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Identification of Jet fuel (JP-8) in Petroleum Hydrocarbon Contaminated Soil through the Qualitative Analysis of Antioxidants (유류 오염 토양 중 산화방지제 정성 분석을 통한 항공유(JP-8) 유종 판별)

  • Kim, Yonghun;Lee, Goontaek;Jang, Hanjeon;Jo, Yunju;Kim, Moongun;Choi, Jaeho;Kang, Jiyoung
    • Journal of Soil and Groundwater Environment
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    • v.27 no.4
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    • pp.37-48
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    • 2022
  • Accurate analysis of petroleum hydrocarbons in soil is an important prerequisite for proper source tracking of contamination. Identification of petroleum compounds is commonly carried out by peak pattern matching in gas chromatography. However, this method has several technical limitations, especially when the soils underwent biological, physical and chemical transformation. For instance, it is very difficult to distinguish jet fuel (JP-8) from kerosene because JP-8 is derivatized from secondary reaction between chemical agents (e.g. anti-oxidants, antifreezer and so on) and kerosene. In this study, an alternative method to separately analyze JP-8 and kerosene in the petroleum hydrocarbon contaminated soil was proposed. Qualitative analyses were performed for representative phenolic antioxidants [2,6-di-tert-butyl phenol (2,6-DTBP), 2,4-di-tert- butylphenol(2,4-DTBP), 2,6-di-tert-butyl-4-methyl phenol (2,6-DTBMP)] using a two dimensional gas chromatograph mass spectrometer (2D GC×GC-TOF-MS). This qualitative analysis of antioxidants in soil would be a useful complementary tool for the peak pattern matching method to identify JP-8 contamination in soil.

Analysis of Switching Surge Over-voltage in AC/DC Hybrid Transmission Lines (AC/DC 병가선로의 개폐서지 과전압 해석)

  • Yoo, Seong-Soo;Shin, Koo-Yong;Moon, Chae-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.3
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    • pp.459-466
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    • 2022
  • Switching surges are a common type of phenomenon that occur on any sort of power system network. These are more pronounced on long transmission lines and in high voltage converter stations. At AC/DC hybrid transmission lines, the insulation coordination of such lines is mainly dictated by the peak level of switching surges, the most dangerous of which include three phase line energization and AC/DC converter station. The power system structure consist of AC/DC hybrid transmission lines which is combination of AC 765kV and ±500kV HVDC 1 bipole system for contingency analysis. The power system under study and its components are simulated using EMTDC software package, the effects of the various AC/DC mixing power lines are reviewed. The developed models of EMTDC conversion lines based on combination of AC/DC system are simulated and the characteristics of switching surge over-voltage from its results are discussed.

Estimation of critical current density of a YBCO coated conductor from a measurement of magnetization loss (자화손실 측정값으로부터 추정한 YBCO CC의 임계전류밀도 평가)

  • Lee, S.;Park, S.H.;Kim, W.S.;Lee, J.K.;Choi, K.
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.3
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    • pp.16-20
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    • 2010
  • For large scale power applications of HTS conductor, it is getting more important to have a stacked HTS coated conductor with low loss and large current capacity. But it was not easy to measure some electric properties. Stabilizer free YBCO CC for striated/ stacked conductors is easily burned out during the measurement of the critical current density because it has no stabilizer and it is difficult to set-up the current lead and voltage taps because it has many pieces of YBCO CC in a conductor. Instead of direct measuring the critical current of a stacked HTS coated conductor, indirect estimation from measuring a magnetization loss of HTS coated conductor could be useful for practical estimation of the critical current. The magnetization loss of a superconductor is supposed to be affected by a full penetrating magnetic field, and it tends to show an inflection point at the full penetrating magnetic field when we generate the graph of magnetization loss vs. external magnetic field. The full penetrating magnetic field depends on the shape of the conductor and its critical current density, so we can estimate the effective critical current density from measuring the magnetization loss. In this paper, to prove the effectiveness of this indirect estimation of the critical current, we prepared several different kinds of YBCO CC(coated conductor) including a stacked conductor short samples and measured the magnetization losses and the critical currents of each sample by using linked pick up coils and direct voltage measurement with transport current respectively.

Examining the Effect of University Student Ambassadors' Characteristics and SNS Information Characteristics on Corporate Promotion (대학생 홍보대사 특성과 SNS 정보특성이 홍보효과에 미치는 영향)

  • Soohaeng Shin;Haejung Yun;Yoonseuk Woo
    • Knowledge Management Research
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    • v.23 no.4
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    • pp.295-314
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    • 2022
  • Effectiveness of corporate promotion using SNS will be meaningful from theoretical and practical perspectives. This study attempts to explore the implications of running corporate ambassador programs composed of university students, different from previous studies focused mainly on celebrity influencers. To this end, the research model was generated and the hypotheses were tested by the responses of 287 subjects who received promotional messages from university student ambassadors of a public corporation. Research findings confirmed that ambassador characteristics (intimacy, expertise) had a significant influence on corporate promotion by mediating SNS information characteristics (information provision, information playfulness, and information reliability). Furthermore, it is found that MZ generation perceived the higher intimacy, the higher information playfulness, while the older generation perceived the higher expertise, the higher information reliability. In order to generalize these research findings, further research considering more diverse demographic characteristics is necessary.

An Analysis of Operational Stability of the KOSPI-listed Energy Public Enterprise from the Perspective of Median Voter Theory (상장 에너지 공기업 경영 안정성 분석: 중위투표자이론의 관점에서)

  • Youngshin Kim
    • Environmental and Resource Economics Review
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    • v.32 no.2
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    • pp.77-105
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    • 2023
  • This paper investigates the management stability of KOSPI-listed energy public enterprises from the perspective of median voter theory. We analyze the profitability and stability of five energy public enterprises during the period 2011~2022, and conduct an empirical analysis to determine whether they are related to the preferences of median voters who can represent the general public. Our analysis of the profitability and stability of the energy public enterprises shows that the stability of their has been deteriorating in recent years. The results of the empirical analysis also show that the management stability of the energy public enterprises is related to the preference of median voter. Specifically, they indicate that when the median voter's income is smaller than the average income, the profitability of the utility decreases and the debt ratio increases. This paper suggests that from the median voter's point of view, excessive utility and energy bills may strengthen the incentives for governments and politicians to suppress rate increases, leading to lower profitability and higher debt for public enterprises.

Shell Finite Element of Reinforced Concrete for Internal Pressure Analysis of Nuclear Containment Building (격납건물 내압해석을 위한 철근콘크리트 쉘 유한요소)

  • Lee, Hong-Pyo;Choun, Young-Sun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.6A
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    • pp.577-585
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    • 2009
  • A 9-node degenerated shell finite element(FE), which has been developed for assessment of ultimate pressure capacity and nonlinear analysis for nuclear containment building is described in this paper. Reissner-Midnlin(RM) assumptions are adopted to develop the shell FE so that transverse shear deformation effects is considered. Material model for concrete prior to cracking is constructed based on the equivalent stress-equivalent strain relationship. Tension stiffening model, shear transfer mechanism and compressive strength reduction model are used to model the material behavior of concrete after cracking. Niwa and Aoyagi-Yamada failure criteria have been adapted to find initial cracking point in compression-tension and tension-tension region, respectively. Finally, the performance of the developed program is tested and demonstrated with several examples. From the numerical tests, the present results show a good agreement with experimental data or other numerical results.

A Study on the Effect of Involuntary Participation in Communication Program Satisfaction on Empathy and Organizational Commitment (비자발적으로 참여하는 소통프로그램만족도가 공감능력과 조직몰입에 미치는 영향에 관한 연구)

  • Shin Soo Haeng
    • Knowledge Management Research
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    • v.24 no.4
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    • pp.43-61
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    • 2023
  • Businesses recognize the importance of empathy among members for achieving organizational goals. Accordingly, they have developed and implemented communication programs aimed at enhancing mutual understanding between the MZ generation and the older generation. However, recent communication programs conducted by businesses differ in that they involve compulsory participation driven by the organization. This study sought to empirically examine their effectiveness. Data was collected from 697 participants in communication programs to validate the proposed research model, which was empirically tested through regression analysis. The results of the analysis confirmed the effectiveness of communication programs even in non-voluntary situations and highlighted intergenerational perception differences. The findings of this study emphasize the significant role of communication and empathy within organizations. Consequently, they have impacted the development of communication strategies and culture within organizations, and are expected to provide theoretical and practical insights valuable to researchers and practitioners interested in intergenerational perception differences from a knowledge management perspective.

0.1 MW Test Bed CO2 Capture Studies with New Absorbent (KoSol-5) (신 흡수제(KoSol-5)를 적용한 0.1 MW급 Test Bed CO2 포집 성능시험)

  • Lee, Junghyun;Kim, Beom-Ju;Shin, Su Hyun;kwak, No-Sang;Lee, Dong Woog;Lee, Ji Hyun;Shim, Jae-Goo
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.391-396
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    • 2016
  • The absorption efficiency of amine $CO_2$ absorbent (KoSol-5) developed by KEPCO research institute was evaluated using a 0.1 MW test bed. The performance of post-combustion technology to capture two tons of $CO_2$ per day from a slipstream of the flue gas from a 500 MW coal-fired power station was first confirmed in Korea. Also the analysis of the absorbent regeneration energy was conducted to suggest the reliable data for the KoSol-5 absorbent performance. And we tested energy reduction effects by improving the absorption tower inter-cooling system. Overall results showed that the $CO_2$ removal rate met the technical guideline ($CO_2$ removal rate : 90%) suggested by IEA-GHG. Also the regeneration energy of the KoSol-5 showed about $3.05GJ/tonCO_2$ which was about 25% reduction in the regeneration energy compared to that of using the commercial absorbent MEA (Monoethanolamine). Based on current experiments, the KoSol-5 absorbent showed high efficiency for $CO_2$ capture. It is expected that the application of KoSol-5 to commercial scale $CO_2$ capture plants could dramatically reduce $CO_2$ capture costs.

Development and Economic Effect of Integrated Optimum Operation System using Wide Area Energy (광역에너지이용 통합 최적화 운전 시스템 개발 및 경제적 효과)

  • Lee, Hoon;Kim, Lae-Hyun;Chang, Won-Seok
    • Journal of Energy Engineering
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    • v.18 no.4
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    • pp.221-229
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    • 2009
  • This study develops the optimized operation program which enables effective and economic operation between individual and connected branch offices by analyzing the current status and influential indicators of district heating companies' capital branch offices. Accordingly, the study examines the efficiency of optimized operation program. In doing so, this study has diagnosed and analyzed various factors, such as boilers, pumps, and relevant tags (temperature, pressure, fuel amount) through investigation of individual branch offices, and finally succeeded in developing wide-ranging data base by factor covering one-year time period. Additionally, after running the optimized operation program, different branch offices, optimum preference has turned out "incinerator receiving heat from KEPCO>CHP >PLBs>PLBw." Meantime, except the connected offices, there has been no big difference between actual and optimum operation program in branch offices. Meanwhile, the integrated optimum operation program has made it possible the most optimal result only via the connecting supply and demand heat without changing received Heat from KEPCO which is the same as total productive heat. The result has showed that the reduction percentage per day is 2.45~6.80%, and the reduction cost per day is 22,727~60,077 thousand won given the randomly selected sample days. In particular, winter time shows the highest demand with the largest reduction cost whereas summer time illustrates the lowest demand with the smallest reduction cost. Given this result, reduction cost per year compared to actual heat production cost for one year theoretically would be 84 hundred million won. Also, the economic effect showed that the reduction cost percentage per year is more than 2.74% on heat production cost per year for all capital branch offices.

An Experimental Study on Ground Resistivity and Grounding Resistance of Water Environment (수상환경의 대지저항률 및 접지저항 측정의 실험적 연구)

  • Choi, Young-Kwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.4
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    • pp.2343-2348
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    • 2014
  • Main ground net of power plant is formed to protect human body from increase in potential gradient caused by grounding current during ground fault. Calculations during ground design are generally performed according to IEEE Std-80-2000 (Kepco Design Standard 2602). However, it is difficult to apply this Standard to water environment, and a grounding technology is required to secure grounding resistance of floating photovoltaic system. Therefore the aim of this paper is to investigate and analyze ground resistivity on the water surface and underwater of reservoir using Wenner 4-pin method, a general method of measuring ground resistivity. Also, grounding resistance of floating photovoltaic systems currently in operation was measured and analyzed using the voltage drop method suggested in the international standard (IEEE Std-81) to propose a grounding method for stable grounding of floating photovoltaic system. The resistivity at 1m below the surface of water ($126.3969[{\Omega}{\cdot}m]$) is mostly higher than resistivity at the river bed ($97.5713[{\Omega}{\cdot}m]$). Also the proposed grounding anchor method was determined as the most effective method of securing stable grounding resistance in floating photovoltaic systems and is expected to be utilized as a ground method for future floating photovoltaic generation systems.