• Title/Summary/Keyword: 폴리머 바인더

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Evaluation of Healing Properties of Asphalt Mixtures (아스팔트 혼합물의 손상회복 특성 평가)

  • Kim, Boo-Il
    • International Journal of Highway Engineering
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    • v.7 no.2 s.24
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    • pp.69-76
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    • 2005
  • While the repeated traffic loading accumulates the damage of asphalt pavement, the damage has being healed during rest periods. And then, this healing enhances the fatigue life of asphalt pavement. A method was developed to determine the healing rate of asphalt mixture in terms of recovered dissipated creep strain energy (DCSE) per unit time, and the healing properties of four different asphalt mixtures were evaluated. The test procedure consists of repeated loading test and periodical resilient modulus tests. A normalized healing rate in terms of $DCSE/DCSE_{applied}$ was defined to evaluate the healing properties independently of the amount of damage incurred in the mixture. From the test results, it was concluded that the healing rates of asphalt mixtures were increased exponentially as the temperature was increased and more affected by the structural characteristics of mixture such as asphalt content than the binder characteristics such as the polymer modification.

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Electrochemical Study of Electrode Material of Ni-MH Battery for HEV and PEMFC Fuel Cell (HEV 및 PEMFC 연료전지용 니켈수소 전지의 전극재료에 대한 전기화학적 평가)

  • Kim, Ho-Sung
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.2
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    • pp.24-28
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    • 2006
  • Electrochemical hydrogenation/dehydrogenation properties were studied for a single particle of a Mm-based(Mm : misch metal) hydrogen storage alloy($MmNi_{3.55}Co_{0.75}Mn_{0.4}Al_{0.3}$) for the anode of Ni-MH batteries. A carbon fiber microelectrode was manipulated to make electrical contact with an alloy particle, and the cyclic voltammetry and the galvanostatic charge/discharge experiments were performed. A single particle of the alloy showed the discharge capacity of 280[mAh/g], the value being 90[%] of the theoretical capacity. Data were compared with that of the composite film consisting of the alloy particles and a polymer binder, which is more practical form for Ni-MH batteries. Additionally, pulverization of the alloy particles are directly observed. Compared with the conventional composite film electrodes, the single particle measurements using the microelectrode gave more detailed, true information about the hydrogen storage alloy.

Development of Pressure Sensitive Paint(PSP) technique for low-speed flows and its application (아음속 저속 유동용 Pressure Sensitive Paint의 개발과 응용)

  • Kang, Jong-Hoon;Lee, Sang-Joon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.4
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    • pp.12-17
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    • 2004
  • The PSP technique has been used to measure pressure distribution on model surfaces ins high-speed flows. The objective of this study is to develop a PSP technique which can be applied to low-speed aerodynamic flows. Four different PSP formulations including two porphyrins (PtOEP and PtTFPP) and two polymers (Poly(TMSP) and RTV-118) were tested and the performance of each combination was evaluated. In a static calibration, the luminescent intensity of the PSP coatings was measured from 0kPa to 11kPa with 0.5, 1, 2kPa increments. Among 4 PSP formulations tested, the combination of PtOEP and RTV-118 shows the best performance. The developed PSP technique was applied to an oblique impinging jet to measure the pressure field distribution on the impinging plate.

Applicability of Color Bituminous Mixtures for Highway Pavement (차도용 칼라 역청 혼합물의 적용성 연구)

  • Doh, Y.S.;Oh, S.K.;Choi, Y.K.;Kim, K.W.
    • International Journal of Highway Engineering
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    • v.6 no.4 s.22
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    • pp.91-100
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    • 2004
  • This study was Performed to evaluate applicability of color flexible pavement concrete (CFPC) for motorway pavement. Color flexible pavement has been applied to non-motorway pavements, such as pedestrian and bicycle road. Two polymers were used to modify the binder and to strengthen the stiffness of pavement mixture. Waste paper was used to prevent the asphalt of gap-grade mixture from draining. Marshall properties, indirect tensile strength(ITS), tensile strength ratio(TSR) before and after freezing-and-thawing treatment and artificial aging, permanent deformation and fatigue life were measured. Color bituminous concrete mixtures used this study had nearly the same quality in mechanical properties when compared with conventional asphalt concrete mixtures manufactured with AP-3 and all mixtures satisfied with domestic specification for motorway pavement. Therefore, it is proved that the color bituminous concrete used this study can be applied for motorway pavement.

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Assessment of Adhesion and Frictional Properties of Polymer Binders for Secondary Cells using Colloidal Probe Atomic Force Microscope (Colloidal Probe 원자현미경을 이용한 2차전지 전극용 폴리머 바인더의 응착 및 마찰 특성 평가)

  • Nguyen, Quang Dang;Chung, Koo-Hyun
    • Tribology and Lubricants
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    • v.35 no.3
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    • pp.169-175
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    • 2019
  • In lithium-ion batteries (LIBs), the stress induced by the volume change of an electrode during charge-discharge processes may often cause the mechanical integrity of the electrode to degrade. Polymer binders with enhanced mechanical properties are preferred for improved mechanical integrity and cycling stability of the electrode. In addition, given that sliding and shearing between the polymer binder and components in the electrode may readily occur, frictional and adhesion characteristics of the polymer binder may play a critical role in the mechanical integrity of the electrode. In this study, frictional and adhesion characteristics of polyacrylonitrile (PAN) and polyvinylidene fluoride (PVDF) were investigated using a colloidal probe atomic force microscope. Friction loops were obtained under various normal forces ranging from 0 to 159 nN in air and electrolyte and then the interfacial shear strengths of PAN and PVDF in air were calculated to be $1.4{\pm}0.5$ and $1.3{\pm}0.3MPa$, respectively. The results show that in electrolyte, interfacial shear strength of PAN decreased slightly ($1.2{\pm}0.2MPa$), whereas that of PVDF decreased drastically ($0.06{\pm}0.01MPa$). Decreases in mechanical properties and adhesion in electrolyte may be responsible for the decrease in interfacial shear strength in electrolyte. The findings from this study may be helpful in developing polymer binders to improve the mechanical integrity of electrodes in LIBs.

Examination of Color Difference in Elastic Pavement that uses EPDM Chip using Ultraviolet Ray Accelerated Weathering Test (자외선 촉진 내후성 시험에 의한 EPDM Chip을 사용한 탄성포장의 색차분석)

  • Hong, Chang Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.1D
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    • pp.91-98
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    • 2011
  • Recently, the usage of elastic paving using EPDM Chip instead of pedestrian sidewalk blocks or permeable concrete used mostly for pedestrian walk, trails and in parks has been increassed as it can absorb impact during walking and produce wide range of colors and designs. However, the properties of EPDM Chip including elasticity and durability are decreased when exposed to ultraviolet ray and scenic paving functions through various colors are lowered due to the yellowing phenomenon. In this study, ultraviolet ray accelerated weathering test has been conducted to analyze the color changes in EPDM Chip and polyurethane resin, which are the main ingredients of elastic paving, when exposed to ultraviolet ray. The color differences are quantitatively analyzed through the color value coordination of the colored space by using the color difference scheme. The experimental results show that the color changes in BL polyurethane resin which is used most frequently at present was larger than that of EPDM Chip. Moreover, the total color difference, ${\Delta}E$, of BC polyurethane resin are 3.162 on the $14^{th}$ day of commencement of acceleration, which is 6 times greater color change resistance against ultraviolet ray than that of BL polyurethane resin with total color difference of 20.639. Therefore, the usage of BC polyurethane resin, which is manufactured to have chain-type molecular structure by using the isocyanate as the HMDI at the time of producing polymer, as binder in elastic paving with EPDM Chip is found to be a highly efficient method of restraining the color changes due to the ultraviolet ray.

The Characterization of Controlled Low Strength Material (CLSM) Using High CaO Fly Ash without Chemical Alkaline Activator (고칼슘 플라이애쉬를 이용한 알칼리 활성화제 무첨가 저강도 유동화 채움재 특성 평가)

  • Lim, Sanghyeong;Choo, Hyunwook;Lee, Woojin;Lee, Changho
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.12
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    • pp.17-26
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    • 2016
  • The experimental investigation aims at developing controlled low strength materials (CLSM) using a self-cementitious fly ash (FA) as a binder and a bottom ash (BA) as a aggregate. The fly ash and bottom ash used in this study were obtained from a circulating fluidized bed combustion boiler (CFBC) which produces relatively high CaO containing fly ash. To find the optimum mixing condition satisfying flow consistency and unconfined compression strength (UCS), the CLSM specimens were prepared under various mixing conditions, including two types of aggregate and different weight fractions between fly ash and aggregate. Additionally, the prepared specimens were evaluated using a scanning electron microscope (SEM) and X-ray diffraction (XRD). The results of this study demonstrate that the water content satisfying flow consistency ranges from 42% to 85% and the flowability is improved with increasing the fraction of aggregate in whole mixture. The USC ranges from 0.3 MPa to 1.9 MPa. The results of UCS increases with increasing the fraction of aggregate in FA-sand mixtures, but decreases with increasing the fraction of aggregate in FA-BA mixtures. SEM images and XRD patterns reveal that the occurrence of both geopolymerization and hydration. The results of this study demonstrate that CFBC fly ash could be used as an alternative binder of CLSM mixtures.

Synthesis and Characterization of Composite Paper Using Polyamide Fiber and Surface Modified Microfibrillated Cellulose (표면 개질된 마이크로피브릴화 셀룰로오스를 이용한 폴리아마이드 섬유와의 복합페이퍼 제조 및 특성평가)

  • Lee, Jong-Hee;Lim, Jung-Hyurk;Kim, Ki-Young;Kim, Kyung-Min
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.74-79
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    • 2014
  • Microfibrillated cellulose (MFC) was chemically modified with two different silane coupling agents (3-aminopropyltriethoxysilane and 3-mercaptopropyltriethoxysilane) and lauroyl chloride. The surface modification of MFC was confirmed by infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX), and contact angle measurements. Composite paper was successfully prepared with surface modified MFC and polyamide (PA) fiber. The surface modification of MFC not only prevented aggregation of MFC but also improved adhesive property between PA fiber and surface modified MFC. It was impossible to prepare papers of only PA fiber because there is no binder to connect PA fibers. That is, surface modified MFC as a binder in PA fiber played a crucial role in making composite paper. Composite paper with silane modified MFC showed higher tensile strength and modulus than composite paper with lauroyl moiety modified MFC. The structure, morphology, and mechanical properties of composite paper were analyzed by scanning electron microscope (SEM) and universal testing machine (UTM).