• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.505-508
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• 2008

Concrete is a type of porous materials and is physically and chemically damaged due to exposure to various environments from the placing to the service life. These reactions affect the corrosionof steel bars applied in concrete and that decreases the durability life and strength of such steel bars. Thus, it is very important to insert rust inhibitors into steel bars in the case of a deterioration element that exceeds the critical amount of corrosion in the location of steel bars. However, it is very difficult to guarantee corrosion resistance at the location of steel bars using conventional technology that applies corrosion inhibitors only on the surface of concrete. This study attempts to develop a method that penetrates corrosion inhibitors up to the location of steel bars and investigate the penetration depth of corrosion inhibitors by verifying moisture migration in concrete under an applied pressure.

• Membrane Journal
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• v.15 no.2
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• pp.105-113
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• 2005

Silica membranes were prepared on a porous metal sheet by ultrasonic spray pyrolysis method for gas separation at high temperatures. In order to improve the permselectivity, silica was deposited in the sol-gel derived $silica/\gamma-alumina$ intermediate layer by pyrolysis of tetraethyl orthosilicate (TEOS) at 873 K. The pyrolysis with forced cross flow through the porous wall of the support was very effective in plugging mesopores, Knudsen diffusion regime, that were left unplugged in the membranes. At permeation temperature of 523 K, the silica/alumina composite membrane showed $H_2/N_2$ and water/methanol selectivity as high as 17 and 16, respectively, by molecular sieve effect.

• Tunnel and Underground Space
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• v.9 no.4
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• pp.306-314
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• 1999

In underground spaces including nuclear waste repository, prediction of air quantity, temperature/humidity and pollutant concentration is utmost important for space construction and management during the normal state as well as for determining the measures in emergency cases such as underground fires. This study aims at developing a model for underground space environment which has capabilities to take into account the effects of autocompression for the natural ventilation head calculation, to find the optimal location and size of fans and regulators, to predict the temperature and humidity by calculating the convective heat transfer coefficient and the sensible and latent heat transfer rates, and to estimate the pollutant levels throughout the network. The temperature/humidity prediction model was applied to a military storage underground space and the relative differences of dry and wet temperatures were 1.5 ~ 2.9% and 0.6 ~ 6.1%, respectively. The convection-based pollutant transport model was applied to two different vehicle tunnels. Coefficients of turbulent diffusion due to the atmospheric turbulence were found to be 9.78 and 17.35$m^2$/s, but measurements of smoke and CO concentrations in a tunnel with high traffic density and under operation of ventilation equipment showed relative differences of 5.88 and 6.62% compared with estimates from the convection-based model. These findings indicate convection is the governing mechanism for pollutant diffusion in most of the tunnel-type spaces.

• Clean Technology
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• v.26 no.1
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• pp.30-38
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• 2020

The kinetic and thermodynamic parameters of Acid Red 66, adsorbed by granular activated carbon, were investigated on areas of initial concentration, contact time, and temperature. The adsorption equilibrium data were applied to Langmuir, Freundlich, Temkin, Redlich-Peterson, and Temkin isotherms. The agreement was found to be the highest in the Freundlich model. From the determined Freundlich separation factor (1/n = 0.125 ~ 0.232), the adsorption of Acid Red 66 by granular activated carbon could be employed as an effective treatment method. Temkin's constant related to adsorption heat (B_T = 2.147 ~ 2.562 J mol^-1) showed that this process was physical adsorption. From kinetic experiments, the adsorption process followed the pseudo-second order model with good agreement. The results of the intraparticle diffusion equation showed that the inclination of the second straight line representing the intraparticle diffusion was smaller than that of the first straight line representing the boundary layer diffusion. Therefore, it was confirmed that intraparticle diffusion was the rate-controlling step. From thermodynamic experiments, the activation energy was determined as 35.23 kJ mol^-1, indicating that the adsorption of Acid Red 66 was physical adsorption. The negative Gibbs free energy change (ΔG = -0.548 ~ -7.802 kJ mol^-1) and the positive enthalpy change (ΔH = +109.112 kJ mol^-1) indicated the spontaneous and endothermic nature of the adsorption process, respectively. The isosteric heat of adsorption increased with the increase of surface loading, indicating lateral interactions between the adsorbed dye molecules.

• Korean Chemical Engineering Research
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• v.57 no.5
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• pp.679-686
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• 2019

Characteristics of adsorption equilibrium, kinetic and thermodynamic of aniline blue onto activated carbon from aqueous solution were investigated as function of initial concentration, contact time and temperature. Adsorption isotherm of aniline blue was analyzed by Langmuir, Freundlich, Redlich-Peterson, Temkin and Dubinin-Radushkevich models. Langmuir isotherm model fit better with isothermal data than other isotherm models. Estmated Langmuir separation factors ($R_L=0.036{\sim}0.068$) indicated that adsorption process of aniline blue by activated carbon could be an effective treatment method. Adsorption kinetic data were fitted to pseudo first order model, pseudo second order model and intraparticle diffusion models. The kinetic results showed that the adsorption of aniline blue onto activated carbon well followed pseudo second-order model. Adsorption mechanism was evaluated in two steps, film diffusion and intraparticle diffusion, by intraparticle diffusion model. Thermodynamic parameters such as Gibbs free energy, enthalpy and entropy for adsorption process were estimated. Enthalpy change (48.49 kJ/mol) indicated that this adsorption process was physical adsorption and endothermic. Since Gibbs free energy decreased with increasing temperature, the adsorption reaction became more spontaneously with increasing temperature. The isosteric heat of adsorption indicated that there is interaction between the adsorbent and the adsorbate because the energy heterogeneity of the adsorbent surface.

• Clean Technology
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• v.27 no.2
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• pp.182-189
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• 2021

The adsorption of disperse yellow 3 (DY 3) on granular activated carbon (GAC) was investigated for isothermal adsorption and kinetic and thermodynamic parameters by experimenting with initial concentration, contact time, temperature, and pH of the dye as adsorption parameters. In the pH change experiment, the adsorption percent of DY 3 on activated carbon was highest in the acidic region, pH 3 due to electrostatic attraction between the surface of the activated carbon with positive charge and the anion (OH^-) of DY 3. The adsorption equilibrium data of DY 3 fit the Langmuir isothermal adsorption equation best, and it was found that activated carbon can effectively remove DY 3 from the calculated separation factor (R_L). The heat of adsorption-related constant (B) from the Temkin equation did not exceed 20 J mol^-1, indicating that it is a physical adsorption process. The pseudo second order kinetic model fits well within 10.72% of the error percent in the kinetic experiments. The plots for Weber and Morris intraparticle diffusion model were divided into two straight lines. The intraparticle diffusion rate was slow because the slope of the stage 2 (intraparticle diffusion) was smaller than that of stage 1 (boundary layer diffusion). Therefore, it was confirmed that the intraparticle diffusion was rate controlling step. The free energy change of the DY 3 adsorption by activated carbon showed negative values at 298 ~ 318 K. As the temperature increased, the spontaneity increased. The enthalpy change of the adsorption reaction of DY 3 by activated carbon was 0.65 kJ mol^-1, which was an endothermic reaction, and the entropy change was 2.14 J mol^-1 K^-1.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.2
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• pp.50-59
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• 2020

Superabsorbent Polymer (SAP) expands inside concrete by absorbing water and contracts as it discharges water. Through this process, concrete can achieve the internal curing effect, but the space occupied by the expanded SAP remains as a void. In this study, the effects of SAP internal curing and voids were evaluated by evaluating the fundamental properties and chloride penetration resistance of SAP mixed concrete. Also, to evaluate the internal curing effect by SAP, the tests were carried out under water and sealed curing conditions, respectively. From the result, the compressive strength of water curing did not differ significantly according to the mixing ratio of SAP. In the case of sealed curing, however, the compressive strength tended to increase as the mixing ratio of SAP increased. The internal curing effect of sealed curing was considered to have influenced the increase in compressive strength. In the case of the chloride diffusion coefficient, the diffusion coefficient tended to decrease as the mixing ratio of SAP increased. In particular, as the sealed curing is applied, the chloride penetration resistance is further improved due to internal curing effect. If the curing conditions are different, it is considered inappropriate to estimate the chloride penetration resistance by the surface electrical resistivity.

• Journal of the Institute of Electronics and Information Engineers
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• v.51 no.11
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• pp.221-228
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• 2014

The color and shape of the tongue reflect the physiological and clinico-pathological condition of the body. Recently, various tongue image acquisition devices have been developed for accurate diagnosis based on quantitative and objective tongue features. Since a color information is essential for tongue diagnosis, the performance of an illuminator is very important for the tongue image acquisition device. In this study, we developed an indirect illumination, which is possible to improve a homogeneity of light intensities on the tongue surface, and evaluated its performances. In order to realize the indirect illumination (II), a semi-ellipsoidal solid structure (SESS) for the light reflex was located in the system, and two high-brightness white LEDs were placed for illuminating the areas under frontal camera in the SESS. The tongue surface was illuminated by reflected light from the SESS. The light homogeneity induced by three different illuminations including the II was evaluated by calculating coefficient of variation (CV) of illuminance of five regions. The II showed less than 0.01 of CV and the direct illumination (DI) and the direct illumination with a light diffusion plate (DILDP) showed 0.16 and 0.13, respectively. The reflexed pixel ratios of tongue phantom images show 5.76%, 4.22%, 1.79% for the DI, the DILDP and the II, respectively. The homogeneity of a tongue phantom was evaluated by calculating CV of mean pixel values of six different tongue regions, and showed less than 0.06 in the II. If the II technique apply to tongue diagnosis system, it is expected to improve diagnostic accuracy in clinic.

• Journal of the Korean Electrochemical Society
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• v.7 no.1
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• pp.21-25
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• 2004

The electrochemical behaviors of dissolved hydrogen and hydrogen peroxide at a platinum disk electrode were investigated in boric acid solution by potentiostatic polarization method at the temperature of 25 and $200^{\circ}C$. The oxidation of dissolved hydrogen at $25^{\circ}C$ was kinetically controlled reaction, the rate of which depends upon the electron transfer on the electrode surface. As temperature was raised, however, the electrochemical characteristics of dissolved hydrogen were changed from a kinetically controlled reaction to a diffusion controlled one. One notable feature, with dissolved hydrogen at high temperature, is that an abnormal potential range was observed, where the oxidation rate of dissolved hydrogen rapidly decreased just before starting potential of water oxidation. We think it is caused by the deactivation of the electrode that results from the adsorption of hydroxyl ion on the surface of the platinum disk. On the contrary, a definite change with temperature was not identified in the case of the hydrogen peroxide except for the increase in current density that was due to the increasing diffusion coefcient with an increase of temperature.

• Journal of Bio-Environment Control
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• v.29 no.1
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• pp.73-79
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• 2020

The objective of this study is to analyze the heat transfer loss of covering materials in a single-span plastic greenhouse under the steady-state wind environment. To achieve this objective, the following were conducted: (1) design of a small-scaled wind tunnel (SCWT) to analyze heat losses of the greenhouse and its performance; (2) determination of the overall heat transfer coefficient (OHTC) for the covering materials using a small-scaled greenhouse model. The SCWT consists of the blowing, dispersion, steady flow, reduction and testing areas. Each part of the SCWT was customized and designed to maintain air flow at steady state and to minimize the variances in the SCWT test. In this study, the OHTCs of the covering materials were calculated by separating each with the roof, side wall, front and back of the small-scaled greenhouse model. The results of this study show that the OHTC of the roof increases as wind speed increases but the zones in which the increase rate of the OHTC decreased, were distinguished by wind tunnel wing speed of 2 ms^-1. For the side wall, the increase rate of the OHTC was particularly higher in the 0-1 ms^-1 zone.