• Title/Summary/Keyword: 폐자원 에너지화

Search Result 48, Processing Time 0.021 seconds

Adsorption/Desorption Characteristics of Vanadium from Ammonium Metavanadate using Anion Exchange Resin (음(陰)이온교환수지(交換樹脂)를 이용한 Ammonium Metavanadate로부터 바나듐 흡탈착(吸脫着) 특성(特性))

  • Jeon, Jong Hyuk;Kim, Young Hun;Hwang, In Sung;Lee, Jin Young;Kim, Joon Soo;Han, Choon
    • Resources Recycling
    • /
    • v.22 no.1
    • /
    • pp.55-63
    • /
    • 2013
  • Considering considerable contents of vanadium and tungsten in spent SCR DeNOx catalysts, separation and recovery of those metals are required. In this respect, commercial anion exchange resin (MP600) was employed to recover vanadium from the synthetic solution of ammonium metavanadate. Experimental results indicated that vanadium exist as anion under the acidic condition (pH 2 ~ 6) and adsorbed on the resin. Although the adsorption rate was increased with temperature, the maximum amount of adsorption was not affected by temperature. Desorption took place under either strong acidic (less than pH 1) or strong caustic (higher than pH 13) condition. However, desorption seldom took place under moderate conditions (pH 3~11). Furthermore, adsorption equilibrium results agreed well with Freundlich isotherm and pseudo-second-order reactions. And, adsorption energy was evaluated using Dubinin-Radushkevich and Temkin isotherm.

SRF Conversion Potential of Biomass and Mixed Plastic Waste Generated in D City (D시 내에서 발생하는 바이오매스 및 폐플라스틱 혼합 폐기물의 SRF 전환 포텐셜 분석)

  • Yang, Han-Sol;Kim, Ki-Kwang;Lim, Chae-Wook;Hyun, Jae-Hyuk
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.26 no.3
    • /
    • pp.55-61
    • /
    • 2018
  • This study evaluated if the selected samples meets the Solid Refuse Fuel quality criteria in Korea. Biomass and plastic wastes generated in D City were mixed in diverse ratio. When the biomass content was about 40%, the moisture content was close to the SRF criteria and was measured to be 9.8%. The ash contents were analyzed up to 4.19%, and the lower calorific values based on Steuer, Dulong Equation and Bomb Calorimeter were at least 4,851, 4,181 and 3,847 kcal/kg, respectively. As a result of the elemental analysis, sulfur and chloride content were measured up to 0.05%. Those values satisfied the SRF criteria. Also, heavy metals(Hg, Cd, Pb, As) were analyzed to be below the SRF criteria. This makes it possible to use efficiently the wood byproducts abandoned in the woods, and the physical properties of wood being weak to moisture can be supplemented with plastics. Consequently, if plastic and biomass were well mixed and made into SRF, it would overcome the problem of shortening the life span of incineration facilities due to the high temperature of plastic wastes in the incinerator.

A Study on Combustion and Emission Characteristics of a Diesel Engine Fuelled with Pyrolysis Oil-Ethanol and Pilot Diesel (바이오원유-에탄올/파일럿 디젤유 이종연료 혼소를 통한 디젤엔진의 연소 및 배출가스 특성에 관한 연구)

  • Kim, Min-Jae;Lee, Seok-Hwan;Cho, Jeong-Kwon;Yoon, Jun-Kyu;Lim, Jong-Han
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.18 no.5
    • /
    • pp.420-427
    • /
    • 2017
  • Recently, the depletion of fossil fuels, global warming and environmental pollution have emerged as a worldwide problem, and studies of new renewable energy sources have been progressed. Among the many renewable energy sources, the use of bio fuel has the potential to displace fossil fuels due to low price, easy to handle, and the abundant sources. Pyrolysis oil (PO) derived from waste wood and sawdust is considered an alternative fuel for use in diesel engines. On the other hand, PO is limited to diesel engines because of its low cetane number, high viscosity, high acidity, and low energy density. Therefore, to improve its poor properties, PO was mixed with alcohol fuels, such as ethanol. Early mixing with ethanol has the benefit of improving the storage and handling properties of the PO. Furthermore, a PO-ethanol blended fuel was injected separately, which can be fired through pilot-injected diesel in a dual-injection diesel engine. The experimental results showed that the substitution of diesel with blended fuel increases the amount of HC and CO, but reduces the NOx and PM significantly.

Nanoscale Pattern Formation of Li2CO3 for Lithium-Ion Battery Anode Material by Pattern Transfer Printing (패턴전사 프린팅을 활용한 리튬이온 배터리 양극 기초소재 Li2CO3의 나노스케일 패턴화 방법)

  • Kang, Young Lim;Park, Tae Wan;Park, Eun-Soo;Lee, Junghoon;Wang, Jei-Pil;Park, Woon Ik
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.27 no.4
    • /
    • pp.83-89
    • /
    • 2020
  • For the past few decades, as part of efforts to protect the environment where fossil fuels, which have been a key energy resource for mankind, are becoming increasingly depleted and pollution due to industrial development, ecofriendly secondary batteries, hydrogen generating energy devices, energy storage systems, and many other new energy technologies are being developed. Among them, the lithium-ion battery (LIB) is considered to be a next-generation energy device suitable for application as a large-capacity battery and capable of industrial application due to its high energy density and long lifespan. However, considering the growing battery market such as eco-friendly electric vehicles and drones, it is expected that a large amount of battery waste will spill out from some point due to the end of life. In order to prepare for this situation, development of a process for recovering lithium and various valuable metals from waste batteries is required, and at the same time, a plan to recycle them is socially required. In this study, we introduce a nanoscale pattern transfer printing (NTP) process of Li2CO3, a representative anode material for lithium ion batteries, one of the strategic materials for recycling waste batteries. First, Li2CO3 powder was formed by pressing in a vacuum, and a 3-inch sputter target for very pure Li2CO3 thin film deposition was successfully produced through high-temperature sintering. The target was mounted on a sputtering device, and a well-ordered Li2CO3 line pattern with a width of 250 nm was successfully obtained on the Si substrate using the NTP process. In addition, based on the nTP method, the periodic Li2CO3 line patterns were formed on the surfaces of metal, glass, flexible polymer substrates, and even curved goggles. These results are expected to be applied to the thin films of various functional materials used in battery devices in the future, and is also expected to be particularly helpful in improving the performance of lithium-ion battery devices on various substrates.

An Analysis on Punching Shear of Two-way Void Slab (이방향 중공슬래브-기둥 접합부 뚫림전단성능의 해석적 평가)

  • Lee, Yung Eun;Ryu, Jaeho;Ju, Young Kyu;Kim, Sang Dae
    • 한국방재학회:학술대회논문집
    • /
    • 2011.02a
    • /
    • pp.32-32
    • /
    • 2011
  • 최근 국내외에서 친환경건축물에 관한 관심이 매우 높아짐으로 인해 콘크리트의 물량을 절감하여 이산화탄소량을 줄이는 중공슬래브는 다양한 형태로 세계적으로 개발이 되고 있는 추세이다. 특히 이방향 중공슬래브는 환경적인 측면에서 이방향 중공슬래브는 중공부 생성에 재생플라스틱을 활용하여 폐자원을 재사용하고, 콘크리트와 철근의 사용량 절감에 따른 화석에너지 및 이산화탄소 발생량을 감소한다는 장점이 있다. 또한 시스템 측면에서 이방향 중공슬래브는 기존의 철근콘크리트 플랫플레이트 바닥구조 시스템의 자중을 절감하여 구조체를 경량화 시키고, 이에 따라 장스팬 구현이 가능하며, 단열효과가 뛰어나다. 이와 같이 이방향 중공슬래브는 장점이 많지만 플랫플레이트 슬래브의 취약점인 뚫림전단 파괴에 주의해야 한다. 이에 본 연구에서는 선행으로 실시된 이방향 중공슬래브-기둥 접합부 뚫림전단 성능평가 실험을 바탕으로 하여 경량체가 이방향 중공슬래브-기둥 접합부 뚫림전단 성능에 미치는 영향을 살펴보기 위해 범용 유한요소해석 프로그램인 ABAQUS를 사용하여 경량체량 및 위치를 주요변수로 한 해석적인 변화를 검토하였다. 본 연구를 통해 경량체가 삽입된 이방향 중공슬래브의 뚫림전단 성능에 대해, 해석결과 경량체 량과 위치에 따라 최대 뚫림전단강도는 기준 실험체에 비해 74.3%, 73%의 강도저하를 나타내는 것으로 알 수 있었다. 이는 실험상의 강도저하 값인 84.1%, 56.4%와 다소 차이가 있으며, 해석에서 중공부 주위의 응력집중 현상이 제대로 반영되지 않은 것으로 판단된다. 또한 이방향 슬래브에 경량체를 삽입 할 경우 경량체가 시작하는 부분에서 응력이 급격히 감소하는 현상이 나타났으며, 이러한 급격한 응력감소는 기둥 주위 위험단면의 변화를 가져오는 것으로 추정된다. 즉, 위험단면의 변화는 기둥으로부터 경량체 사이의 거리에 따라 달라지며, 위험단면 내의 콘크리트 단면 손실은 뚫림전단 강도를 감소시킨다. 본 연구에서는 이방향 중공슬래브의 뚫림전단강도를 산정할 수 있는 근사식을 제안하였으며, 보다 정확한 이방향 중공슬래브의 뚫림전단강도의 산정식을 위해서는 위험단면의 변화와 콘크리트 단면손실로 인한 전단강도 저하의 관계에 대한 추가적인 연구가 필요하다.

  • PDF

Long-Term Performance Evaluation on the Recycled Asphalt Concrete Using the Steel Slag and Reclaimed Asphalt Pavement Aggregates (제강 슬래그 및 순환골재를 사용한 순환 아스팔트 혼합물의 장기 공용성 평가)

  • Park, Kyung-Won;Jang, Dong-Bok;Lee, Jong-Min;Kang, Byung-Hwa;Kim, Hyung-Bae
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.9 no.4
    • /
    • pp.633-641
    • /
    • 2021
  • The study performed long-term performacne evaluation on the hot mix asphalt using the steel slag aggregates and Reclaimed Asphalt Pavement (RAP). The laboratory comparative evaluation was conducted between conventional Hot Mix Asphalt (HMA) which is entitled WC-2 and HMA containing steel slag and RAP which is entitled ES WC-2(R). Dynamic stability test, dynamic modulus test, and fatigue crack test were conducted during the comparative evaluation process. The dynamic stability test result showed that ES WC-2(R) was 140% higher than WC-2. It is noted that ES WC-2(R) showed no inflection point whereas WC-2 showed inflection point during the dynamic stability test which implies ES WC-2(R) has the higher moisture susceptability than WC-2. The dynamic modulus of ES WC-2(R) were 342.3%, 486.7%, and 350.0% higher than WC-2 at medium temperature of 21℃, low temperature of -10℃, and high temperature of 38℃ respectively. The test result showed that rutting resistance of ES WC-2(R) is higher than WC-2 at all temperature spectrum. The fatigue resistance of ES WC-2(R) were 31.7%, 325.3%, 899.9% higher at low stress level, medium stress level, and high stress level, respectively. The test result showed that ES WC-2(R) is higher than WC-2 at all stress levels. Based on the laboratory comparative evaluation, The in-situ scale Accelerated Pavement Test (APT) was conducted comparing WC-2 and WC-2(R). APT found that the rutting resistance of WC-2(R) was 45% higher than WC-2.

Greenhouse Gas Mitigation Effect Analysis by Cool Biz and Warm Biz (쿨맵시 및 온맵시 복장 착용에 의한 온실가스 감축 효과 분석)

  • Yeo, So-Young;Ryu, Ji-Yeon;Lee, Sue-Been;Kim, Dai-Gon;Hong, Yoo-Deog;Seong, Mi-Ae;Lee, Kyoung-Mi
    • Journal of Climate Change Research
    • /
    • v.2 no.2
    • /
    • pp.93-106
    • /
    • 2011
  • Republic of Korea officially announced its mid term reduction target which reduce about 30% of BAU GHG emission by 2020 in the 15th meeting of UNFCCC(COP 15) held in Copenhagen, Denmark 2009. To achieve this goal, it is necessary to understand the serious of climate change and take part in GHG reduction not only industry but also the nation. However, such positive participation in green life which may cause inconvenient of the life of the people. It should be accomplished with providing reliable information. This study suggests the scientific potentialities of GHG emission by guideline on low carbon life and green life to form and change a lifestyle suitable for coping with climate change. And also, this study quantitate the GHG reduction which may reduce demand for air conditioning by cool biz and warm biz. In Korea, this campaign has become known as 'CoolMaebsi' by Ministry of Environmental of Korea. 'CoolMaebsi' is a compound word of 'Cool' which means feel refreshed, and 'Maebsi' is a Korean word which means attire. Though this campaign is effective and significant to reduce the GHG emission yet there were no study on quantitative analysis. Therefore this study calculated reduced energy consumption and potential GHG emission by measuring variation of skin temperature. As the result, wearing warm biz and cool biz have an effect of reducing not only the energy consumption but also GHG emission. To achieve the low carbon society, it is necessary to improve the energy saving system and introduce the policy which guide to change a life style.

An analysis of the Domestic Interior Materials as the Ecological Design Aspects (친환경측면에서 본 국내 실내건축자재의 현황 조사 및 분석)

  • Chun Jin-Hie;Kim Jung-Ah
    • Archives of design research
    • /
    • v.19 no.4 s.66
    • /
    • pp.133-144
    • /
    • 2006
  • According to the latest report by the Customer Protection Board, those who moved into newly constructed buildings are complaining about unidentified pains, asking for more careful selection of constructive materials for prevention of such potential problems. It is internationally recognized today that ecological materials can serve a significant factor for users' health, environmental protection and better industrial competitiveness. This study examined eco-design aspects of each interior material through web site search, in order to help customers learn about and capitalize on eco materials in a proper manner. As a result, 1. It turned out that the domestic industry are giving an impetus to releasing new eco items focusing on lower VOCs emission or addition of functional components as part of the marketing strategy. However, it is recommended that company understand significance of life cycle, and produce eco-concept materials. 2. The reliable standard for choosing the domestic material is EL, HB, GR marks. It is desirable to enhance recycling technologies and expand the sustainable consumption. customer class, since many recycled items are not developed. 3. The sourcing is a vulnerable part in terms of the concept of being environment-friendly material. Therefore, many manufacturers should design the easy knock-down products and produce the good items using recycled materials instead of new raw materials. Also solutions for making the energy from burning material should be studied. 4. The guidebook or manual with correct information about eco-materials is required to promote production and consumption with sustainable concept. 5. Many manufacturers are emphasizing ecological materials for customers, but some of them intended to disrupt customers' proper selection by promoting even unverified items to be environment-friendly.

  • PDF