• 제목/요약/키워드: 폴리스티렌

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플라즈마중합법에 의한 폴리스티렌의 분자구조 제에 및 레지스트 특성 조사 (Resist characteristics and molecular structure control of polystyrene by plasma polymerization method)

  • 박종관;김영봉;김보열;임응춘;이덕출
    • 대한전기학회논문지
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    • 제45권3호
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    • pp.438-443
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    • 1996
  • The effect of plasma polymerization conditions on the structure of the plasma polymerized styrene were investigated by using Fourier Transform Infrared Ray(FT-IR), Differential Scanning Calorimetry (DSC), Gel Permeation Chromatography(GPC). Plasma polymerized thin film was prepared using an interelectrode inductively coupled gas-flow-type reactor. We show that polymerization parameters of thin film affect sensitivity and etching resistance of plasma polymerized styrene is 1.41~3.93, and deposition rate of that are 32~383[.angs./min] with discharge power. Swelling and etching resistance becomes more improved with increasing discharge power during plasma polymerization. (author). 11 refs., 10 figs., 1 tab.

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고밀도 EPS를 이용한 돔 구조 안전성에 대한 고찰 (Dome Structure using High-Density EPS Review of Safety)

  • 장석준;이동운
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 춘계 학술논문 발표대회 1부
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    • pp.119-120
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    • 2011
  • Dome structure to form a space-efficient, applied a lot of beautiful buildings with structural systems, as well as a large space structure in the form of new residential lots have been applied. And domestic demand for housing in the dome with increasing dome house using various materials, are becoming commonplace. But now the Dome House is mainly used in construction steel, wood, stone, FRP construction and building materials per unit area and the high cost, long construction time, energy efficiency, has some disadvantages such as degradation. And structural strength of the structure is weak, the natural ingredients used come from natural damage is so big. In addition, demolition of buildings in trouble when handling the environmental problems has emerged. Recently expanded polystyrene to improve these problems by using the various approaches and research is being attempted and there.

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나노미터 규격의 친수성 박막 패터닝을 이용한 선택적 폴리스티렌 입자 배열 (Selective Array of Polystyrene Beads by Using Nanometer-Scaled Hydrophilic Thin Film Patterning)

  • 강정화;김경섭;김남훈;노용한
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.103-104
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    • 2007
  • Nanometer-scaled polymer beads, such as polystyrene beads, were used as nanometer fabrication materials due to their some advantages such as self-assembled monolayer, nanometer scaled size and excellent compatibility with silicon based devices. Thus, the investigation on these properties of polymer beads was required. It is difficult to control the array of polystyrene beads on silicon substrate. In this study, we investigated the condition of selective array of polystyrene beads on nanometer-scaled hydrophilic surface which was obtained by APS coating. A tilting method was used to array the polystyrene beads selectively on the substrate. The polystyrene beads could be arrayed selectively by this method. From these results, we verified that there are possibilities to fabricate unique tools for the nanometer-scaled electrical devices.

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난류교반되는 오일/오일 분산계의 평균입자경 예측 (Predictionof Average Drop Size in Turbulently Agitated Oil-in-Oil Dispersions)

  • 이성재
    • 유변학
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    • 제10권1호
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    • pp.1-6
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    • 1998
  • 액체와 액체를 교반할 경우 혹은 두가지 이상의 상이 함께 반응하는 화학공정의 경 우에서는 비상용성인 액체들을 난류조건하에 분산시켜 섞이게 한다. 부산계로 구성된 중합 반응기의 경우 분산입자의 크기는 최종제품의 생산성 및 품질에 큰 영향을 미치게 되므로 분산입자의 크기를 예측하는 것은 대단히 중요하다. 이러한 분산계에서 분산입자의 크기는 분산입자가 겪는 유동장에 의해 결정된다. 오일/오일 분산계로 이루어진 고분자 유탁액의 난류교반시 유동장은 종종 점성전단 부영역에 속하게 되는데 이경우의 분산입자의 크기를 예측하는 모델에 대한 연구는 별로 이루어지지않았다. 본연구에서는 오일/오일 분산계의 고 분자 유탁액에 대한 분산입자의 크기를 예측하는 모델식을 유체동력학적인 이론을 배경으로 하여 개발하였다. 개발한 모델식을 난류교반을 겪은 오일/오일 분산계를 거쳐 생산된 제품 인 내충격성 폴리스티렌으로 검증하여 모델식의 타당성을 입증하였다.

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사출성형 조건이 디스크의 복굴절에 미치는 영향 (Influences of Injection Molding Conditions on the Birefringence of a Disk)

  • 박민규;이동호;이호상
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 추계학술대회 논문집
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    • pp.305-309
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    • 2005
  • A computer code was developed to simulate all three stages of the injection molding process ? filling, packing and cooling by finite element method. The constitutive equation used here was compressible Leonov model. The PVT relationship was assumed to follow the Tait equation. The flow-induced birefringence was related to the calculated flow stresses through the linear stress-optical law. Based on the simulation, the Taguchi method was used to investigate the influences of injection molding conditions on the birefringence of a center gate disk. In addition, the optimal processing conditions were selected to minimize the birefringence and the birefringence difference along the positions of the disk.

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사출성형 공정에서 고화층이 캐비티 압력에 미치는 영향 (Frozen Layer Effect on Internal Cavity Pressure during Injection Molding)

  • 이호상
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 추계학술대회 논문집
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    • pp.474-479
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    • 2005
  • Experimental and theoretical studies of internal cavity pressure during injection molding of a spiral tube cavity were carried out. The frozen layer thickness and the evolution of internal cavity pressure were calculated using a commercial software (C-MOLD). The evolution of the internal cavity pressure was recorded during injection molding of polystyrene into a spiral tube mold. To explain the differences observed between the calculated and measured internal cavity pressure, a pressure correction factor (PCF) was introduced based on the plane stress theory. This factor was determined by analyzing the stress state in the melt and calculating the frozen layer thickness near the mold wall. The corrected and experimental pressures have been compared to validate the applicability of the pressure correction factor.

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폴리스티렌 라텍스 제조에 있어서 Triton X-100/SDS 계면활성제 혼합이 단량체/수용액 간의 계면물성 및 라텍스의 특성에 미치는 영향 (The Effects of Interfacial Properties of the Styrene/Water on the Styrene Latex Particle Properties using Triton X-100/SDS Surfactant Mixture)

  • 박아름이;김영호
    • 한국응용과학기술학회지
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    • 제27권3호
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    • pp.240-248
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    • 2010
  • The blending effects of surfactants on the polystyrene emulsion polymerization were studied. The blending of Triton X-100 and SDS affects to the interfacial properties of the styrene monomer and water phases, and finally, the properties of the polystyrene latex particles. As the blending ratio of SDS/Triton X-100 increases, the interfacial tension and CMC of the blended surfactants were decreased and results in a reducing the size of the latex particles. It was found that the interfacial tension was reduced when the surfactant were blended. By increasing the SDS content, the interfacial tension was reduced, and, at a certain condition, the interfacial tension was reached to an extremely low value to form micro-emulsion and the nano-sized latex particles (80~110 nm).

알루미늄 호일 부착 발포 폴리스티렌 단열재의 열전도율, 열방출시험 및 가스 유해성 시험 (Heat Transfer Coefficient, Heat Release and Gas Hazard Tests for Expanded Polystyrene Heat Insulating Materials with Aluminum Foil)

  • 공하성
    • 대한안전경영과학회지
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    • 제20권4호
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    • pp.15-19
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    • 2018
  • The purpose of this study is to enhance heat insulation effect and to decrease fire hazard by attaching aluminum foil to expanded polystyrene, which is mainly used for insulating materials, to have fire retardant. The result of the test confirmed that the insulating materials, expanded polystyrene of $10kg/m^3$ and $14kg/m^3$ of density attached aluminum foil on both sides, showed 12%, 14% of improved heat transfer coefficient respectively compared to existing expanded polystyrene of the same density. Besides, they met all the standards for the testing of heat release and gas hazard. On the other hand, the one made of general expanded polystyrene could not meet the standards of the heat release test and the gas hazard test.

EPS Bead 혼입비율에 따른 CLC의 단열특성 (Insulation Properties of CLC according to Mixing Ratio of EPS Bead)

  • 이정택;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
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    • pp.45-46
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    • 2023
  • CLC is used as a filling material for many buildings, and according to energy saving design standards, CLC also requires insulation performance. However, it shows lower insulation performance compared to organic insulation, so additional research is needed. Therefore, in this study, the insulation properties of CLC were analyzed by incorporating EPS beads with high insulation performance into CLC. In this experiment, EPS beads and blast furnace slag were replaced, and W/B was fixed at 33%. The EPS Bead mixing ratio was divided into 5 levels: 0, 0.5, 1.0, 1.5, 2.0 (%), and the experimental items were measured for apparent density and thermal conductivity. As a result of the experiment, the apparent density and thermal conductivity tended to decrease as the mixing ratio of EPS beads increased. It is judged that the density decreased due to the low density and the micropores inside, and the thermal conductivity also decreased.

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Investigation of Heavy Metal Migration from Food Contact Materials used for Food Delivery Using an Inductively Coupled Plasma-Mass Spectrometer

  • Chae-Yeon Hwang;Young-Jun Kim
    • 한국식품위생안전성학회지
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    • 제38권2호
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    • pp.37-45
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    • 2023
  • 국내 유통되고 있는 배달식품용 폴리프로필렌, 폴리에틸렌 및 폴리스티렌 기구류가 안전하게 관리되고 있는지 파악하기 위해 배달식품용 기구류를 수거하여 중금속 이행량(납, 카드뮴 및 비소)을 조사하였다. 모니터링에 사용된 시료는 용기, 뚜껑, 컵, 테이블용 기구, 파우치, 포장재로 총 6개의 품목으로 구성되어 있으며, 폴리프로필렌 51건, 폴리에틸렌 21건, 폴리스티렌 32건으로 총 104건이었다. 「식품용 기구 및 용기·포장 공전」의 시험법에 따라 식품모사용매로는 4% acetic acid를 사용하였고, 총 104건의 시료를 가혹조건인 100℃로 통일하여 용출한 것을 시험용액으로 하여 ICP-MS를 이용하여 납, 카드뮴 및 비소를 분석하였다. 납, 카드뮴 및 비소의 직선성은 결정계수(R2) 값이 0.9999 이상의 우수한 직선성을 보였으며, 납, 카드뮴 및 비소의 검출한계는 각각 0.001 ㎍/L, 0.001 ㎍/L 및 0.001 ㎍/L이었고, 정량한계는 각각 0.002 ㎍/L, 0.003 ㎍/L 및 0.003 ㎍/L로 나타났다. 또한, 정확성 및 정밀성은 JRC 가이드라인에서 제시하고 있는 기준을 만족하였다. 중금속 이행량 결과를 살펴보면, 총 104건의 시료에서 검출된 납, 카드뮴 및 비소의 이행량은 평균 0.009-0.260 ㎍/L로 「식품용 기구 및 용기·포장 공전」에서 설정된 용출규격인 1,000 ㎍/L 대비 매우 낮은 수준이었고, 기준·규격을 초과하는 시료는 없었다. 이를 통하여 현재 유통되고 있는 배달식품용 폴리프로필렌, 폴리에틸렌 및 폴리스티렌 기구류의 중금속 함량이 안전한 수준으로 관리되고 있음을 확인하였다. 본 연구 결과는 배달식품용 기구류의 중금속 이행량 관리에 대한 과학적 기초자료로 활용될 수 있을 것으로 사료된다.