• Title/Summary/Keyword: 프로필

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Dissolution Kinetics of Thiourea in Triglycol Solution (트리글리콜용액에서 싸이오우레아 용해 반응속도론)

  • Li, Hua;Guo, Feng;Hu, Guoqin;Zhao, Lei;Zhang, Yadong
    • Journal of the Korean Chemical Society
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    • v.54 no.1
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    • pp.88-92
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    • 2010
  • Isopropyl mercaptan is an important pharmaceutical intermediate and chemical material. And thiourea and triglycol are the main materials for the synthesis of isopropyl mercaptan. Therefore the dissolution of thiourea in triglycol solution is very important for the production of isopropyl mercaptan. The aims of this study are to examine the dissolution kinetics of thiourea in triglycol solution, and to present an alternative process for producing isopropyl mercaptan. In order to investigate the dissolution kinetics of thiourea in triglycol solution, the concentrations of solution and reaction temperature were selected as experimental parameters. It was determined that the dissolution rate of thiourea increased with the increase in solution concentration and temperature. An empirical equation was used in fitting the data. Statistical analysis indicated small errors and the results should be reliable.

Applying Rating Score's Reliability of Customers to Enhance Prediction Accuracy in Recommender System (추천 시스템의 예측 정확도 향상을 위한 고객 평가정보의 신뢰도 활용법)

  • Choeh, Joon Yeon;Lee, Seok Kee;Cho, Yeong Bin
    • The Journal of the Korea Contents Association
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    • v.13 no.7
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    • pp.379-385
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    • 2013
  • On the internet, the rating scores assigned by customers are considered as the preference information of themselves and thus, these can be used efficiently in the customer profile generation process of recommender system. However, since anyone is free to assign a score that has a biased rating, using this without any filtering can exhibit a reliability problem. In this study, we suggest the methodology that measures the reliability of rating scores and then applies them to the customer profile creation process. Unlikely to some related studies which measure the reliability on the user level, we measure the reliability on the individual rating score level. Experimental results show that prediction accuracy of recommender system can be enhanced when ratings with higher reliability are selectively used for the customer profile configuration.

Gamma-Radiolysis of Carbon Dioxide (V). Radiolysis of Carbon Dioxide-Alcohol Mixtures (이산화탄소와 알코올류의 혼합물에 대한 방사선 분해반응에 관한 연구)

  • Choi Sang Up;Pyun Hyung Chick;Jin Joon Ha
    • Journal of the Korean Chemical Society
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    • v.35 no.1
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    • pp.3-15
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    • 1991
  • The gaseous mixtures of iso-propanol of 10 torr with carbon dioxide of 0∼1990 torr were irradiated with Co-60 gamma radiation up to 50 kGy, and the products such as carbon monoxide, acetone, methane, ethane, C$_3$H$_a$, C$_4$H$_b$ and tert-butanol were analyzed by gas chromatography. G(CO) value of 4 was obtained from the gas mixtures containing more than 490 torr of carbon dioxide. The production rates of the organic products and the decomposition rate of iso-propanol increased linearly with the pressure of carbon dioxide, and G(-iso-Propanol) and G(Acetone) values increased by 4 and 2, respectively, with each 10 torr increment of carbon dioxide pressure. The mechanisms of the radiolytic decomposition of iso-propanol and the production of carbon monoxide and organic materials are discussed on the basis of the experimental results of the present study.

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Synthesis and Thermo-responsive Properties of Amino Group Terminated Poly(N-isopropylacrylamide) and Sodium Alginate-g-Poly(N-isopropylacrylamide) (말단 아민기를 갖는 폴리(N-이소프로필아크릴아미드) 및 알긴산 나트륨-g-폴리(N-이소프로필아크릴아미드)의 합성과 열응답 특성)

  • Lee, Eun Ju;Kim, Young Ho
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.539-546
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    • 2013
  • Amino group-terminated poly(N-isopropylacrylamide) (PNIPAAm-$NH_2$) was synthesized via a radical polymerization of N-isopropylacrylamide (NIPAAm) using 2-aminoethanethiol hydrochloride (AESH) as a chain transfer agent. The molecular weight of the PNIPAAm-$NH_2$ was controlled by changing the concentration of AESH. The LCST of the aqueous solution of PNIPAAm-$NH_2$ increased slightly with increasing the AESH concentration. Alginate-g-PNIPAAm copolymer was synthesized by grafting PNIPAAm-$NH_2$ onto sodium alginate using N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide and N-hydroxysuccinimide. The formation of the grafted copolymers was confirmed by FTIR spectroscopy, solubility in water, and SEM-EDS. Alginate-g-PNIPAAm also exhibited swelling-deswelling behavior. However, it showed a LCST at a slightly increased temperature compared to PNIPAAm. The swelling ratio of the alginate-g-PNIPAAm hydrogel increased with the increase of the grafted PNIPAAm content.

Profile Management System for Contact Information Privacy in Social Network Service (소셜 네트워크 서비스에서 사용자 연락정보 프라이버시 강화를 위한 개인 프로필 관리 시스템 연구)

  • Youn, Taek-Young;Hong, Do-Won
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.21 no.5
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    • pp.141-148
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    • 2011
  • Recently, various social network services have been grown. Among them, personal relationships based social network services such as Facebook and Twitter make a remarkable growth of industry. In such services, users' profiles are very important for establishing the relationship between two users. However some information in a user's profile causes the leakage of the user's privacy, and thus we have to deal with the information in the profile. Especially, we have to treat contact information, such as the phone number and the e-mail address, very carefully since an adversary can use the information to violate the user's privacy in real life. In this paper, we propose two profile management systems that can enhance the privacy of users in social network services. We compare our systems with existing profile management techniques in well-known social network services such as Facebook and Twitter, and show that our systems provide enhanced privacy.

Oestrogenic Activity of Parabens in Uterotrophic Assay (자궁비대시험 연구에서 에틸, 프로필, 이소프로필, 부틸, 이소부틸 파라벤의 내분비독성)

  • Jo Eun-Hye;Jung Ji-Youn;Park Cheol-Beom;Park Sun-Hee;Shim Yhong-Hee;Kang Dae-Hyuck;Lee Sung-Ho;Yu Jong-Hoon;Kim Sun-Jung;Lee Sung-Hoon;Park Jung-Ran;Lee Yong-Soon;Kang Kyung-Sun
    • Journal of Food Hygiene and Safety
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    • v.21 no.2
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    • pp.118-128
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    • 2006
  • This study was conducted to determination of the endocrine distruptor function of 'Parabens' by dosing ethyl paraben, propyl paraben, isopropyl paraben, butyl paraben and isobutyl paraben to the immature SD rats. 18 groups were given vehicle control group, negative control group (Dibutyl phthalate), postive control group ($1'7-{\alpha}$ Ethynylestrdiol) and each paraben groups involved 3 dose level. Rats were injected with 62.5, 250 and 1,000mg/kg from postnatal day 19 till 21 once a day in subcutaneous and a total 3, times. There was no treatment related death. but, subcutaneous nodule, edema, alopecia and scrub formation on injection site was observed. These signs was become worse in high dose level. these signs was cause from physical stimulation by test substance which parabens were mix with com oil as vehicle. In the analysis of organ weights, absolute and relative weights of brain, spleen, liver, thymus, heart, kidneys, adrenals, ovaries and vagina were no difference with control group. but, wet and blotted weight of uterus was increased in every high dose parabens treat group. Especially, all dose level of isobutyl paraben was showed increment of uterus weight. uterus dilatation of parabens treated group was observed in gross anatomic pathology and these result was agree with wet and blotted weight of uterus. In the result of this study, estrogenic effect as endocrine distruptor was observed in ethyl paraben, propyl paraben, isopropyl paraben, butyl paraben and isobutyl paraben. and it was considered isobutyl paraben has highest estrogrnic effect under the condition of this study.