• Journal of the Korean Chemical Society
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• v.42 no.4
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• pp.391-397
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• 1998

The geometry of furan, relevant to the binding of bis-furan lexitropsin that contains this ring to the base pair of minor groove of DNA, is optimized by semiempirical (MNDO) and ab initio (Hartree-Fock) methods. The proton affinity and electronic structure are evaluated at the 6-31G and $6-31G^{\ast}$ level of theory for the optimized geometry. The proton affinities are also studied for various substituted furans with the electrondonating and -withdrawing groups to estimate the substituent effect on the proton affinity of furans. It has been found that the electron-donating substituents increase the proton affinity of furan, whereas the electron-withdrawing substituents decrease it. This result can be explained with atomic charge and electron density at oxygen of substituted furans.

• Journal of the Korean Vacuum Society
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• v.20 no.4
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• pp.252-257
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• 2011

The ring formation and electronic properties of furan adsorbed on graphene layers grown on 6H-SiC (0001) has been investigated using atomic force microscopy (AFM), near edge X-ray absorption fine structure (NEXAFS) spectra for the C K-edge, and core level photoemission spectroscopy (CLPES). Moreover, we observed that furan molecules adsorbed on graphene could be used for chemical functionalization via the lone pair electrons of the oxygen group, allowing chemical doping. We also found that furan spontaneously form rings with one of three different bonding configurations and the electronic properties of the ring formed by furan on graphene can be described using by AFM, NEXAFS and CLPES, respectively.

• Journal of the Korean Chemical Society
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• v.50 no.5
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• pp.420-423
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• 2006

• Bulletin of Food Technology
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• v.20 no.3
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• pp.80-88
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• 2007

• Proceedings of the Korean Fiber Society Conference
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• 1994.10a
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• pp.126-127
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• 1994

• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.2047_2048
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• 2009

절연유중 용존가스분석에 의한 진단방법은 변압기 내부에 이상유무를 판단하는 좋은 방법이다. 이중에서 $CO_2$와 CO가스에 의한 열화진단도 가능하나, 이들 가스들은 운전 중인 변압기 내에서 절연지 속으로 매우 잘 흡수되어 진다고 알려져 있다. 절연지는 도체의 주위를 감싸고 있어서 변압기를 폐기할 때까지는 종이로 된 절연물의 상태를 분석하기가 어렵기 때문에 절연유중에 용해되어 있는 CO와 $CO_2$ 농도를 분석하여 절연지의 열화 정도를 판단하고 있지만, 절연유의 일반적인 열화에 의해서도 이들 가스가 발생하기 때문에 정확하게 판단하기가 어렵다. 따라서, 절연물의 열화정도를 파악하기 위해 절연유중의 퓨란화합물에 대한 최적 분석법을 도출하여 열화진단에 대한 정확도를 높이고자 하였다.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2004.05a
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• pp.265-267
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• 2004

• Journal of the Korean Chemical Society
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• v.43 no.4
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• pp.12-494
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• 1999

• Journal of the Korean Chemical Society
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• v.27 no.3
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• pp.201-207
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• 1983

The rate constants for solvated electrons with benzene in the binary mixture (tetrahydrofuran-water) were measured at a various temperatures$(-18{\circ}C{\sim}+51{\circ}C)$ by photolysis. From Arrhenius plots of rate constants it was observed that the activation energies were decreased with increasing tetrahydrofuran(THF) content. Decreasing the viscosity of solvent mixtures by adding water, the rate constants were also decreased. It indicates that the reaction of solvated electrons are not controlled by diffusion. The change of activation enthalpy in kcal $M^{-1}$ and the rate constants in$ M^{-1}sec^{-1}$ were 4.90 and $8.80{\times}10^8$ for 30M% of THF, 2.80 and $5.14{\times}10^8$ for 49M% of THF, and -0.30 and %1.43{\times}10^8$ for 75M% of THF, respectively. The slope of the linear plot of activation enthalpies against activation entropies was $244{\circ}K$, which supports the reaction parameter is the change of activation entropy in the range of the experimental temperature. From the solvent effect on the activation energy, it was found that the step of the reaction, ${e_s}^-+B{\rightleftharpoons}B^-$ shifted to the exothermic reaction with increasing THF content.

• Composites Research
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• v.34 no.1
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• pp.57-62
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• 2021

As interest in the eco-friendly ships and lightweight equipment is increasing in the shipbuilding and marine industry, composite materials are applied to equipment such as pipes. In this study, a basalt fiber reinforced furan composite (BFC), an eco-friendly material, was manufactured to apply the pipe insulation cover that requires environment-friendly and heat/flame retardant performance. An optimization study of post-curing conditions of BFC was conducted, and experiments and analysis were performed on mechanical strength, heat/flame retardant properties, and affinity properties. Finally, as a result of the study BFC material is proved to be a good candidate to apply pipe insulation cover.