• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.170-170
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• 2013

형광체를 조명과 디스플레이 산업에 응용하기 위해서는 충분히 밝은 빛을 제공하는 형광체의 발광 세기가 중요한 변수이다. 이러한 발광 특성은 주로 모체 격자에 도핑 되는 활성제의 농도, 입자의 형상과 크기 분포의 균일성, 결정성에 따라 달라진다. 본 연구에서는 Ca2SiO4 모체 결정에 도핑한 활성제 Eu3+와 Dy3+ 이온의 농도를 변화시키면서 고상 반응법을 사용하여 높은 발광 효율을 갖는 Ca2-1.5xSiO4::Eux3+ 적색 형광체와 Ca2-1.5xSiO4:Dyx3+ 백색 형광체를 합성하였다. 특히, 활성제 Eu3+와 Dy3+ 이온 농도의 변화가 형광체의 결정 구조, 소성 온도, 입자의 표면 형상, 광학 스펙트럼의 발광 효율에 미치는 영향을 조사하여 최적의 합성 조건을 결정하였으며, 회절 신호의 반치폭과 발광 세기의 상호 관계를 조사하였다. Ca2-1.5xSiO4::Eux3+와 Ca2-1.5xSiO4:Dyx3+ 형광체 초기 분말 시료는 CaO (99.9% 순도), SiO2 (99.9%), Dy2O3 (99.9%)와 Eu2O3 (99.9%)인 화학 물질을 구입하여 초정밀 저울로 화학양론적으로 측정하였다. 이때 Eu와 Dy의 함량비는 x=0, 0.01, 0.05, 0.1, 0.15, 0.2 mol로 변화 시키면서 합성하였다. Ca2-1.5xSiO4: Dyx3+ 형광체 분말 시료의 경우에 소결 온도를 각각 $1000^{\circ}C$와 $1100^{\circ}C$로 달리하여 흡광과 발광 스펙트럼의 세기를 비교해 본 결과, 서로 다른 두 소결 온도에서 합성한 두 형광체 분말은 동일하게 Dy3+의 몰 비가 0.05 mol일 때 주 발광 스펙트럼의 세기는 최대값을 나타내었다. 파장 355 nm로 여기시킨 Dy3+ 함량비에 따른 Ca2-1.5xSiO4:Dyx3+ 형광체 분말의 발광 스펙트럼은 Dy3+ 함량비에 관계 없이 581 nm에서 가장 강한 황색 발광을 보였다. 함량비가 증가함에 따라 발광 스펙트럼의 변화가 관측되었는데, Dy3+의 몰 비가 0.01 mol~0.05 mol인 영역에서는 발광 세기가 증가하여 0.05 mol에서 최대를 나타내다가 Dy3+의 몰 비가 더욱 증가함에 따라 발광세기는 현저히 감소하는 경향을 나타내었는데, 이 현상은 농도 소광 현상으로 해석 할 수 있다. 이외에도, Eu3+와 Dy3+ 이온의 함량비와 소결 온도가 결정 입자의 크기와 흡광 스펙트럼에 미치는 결과를 조사하였다.

• Resources Recycling
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• v.26 no.5
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• pp.54-60
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• 2017

In this study, we investigated the effect of $TiCl_4$ injection time on the Kroll reaction at a given weight ratio of $TiCl_4$ and Mg. The reduction reaction was investigated by measuring the temperature change according to $TiCl_4$ injection time and observing the cross section and appearance of the Ti sponge after the reaction. The temperature increment due to Kroll reaction heat generation was found to be linearly proportional to the $TiCl_4$ feed rate. In the graph of $TiCl_4$ injection time and reduction tank temperature, initial temperature peaks were observed irrespective of the injection conditions. This is interpreted to mean a temporary interruption of reaction due to $MgCl_2$ formation after the initial Kroll reaction. In addition, when the cross section of the sponge was observed, a large amount of spherical Mg particles was observed in $MgCl_2$. We can infer that this is the process of continuously feeding the unreacted Mg surface, so that a continuous Kroll reaction takes place. The sponge appearance showed that the coalescence or growth of the Kroll reacted Ti particles can be controlled by the cooling rate.

• Journal of Conservation Science
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• v.37 no.2
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• pp.77-89
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• 2021

In this study, materials and color formation techniques were assessed for black potteries excavated from the Janghyeon-dong, Jungsan-dong and Gyodong-ri sites during the Proto-Three Kingdoms period in Ulsan, Korea. Although the black potteries were black superficially, the inner cores were either black or reddish yellow. Microscopy analysis identified that body clay was used for reddish iron oxide rich soils with quartz, alkali feldspar and mica, along with grains of myrmechite texture. Additionally, as marginal differences exist in the contents of SiO₂, Fe₂O₃ and CaO, the composition of the host rock and clay distributed around the sites was affected. Thus, we can deduce that pottery was made by soiling at a short distance. Raman spectroscopy results revealed that the black layer of the black pottery was used as amorphous combustion carbon. In addition, as a transparent layer of brown lacquer was observed on the substrate that was in contact with the surface layer, the black layer of the pottery induced black color development by a combination of combustion carbon and lacquer. Based on the mineral composition and microtexture of the body clay, the firing temperature of the potteries seemed to range from 750 to 850℃, whereas the lacquer layer was pyrolyzed at 468℃ by thermal analysis. Therefore, a combined layer of combustion carbon and lacquer, which formed the black color, was painted after the body clay was fired.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.9
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• pp.605-612
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• 2016

In this study, numerical simulations were conducted for conjugate heat transfer around ice balls in an encapsulated ice thermal storage system. Four shapes of ice balls were modeled; the default one was a sphere, and the other three shapes were designed to enhance convective heat transfer through the ball surface. The flow around the ball was laminar, for which the Reynolds number was 300, and both forced and natural convections inside and outside the balls were considered. The simulations revealed that the magnitude of convective heat transfer for the different shapes decreased in the following order: bone, dimple, hole, and sphere. For the entire simulation, the maximum difference in the average temperatures of water inside the capsules was found to be $0.9^{\circ}C$. Therefore, it can be said that the effect of ice-ball shape on the performance of the ice thermal storage system is significant, considering that more than 0.3 million balls are used in this system.

• Proceedings of the Korean Nuclear Society Conference
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• 1997.05a
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• pp.581-586
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• 1997

중대사고시 노심의 손상에 의한 노심용융물이 원자로 용기 하부 반구로 재배치될 때 고온의 노심용융물에 의한 열적 부하로 원자로 용기의 파손을 일으키게 된다. 원자로 용기하부 반구 내에서의 노심용융물의 열적 거동 및 하부 반구에 대한 열적 부하에 대한 분석은 용융물의 성분 및 재배치 과정의 복잡성 등으로 인한 실험적 모사의 한계성 및 현상 분석의 난이함에도 불구하고 기존 원자로의 중대사고에 대한 안전 여유도의 제고와 이에 따른 노내외 사고 관리 전략의 수립을 위하여 연구의 필요성이 제기된다. 본 연구에서는 노심용융물 냉각연구(SONATA-IV)의 예비 실험으로 노심용융물의 상사물로 $Al_2$O$_3$/Fe Thermite 용융물을 이용하여 실제 원자로 용기 하부 반구를 1/8 로 선형 축소한 반구형 실험 용기로 주입하는 실험을 수행하였다. 아울러 원자로 용기 하부 반구로 재배치된 노심용융물에 의한 열적, 기계적 부하에 대한 분석을 수행하기 개발된 유한 요소 프로그램인 CALF (Computer Analysis for Lower Head Failure ) 코드를 이용한 하부 반구의 열적 거동에 대한 해석 결과를 정리하였다. 용융물 주입 실험 결과 용융물 주입과 동시에 하부 반구에 직경 5cm 크기의 하부 반구 파손이 발생하였다. 이는 고온 용융물에 의한 제트류(Jet Impingement)의 효과로 생각된다 동일한 조건에서 CALF 코드로 하부 반구의 열적 거동을 분석하였는데, 실험과는 달리 하부 반구의 파손이 발생하지 않았다 이같은 해석 결과는 용융물의 제트류 효과가 존재하지 않는다면 고온의 용융물이 하부 반구 내로 재배치되더라도 하부 반구의 파손이 발생하지 않는다는 것을 보여준다.>$_3$ 흡착제 제조시 TiO$_2$ 함량에 따른 Co$^{2＋}$ 흡착량과 25$0^{\circ}C$의 고온에서 ZrO$_2$와 $Al_2$O$_3$의 표면에 생성된 코발트 화합물을 XPS와 EPMA로 부터 확인하였다.인을 명시적으로 설명할 수 있다. 둘째, 오류의 시발점을 정확히 포착하여 동기가 분명한 수정대책을 강구할 수 있다. 셋째, 음운 과 정의 분석 모델은 새로운 언어 학습시에 관련된 언어 상호간의 구조적 마찰을 설명해 줄 수 있다. 넷째, 불규칙적이며 종잡기 힘들고 단편적인 것으로만 보이던 중간언어도 일정한 체계 속에서 변화한다는 사실을 알 수 있다. 다섯째, 종전의 오류 분석에서는 지나치게 모국어의 영향만 강조하고 다른 요인들에 대해서는 다분히 추상적인 언급으로 끝났지만 이 분석을 통 해서 배경어, 목표어, 특히 중간규칙의 역할이 괄목할 만한 것임을 가시적으로 관찰할 수 있 다. 이와 같은 오류분석 방법은 학습자의 모국어 및 관련 외국어의 음운규칙만 알면 어느 학습대상 외국어에라도 적용할 수 있는 보편성을 지니는 것으로 사료된다.없다. 그렇다면 겹의문사를 [-wh]의리를 지 닌 의문사의 병렬로 분석할 수 없다. 예를 들어 누구누구를 [주구-이-ν가] [누구누구-이- ν가]로부터 생성되었다고 볼 수 없다. 그러므로 [-wh] 겹의문사는 복수 의미를 지닐 수 없 다. 그러면 단수 의미는 어떻게 생성되는가\ulcorner 본 논문에서는 표면적 형태에도 불구하고 [-wh]의미의 겹의문사는 병렬적 관계의 합성어가 아니라 내부구조를 지니지 않은 단순한 단어(minim

• Applied Chemistry for Engineering
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• v.25 no.4
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• pp.401-408
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• 2014

In membrane bio-reactor (MBR), the aeration control is one of the important independent variables to decrease fouling and to save energy with shear stress change on the membrane surface. The paper was carried out for numerical simulation of 3-dimensional fluid flow phenomena of the cylindrical bioreactor with submerged flat membranes equipped in the center and supplied the air from the bottom by using the COMSOL program. The viscosity and temperature of solution were assumed to be constant, and the specific air demand based on permeate volume ($SAD_p$) defined as scouring air per permeate rates was used as a variable. The calculated CFD velocities were compared with those of the velocity meter measurement and video image analysis, respectively. The results were good agreement each other within 11% error. For fluid flow in the reactor the liquid velocity increased rapidly between the air diffuser and membrane module, but the velocity decreased during flowing of the membrane module. Also, the velocity increased as it was near from the reactor wall to the central axis. The calculated shear stress on the membrane surface showed the highest value at the center part of the module bottom side and increased as aeration rate increased. Especially, the wall shear stress increased dramatically as the aeration rate increased from 0.15 to 0.25 L/min.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.4
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• pp.527-535
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• 2017

Heat management is one of the most critical issues in Polymer Electrolyte Membrane Fuel Cells (PEMFCs) installed inside the fuel cell power pack of a fuel cell battery hybrid UPS. If the heat generated by the chemical reaction in the fuel cell is not rapidly removed, the durability and performance of the fuel cell may be affected, which may shorten its lifetime. Therefore, the objective of this study is to select and propose a proper cooling method for the fuel cells used in the fuel cell power pack of a UPS. In order to find the most appropriate cooling method, the various design factors affecting the cooling performance were studied. The numerical analysis was performed by a commercial program, i.e., COMSOL Multiphysics. Firstly, the surface temperature of the 1 kW class fuel cell stack with the cooling fans placed at the top was compared with the one with the cooling fans placed at the bottom. Various rotation speeds of the cooling fan, viz. 2,500, 3,000, 3,500, and 4,000 RPM, were tested to determine the proper cooling fan speed. In addition, the influence of the inhaled air flow rate was investigated by changing the porous area of the grille, which is the entrance of the air flowing from the outside to the inside of the power pack. As a result, it was found that for the operating conditions of the 1 kW class PEMFC to be acceptable, the cooling fan was required to have a minimum rotating speed of 3500 RPM to maintain the fuel cell surface temperature within an acceptable range. The results of this study can be effectively applied to the development of thermal management technology for the fuel cells inside the fuel cell power pack of a UPS.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.38 no.12
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• pp.1427-1430
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• 2014

A thermal barrier coating (TBC) prevents heat directly transferring from a high-temperature flame to a substrate. The TBC system comprises a top coating and bond coating. TBC technology reduces the substrate surface temperature by about $100{\sim}170^{\circ}C$. In the TBC system, internal stress is generated by the difference in thermal expansion coefficients of the substrate and coating. The internal stress also differs according to the shape and position of the blade. In this study, finite element analysis was performed for different curvatures of coin-shaped specimens, which are commonly used for thermal fatigue tests, and the changes in internal stress of the TBC system were compared. Based on the results, the curvature at which the minimum stress occurs was derived, and the thermal stress was confirmed to increase with the difference between a given curvature and the curvature with the minimum stress.

• Clean Technology
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• v.20 no.1
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• pp.35-41
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• 2014

Batch adsorption studies were carried out for equilibrium, kinetic and thermodynamic parameters for quinoline yellow adsorption by granular activated carbon ($8{\times}30mesh$, $1,578m^2/g$) with varying the operating variables like initial concentration, contact time and temperature. Equilibrium adsorption data were fitted into Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms. From estimated Langmuir constant ($R_L=0.0730{\sim}0.0854$), Freundlich constant (1/n = 0.2077~0.2268), this process could be employed as effective treatment for removal of quinoline yellow. From calculated Temkin constant (B = 15.759~21.014 J/mol) and Dubinin-Radushkevich constant (E = 1.0508~1.1514 kJ/mol), this adsorption process is physical adsorption. From kinetic experiments, the adsorption process were found to confirm to the pseudo second order model with $r^2$ > 0.99 for all concentrations and temperatures. Thermodynamic parameters like activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption. The activation energy value (+35.137 kJ/mol) and enthalpy change (35.03 kJ/mol) indicated endothermic nature of the adsorption process. Entropy change (+134.38 J/mol K) showed that increasing disorder in process. Free energy change found that the spontaneity of process increased with increasing adsorption temperature.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.4
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• pp.367-375
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• 2014

In numbers of kinds of heat exchanger, the shell-tube heat exchanger is the most commonly used type of heat exchanger in the industry field. In order to improve the thermal performance of the heat exchanger, this study was analyzed heat transfer characteristics according to arrangement of baffle and direction of baffle and bump phase of baffle about shell-tube heat exchanger using appropriate SST (Shear Stress Transport) turbulence model for flow separation and boundary layer analysis. As the boundary condition for CFD (Computational Fluid Dynamics) analysis, the inlet temperature of shell side was constantly 344 K and the variation of the water flow rate was 6, 12, 18 and 24 l/min. As the result of analysis, zigzag baffle arrangement enhances heat transfer rate and pressure drop. Furthermore, in the direction of the baffle, heat transfer rate is more improved with vertical type and angle $45^{\circ}$ type than existing type, and pressure drop was little difference. Also, the bump shape of baffle surface contributes to heat transfer rate and pressure drop improvement due to the increased heat transfer area. Through analysis results, we knew that the increase of the heat transfer was influenced by flow separation, fluid residual time, contact area with the tube, flow rate, swirl and so on.