that uses flux, and contains NaCl, KCl, Al2O3, MgO, etc. Black dross is separated into soluble substances (NaCl, KCl) and insoluble substances (Al2O4, MgO) through the dissolution process. Soluble materials can be reused as salt flux, and Al2O3 and MgO can be upcycled to various ceramic materials through the synthesis process. In this study, Mayenite was synthesized using Al2O3 and MgO recovered from black dross, and the synthesis was performed according to the mixing ratio and reaction temperature. It was confirmed that when Mayenite was synthesized using black dross (spinel) and CaCO3, precursors were changed to Mg0.4Al2.4O4 and CaO at 700 ℃, and to Ca12Al14O33 (Mayenite) after 800 ℃. In the mixing conditions experiment, it was confirmed that the Mayenite XRD peak increased with increase of the CaCO3 content, and the Mg0.4Al2.4O4 XRD peak decreased. As a result of the BET analysis of the synthesized powder, the surface area decreased as the fine particles were grown and agglomerated in the process of generating mayenite.

Cell ID Detection Schemes Using PSS/SSS for 5G NR System (5G NR 시스템에서 PSS/SSS를 이용한 Cell ID 검출 방법)

  • Ahn, Haesung;Kim, Hyeongseok;Cha, Eunyoung;Kim, Jeongchang
    • Journal of Broadcast Engineering
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    • v.25 no.6
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    • pp.870-881
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    • 2020
  • This paper presents cell ID (cell identity) detection schemes using PSS/SSS (primary synchronization signal/secondary synchronization signal) for 5G NR (new radio) system and evaluates the detection performance. In this paper, we consider two cell ID detection schemes, i.e. two-stage detection and joint detection schemes. The two-stage detection scheme consists of two stages which estimate a channel gain between a transmitter and receiver and detect the PSS and SSS sequences. The joint detection scheme jointly detects the PSS and SSS sequences. In addition, this paper presents coherent and non-coherent combining schemes. The coherent scheme calculates the correlation value for the total length of the given PSS and SSS sequences, and the non-coherent combining scheme calculates the correlation within each group by dividing the total length of the sequence into several groups and then combines them non-coherently. For the detection schemes considered in this paper, the detection error rates of PSS, SSS and overall cell ID are evaluated and compared through computer simulations. The simulation results show that the joint detection scheme outperforms the two-stage detection scheme for both coherent and non-coherent combining schemes, but the two-stage detection scheme can greatly reduce the computational complexity compared to the joint detection scheme. In addition, the non-coherent combining detection scheme shows better performance under the additive white Gaussian noise (AWGN), fixed, and mobile environments.

A Study on the Preparation of Ternary Transition Metal Coated-Dimensionally Stable Anode for Electrochemical Oxidation (전기화학적 산화를 위한 삼원 전이 금속 코팅 불용성 산화 전극 제조에 관한 연구)

  • Park, Jong-Hyeok;Choi, Jang-Uk;Park, Jin-Soo
    • Applied Chemistry for Engineering
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    • v.32 no.4
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    • pp.409-416
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    • 2021
  • Dimensionally stable electrodes are one of the important components in electrochemical water treatment processes. In the manufacturing of the dimensionally stable electrodes, the type of metal catalyst coated on the surface of the metal substrate, the coating and sintering methods substantially influence their performance and durability. In this study, using Ir-Ru-Ta ternary metal coating, various electrodes were prepared depending on the coating method under the same pre-treatment and sintering conditions, and its performance and durability were studied. As a coating method, brush and spray coating were used. As a result, the reduction in the amount of catalyst ink was achieved because more amount of metal could be coated for the electrode using spraying with the same amount of catalyst ink. In addition, the spray_2.0_3.0 electrode prepared by a specific spray coating method shows the phenomenon of cracking and the uniform coating of the ternary metal on the surface of the coating layer, and results in a high electrochemically active specific surface area, and the decomposition performance of 4-chlorophenol was superior to the other electrodes. However, it was found that there was no significant difference in durability depending on the coating method.

Feasibility test of treating slaughterhouse by-products using microbial electrolysis cells (미생물전기분해전지를 이용한 도축부산물 처리 가능성 평가)

  • Song, Geunuk;Baek, Yunjeong;Seo, Hwijin;Kim, Daewook;Shin, Seunggu;Ahn, Yongtae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.2
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    • pp.31-38
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    • 2021
  • The aim of this study is to evaluate the possibility of treating slaughterhouse by-products using microbial electrolysis cells (MECs). The diluted pig liver was fed to MEC reactors with the influent COD concentrations of 772, 1,222, and 1,431 mg/L, and the applied voltage were 0.3, 0.6, and 0.9 V. The highest methane production of 5.9 mL was obtained at the influent COD concentration of 1,431 mg/L and applied voltage of 0.9 V. In all tested conditions, COD removal rate was increased as the influent COD concentration increased with average removal rate of 62.3~81.1%. The maximum methane yield of 129~229 mL/g COD was obtained, which is approximately 80% of theoretical maximum value. It might be due to the bioelectrochemical reaction greatly increased the biodegradability of pig liver. Future research is required to improve the methane yield and digestibility through optimizing the reactor design and operating conditions.

Removal of COD and Color from Anaerobic Digestion Effluent of Livestock Wastewater by Advanced Oxidation Using Microbubbled Ozone (마이크로버블 오존 고도산화를 이용한 축산폐수 혐기소화 배출수의 COD와 색도의 제거)

  • Lee, Inkyu;Lee, Eunyoung;Lee, Hyejung;Lee, Kisay
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.617-622
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    • 2011
  • Ozone-based advanced oxidation was applied for the treatment of anaerobic digestion effluent of livestock wastewater. Initial COD and color value were 930 mg/L and 0.04, respectively, and the 1/10-diluted wastewater was used for the study. The treatment characteristics were compared between the conventionally generated ozone ($105{\mu}m$) and microbubbled ozone ($13{\mu}m$). The use of microbubbled ozone improved the removal of chemical oxygen demand (COD) and color by 85% and 26%, respectively, compared with the conventionally bubbled ozone. The application of microbubbled $O_3/UV$, $O_3/H_2O_2$, $O_3/UV/H_2O_2$ combinations resulted in 5~10% higher color removal than ozone alone, which implies that the contribution of UV or $H_2O_2$ is not significant in color removal. On the other hand, COD removal could be increased two folds compared with ozone alone through $O_3/UV/H_2O_2$ combination. The contribution of $H_2O_2$ was bigger than UV for COD removal with microbubbled ozone. Due to the enhancement of dissolved ozone and radical activity, the microbubbling enabled us to additional COD removal even after stopping ozone supply in the presence of UV or $H_2O_2$.

Morphological Landscape of Patagonia and Atacama in the Andes based on Geotourism (지오투어리즘 관점에서 본 안데스 파타고니아와 아타카마의 지형경관)

  • PARK, Jongkwan
    • Journal of The Geomorphological Association of Korea
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    • v.20 no.4
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    • pp.15-28
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    • 2013
  • This paper was made on the basis of geotourism to explain morphological characteristics of Patagonia and Atacama region in the Andes through 10-day fieldwork. The Patagonian landscape was focused on the Torres del Paine National Park, Chile and the Los Glacier National Park, Argentina; on the other hand, the Atacama morphological landscape was investigated around the San Pedro de Atacama. Many geomorphological features such as uplift, semiarid and glacier landscapes can be found in Patagonia, so it is strongly recommended to have an opportunity to enjoy these landforms by geotourism. Massive intrusive rock bodies of granite can be shown in those two National Parks declared a Biosphere Reserve by UNESCO. And, the Atacama Desert located on the forearc depression in the Andes, Chile has also many geomorphological destinations of arid and volcanic landforms; badland, pediplain, pediment, salt lake and geyser. Especially, huge pediplain is one of the greatest view points in the Atacama Desert. Patagonia and Atacama are the best geographical tourism sites to know diverse tectonic landforms made by the conflict between South American and Pacific plates.

Adsorption of Antibiotics on Serum Albumin Nanoparticle (혈청 알부민 나노입자를 이용한 항생제 흡착)

  • Kim, Hyunji;Lim, Sung In
    • Clean Technology
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    • v.27 no.1
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    • pp.55-60
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    • 2021
  • Antibiotics are compounds broadly used to treat patients with infectious diseases and to enhance productivity in agriculture, fisheries, and livestock industries. However, due to the overuse of antibiotics and their low biodegradability, a substantial amount of antibiotics is leaking into the sewer, subsequently resulting in pollution and the emergence of antibiotic-resistant bacteria. This study explores biodegradable serum albumin's potential as an adsorbent to remove antibiotics from water. Serum albumin is a natural blood protein that transports various metabolites and hormones to all tissues' extravascular spaces. While serum albumin is highly water-soluble, it has intrinsic binding sites which readily accommodate ionic, hydrophilic, or hydrophobic molecules, rendering it a good building block for a nano-adsorbent. To induce coacervation, a desolvating agent, ethanol, was added dropwise into the aqueous albumin solution, resulting in dehydration and liquid-liquid phase separation of albumins into albumin nanoparticles within a size range of 150 ~ 170 nm. The addition of glutaraldehyde as a cross-linker improved the size stability and homogeneity of albumin nanoparticles. Adsorption of amoxicillin antibiotics on albumin nanoparticles was dependent upon glutaraldehyde concentration used in desolvation and pH during adsorption. The maximum adsorption capacity measured by spectrophotometry was found to be 12.4 micrograms of amoxicillin per milligram of albumin nanoparticle. These results demonstrate serum albumin's potential as a building block for fabricating a natural nano-adsorbent to remove antibiotics from water.

Detection Scheme Based on Gauss - Seidel Method for OTFS Systems (OTFS 시스템을 위한 Gauss - Seidel 방법 기반의 검출 기법)

  • Cha, Eunyoung;Kim, Hyeongseok;Ahn, Haesung;Kwon, Seol;Kim, Jeongchang
    • Journal of Broadcast Engineering
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    • v.27 no.2
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    • pp.244-247
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    • 2022
  • In this paper, the performance of the decoding schemes using linear MMSE filters in the frequency and time domains and the reinforcement Gauss-Seidel algorithm for the orthogonal time frequency space (OTFS) system that can improve robustness under high-speed mobile environments are compared. The reinforcement Gauss-Seidel algorithm can improve the bit error rate performance by suppressing the noise enhancement. The simulation results show that the performance of the decoding scheme using the linear MMSE filter in the frequency domain is severely degraded due to the effect of Doppler shift as the mobile speed increases. In addition, the decoding scheme using the reinforcement Gauss-Seidel algorithm under the channel environment with 120 km/h and 500 km/h speeds outperforms the decoding schemes using linear MMSE filters in the frequency and time domains.

The Determination of Anaerobic Biodegradability and Organic Fractionation of Agricultural Byproducts by Biochemical Methane Potential Assay Using Double First-Order Kinetic Model (반응속도 모델을 적용한 농업부산물의 혐기성 유기물분해율과 메탄생산잠재량 분석)

  • Shin, Kook-Sik;Yoon, Young-Man
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.4
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    • pp.55-65
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    • 2021
  • This study investigated methane productions and a degradation rate of organic matters by German standard method, VDI4630 test. In this study, 11 waste biomasses from agricultural fields were selected for the investigation. The objective of this study was to estimate a distribution of organic matters by using the Double first-order kinetics model in order to calculate the rate of biodegradable organic matters which degrade rapidly in the initial stage and the persistently biodegradable organic matters which degrade slowly later. As a result, all the biomasses applied in this study showed rapid decomposition in the initial stage. Then the decomposition rate began to slow down for a certain period and the rate became 10 times slower than the initial decomposition rate. This trend of decomposition rate changes is typical conditions of biomass decompositions. The easily degradable factors (k1) were raged between 0.097~0.152 day-1 from vegetable crops and persistent degradable factor (k2) were 0.002~0.024 day-1. Among these results, greater organic matter decomposition rates from VDI4630 had greater k1 values (0.152, 0.144day-1) and smaller k1 values (0.002, 0.005day-1) from cucumbers and paprika. In a meanwhile, radishes and tangerine rinds which had low decomposition rates showed 0.097 and 0.094 day-1 of k1 values and decomposition rates seems to affect k1 values.

Biodegradation of 4-t-Octylphenol by Basidioradulum molare and Schizopora paradoxa and Estrogenecity Reduction of its Metabolites (옥틸페놀(4-t-Octylphenol)의 Basidioradulum molare와 Schizopora paradoxa에 의한 분해 및 에스트로겐성 저감효과)

  • Lee, Soo-Min;Ku, Bon-Wook;Lee, Jae-Won;Choi, Don-Ha;Jeung, Eui-Bae;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.4
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    • pp.27-35
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    • 2004
  • Recalcitrant 4-t-Octylphenol used as a surfactant was subjected to the biodegradation with wood rot fungi, Basidioradulum molare and Schizopora paradoxa. Two fungi were grown in the culture medium containing various concentrations of 4-t-Octylphenol in order to investigate their resistance against 4-t-octylphenol Schizopora paradoxa was reached to the full growth within 14 incubation days in the concentration of more than 200 ppm of 4-t-Octylphenol, while Basidioradulum molare showed the inhibitory mycelium growth as the concentration was increased Schizopora paradoxa and Basidioradulum molare biodegraded 95% and 36% of initial concentration of 4-t-Octylphenol at first incubation day, respectively. However, the biodegradation capability reached to more than 95% after 3 incubation days. During the biodegradation of 4-t-Octylphenol, the activity of manganese dependent peroxidase was induced by the addition of 4-t-Octylphenol in the culture medium of Schizopora paradoxa, but that of laccase was maximal before the addition. The reduction of estrogenecity was assayed by MCF-7 cell proliferation test and measurement of pS2 mRNA expression. The level of pS2 mRNA was decreased down to the level of baseline at first incubation day. Also, estrogenecity of 4-t-Ocrylphenol completely disappeared after treatment with supernatant by Schizopora paradoxa and Basidioradulum molare from first incubation day of culture down to the levels of vehicle.