• Title/Summary/Keyword: 폐수 처리

Search Result 2,145, Processing Time 0.023 seconds

Characterization of heterotrophic nitrification and aerobic denitrification by Alcaligenes faecalis NS13 (Alcaligenes faecalis NS13에 의한 호기성 종속영양 질산화 및 탈질화)

  • Jung, Taeck-Kyung;Ra, Chang-Six;Joh, Ki-Seong;Song, Hong-Gyu
    • Korean Journal of Microbiology
    • /
    • v.52 no.2
    • /
    • pp.166-174
    • /
    • 2016
  • In order to find an efficient bacterial strain that can carry out nitrification and denitrification simultaneously, we isolated many heterotrophic nitrifying bacteria from wastewater treatment plant. One of isolates NS13 showed high removal rate of ammonium and was identified as Alcaligenes faecalis by analysis of its 16S rDNA sequence, carbon source utilization and fatty acids composition. This bacterium could remove over 99% of ammonium in a heterotrophic medium containing 140 mg/L of ammonium at pH 6-9, $25-37^{\circ}C$ and 0-4% of salt concentrations within 2 days. It showed even higher ammonium removal at higher initial ammonium concentration in the medium. A. faecalis NS13 could also reduce nitrate and nitrous oxide by nitrate reductase and nitrous oxide reductase, respectively, which was confirmed by detection of nitrate reductase gene, napA, and nitrous oxide reducase gene, nosZ, by PCR. One of metabolic intermediate of denitrification, $N_2O$ was detected from headspace of bacterial culture. Based on analysis of all nitrogen compounds in the bacterial culture, 42.8% of initial nitrogen seemed to be lost as nitrogen gas, and 46.4% of nitrogen was assimilated into bacterial biomass which can be removed as sludge in treatment processes. This bacterium was speculated to perform heterotrophic nitrification and aerobic denitrification simultaneously, and may be utilized for N removal in wastewater treatment processes.

Treatment of TNT Red Water by the Ozone-based Advanced Oxidation Processes (오존을 산화제로 사용한 다양한 고급산화 공정에 의한 TNT Red Water의 처리)

  • Jun, Jun Chul;Kwon, Tae Ouk;Moon, Il Shik
    • Korean Chemical Engineering Research
    • /
    • v.45 no.3
    • /
    • pp.298-303
    • /
    • 2007
  • Several combinations of ozone based advanced oxidation processes were tested for the treatment of red water (RW) containing recalcitrant chemical pollutants produced from 2,4,6-trinitrotoluene (TNT) manufacturing process. $O_3$, $UV/O_3$, $UV/O_3/H_2O_2$, $UV/O_3/H_2O_2/Fe^{2+}$ processes were tested for the treatment of RW. The order of organic and color removal efficiency was found to be : $O_3{\leq}UV/O_3$ < $UV/O_3/H_2O_2$ < $UV/O_3/H_2O_2/Fe^{2+}$. The optimum conditions for the removal of organic and color in the $UV/O_3/H_2O_2/Fe^{2+}$ process were 0.053 g/min of ozone flow rate, 10 mM of $H_2O_2$ concentration and 0.1 mM of $FeSO_4$ concentration. Organic and color removal efficiencies were 96 and 100 % respectively in the $UV/O_3/H_2O_2/Fe^{2+}$ process. tert-butyl alcohol (t-buOH) was used as the hydroxyl radical scavenger. Enhancement of hydroxyl radical production was achieved by the combination of ozone with several oxidants such as UV, $H_2O_2$, $Fe^{2+}$.

A Study on the Dye-Wastewater Treatment by Fenton and Photo-Fenton Oxidation Process (Fenton 및 Photo-Fenton 산화공정을 이용한 염색 폐수의 처리에 관한 연구)

  • 조일형;고영림;이소진;이홍근;조경덕
    • Journal of Environmental Health Sciences
    • /
    • v.26 no.4
    • /
    • pp.29-37
    • /
    • 2000
  • Fenton’s oxidation process is one of the most commonly applied processes to the wastewater which cannot be treated by conventional biological treatment processes. However, it is necessary to minimize the cost of Fenton’s oxidation treatment by modifying the treatment processes or other means of chemical treatment. So, as a method for the chemical oxidation of biorefractory or nonbiodegradable organic pollutants, the Photo-Fenton-Reaction which utilizes iron(11)salt. $H_2O$$_2$ and UV-light simultaneously has been proprosed. Therfore, the purpose of this study is to test a removal efficiency of dye-wastewater and treatment cost with Fenton’s and Photo-Fenton’s oxidation process. The Fe(11)/$H_2O$$_2$ reagent is referred to as the fenton’s reagent. which produces hydroxy radicals by the interaction of Fe(11) with $H_2O$$_2$. In this exoeriment, the main results are as followed; 1. The Fenton oxidation was most efficient in the pH range of 3-5. The optimal condition for initial reaction pH was 3.5 for the high CO $D_{Cr}$ & TOC-removal efficiency. 2. The removal efficiency of TOC and CO $D_{Cr}$ increased up to the molar ration between ferrate and hydrogen peroxide 0.2:1, but above that ratio removal efficiency hardly increased. 3. The highest removal efficiency of TOC and CO $D_{Cr}$ were showed when the mole ration of ferrate to hydrogen peroxide was 0.2:3.4. 4. Without pretreatment process, photo-fenton oxidation which was not absorbed UV light was not different to fenton oxidation. 5. And Fenton oxidtion with pretreatment process was similar to Fenton oxidation in the absence of coagulation, the proper dosage of F $e^{2+}$: $H_2O$$_2$ was 0.2:1 for the optimal removal efficiency of TOC or CO $D_{Cr}$ .6. Also, TOC & CO $D_{Cr}$ removal efficiency in the photo-fenton oxidation with pretreatment was increased when UV light intensity enhanced.7. Optimum light intensity in the range from 0 to 1200 W/$m^2$ showed that UV-intensity with 1200W/$m^2$ was the optimum condition, when F $e_{2+}$:$H_2O$$_2$ ratio for the highest decomposition was 0.2:2.5.EX>$_2$ ratio for the highest decomposition was 0.2:2.5.

  • PDF

Studies on the Effects of Several Amendments on the Uptake of Cd, Cu and Zn by Rice Plant (수도(水稻)의 중금속(重金屬) 흡수(吸收) 경감(經感)에 대(對)한 몇가지 개량제(改良劑)의 효과(效果))

  • Kim, Bok-Jin
    • Korean Journal of Environmental Agriculture
    • /
    • v.6 no.1
    • /
    • pp.25-30
    • /
    • 1987
  • This study was conducted to find out the effect of several improvers such as triple super phosphate, slaked lime, wollastonite and gypsum for reducing Cd content in brown rice. Several improvers were applied to two different types of soils which are contaminated with copper-zinc mine wasted and sludge.(Soil I contained Cd : 7.88, Cu : 57.9, Zn : 175.0 ppm, Soil II contained Cd : 3.95, Cu : 30.2, Zn :124.0 ppm) In general, effects of improvers on reducing content of Cd, Cu and Zn in brown rice were greater in soil I than soil II. In soil I, the Cd content of brown rice was reduced to 0.4ppm below by application of triple superphosphate, fused phosphate, slaked lime and gypsum, 98, 225, 190 and 276Kg/10a, respectively. Triple superphosphate was more effective than fused phosphate in reducing uptake of Cd, Cu and Zn by applying them as an equal amount of phosphorous, also to equal alkalinity, slaked lime had the highest effect. Negatively linear effect was found between soil pH and Cd and Zn content in brown rice. As to above results, it was no doubt that triple superphosphate, fused phosphate and slaked lime would be applied to reduced heavy metals in brown rice. The slaked lime, triple super phosphate and fused phosphate were available to reduce uptake of Cd, Cu and Zn by rice plant grown in the soil contaminated with mine waste and sludge.

  • PDF

Urban Development and Social Circulation of Water in Daegu (대구의 도시 발달과 물의 사회적 순환)

  • Choi, Byung Doo
    • Journal of the Korean association of regional geographers
    • /
    • v.19 no.1
    • /
    • pp.75-96
    • /
    • 2013
  • This paper is to conceptualize the urban social circulation of water from the social constructivism and political ecology, and to analyze the history of development of social circulation of water, that is, the modernization process of water in Daegu. The development of social circulation system of water in Daegu can be divided into 4 stages, that is, the beginning stage of modernization of water mainly during the period of Japanese colonization, the take-off stage from the 1960s to the mid-1980s, the stage of reflexive modernization from the late 1980s to the 1990s, and that of neoliberalization of water since the 2000s. It can be seen that the development of social circulation system of water in Daegu has contributed the increasing urban population and economic development, especially supporting the spatial expansion of the city and the way of modern way of urban life. But the social circulation system of water in Daegu seems to meet with a lot of problems such as relocation of the water intake station, over-equipment of filtration plants, distrust on tap water, inequality of water use, readjustment of water charge, liquid waste from industrial complexes within the urban area, creative destruction of waterfront environment, and privatization of water.

  • PDF

The Estimation of Bio-kinetic Parameters using Respirometric Analysis (산소이용률을 이용한 생물학적 동력학 계수 추정)

  • Choung, Youn-Kyoo;Kim, Han-Soo;Yoo, Sung-In
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.1
    • /
    • pp.11-19
    • /
    • 2000
  • In order to predict the performance of biological wastewater treatment plant, the kinetic parameters and stoichiometric coefficient must be known. The theories and experimental procedures for determining the biological kinetic parameters were discussed in this study. Respirometric analysis in the batch reactor was carried out for the experimental assessment of kinetic parameters. A simple procedure to estimate kinetic parameters of heterotrophs and autotrophs under aerobic condition was presented. The difficulties in the interpretation of COD and VSS measurements encouraged the conversion of respirometric data to growth data. Maximum specific growth rate, yield coefficient, half saturation constant and decay rate of heterotrophic biomass were obtained from OUR(Oxygen Uptake Rate) data. Maximum specific growth rate of autotrophic biomass was obtained from the increase of nitrate concentration. The aim of this paper is to estimate the kinetic parameters of heterotrophic and autotrophic biomass by means of the respirometric analysis of activated sludge behavior in the batch reactors. These procedures may be used for the activated sludge modeling with complex kinetic parameters.

  • PDF

The Effect of Substrates and Nitrate on Biological Phosphorus Release (생물학적 인 방출시 유기물 및 질산염에 대한 영향)

  • Min, Kyung-Kook;Weon, Seung-Yeon;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.1
    • /
    • pp.141-148
    • /
    • 2000
  • In this study, effects of substrates and nitrate on biological phosphorus release in EBPR(enhanced biological phosphorus removal) process were examined using batch test apparatus at anaerobic conditions. The sludge used in this experiments was taken from SBR(sequencing batch reactor) treating swine wastewater at aeration period. Phosphorus release rates obtained with substrates of FSW(fermented swine wastewater), acetate, propionate, domestic wastewater and methanol were 6.19, 5.99, 1.52, 1.2 and $1.03mgP/gVSS{\cdot}hr$, respectively. Those observed with acetate and FSW were 4~5 times greater than those with propionate, methanol and domestic wastewater. Therefore phosphorus release rates were significantly affected by type of substrate added at anaerobic condition. Phosphorus release was greatly affected by concentration of nitrate in anoxic condition. Comparing to acetate, propionate and FSW, phosphorus release was observed after almost completely depletion of nitrate concentration with methanol and domestic wastewater added as substrate. In the cases supplied with acetate, propionate and FSW, phosphorus release rates were less influenced by a nitrate concentration than those with methanol and domestic wastewater.

  • PDF

Removal of Heavy Metal and Phenol from Aqueous Solution Using Fe(III) loaded Adsorbent (3가철 함유 흡착제를 이용한 수용액상의 중금속 및 페놀제거연구)

  • Kim, Seok-Jun;Kim, Won-Gee;Lee, Seung-Mok;Yang, Jae-Kyu;Lee, Nam-Hee
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.31 no.7
    • /
    • pp.541-548
    • /
    • 2009
  • Iron coated media (activated carbon, sand and starfish) were prepared at pH 4 and applied for the treatment of landfill leachate containing organic compounds and soluble metal ions such as $Zn^{2+},\;Cu^{2+},\;Mn^{2+}$ in batch and column experiment. The amount of iron coated in media was analyzed with EPA 3050B method. The removal efficiency of metal ions and phenol was compared with iron coated media. The amount of iron coated in Fe-AC and ICS(iron coated sand) were 1,612 mg/kg and 1,609 mg/kg, respectively, while it was higher with 1,768 mg/kg in ICSF(iron coated starfish). The result of batch study represent the highest removal efficiency in the treatment of wastewater using iron coated starfish. In column study, the removal efficiency of phenol and metal ions was higher in multi-layered system of ICS, Fe-AC and ICSF compared to single layered system. Breakthrough time in the effluent was relatively enhanced for $Cu^{2+}$ and $Zn^{2+}$ in multi-layered system while the removal efficiency of $Mn^{2+}$ were not varied much. Therefore, multi-layered system was identified as the better system for the treatment of wastewater containing of metal ions and organic compound.

Biodiesel Production and Nutrients Removal from Piggery Manure Using Microalgal Small Scale Raceway Pond (SSRP) (미세조류 옥외배양 시스템을 이용한 돈분 액체 비료의 영양염류 제거 및 바이오디젤 생산)

  • Choi, Jong-Eun;Kim, Byung-Hyuk;Kang, Zion;Oh, Hee-Mock;Kim, Hee-Sik
    • Korean Journal of Environmental Biology
    • /
    • v.32 no.1
    • /
    • pp.26-34
    • /
    • 2014
  • Due to the rapid energy consumption and fossil fuel abundance reduction, the world is progressively in need of alternative and renewable energy sources such as biodiesel. Biodiesel from microalgae offers high hopes to the scientific world for its potential as well as its non-competition with arable lands. Taking consideration to reduce the cost of production as well as to attain twin environmental goals of treatment and use of animal waste material the microalgal cultivation using piggery manure has been tested in this study. Unialgal strains such as Chlorella sp. JK2, Scenedesmus sp. JK10, and an indigenous mixed microalgal culture CSS were cultured for 20 days in diluted piggery manure using Small Scale Raceway Pond (SSRP). Biomass production and lipid productivity of CSS were $1.19{\pm}0.09gL^{-1}$, $12.44{\pm}0.38mgL^{-1}day^{-1}$, respectively and almost twice that of unialgal strains. Also, total nitrogen and total phosphorus removal efficiencies of CSS was 93.6% and 98.5% respectively and 30% higher removal efficiency compared to the use of unialgal strains. These results indicate that the piggery manure can provide microalgae necessary nitrogen and phosphorus for growth thereby effectively treating the manure. In addition, overall cost of microalgal cultivation and subsequently biodiesel production would be significantly reduced.

Characteristic of Mixing and DO Concentration Distribution in Aeration Tank by Microbubble Supply (마이크로버블 공급에 의한 폭기조내 교반과 용존산소 분포 특성)

  • Lim, Ji-young;Kim, Hyun-Sik;Park, Dae-Seok;Cho, Young-Gun;Song, Seung-Jun;Park, Soo-Young;Kim, Jin-Han
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.17 no.5
    • /
    • pp.251-259
    • /
    • 2016
  • This study examined the DO concentration distribution and ORP distribution using microbubbles on pilot-scale aeration tanks. As a result of MLSS mixing and oxygen transfer phenomenon using microbubbles, different DO concentrations were observed depending on the circulation of the liquid with the microbubble supply location on the lateral of an aeration tank. The simulation results of CFD (computational fluid dynamics) program showed that MLSS mixed with a microbubble supply in the middle the reactor is much better than on the left side of the reactor. A single reactor containing an anaerobic, anoxic, and aerobic zone, was evaluated without partition according to the location of the microbubble supply based on the experiments and CFD analysis. MLSS was separated into solid-liquid by the microbubble supply in the aeration tank. Consequently, selecting the appropriate microbubble size is important for MLSS mixing and was maintained at the proper DO concentration for biological treatment.