• Journal of the Korean Society of Safety
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• v.25 no.3
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• pp.53-60
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• 2010

LPG(Liquefied Petroleum Gas) vehicles in metropolitan area are being applied to improve air quality and have been proven effective for the reduction of air pollutant. In addition, LPG demand is growing rapidly as an environmentally friendly energy source and its gas station is also increasing every year. Consequently, this study tries to find out the influence of flame caused by the VCE(Vapor Cloud Explosion) in filling station on the adjacent combustibles and people by simulating relevant quantity of TNT. In addition, the damage estimation was conducted by using API regulations. If the scale of the radiation heat is known by calculating the distance of flame influence from the explosion site, the damage from the site can be easily estimated. And the accident damage was estimated by applying the influence on the adjacent structures and people into the PROBIT model. According to the probit analyze, the spot which is 30m away from the flame has 100% of the damage probability by the first-degree burn, 99.2% of the damage probability by the second-degree burn and 93.4% of the death probability by the fire.

• Journal of Korean Society of Disaster and Security
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• v.10 no.2
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• pp.29-34
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• 2017

LPG is a substance that requires a lot of attention because it can cause fatal damage to people and environment when an accident occurs. LPG is frequently accidents in transportation facilities as well as fixed facilities, among which LPG tank lorries are the most frequent accidents. When the LPG tank is evacuated, the LP gas leaks into two phases, leaks mostly to the gas and leaks to some liquid. At this time, the leaked gas will also sink downward because it is heavier than air, and if it continues to leak, it may form an explosion and explode by the ignition source. The purpose of this study is to present the evacuation distance by analyzing the effect distance of the LPG liquefied petroleum gas in the event of explosion. As a result of calculation of the scattering radius of the fragment, the cylinder fragment was scattered up to 561 m. Therefore, it is appropriate to set the distance to be escaped when the LPG tanker leaks to 561m or more.

• Journal of the Korean Institute of Gas
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• v.2 no.3
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• pp.25-36
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• 1998

Explosion and fires can occur in all segments of chemical and petroleum industries because of complexity of process, usage and storage of flammable and reactive chemicals, and operating conditions of high pressure and temperatures. Especially chemical plants have high possibility of the occurrence of BLEVE(Boiling Liquid Expanding Vapor Explosion)and Fireball. In this study, a computer program was developed for the effect assessment of BLEVE and Fireball. BLEVE was analysed by three explosion models of physical explosion model, isothermal expansion model and adiabatic expansion model and Fireball using solid model. The parametric sensitivity analysis has been done for the models of BLEVE and Fireball. The damage by BLEVE and Fireball of Benzene and Toluene and m-Xylene were estimated.

• Journal of the Korean Institute of Gas
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• v.25 no.1
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• pp.40-47
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• 2021

In this study, hazards of decomposition and explosion for tert-butylperoxymaleate(TBPM), an organic peroxide, were evaluated by using various equipment to determine the cause of a fire explosion accident. As a result of DSC analysis, the instantaneous power density of TBPM was 26,401 kW/ml, and the NFPA reactive index(Nr) was classified as 4. And the positive value of EP(explosive propagation) and SS(shock sensitivity) showed that the TBPM had a potential hazard of explosion. From the experimental results, the shock sensitivity and friction sensitivity was rated as class 4 and 5, respectively. In the pressure vessel test, TBPM was ranked USA-PVT No.4 and evaluated as a self-reactive substance. In the combustion rate test, TBPM had the combustion rate of 167 mm/sec and was evaluated as the flammable solid classification 2 in GHS.

• Journal of the Korean Institute of Gas
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• v.26 no.5
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• pp.22-27
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• 2022

Atomic Layer Deposition (ALD) is a facility that deposits an atomic layer on a wafer by causing a chemical reaction after decomposition using heat or plasma by inputting two or more gases during the semiconductor process. The main gas used at this time is NH₃ (Ammonia). NH₃ has a relatively narrow explosive range with an upper limit (UFL) of 33.6% and a lower limit (LEL) of 15%, but it can explode if a large amount suddenly gathers in one place. It is Velocity and fatal if inhaled or in contact with the skin. NH₃ (Ammonia) of ALD (Atomic Layer Deposition) facility is supplied to the chamber through the gas inlet and discharged after the reaction.

• Journal of the Korean Institute of Gas
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• v.20 no.4
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• pp.15-24
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• 2016

In the semiconductor industry, the risk of chemical accidents due to miscibility between the many types of chemicals and leakage of toxic chemicals has increased. In order to evaluate the reactivity with miscibility of chemicals, experimental method is the most reliable, but there is a time and cost limitations to be evaluated through experiment all the chemicals. In the study, the reactivity of process gases in the semiconductor industry was considered by the CRW (Chemical Reactivity Worksheets) 3.0 program developed by US NOAA (National Oceanic and Atmospheric Administration) and EPA. The reactivity informations with the miscibility of process gases for semiconductor industry provided, and also a KOSHA guide for the storage/separation of gas cylinders in dispensing cabinets in the semiconductor industry was proposed.

• Journal of the Korean Institute of Gas
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• v.16 no.6
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• pp.87-101
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• 2012

In gas industries, the potential risks of serious accidents have been increased due to high technology application and process complexities. Especially, in case of gas-related accidents, the extent of demage is out of control since gas plants handle and produce combustible, flammable, explosive and toxic materials in large amounts. The characteristics of this kind of disaster is that accident frequency is low, while the impact of damage is high, extending to the neighboring residents, environment and related industries as well as employees involved. The hydrogen gases treated important things and it used the basic material of chemical plants and industries. Since 2000, this gas stood in the spotlight the substitution energy for reduction of the global warming in particular however it need to compress high pressure(more than 150 bar.g) and store by using the special cylinders due to their low molecular weight. And this gas led to many times the fire and explosion due to leak of it. To reduce these kinds of risks and accidents, it is necessary to improve the new safety management system through a risk management after technically evaluating potential hazards in this process. This study is to carry out the quantitative risk assesment for hydrogen filling plant which are very dangerous(fire and explosive) and using a basic materials of general industries. As a results of this risk assessment, identified the elements important for safety(EIS) and suggested the practical management tools and verified the reliability of this risk assessment model through case study of accident.

• Journal of the Geological Society of Korea
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• v.54 no.5
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• pp.513-527
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• 2018

We have carried out granulometry and component analysis on pyroclastic deposits of the Maljandeung Tuff, Ulleung Island, to interpret the eruption types and prime dynamic mechanisms. It is divided into three members in the extracaldera area, each of which comprises the lithofacies of coarse tuffs and lapillistones in the lower part, and pumice deposits in upper one. The lithofacies present quantitative evidences in the granularity and component distribution patterns. As compared to the pumice deposits, the coarse tuffs and lapillistones exhibit a relative increase in both the lithic/juvenile and the crystal/juvenile ratios, and a preferential fragmentation of the juvenile fraction. The abundance of lithics and crystals in the tuffs and lapillistones can be attributed to preferential fragmentation of the aquifer-hosting rocks due to explosive evaporation of ground water, and indirect enrichment in lithics and crystals due to removal of juvenile fines from eruptive cloud. The above data exhibit that early phreatopmagmatic phase was followed by purely magmatic fragmentation phases. The coarse tuffs and lapillistones suggest phreatoplinian eruption derived from explosive interaction of magma with ground water near the conduit, while pumice deposits indicate magmatic eruption by magmatic explosion from juvenile gas pressure. In early stage, phreatoplinian eruption occurred from explosive magma/water interaction in connecting confining water with drawdown of the magma column in the conduit; Later it shifted to plinian eruption by explosive expansion of only magmatic volatiles in intercepting water influx due to higher magmatic gas pressure than confining water pressure with rising of the magma column in the conduit.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.17-24
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• 2019

The combustion properties of the flammable substance used in industrial fields include lower/upper flash point, lower/upper explosion limit, autoignition temperature(AIT), fire point, and minimum oxygen concentration(MOC) etc.. The accurate assessment of these characteristics should be made for process and worker safety. In this study, tert-amylalcohol(TAA), which is widely used as a solvent for epoxy resins, oxidizers of olefins, fuel oils and biomass, was selected. The reason is that there are few researches on the reliability of combustion characteristics compared to other flammable materials. The flash point of the TAA was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of the TAA was measured by ASTM 659E. The lower/upper explosion limits of the TAA was estimated using the measured lower/upper flash points by Setaflash tester. The flash point of the TAA by using Setaflash and Pensky-Martens closed-cup testers were experimented at 19 ℃ and 21 ℃, respectively. The flash points of the TAA by Tag and Cleveland open cup testers were experimented at 28 ℃ and 34 ℃, respectively. The AIT of the TAA was experimented at 437 ℃. The LEL and UEL calculated by using lower and upper flash point of Setaflash were calculated at 1.10 vol% and 11.95 vol%, respectively.

• Journal of the Korean Chemical Society
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• v.66 no.3
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• pp.185-193
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• 2022

The theoretical investigation has been performed to predict thermodynamic stability, density, detonation velocity, and detonation pressure of energetic salts produced by pairing of nitrogen-rich anions (tetrazine, oxadiazole etc.) and cations (NH₃OH⁺, NH₂NH₃⁺, CH₉N₆⁺, C₂H₆N₅⁺). All possible geometries and the binding energy for the trigger bond of energetic salts have been optimized at the B3LYP/cc-pVDZ level of theory. The detonation velocity and detonation pressure have been calculated using Kamlet-Jacobs equation, while enthalpy has been predicted at the G2MP2 level of theory. The predicted results reveal that the energetic salts including small sized NH₃OH⁺(1) and NH₂NH₃⁺(2) cations increase detonation property. And also the energetic salts including more amino group (-NH₂) such as CH₉N₆⁺(3) cation increase thermodynamic stability. These results provide basic information for the development the high energy density materials (HEDMs).