• Clean Technology
• /
• v.19 no.4
• /
• pp.423-429
• /
• 2013

This study aimed to develop flowable backfill material using oyster shell, coal ash, and surplus soil. The high temperature (> $800^{\circ}C$) reaction was required to convert $CaCO_3$ to CaO. The solid specimens formed by pozzlanic reaction between CaO and coal ash showed low unconfined compressive strength. The effect of kaolin and blast furnace slag was also examined. It was found that CaO and coal ash could not be utilized due to high cost and low performance. The use of oyster shell without calcination ($CaCO_3$) was evaluated. The specimens composing of oyster shell and cement showed the higher unconfined compressive strength than that composing of coal ash and cement. However, use of oyster shell is limited in mortar due to the presence of salt. Addition of soil into oyster shell-coal ash-cement mixture satisfied the specification of flowable backfill material by optimizing their ratio.

• Journal of the Korean Geophysical Society
• /
• v.6 no.1
• /
• pp.13-23
• /
• 2003

Dipole-dipole resistivity and ground penetrating radar(GPR) surveys were performed on an abandoned landfill site filled with asbestos containing material. The main purpose of the study was to estimate spatial extension and volume of the landfill for evaluting the cost for developing appropriate remedial alternatives. Assuming that the bedrock is within 10 m depth, dipole spacings of 2, 2.5 and 5m were set for six survey lines for resistivity measurements. For More detailed information, GPR suvey using 225 Mhz antenna was carried out for twelve survey lines for the shallower information. DC resistivity structures showed few tens ~ hundreds ohm-m for the landfill or alluvial laver, and 1,000~ 5,000 ohm-m for the bedrock. The depth to bedrock is found out to be approximately 5m. GPR survey results represented very clear reflection and/or diffraction events from the boundaries as well as from the blocky construction wastes. With high-resolution GPR survey, depth of the bedrock was resolved up to 2m, which in turn, could be a good indicator for estimating the volume of the landfill. Those depths of bedrock were confirmed by backhoe excavation data for 13 sites. The total area and volume of the landfill were to be approximately 3,953 .$m^2$ and 4,033 $m^3$, respectively.

• Resources Recycling
• /
• v.18 no.3
• /
• pp.11-19
• /
• 2009

Recently the problem of global environment is became by social issue. Accordingly the interests to recycling and saving of resources are growing from daily life to varieties field of industry. To preserve the global environment, prevent global warming, environmental destruction, environmental pollution by wastes, the drain of aggregate, plasticity energy of cement and decrease in carbon dioxide are an urgent problem that must be resolved. So there is to a field of building industry and stands but on the inside of the building the many double meaning resources usefully, applies. Also the seller masterpiece building where the service life is long planned is safe and comfortably, maintenance, suppresses the construction which is not necessary is unnecessary. Also the seller masterpiece building where the service life is long planned is safe and comfortably, maintenance, suppresses the construction which is not necessary is unnecessary. By revitalizing effective use of limited earth resources, recycling and controling production of construction waste, this study introduced to a method for Long-Term Durability of Construction Structure and Effective Use of Technology for Construction Waste considering architectural demand and earth environment. It is for reduction of an earth environment load from the side of construction production and performance design of a structure.

• Polymer(Korea)
• /
• v.36 no.2
• /
• pp.216-222
• /
• 2012

We synthesized microcapsule absorbent with crosslinked poly(styrene-$alt$-maleic anhydride) (PSMA) as a core and PSMA as a shell by a precipitation polymerization method for the delayed absorption of excess water in cement mortar. cPSMA-PSMAs with core-shell structure were synthesized with ratios of 1/1, 1/2 and 1/3 as core monomer mass to shell monomer mass to control shell thickness. We observed the hydrolysis of PSMA in cement-saturated aqueous solution by a FTIR spectrometer. We observed good core-shell structure microcapsules for 1/2(cPSMA #3), but observed incomplete core-shell structure for 1/1(cPSMA #2) and 1/3(cPSMA #4) of core/shell monomer ratios. The swelling ratio of cPSMA #3 in cement-saturated aqueous solution was increased until 20 min. After that it was decreased until 2 hrs swelling time, and they started to increase again. The viscosities of cement paste with cPSMA #3 microcapsules were very slowly increased until 1 hr and increased fast after 1.5 hrs. Cement mortar with 0.5 wt% cPSMA #1 having only core part showed about 5% increase in compressive strength compared to that of plain cement mortar. cPSMA #3 added cement mortar showed the highest compressive strength with 7% increase.

• Polymer(Korea)
• /
• v.36 no.2
• /
• pp.208-215
• /
• 2012

To study the effect of surface crosslinked layer on the crosslinked poly(sodium acrylate) (cPSA) absorbent, we synthesized several surface crosslinked cPSAs with 5, 10 and 20 g of ethylene glycol dimethacrylate (EGDMA) by an inverse emulsion polymerization method to delay the absorption of excess water in concrete. We measured the compressive and flexural strength of mortars having 0.5, 1.0 and 1.5 wt% cPSA-EGDMA. We observed the increase of compressive and flexural strength of the cPSA-EGDMA added cement mortars except for the 0.5 wt% cPSA-EGDMA (20 g) added cement mortar. 1.0 wt% cPSA-EGDMA (5 g) added cement mortar showed about 16% and 10% increased compressive and flexural strength than those of plain cement mortar. To study the effect of porosity on compressive and flexural strength, we used FE-SEM and porosimeter. FE-SEM analysis showed swollen cPSMAEGDMA (5 g) filled between calcium silicate hydrate (C-S-H) crystals. We observed the decreased porosity of the cPSA-EGDMA added cement mortars than that of plain cement mortar. 1.0 wt% cPSA-EGDMA (5 g) cement mortar showed the lowest porosity of 16.5%.

• Resources Recycling
• /
• v.29 no.2
• /
• pp.28-36
• /
• 2020

To enhance the recycling rate of wasted glass bottles toward recycled aggregates, the study would decide optimal comminution equipment based on the particle size distribution, aspect ratio and equipment energy analysis. The impact, compress and abrasion is type of generated force by comminution. So, hammer crusher, shredder, roll crusher and ball mill have been selected because they have characteristic which is each type of force. As a result of the particle size analysis of each product, only the shredder product satisfied concrete and asphalt aggregate quality standard condition. Also, as a result of aspect ratio analysis using Imaging software program (Image J, National institute of health), most of size fraction is confirmed under 1.6 value. It was confirmed that the product has low dangerousness and satisfying to shpage index. Also, the particle reduction ratio against input energy of shredder product was the most high. Therefore, we can decide that the optimal equipment which applicable for comminuting waste glass bottle in certain particle size under 10mm is shredder. The result of study will make contribution to increasing energy efficiency of comminution processing and competitiveness of product.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.14 no.3
• /
• pp.235-243
• /
• 2016

In the near future, many countries, including the Republic of Korea, will face a significant increase in low level radioactive waste (LLW) from nuclear power plant decommissioning. The purpose of this paper is to look at blending as a method for enhancing disposal options for low-level radioactive waste from the decommissioning of nuclear reactors. The 2007 U.S. Nuclear Regulatory Commission strategic assessment of the status of the U.S. LLW program identified the need to move to a risk-informed and performance-based regulatory approach for managing LLW. The strategic assessment identified blending waste of varying radionuclide concentrations as a potential means of enhancing options for LLW disposal. The NRC's position is that concentration averaging or blending can be performed in a way that does not diminish the overall safety of LLW disposal. The revised regulatory requirements for blending LLW are presented in the revised NRC Branch Technical Position for Concentration Averaging and Encapsulation (CA BTP 2015). The changes to the CA BTP that are the most significant for NPP operation, maintenance and decommissioning are reviewed in this paper and a potential application is identified for decommissioning waste in Korea. By far the largest volume of LLW from NPPs will come from decommissioning rather than operation. The large volumes in decommissioning present an opportunity for significant gains in disposal efficiency from blending and concentration averaging. The application of concentration averaging waste from a reactor bio-shield is also presented.

• Polymer(Korea)
• /
• v.35 no.4
• /
• pp.363-369
• /
• 2011

To study the effect of incorporation of a surface crosslinking layer on a crosslinked poly (sodium acrylate) (cPSA) absorbent with ethylene glycol dimethacrylate CEGDMA), we synthesized several surface crosslinked cPSAs with EGDMA by an inverse emulsion polymerization method to delay the absorption of excess water in concrete, Liquid paraffin was used as a continuous phase. cPSA was synthesized with acrylic acid (AA) neutralized with aqueous 8 M sodium hydroxide solution as a monomer, N,N-methylene bisacrylamide (MBA) as crosslinking agent and ammonium persulfate (APS) and sodium metabisulfite (SMBS) as a redox initiator system by inverse emulsion polymerization. FTIR spectroscopy was used to characterize $Ca^{2+}$ ion interaction with cPSA and cPSA-EGDMAs. The swelling ratios of synthesized absorbents were evaluated from the absorption in deionized water, cement saturated aqueous solution and aqueous solution of calcium hydroxide (pH 12). Equilibrium swelling times for cPSA and surface crosslinked cPSA with EGDMA were 2 and 3 hrs, respectively. We also observed an increase in setting time of the cement and an increase in the compressive strength of mortar by addition of the synthesized cPSA-EGDMA.

• Tunnel and Underground Space
• /
• v.20 no.5
• /
• pp.352-359
• /
• 2010

Stability of twin tunnels depends on the pillar width and the ground condition. In this study, large scale model tests were conducted for investigating the influence of the pillar width of twin tunnels on their behavior in the regular horizontal jointed rock mass. Jointed rocks was composed of concrete blocks. Pillar width of twin tunnels varied in 0.29D, 0.59D, 0.88D and 1.18D, where D is the tunnel width. During the test, pillar stress, lining stress, tunnel distortion, and ground displacement were measured. Lateral earth pressure coefficient was kept in a constant value 1.0. As a result, it was found that the pillar stress and the displacement of the ground and tunnel were increased by decreasing pillar width. The maximum displacement rate was measured just after the upper excavation in each construction sequence. And the maximum influence position was the right shoulder of the preceeding tunnel at the pillar side. It was also found that for the stability assessment the inner displacement was more critical than the crown displacement. The influence zone was formed at the pillar width 0.59D~0.88D that was smaller than 0.8D~2.0D, which was proposed by experience for a good ground condition. And it would be concluded that horizontal joints could also influence on the stability of the twin tunnels.

• Tunnel and Underground Space
• /
• v.23 no.3
• /
• pp.241-259
• /
• 2013

A packed bed thermal energy storage (TES) consisting of solid storage medium of rock or concrete through which the heat transfer fluid is circulated is considered as an attractive alternative for high temperature sensible heat storage, because of the economical viability and chemical stability of storage medium and the simplicity of operation. This study introduces the technologies of packed bed thermal energy storage, and presents a numerical model to analyze the thermal energy balance and the performance efficiency of the storage system. In this model, one dimensional transient heat transfer problem in the storage tank is solved using finite difference method, and temperature distribution in a storage tank and thermal energy loss from the tank wall can be calculated during the repeated thermal charging and discharging modes. In this study, a high temperature thermal energy storage connected with AA-CAES (advanced adiabatic compressed air energy storage) was modeled and analyzed for the temperature and the energy balance in the storage tank. Rock cavern type TES and above-ground type TES were both simulated and their results were compared in terms of the discharging efficiency and heat loss ratio.