• Title/Summary/Keyword: 한국 제4기학회

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Dehydration of Alcohol Solutions Through Crosslinked Chitosan Composite Membranes II. Dehydration of Ethanol Solution Through Modified Chitosan Composite Membranes (가교키토산 복합막을 통한 알콜수용액의 탈수 II. 변성 키토산 복합막을 통한 에탄올의 탈수)

  • 이영무;남상용;유제강;류경옥
    • Membrane Journal
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    • v.6 no.4
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    • pp.242-249
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    • 1996
  • To improve pervaporation performance of water/ethanol mixtures, chitosan/poly(vinyl alcohol) blended and phosphorylated chitosan composite membranes were prepared. Chitosan/poly(vinyl alcohol) blends were prepared with various blend ratios and then crosslinked with glutaraldehyde by two methods. With increasing crosslinking agent content and crosslinking times separation factor increased and permeate flux decreased. Separation factor of the membrane which contains glutaraldehyde as a crosslinking agent was higher than that of the membrane surface crosslinked. Phosphorylated chitosan was prepared with various reaction times and composite membrane was prepared. As reaction times increased, the separation factor increased with high affinity for water.

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Scattering Effectiveness of Monoenergetic Neutrons in the Various Shielding Materials

  • Yoo, Young-Soo
    • Nuclear Engineering and Technology
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    • v.4 no.1
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    • pp.39-45
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    • 1972
  • In neutron shielding, the scattering effect is equally important as the attenuations in shielding materials. In the present study, the scattered dose equivalent was measured using a Rem counter for water, paraffin, borated paraffin, ordinary and heavy concrete, lead, iron, and tissue equivalent material in three different angles: 45$^{\circ}$, 90$^{\circ}$, and 135$^{\circ}$, respectively. The measurements were performed for the neutron, having the energies of 0.5, 1, 2, 5, and 18 MeV, which are produced from the Van do Graaff accelerator. The scattered dose equivalent ratios were increased with increasing the thickness of scattering materials and saturated at a certain thickness although they were different from one to other materials under study. The ratios were large for lead and iron while they were small for the hydrogen containing materials such as water and paraffin etc.

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Statistical analysis for small power module (소형전원장치에 대한 통계적 분석)

  • Shin, Jae-Kyoung
    • Journal of the Korean Data and Information Science Society
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    • v.22 no.4
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    • pp.735-740
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    • 2011
  • In recent, electronic devices were able to develop and focus for ultra-compact size, intelligence, multifunction and broadband. Their SMPS is realized to ultra-compact size, light weight, high efficiency, high reliability, low noises. The power module which can be used to supply DC output from a commercial power supply (85 to 265 VAC). A switching power supply can be made easily by adding simply external circuit, such as microcontroller, a relay, etc. It would be apply to mostly electronic devices, and fit the global project "Saving energy". But we need to statistical analysis for a quality and performance about a load and an output voltage in product.

Improvement of Ethanol Yield by Addition of Acetic Acid and Acetatdehyde in Ethanol Fermentation (에탄올 발효에서 초산 및 아세트알데히드 첨가에 의한 에탄올 수율의 증진)

  • 김진현;여주상유영제
    • KSBB Journal
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    • v.10 no.4
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    • pp.370-373
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    • 1995
  • The major by-products in ethanol fermentation by Saccharomyces cerevisiae were glycerol, acetaldehyde, acetic acid, lactic acid, and formic acid. The effects of these by-products on the cell growth and ethanol production were studied. By adding acetaldehyde or acetic acid in the fermentation broth, the cell growth decreased while the ethanol production increased. But glycerol and lactic acid had nearly no effects on the cell growth and the ethanol production. Acetic acid and acetaldehyde inhibited the cell growth by diminishing the growth rate as well as by prolonging the lag phase. The ethanol yield increased with the elevation of concentrations of acetic acid and acetaldehyde in the fermentation broth. The maximum ethanol yield was obtained for $3g/\ell$ acetic acid and $2g/\ell$ acetaldehyde, respectively.

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A Study on the Effects of Additives on the Friction and Wear Properties of PTFE Composite (첨가제에 의한 PTFE 복합재료의 마찰마모 특성에 관한 연구)

  • 김용직;김윤해
    • Composites Research
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    • v.13 no.4
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    • pp.11-18
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    • 2000
  • This study is mainly concerned with friction and wear properties for the piston ring of non-lubricating air compressor which made of PTFE-polyimide composites. At the PTFE and polyimide alone mixture specimens, PTFE80%-polyimide20%, which shows the lowest mean friction coefficient and specific wear rate at 0.94m/s sliding speed. In case of the specific wear rate, copper30% specimen shows the lowest value of 2.537-5(mm3/Nm) in all specimens. It considered that the friction coefficient is affected by generating speed and quantity of wear film. In case specific wear rate, it is attributed to the fact that the surface hardness of wear film is proportioned to specific wear rate.

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Intra-/lntermolecular Excimer Emission of Syndiotactic Polystyrene Having Carbazole Substituents (카바졸 치환체를 가지는 신디오탁틱 폴리스티렌의 분자내/분자간 엑시머 발광)

  • Jeong, Seon-Ju;Jung, In-Tae;Yoon, Keun-Byoung
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.314-319
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    • 2011
  • The syndiotactic and atactic poly (2-N-carbazoylrnethyl) styrenes were obtained by a half-titanocene catalyst and a radical initiator for the investigation of photophysical properties, especially excimer formation. The atactic polymer exhibited only monomer emission, but the syndiotactic polymer showed both excimer emission and monomer emission resulting from the partial overlapping arrangement of carbazole pendants, The emission band of syndiotactic polymer was considerably dependent on solution concentration and temperature, however atactic polymer was independent because the excimer formation of syndiotactic helical conformation was more favorable than that of the random coil conformation of atactic polymer.

The vibration and noise characteristics analysis of Sound Insulation Panel for Transformer (변압기용 차음판의 진동 소음 특성 분석)

  • Joeng, Han-E;Kim, H.J.;Gu, D.S.;Choi, B.K.
    • Journal of Power System Engineering
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    • v.10 no.4
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    • pp.78-82
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    • 2006
  • Recently, The demands for the reduction of noise generated by transformers have been increasing. Almost all of the noise generated by transformers is a result of magnetostricitive vibration in the core. The noise radiates into the atmosphere from the tank through the insulation oil. As the noise of transformer irritates residents, needs for decreasing the noise of transformer have been arised. One method of reduction such a noise is to build a free-standing enclosure of concrete and steel plates around the transformer. However, this method has some disadvantages. Another method of noise reduction is to mount a close-fitting sound insulation panel on the side of a transformer tank. Side plate vibrations of transformer are transmitted to such a sound insulation panel along two paths. In one case, they are transmitted through air by sound pressure and in the other through supporting structures. In the paper, the vibration and noise effect which is transferred from reinforce channel to insulation panel generated by transformer have been identified for the several kinds of insulation panel and damping sheet analytically and experimetally.

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Synthesis and Comparison of EB- and UV-curable Monomers for Anti-fogging Coatings (전자선 및 자외선 경화형 방무코팅용 모노머의 합성 및 물성비교)

  • Cho, Jung-Dae;Lee, Jae-Sung;Kim, Yang-Bae;Hong, Jin-who
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.449-455
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    • 2005
  • Electron beam (EB) and ultraviolet (UV) curable monomers (AF-1 with mono functionality and AF-2 with tetra functionality) containing hydroxy and acrylate group for anti-fogging coating were synthesized and applied to EB and UV-curable coating systems. The synthesized reactive AF-1 and AF-2 monomers were first formulated into UV-curable system and the optimization of film properties for anti-fogging coating was investigated. The 5:17.5 ratio for AF-1 and AF-2 was found to be the best optimized formulation for anti-fogging coating without destroying the other essential properties such as hardness, solvent resistance, and adhesion. The optimized formulation was applied to the EB-curable system, and EB and UV-curable systems were compared. The results demonstrated that both EB and UV-cured films coated on PC sheet showed excellent anti-fogging properties; however, the EB-cured film exhibited better hardness, adhesion, and water repellent properties than the UV-cured film.

Preparation of Organic-inorganic Hybrid PES Membranes using Fe(II) Clathrochelate (Fe(II) clathrochelate을 이용한 유.무기 PES 복합막의 제조)

  • Jung, Bo Ram;Son, Yeji;Lee, Yong Taek;Kim, Nowon
    • Membrane Journal
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    • v.23 no.1
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    • pp.80-91
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    • 2013
  • Metal-templated condensation of cyclohexanedione dioxime and phenylboronic acid in the presence of Fe(II) sulfate heptahydrate proceeds cleanly in methanol to furnish the Fe(II) clathrochelate. An organic/inorganic hybrid membranes composed of Fe(II) clathrochelate and polyethersulfone was prepared by using phase inversion method. For membrane preparation, the Fe(II) clathrochelate was highly soluble (3~5 g/L) in DMF, NMP, and DMAc, which meets the requirements for the solubility of metal complexes in polar aprotic solvent used in membrane preparation. It was stable even in the presence of strong acids, such as trifluorosactic acid (pKa = 0.3). It was characterized by UV-vis spectroscopy, and their stability in solution phase studied in the presence of (i) strong acids or (ii) competing chelates. Organic/inorganic hybrid membranes were prepared with polyethersulfone, polyvinylpyrrolidone, p-toluenesulfonic acid, Fe(II) clathrochelate and DMF by using nonsolvent induced phase inversion method. The addition of Fe(II) clathrochelate leads increase of surface pore density, mean pore size and flux. We can obtain highly asymmetric membranes by addition of Fe(II) clathrochelate.

Synthesis and Surface Active Properties of Diglycerol N-Acyl Glutamic Acid Esters (디글리세롤 N-아실 글루탐산 에스테르류의 합성 및 계면성)

  • Jeong, Hwan-Kyeong;Jeong, No-Hee;Nam, Ki-Dea
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.247-254
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    • 1994
  • Nonionic surfactants, diglycerol N-acyl glutamates were prepared through the esterification of N-acryl glutamic acids and glycidol in the presence of quarternary ammonium salts. Their cmc evaluated by the surface tension method was $0.15{\sim}0.75mol/{\ell}$, and the surface tension of aqueous solution was decreased to 28~35dyne/cm. L-DGLG with acyl group of carbon number of 12 showed good foaming power and emulsifying power, and the emulsifying power in toluene was stronger than in soybean oil. Dispersion effect of L-DGPG and L-DGSG with acyl group of carbon number of 16 and 18 in carbon black and ferric oxide were higher than L-DGLG. All of them showed good biodegradability at $20^{\circ}C$.

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