• Membrane Journal
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• v.19 no.2
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• pp.96-103
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• 2009

A series of organic-inorganic composite membranes from poly(vinyl chloride) (PVC) graft copolymer electrolyte and heteropolyacid (HPA) were prepared for proton conducting membranes. First, poly(vinyl chloride)-g-poly(styrene sulfonic acid) (PVC-g-PSSA) was synthesized by atom transfer radical polymerization (ATRP) using direct initiation of the secondary chlorines of PVC. HPA nanoparticles were then incorporated into the PVC-g-PSSA graft copolymer though the hydrogen bonding interactions, as confirmed by FT-IR spectroscopy. The proton conductivity of the composite membranes increased from 0.049 to 0.068 S/cm at room temperature with HPA contents up to 0.3 weight traction of HPA, presumably due to both the intrinsic conductivity of HPA particles and the enhanced acidity of the sulfonic acid of the graft copolymer. The water uptake decreased from 130 to 84% with the increase of HPA contents up to 0.45 of HPA weight traction, resulting from the decrease in number of water absorption sites due to hydrogen bonding interaction between the HPA particles and the polymer matrix. Thermal gravimetric analysis (TGA) demonstrated the enhancement of thermal stabilities of the composite membranes with increasing concentration of HPA.

• Research in Plant Disease
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• v.11 no.2
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• pp.179-184
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• 2005

A previous study reported that the stem and root rot of paprika (Capsicum annum L. var, grossum) caused by Nectria haematococca became a threat to safe cultivation of the plant in the country. However, no strategies for control the disease have been suggested. In this study, fungicides registered for pepper were screened to evaluate their control effects on the disease. Among fungicides tested, prochloraz manganase complex com pletely suppressed mycelial growth of the pathogen at 10 ppm a.i. tebuconazole, benomyl, and carbendazim $\cdot$kasugamycin also effectively inhibited mycelial growth of the fungus. However, kresoxim-methyl and triflox ystrobin did not suppress mycelial growth but significantly suppressed conidial germination of the fungus. Azoxystrobin, benomyl, prochloraz, tebuconazol, and carbendazim$\cdot$ kasugamycin were also effective to retard conidial germination. In vivo tests, tebuconazole strongly inhibited the plant growth even at 16,000x (15.6 ppm a.i.), while others did not induce chemical injury at 4,000x or 8,000x when drenched into a rockwool cube. In a greenhouse test, prochloraz manganase complex at 125 ppm a.i. (4,000x) showed highest control value by $89.9\%$. Other fungicides thiophanate-methylthiram, axozystrobin, trifloxystrobin, and benomyl presented $60-80\%$ control value in the hydroponic cultivation system. However, application time and interval remained to be investigated for identify maximum residue limit.

• Tunnel and Underground Space
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• v.11 no.1
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• pp.42-58
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• 2001

In order to protect the environment from waste disposal activities, the prediction of the flux and flow paths of the contaminants from underground facilities should be assessed as accurately as possible. Especially, the prediction of the pathways and travel times of the nuclides from high level radioactive wastes in a deep repository to biosphere is one of the primary tasks for assessing the ultimate safety and performance of the repository. Since the contaminants are mainly transported with groundwater along the discontinuities developed within rock mass, the characteristics of groundwater flow through discontinuities is important for the prediction of contaminant fates as well as safety assessment of a repository. In this study, the actual fracture network could be effectively generated based on in situ data by separating geometric parameter and hydraulic parameter. The calculated anisotropic hydraulic conductivity was applied to a 3D porous medium model to calculate the path flow and travel time of the large studied area with the consideration of the complex topology in the area. Using the model, the pathways and travel times for groundwater were analyzed. From this study, it was concluded that the suggested techniques and procedures for predicting the pathways and travel times of groundwater from underground facilities to biosphere is acceptable and those can be applied to the safety assessment of a repository for radioactive wastes.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.4
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• pp.265-282
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• 2008

Based on the site characterization works in a low and intermediate level waste(LILW) repository site, the numerical simulations for groundwater flow were carried out in order to understand the groundwater flow system of repository site. To accomplish the groundwater flow modeling in the repository site, the discrete fracture network(DFN) model was constructed using the characteristics of fracture zones and background fractures. At result, the total 10 different hydraulic conductivity(K) fields were obtained from DFN model stochastically and K distributions of constructed mesh were inputted into the 10 cases of groundwater flow simulations in FEFLOW. From the total 10 numerical simulation results, the simulated groundwater levels were strongly governed by topography and the groundwater fluxes were governed by locally existed high permeable fracture zones in repository depth. Especially, the groundwater table was predicted to have several tens meters below the groundwater table compared with the undisturbed condition around disposal silo after construction of underground facilities. After closure of disposal facilities, the groundwater level would be almost recovered within 1 year and have a tendency to keep a steady state of groundwater level in 2 year.

• Korean Journal of Environmental Biology
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• v.37 no.4
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• pp.508-525
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• 2019

Algific talus slopes provide microclimates suitable for disjunct or relict populations of northern plant species at low elevation habitats in the temperate zones. The propose of this study was to assess the phytogeographical significance and produce a strategy for the comprehensive conservation of the vegetation on algific talus slopes. Therefore, we studied the floristics of bryophytes on 15 algific talus slopes in Korea. The bryophytes on the algific talus slopes in Korea consisted of 59 families, 138 genera, 226 species, two subspecies, and five varieties, totaling 233 taxa. Peculiarly, many northern bryophytes, such as Andreaea rupestris var. fauriei (Besch.) Takaki., Buxbaumia minakatae S. Okamura, Racomitrium lanuginosum (Hedw.) Brid., Hylocomium splendens (Hedw.) Schimp., and Pleurozium schreberi (Willd. ex Brid.) Mitt. were found on the algific talus slopes. Of them, unrecorded species from south Korea numbered 14 taxa and unrecorded species from the Korean peninsula numbered seven taxa. A similarity analysis based on the bryophyte flora showed that the index of similarity between regions with similar environmental factors was high. This means that the bryophyte flora composition on each algific talus slopes was affected by topography and microclimate. Algific talus slopes are phytogeographically significant microhabitats where northern plant species that advanced southward during the latest glacial age have been isolated and adapted. However, algific talus slopes have constantly been destroyed or damaged by humans without consideration of conservation. Conservation strategies to ensure the biodiversity and effective management of algific talus slopes in Korea are discussed in detail.

• Korean Journal of Environmental Biology
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• v.38 no.3
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• pp.371-387
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• 2020

This study was conducted to investigate the flora of Mt. Unbongsan in the basalt areas of Korea. From the results of eight field surveys undertaken from March to October 2017, we identified 404 total taxa, representing 364 species, seven subspecies, and 33 varieties, which were placed in 256 genera and 91 families. The plant formation of Mt. Unbongsan is a deciduous broad-leaved and conifer mixed forest, which is common in the middle part of the Korean peninsula. Most of the mountain is covered by a young secondary forest, which is mainly composed of Quercus monglica and Pinus densiflora. Out of these 404 taxa, 193 were the first records for the region, six were endemic to Korea, three were listed on the Korean Red List of threatened species, 34 were floristic target species, and 40 were invasive alien species. The naturalized index(NI) percentage was 9.9%. Mt. Unbongsan has plant diversity, which was associated with the geomorphological landscapes. We considered that the composition and distribution of the species were affected by different environmental factors according to the presence of granite, taluses, block streams, drying ridges, valleys, puddles, wetlands, and streams.

• Journal of Environmental Impact Assessment
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• v.15 no.1
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• pp.1-12
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• 2006

Changes in the soil physical property and the topographic condition derived from agricultural activities like as farming activities, land clearance and cutting down resulted in environmental and economic problems including the outflow of nutrient from farms and the water pollution. Several theories on the soil conservation have been developed and reviewed to protect soil erosion in the regions having a high risk of erosion. This study was done using the USLE model developed by Wischmeier and Smith (1978), and model for the slope length and steepness made by Desmet and Govers (1996), and Nearing (1997) to evaluate the potential of the soil erodibility. Therefore, several results were obtained as follows. First, factors affecting the soil erosion based on the USLE could be extracted to examine the erosion potential in farms. Soil erodibility (K), slope length (L), and slope steepness (S) were used as main factors in the USLE in consideration of the soil, not by the land use or land cover. Second, the soil erodibility increased in paddy soils where it is low in soil content, and the very fine sandy loam exists. Analysis of the slope length showed that the value of a flat ground was 1, and the maximum value was 9.17 appearing on the steep mountain. Soil erodibility showed positive relationship to a slope. Third, the potential soil erodibility index (PSEI) showed that it is high in the PSEI of the areas of steep upland and orchard on the slope of mountainous region around Dokjigol mountain, Dunji mountain, and Deummit mountain. And the PSEI in the same land cover was different depending on the slope rather than on the physical properties in soil. Forth, the analysis of land suitability in soil erosion explained that study area had 3,672.35ha showing the suitable land, 390.88ha for the proper land, and 216.54ha for the unsuitable land. For unsuitable land, 8.71ha and 6.29ha were shown in fallow uplands and single cropping uplands, respectively.

• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1155-1160
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• 1999

The screening methodology modeling, dispersion modeling procedures for continuous and instantaneous releases of the gas phase flow from the storage tank and pressure relief valve were considered. This study was performed to develop the screening methodology for prediction and control of hazardous/toxic gas releases by estimating the 1-hr average maximum ground-level concentration of $Cl_2$ gas vs. downwind distance by incorporating source term model including the general/physical properties of released material and release mode of the $Cl_2$ storage tank of the chemical plant facilities, dispersion model, and meteorological/topographical data into the TSCREEN model. As the results of the study, it was found that dispersion modes of the dense gas were affected by the state of the released material, the released conditions, physical-chemical properties of released material, and the released modes (continuous and instantaneous releases), and especially largely affected by initial (depressurized) density of the released material and release emission rate as well as the wind velocity. Especially, this study was considered to release hazardous material as meteorological data. It was thought that this screening methodology can be useful as a preliminary guideline for application of the refined analysis model by developing the generic sliding scale methodology for various senarios selected.

• Journal of Engineering Education Research
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• v.17 no.6
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• pp.69-76
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• 2014

This paper examined the influence of interdisciplinary education on technology and society over engineering identities of male and female students. For this purpose, we analyzed survey and essays of UNIST students who took the course of in 2013. Favorable feeling toward engineers, satisfaction with future career as engineers, positive regards of engineers' contribution to society increased to a statistically significant level within the group of female students who took the course. Interestingly, male students also formed more positive engineering identities after taking the course. Gender difference in engineering identities, which was statistically significant within the control group of non-takers, disappeared within students who took the course. Both male and female students learned to perceive engineering as a goal-oriented and contextualized exercises that can materialize new social values. In conclusion, interdisciplinary education on technology and society can make positive impacts on students' formation of engineering identities and sense of commitment.

• Journal of Environmental Impact Assessment
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• v.29 no.1
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• pp.45-60
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• 2020

In the past, air pollution, water pollution and solid waste were very important items, but at present environmentally sound land use, ecosystem conservation and sustainable socio-economy have become very important in EIA. According to the consultation result of SEA and Small scale EIA during 2012~2019, most results are 'Conditional Agreement'. Especially EIA consultation results before 2016 were mostly (94.1 %) 'Agreement', but since 2017 most (87.4 %) are 'Conditional Agreement'. And the percentage of 'Non Agreement' have sharply increased from 0.3~0.6 % (during 2013~2016) to 1.3~3.1 % (during 2017~2019). In case there have been no change in EIA system and consultation techniques, the problems of inconsistency and unfairness could be raised. Therefore are urgently required researches on environmentally sound land use, ecosystem conservation and sustainable socio-economy which decide location feasibility assessment. The purpose of this study is to analyse the consultation cases of SEA, EIA, and Small scale EIA since 2012, and to identify key factors which result in the decision of nonagreement of development plans and development projects, and to suggest the improvements on EIA consultation based on land use regulation and environmental grade.